• Title/Summary/Keyword: Nanosized

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Formation of Antibacterial Film dried at Room Temperature using nano-sized TiO2 Particle (TiO2 나노 입자를 이용한 상온건조용 항균 코팅)

  • Choi, Young Jin;Kim, Donggyu;Kim, Insoo
    • Korean Journal of Metals and Materials
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    • v.48 no.5
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    • pp.401-409
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    • 2010
  • This study was performed to develop an antibacterial film that can be dried at room temperature. A nanosized TiO$_2$ particle-dispersed solution was prepared by the hydrothermal treatment of peroxo-titanic acid at 160${^{\circ}C}$ for 4h. The binder was synthesized through the hydrolysis and condensation reactions of TEOS (10cc) and GPTS (3.5cc) in the mixture of H$_2$O (30cc) and EtOH (30cc). The synthesized binder was mixed with 0.1 M of TiO$_2$ solution in a volume ratio of binder/TiO$_2$ solution=0.25~0.5. The glass substrate was coated after using the dip coating method, which was then followed by drying for over 2h at room temperature. Although the TiO$_2$ particles did not chemically-bond to the binder, the coating layer strongly adhered to the substrate and displayed good antibacterial properties.

Precise Analysis of the Surface Oxidation Layer on Cu Powders Using FE-TEM Techniques (전계방출 투과전자현미경 분석기술을 이용한 Cu 입자 표면산화층의 정밀평가)

  • Lee, Tae Hun;Yoo, Jung Ho;Hyun, Moon Seop;Yang, Jun-Mo;Seong, Mi-Ryn;Kwon, Jinhyeong;Lee, Caroline Sunyong;Kim, Jeong-Sun;Baik, Kyeong Ho
    • Korean Journal of Metals and Materials
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    • v.48 no.1
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    • pp.57-61
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    • 2010
  • Nanosized surface structures of Cu powders were investigated at the atomic scale by field-emission transmission electron microscope techniques. The nanoscale surface oxide layer on the Cu powder was analyzed to be the $CU_2O$ phase by electron diffraction pattern and electron energy-loss spectroscopy. In addition, it was found from high-resolution transmission electron microscopy study that there are formed no surface oxide layers on the surface of alkanethiol coated Cu powders.

Can a nanofluid enhance the critical heat flux if the recirculating coolant contains debris?

  • Han, Jihoon;Nam, Giju;Kim, Hyungdae
    • Nuclear Engineering and Technology
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    • v.54 no.5
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    • pp.1845-1850
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    • 2022
  • In-vessel corium retention (IVR) during external reactor vessel cooling (ERVC) is a key severe accident management strategy adopted in advanced nuclear power plants. The injection of nanofluids has been regarded as a means of enhancing CHF when using the IVR-ERVC strategy to safeguard high-power nuclear reactors. However, a critical practical concern is that various types of debris flowing from the contaminant sump during operation of an ERVC system might degrade CHF enhancement by nanofluids. Our objective here was to experimentally assess the viability of nanofluid use to enhance CHF in practical ERVC contexts (e.g., when fluids contain various types of debris). The types and characteristics of debris expected during IVR-ERVC were examined. We performed pool boiling CHF experiments using nanofluids containing these types of debris. Notably, we found that debris did not cause any degradation of the CHF enhancement characteristics of nanofluids. The nanoparticles are approximately 1000-fold smaller than the debris particles; the number of nanoparticles in the same volume fraction is 1 billion-fold greater. Nanofluids increase CHF via porous deposition of nanosized particles on the boiling surface; this is not hindered by extremely large debris particles.

On bending of cutout nanobeams based on nonlocal strain gradient elasticity theory

  • Alazwari, Mashhour A.;Eltaher, Mohamed A.;Abdelrahman, Alaa A.
    • Steel and Composite Structures
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    • v.43 no.6
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    • pp.707-723
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    • 2022
  • This article aims to investigate the size dependent bending behavior of perforated nanobeams incorporating the nonlocal and the microstructure effects based on the nonlocal strain gradient elasticity theory (NSGET). Shear deformation effect due to cutout process is studied by using Timoshenko beams theory. Closed formulas for the equivalent geometrical characteristics of regularly squared cutout shape are derived. The governing equations of motion considering the nonlocal and microstructure effects are derived in comprehensive procedure and nonclassical boundary conditions are presented. Analytical solution for the governing equations of motion is derived. The derived non-classical analytical solutions are verified by comparing the obtained results with the available results in the literature and good agreement is observed. Numerical results are obtained and discussed. Parametric studies are conducted to explore effects of perforation characteristics, the nonclassical material parameters, beam slenderness ratio as well as the boundary and loading conditions on the non-classical transverse bending behavior of cutout nanobeams. Results obtained are supportive for the design, analysis and manufacturing of such nanosized structural system.

Perspectives on Bovine Milk-Derived Extracellular Vesicles for Therapeutic Applications in Gut Health

  • Mun, Daye;Oh, Sangnam;Kim, Younghoon
    • Food Science of Animal Resources
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    • v.42 no.2
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    • pp.197-209
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    • 2022
  • Extracellular vesicles (EVs) are nanosized vesicles secreted from cells into the extracellular environment and are composed of a lipid bilayer that contains cargos with biological activity, such as lipids, proteins, mRNAs, and noncoding microRNAs (miRNAs). Due to their biological activity and their role in cell-to-cell communication, interest in EVs is rapidly increasing. Bovine milk is a food consumed by people of all ages around the world that contains not only a significant amount of nutrients but also EVs. Milk-derived EVs also exhibit biological activity similar to other source-derived EVs, and studies on bovine milk EVs have been conducted in various research fields regarding sufficient milk production. In particular, not only are the effects of milk EVs themselves being studied, but the possibility of using them as drug carriers or biomarkers is also being studied. In this review, the characteristics and cargo of milk EVs are summarized, as well as their uptake and stability, efficacy and biological effects as carriers, and future research directions are presented.

