• Title/Summary/Keyword: Natural Degradation

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Evaluation of Natural Attenuation of Petroleum Hydrocarbons in a Shallow Sand Aquifer: a Modeling Study (자연저감 모델링 연구)

  • 이진용;이명재;이강근;이민효;윤정기
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.04a
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    • pp.128-131
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    • 2001
  • We evaluated natural attenuation of petroleum hydrocarbons in a shallow aquifer using a modeling study. The studied shallow aquifer was severely contaminated with petroleum hydrocarbons, especially toluene, ethylbenzene and xylenes (i.e, TEX). The exact spill history was not known. Therefor we used a contaminant level in May 1999 (the first sampling date of our integrated study) as an initial contaminant concentration. we calibrated required transport parameters using the contamination levels obtained from groundwater analyses in September of 1999. For fate and transport of the petroleum contaminants, five case 2 with sorption and degradation. case 3 with sorption and degradation (half decay constant compared with case 2), case 4 with degradation but no sorption, and case 5 with sorption but no degradation. For sorption and degradation, a linear sorption isotherm and first order irreversible decay was assumed, respectively and no additional contamination source to groundwater is also assumed.

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The C-terminal domain of PLD2 participates in degradation of protein kinase CKII β subunit in human colorectal carcinoma cells

  • Lee, Young-Hoon;Uhm, Jong-Su;Yoon, Soo-Hyun;Kang, Ji-Young;Kim, Eun-Kyung;Kang, Beom-Sik;Min, Do-Sik;Bae, Young-Seuk
    • BMB Reports
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    • v.44 no.9
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    • pp.572-577
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    • 2011
  • Elevated phospholipase D (PLD) expression prevents cell cycle arrest and apoptosis. However, the roles of PLD isoforms in cell proliferation and apoptosis are incompletely understood. Here, we investigated the physiological significance of the interaction between PLD2 and protein kinase CKII (CKII) in HCT116 human colorectal carcinoma cells. PLD2 interacted with the CKII${\beta}$ subunit in HCT116 cells. The C-terminal domain (residues 578-933) of PLD2 and the N-terminal domain of CKII${\beta}$ were necessary for interaction between the two proteins. PLD2 relocalized CKII${\beta}$ to the plasma membrane area. Overexpression of PLD2 reduced CKII${\beta}$ protein level, whereas knockdown of PLD2 led to an increase in CKII${\beta}$ expression. PLD2-induced CKII${\beta}$ reduction was mediated by ubiquitin-dependent degradation. The C-terminal domain of PLD2 was sufficient for CKII${\beta}$ degradation as the catalytic activity of PLD2 was not required. Taken together, the results indicate that the C-terminal domain of PLD2 can regulate CKII by accelerating CKII${\beta}$ degradation in HCT116 cells.

Photodegradation of Butachlor and Pyrazosulfuron-ethyl in Rice Paddy Water under Natural Sunlight

  • Ok, Junghun;Watanabe, Hirozumi;Cho, Junglai;An, Nanhee;Lee, Byungmo
    • Korean Journal of Environmental Agriculture
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    • v.33 no.2
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    • pp.134-137
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    • 2014
  • BACKGROUND: Dissipation of herbicides in paddy water varies significantly, being dependent on environmental conditions such as sunlight. The photodegradation under natural sunlight may be one of natural degradation routes of herbicides dissipation. Therefore, the aim of this study was to monitor the degradation of butachlor and pyrazosulfuron-ethyl in paddy water under natural sunlight. METHODS AND RESULTS: The 12 water sample bottles of treatment were covered by quart glass plates, which allow about 90% of UV radiation (280-2000 nm) to pass through, to minimize the UV attenuation. The other 12 water sample bottles of the control were covered by glass lids and wrapped with aluminum foils to prevent the sunlight. The concentration of butachlor and pyrazosulfuron-ethyl in paddy water samples bottles was monitored under ambient conditions with and without natural sunlight. The concentration of butachlor and pyrazosulfuron-ethyl for treatment decreased from $355.3{\mu}g/L$ to $37.8{\mu}g/L$ and from $10.5{\mu}g/L$ to $3.9{\mu}g/L$, respectively, during consecutive 21 days after herbicide application under natural sunlight. CONCLUSION: The concentration of butachlor in paddy water decreased quickly under ambient conditions with natural sunlight. The degradation of butachlor in paddy water was enhanced by the natural sunlight. However, the degradation of pyrazosulfuron-ethyl was insignificant under natural sunlight.

