• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.252.2-252.2
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• 2013

ZnO nanostructures have a lot of interest for decades due to its varied applications such as light-emitting devices, power generators, solar cells, and sensing devices etc. To get the high performance of these devices, the factors of nanostructure geometry, spacing, and alignment are important. So, Patterning of vertically- aligned ZnO nanowires are currently attractive. However, many of ZnO nanowire or nanorod fabrication methods are needs high temperature, such vapor phase transport process, metal-organic chemical vapor deposition (MOCVD), metal-organic vapor phase epitaxy, thermal evaporation, pulse laser deposition and thermal chemical vapor deposition. While hydrothermal process has great advantages-low temperature (less than $100^{\circ}C$), simple steps, short time consuming, without catalyst, and relatively ease to control than as mentioned various methods. In this work, we investigate the dependence of ZnO nanowire alignment and morphology on si substrate using of nanosphere template with various precursor concentration and components via hydrothermal process. The brief experimental scheme is as follow. First synthesized ZnO seed solution was spun coated on to cleaned Si substrate, and then annealed $350^{\circ}C$ for 1h in the furnace. Second, 200nm sized close-packed nanospheres were formed on the seed layer-coated substrate by using of gas-liquid-solid interfacial self-assembly method and drying in vaccum desicator for about a day to enhance the adhesion between seed layer and nanospheres. After that, zinc oxide nanowires were synthesized using a low temperature hydrothermal method based on alkali solution. The specimens were immersed upside down in the autoclave bath to prevent some precipitates which formed and covered on the surface. The hydrothermal conditions such as growth temperature, growth time, solution concentration, and additives are variously performed to optimize the morphologies of nanowire. To characterize the crystal structure of seed layer and nanowires, morphology, and optical properties, X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), Raman spectroscopy, and photoluminescence (PL) studies were investigated.

• Journal of Microbiology and Biotechnology
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• v.29 no.3
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• pp.489-499
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• 2019

Subunit vaccines are safer and more stable than live vaccines although they have the disadvantage of eliciting poor immune response. To develop a subunit vaccine, an effective delivery system targeting the key elements of the protective immune response is a prerequisite. In this study, oxidized carbon nanospheres (OCNs) were used as a subunit vaccine delivery system and tuberculosis (TB) was chosen as a model disease. TB is among the deadliest infectious diseases worldwide and an effective vaccine is urgently needed. The ability of OCNs to deliver recombinant Mycobacterium tuberculosis (Mtb) proteins, Ag85B and HspX, into bone marrow derived macrophages (BMDMs) and dendritic cells (BMDCs) was investigated. For immunization, OCNs were mixed with the two TB antigens as well as the adjuvant monophosphoryl lipid A (MPL). The protective efficacy was analyzed in vaccinated mice by aerosol Mtb challenge with a virulent strain of Mtb and the bacterial burdens were measured. The results showed that OCNs are highly effective in delivering Mtb proteins into the cytosol of BMDMs and BMDCs. Upon immunization, this vaccine formula induced robust Th1 immune response characterized by cytokine profiles from restimulated splenocytes and specific antibody titer. More importantly, enhanced cytotoxic $CD8^+$ T cell activation was observed. However, it did not reduce the bacteria burden in the lung and spleen from the aerosol Mtb challenge. Taken together, OCNs are highly effective in delivering subunit protein vaccine and induce robust Th1 and $CD8^+$ T cell response. This vaccine delivery system is suitable for application in settings where cell-mediated immune response is needed.

• Korean Chemical Engineering Research
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• v.59 no.4
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• pp.596-610
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• 2021

For application in adsorption process, we synthesized silica nanospheres by Stober method, and silica particles with wrinkled surface as well as macroporous silica particles were also fabricated by utilizing emulsion droplet as micro-reactors, followed by modification of the particle surface using suitable coupling agents containing amine groups. These particles exhibited improved adsorption capacity for heavy metal ions and anionic dyes, which were difficult to be removed by conventional silica particles without surface modification. Anionic dye, methyl orange could be removed almost completely by adsorption using porous silica particles modified using APTES. The adsorption efficiency of heavy metal like copper ions was close to 100%, when porous silica was used as adsorbent particles modified with AAPTS.