A Study on the Relationship between the Number of Visitors and Degradation of Natural Resources in Bukhansan National Park (북한산국립공원의 탐방객 수와 훼손의 상관관계 연구)

  • Kang, Da-In;Sung, Hyun-Chan
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.19 no.4
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    • pp.81-89
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    • 2016
  • This study aims to understand the relationship between visitors and the degradation of natural resources in Bukhansan national park. We analyzed the trend of the number of visitors, destruction of natural resources and decrease of biodiversity per year. We further compared three types of trails, heavily-used trails and rarely-used trails and a trail with limited access, regarding the degree of destruction in the National Park through a field survey. Our result showed that increasing number of visitors had direct and indirect impact on the destruction of natural resources in the National Park. The direct impact came from visitors' excessive use of trails. Naturally, increasing number of visitors caused an immoderate use of natural resources. Physical degradation such as exposure of tree root, poor drainage of trails, trail erosion was more severe than other types of trails. Decreasing biodiversity or mild disturbance around trails is the indirect impact such as broken bough, worn-bark in rarely-used trails. Destruction scale greatly increased as the number of visitors increased. Real-named reservation system helped to prevent trails from degradation. Our result calls for the need of controlling the number of visitors to Bukhansan National Park to mitigate the degradation. We recommend dispersing visitors from the heavily-used trails to other trails and implementing real-named reservation system in the rarely-used trails for the effective management of the national park.

Photodegradation of Mixtures of Tetracycline, Sulfathiazole, and Triton X-100 in Water (수계 내 테트라사이클린, 설파다이아졸, 트리톤 X-100 혼합물의 광분해)

  • Yun, Seong Ho;Lee, Sungjong;Jho, Eun Hea;Moon, Joon-Kwan
    • Korean Journal of Environmental Agriculture
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    • v.40 no.1
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    • pp.13-19
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    • 2021
  • BACKGROUND: Chemicals such as antibiotics and surfactants can enter agricultural environment and they can be degraded by natural processes such as photolysis. These chemicals exist in mixtures in the environment, but studies on degradation of the mixtures are limited. This study compares the photodegradation of Triton X-100 (TX) and antibiotics [tetracycline (TC) and sulfathiazole (STH)] when they are in a single solution or in mixtures. METHODS AND RESULTS: TC, STH, and TX solutions were exposed to UV-A for the photodegradation tests for 14 days. The residual TC, STH, and TX concentrations were analyzed by using HPLC. The TC degradation was similar regardless of the presence of TX, while the TX degradation was lower in the presence of TC. The STH degradation was similar regardless of the presence of TX, while the TX degradation was greater in the presence of STH. However, the STH degradation was slower in the TC-STH-TX mixture than in the STH-TX mixture. Also, the TX degradation was negligible in the TC-STH-TX mixture. The results show that the photodegradation of TC, STH, and TX can be different in mixtures. This can be attributed to the different emission and absorption wavelengths of each compound and interaction between these compounds and photoproducts. CONCLUSION: Overall, this study emphasizes that photodegradation of single chemicals and chemical mixtures can be different, and more studies on single compounds as well as mixtures are required to understand the fate of chemicals in the environment in order to manage them properly.

Rethink the interlink between land degradation and livelihood of rural communities in Chilga district, Northwest Ethiopia

  • Gashu, Kassahun;Muchie, Yitbarek
    • Journal of Ecology and Environment
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    • v.42 no.4
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    • pp.139-149
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    • 2018
  • Background: Ethiopia is among the poorest countries where land degradation caused livelihood problem to its inhabitants. The livelihood of rural communities in Ethiopia is seriously threatened by land degradation. Land is the major natural resource that economic, social, infrastructure, and other human activities are undertaken on. Thus, land resources play an important role in shaping rural livelihoods, and lack of sustainable land management practices leads to land degradation. Thus, this study aimed to analyze interlink between land degradation and livelihood of rural communities in Chilga district, Northwest Ethiopia. It also addresses the factors which influence income diversification for livelihood of households in the study area. Result: The result depicts that the major causes of land degradation are both natural and anthropogenic. Land degradation and livelihood are negatively interlinked with each other. The livelihood of the majority of the population in the study area is dependent on subsistence agriculture both farming and animal husbandry with low diversification. The survey result showed that more than half (69%) of the sample households have farm size of less than 2 ha, nearly one third (31%) have 2.0-2.5 ha, and insignificant number of farmers have more than 2.5 ha. More than 80% of the respondents pointed out that land degradation has impacts both on crop yield and livestock production. Most of the explanatory variables such as gender, age, education level, farmland size, and family size have statistical significant influence (at P < .01 and P < .05 levels) for income diversification of households, while marital status on the other hand is not statistically significant though it has positive relation with income diversification in this study. Conclusions: Our results suggest awareness should be created in the community about the livelihood diversification mechanisms which enabled them to engage in different income-generating activities and comprehensive watershed management should be implemented.