• Current Optics and Photonics
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• v.6 no.5
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• pp.497-505
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• 2022

Topological photonic nanocavities are considered to possess outstanding optical performance, and provide new platforms for realizing strong interaction between light and matter, due to their robustness to impurities and defects. Here hybrid plasmonic topological photonic nanocavities are proposed, by embedding various plasmon nanoantennas such as gold nanospheres, cylinders, and rectangles in a topological photonic crystal corner-state nanocavity. The maximum quality factor Q and minimum effective mode volume V_eff of these hybrid nanocavities can reach the order of 10⁴ and 10^-4 (𝜆/n)³ respectively, and the high figures of merit Q/V_eff for all of these hybrid nanocavites are stable and on the order of 10⁵ (𝜆/n)^-3. The relative positions of the plasmon nanoantennas will influence the coupling strength between the plasmon structures and the topological nanocavity. The hybrid nanocavity with gold nanospheres possesses much higher Q, but relatively large V_eff. The presence of a gold rectangular structure can confine more electromagnetic energy within a smaller space, since its V_eff is smallest, although Q is lowest among these structures. This work provides an outstanding platform for cavity quantum electrodynamics and has a wide range of applications in topological quantum light sources, such as single-photon sources and nanolasers.

• Bulletin of the Korean Chemical Society
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• v.26 no.11
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• pp.1819-1822
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• 2005

In the search for a simple preparation method of heterogeneous catalyst, the iron porphyrins were coordinated bonded to the surface of a polymeric core-shell nanosphere. The heterogeneous catalyst was characterized by FT-IR, scanning electron microscope, and UV-vis spectrophotometer. The iron porphyrin bound core-shell nanospheres was about 470 nm in diameter and their catalytic activity for cyclohexene oxidation was similar to a homogeneous iron porphyrin in a solvent composition range of 25-75% acetonitrile/water (v/v). In addition, they could be recovered by simple centrifugation and their catalytic activity was maintained more than the third cycle.

• Proceedings of the Materials Research Society of Korea Conference
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• 2011.05a
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• pp.11.1-11.1
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• 2011

We have developed a simple synthetic method for fabricating a wafer-scale colloidal crystal film of 2D crystals in a 1D stack based on a combination of two simple processes : the self-assembly of polystyrene (PS) nanospheres at the water-air interface and the layer-by-layer (LbL) scooping transfer technique. The main advantage of this approach is that it allows excellent control of the thickness (at a layer level) of the crystals and the formation of a vertical crack-free layer over a wafer-scale (4 inch). We investigate the optical and morphological properties of the PhC multilayers fabricated using various mono-sized colloidal crystals (250, 300, 350, 420, 580, 720, and 850 nm), and mixed binary colloidal crystals (300/350 and 250/350 nm).

• Korean Chemical Engineering Research
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• v.54 no.6
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• pp.792-799
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• 2016

Monodisperse silica nanospheres were synthesized by Stober method using rotating cylinder systems with batch or continuous manner. The particle size could be controlled by adjusting the reactant compositions such as the amount of monomer, catalyst, and water in the reaction mixture. The size and monodispersity of the ceramic particles could be controlled by changing the reaction medium with different alcohols other than ethanol or changing the reaction temperature. The effect of Taylor number (Ta) on the average diameter and standard deviation of silica particles were also studied by adjusting the rotation speed of inner cylinder, and the maximum diameter of particles was observed at Ta ${\approx}3,000$.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2010.06a
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• pp.62-62
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• 2010

Photonic quasi-crystals(PQCs) have been fabricated by a multiple-exposure nanosphere lithography (MENSL) method using the self-assembled nanospheres as lens-mask patterns. The multiple-exposing source is collimated laser beam and rotation, tilting system. The arrays of the PQCs exhibited variable lattice structures and shape the control of ratating angle ($\theta$), tilting angle ($\gamma$) and the exposure conditions. The used nanosphere size is upto the $1\;{\mu}m$. Images of prepared 2D PQCs were observed by SEM. We believe that the MENSL method is a suitable useful tool to realize the PQCs arrays of large area.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2006.05a
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• pp.475-476
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• 2006

Self-assembled monolayers (SAMs) formed by the adsorption of alkanethiols, HS(CH2)nX, where X is an organic functional group, onto gold surfaces have attracted widespread interest as templates for the fabrication of molecular and biomolecular microstructures. Previously photopatterning has been thought of as being restricted to the micron scale, because of the well-known diffraction limit. So, we have explored a novel approach to nanofabrication by utilizing a femtosecond laser.

• Bulletin of the Korean Chemical Society
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• v.29 no.3
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• pp.689-692
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• 2008