Enhanced Natural Purification of Crude Oil Contaminated Tidal Flat (원유로 오염된 갯벌 지역의 자연정화 기능 향상 기술의 개발)

  • Kim, Young-A;Sung, Ki-June
    • Journal of Soil and Groundwater Environment
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    • v.16 no.5
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    • pp.24-30
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    • 2011
  • Tidal flats which are ecologically sensitive, are hard to remediate once they are contaminated by oil spill accidents. Traditional oil remediation measures focus on removal efficiency, and their improper implementation can adversely affect crude oil contaminated coastal areas and greatly disrupt the structure and functions of crude oil contaminated tidal flats. In this study, the oil degradation due to the implementation of remediation measures naturally enhanced using air and natural oil sorbents was evaluated in the lower strata of tidal flats. The effects of air and natural oil sorbents on oil degradation for two concentration levels (< 500 ppm and > 500 ppm) were tested at artificially contaminated tidal flats. Fifty days after these treatments, the natural oil sorbent treatment showed the lowest total petroleum hydrocarbon (TPH) concentration ($4.46{\pm}1.47%$) at the low concentration level, whereas both air and natural oil sorbent treatments showed high degradation efficiencies at the high concentration level ($29.30{\pm}4.39%$). Although the phosphatase activity decreased for all treatments, there was no significant difference between the decreases for the different treatments; on the other hand, B-glucosidase activities were high for both air and natural oil sorbent treatments. Although degradation efficiencies decreased as the concentration increased, the air provision and natural oil sorbent treatment could be an effective ecological restoration measure for oil contaminated tidal flats while minimizing the environmental impact of the remediation efforts.

Enzymatic Characteristics of Biosynthesis and Degradation of Poly-$\beta$-hydroxybutyrate of Alcaligenes latus

  • Kim, Tae-Woo;Park, Jin-Seo;Lee, Yong-Hyun
    • Journal of Microbiology and Biotechnology
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    • v.6 no.6
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    • pp.425-431
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    • 1996
  • The enzymatic characteristics of Alcaligenes latus were investigated by measuring the variations of various enzyme activities related to biosynthesis and degradation of poly-${\beta}$-hydroxybutyrate (PHB) during cultivation. All PHB biosynthetic enzymes, ${\beta}$-ketothiolase, acetoacetyl-CoA reductase, and PHB synthase, were activated gradually at the PHB accumulation stage, and the PHB synthase showed the highest value among three enzymes. This indicates that the rate of PHB biosynthesis is mainly controlled by either ${\beta}$-ketothiolase or acetoacetyl-CoA reductase rather than PHB synthase. The enzymatic activities related to the degradation of PHB were also measured, and the degradation of PHB was controlled by the activity of PHB depolymerase. The effect of supplements of metabolic regulators, citrate and tyrosine, was also investigated, and the activity of glucose-6-phosphate dehydrogenase was increased by metabolic regulators, especially by tyrosine. The activities of ${\beta}$-ketothiolase and acetoacetyl-CoA reductase were also activated by citrate and tyrosine, while the activity of PHB depolymerase was depressed. The increased rate and yield of PHB biosynthesis by metabolic regulators may be due to the increment of acetyl-CoA concentration either by the repression of the TCA cycle by citrate through product inhibition or by the activation of sucrose metabolism by the supplemented tyrosine.

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Maltol, an Antioxidant Component of Korean Red Ginseng, Shows Little Prooxidant Activity

  • Suh, Dae-Yeon;Han, Yong-Nam;Han, Byung-Hoon
    • Archives of Pharmacal Research
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    • v.19 no.2
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    • pp.112-115
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    • 1996
  • Some antioxidant phenolic compounds exhibit prooxidant activity mainly due to their abilities to reduce $Fe^{3+}\; to\; Fe^{2+}.$ Reducing ability and prooxidant activity of maltol, an antioxidant component of Korean red ginseng, were compared with those of pyrogallol. Maltol at 2 mM did not appreciably reduce$ Fe^{3+}\; to\; Fe^{2+}$ and also failed to reduce nitroblue tetrazolium. Stimulation of hydroxyl radical mediated-deoxyribose degradation by pyrogallol was maximal at 60 .mu.M. Maltol stimulated the deoxyribose degradation to a much less extent, and a similar stimulatory effect was observed at a concentration of more than 100-fold higher than that of pyrogallol. The stimulatory effect of maltol reached a plateau over 1 mM, suggesting the removal of hydroxyl radicals by excess maltol. In bleomycin-$Fe^{3+}$-DNA assay, maltol at 2 mM produced a 2.5-fold increase of the iron-bleomycin-dependent DNA degradation over the basal value, whereas pyrogallol at 10 .mu.M accelerated DNA degradation by ca. 10-fold. Furthermore, maltol inhibited $Fe^{2+}$-stimulated DNA degradation by bleomycin. These results strongly suggested that maltol is an antioxidant with little prooxidant activity.

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Optimal Remediation Design Considering Effects of Degradation Processes : Pumping strategy with Enhanced Natural Attenuation

  • Park Dong-Kyu;Lee Kang-Kun
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.04a
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    • pp.371-374
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    • 2005
  • We accomplished optimization for pump and treat (P&T) designs in consideration of degradation processes such as retardation and biodegradation, which are significant for contaminant fate in hydrogeology. For more desirable remediation, optimal pumping duration and minimum pumping rate constraint problems are studied. After a specific P&T duration, it replaces the P&T with the enhanced natural attenuation (ENA), which induces aerobic biodegradation by maintaining oxygen concentration. The design in this strategy carries out the optimization for the number and locations of oxygen injection wells.

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