A study on the efficacy of low viscous nanosized biopolymer on the mechanical and hydraulic properties of organic silt

  • Govindarajan Kannan;Evangelin Ramani Sujatha
    • Geomechanics and Engineering
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    • v.34 no.3
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    • pp.221-231
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    • 2023
  • Biopolymer stabilization is a sustainable alternative to traditional techniques that cause a lesser negative impact on the environment during production and application. The study aims to minimize the biopolymer dosages by sizing the bio-additives to the nanoscale. This study combines the advantages of bio and nanomaterials in geotechnical engineering applications and attempts to investigate the behaviour of a low viscous biopolymer, nano sodium carboxymethyl cellulose (nCMC), to treat organic soil. Soil is treated with 0.25%, 0.50%, 0.75% and 1.00% of nano-bio additive, and its effect on the plastic behaviour, compaction characteristics, strength, hydraulic conductivity (HC) and compressible nature are investigated. The strength increased by 1.68 times after 90 days of curing at a dosage of 0.5% nCMC through the formation of gel threads connecting the soil particles that stiffened the matrix. The viscosity of 1% nCMC increased exponentially, deterring fluid flow through the voids and reduced the HC by 0.85 times after curing for 90 days. Also, beyond the optimum dosage of 0.50%, the nCMC forms a film around the soil particles that inhibits the inter-particle cohesion causing a reduction in strength. Experimental results show that nCMC can effectively substitute conventional additives to stabilize the soil.

Deposition of aluminum nitride nanopowders and fabrication of superhydrophobic surfaces (질화알루미늄 나노분말의 부착과 이를 활용한 초소수성 표면 제작)

  • Kwangseok Lee;Heon-Ju Choi;Handong Cho
    • Journal of the Korean institute of surface engineering
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    • v.57 no.1
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    • pp.49-56
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    • 2024
  • Superhydrophobic surfaces have been expected to be able to provide considerable performance improvements and introduce innovative functions across diverse industries. However, representative methods for fabricating superhydrophobic surfaces include etching the substrate or attaching nanosized particles, but they have been limited by problems such as applicability to only a few materials or low adhesion between particles and substrates, resulting in a short lifetime of superhydrophobic properties. In this work, we report a novel coating technique that can achieve superhydrophobicity by electrophoretic deposition of aluminum nitride (AlN) nanopowders and their self-bonding to form a surface structure without the use of binder resins through a hydrolysis reaction. Furthermore, by using a water-soluble adhesive as a temporary shield for the electrophoretic deposited AlN powders, hierarchical aluminum hydroxide structures can be strongly adhered to a variety of electrically conductive substrates. This binder-free technique for creating hierarchical structures that exhibit strong adhesion to a variety of substrates significantly expands the practical applicability of superhydrophobic surfaces.

The Photocatalytic Reaction of the Thin Film TiO2-Sr4Al14O25 Phosphors for Benzene Gas (박막 산화티타늄과 Sr4Al14O25 축광체를 조합한 복합소재의 벤젠가스에 대한 광촉매 반응)

  • Kim, Seung-Woo;Kim, Jung-Sik
    • Journal of the Korean Ceramic Society
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    • v.50 no.1
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    • pp.50-56
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    • 2013
  • Phosphorescent materials coated with titanium dioxide were fabricated and photocatalytic reactions between these materials and VOCs gases were examined. A thin film (approx. 100 nm) of nanosized $TiO_2$ was deposited on the $Sr_4Al_{14}O_{25}$ : $Eu^{2+}$, $Dy^{3+}$, $Ag^+$ phosphor using low-pressure chemical vapor deposition (LPCVD). The characteristics of the photocatalytic reaction were examined in terms of the decomposition of benzene gas using a gas chromatography (GC) system under ultraviolet (${\lambda}$ = 365 nm) and visible light (${\lambda}$ > 420 nm) irradiation. $TiO_2$-coated $Sr_4Al_{14}O_{25}$ : $Eu^{2+}$, $Dy^{3+}$, $Ag^+$ phosphor showed different photocatalytic behavior compared with pure $TiO_2$. $TiO_2$-coated phosphorescent materials showed a much faster photocatalytic decomposition of benzene gas under visible irradiation compared to the pure $TiO_2$ for which the result was practically negligible. This suggests that the extension of the absorption wavelength to visible light occurred through energy band bending by a heterojunction at the interface of the $Sr_4Al_{14}O_{25}-TiO_2$ composite. Also, the $Sr_4Al_{14}O_{25}-TiO_2$ composite showed the photocatalytic decomposition of benzene in darkness due to the photon light emitted from the $Sr_4Al_{14}O_{25}$ phosphors.

Phase Evolution and Electrical Properties of PZT Films by Aerosol-Deposition Method (에어로졸 증착법에 의해 제조된 PZT 막의 상변화와 전기적 특성)

  • Park, Chun-Kil;Kang, Dong-Kyun;Lee, Seung-Hee;Kong, Young-Min;Jeong, Dae-Yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.9
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    • pp.541-545
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    • 2017
  • $Pb(Zr_{0.52}Ti_{0.48})O_3$ (PZT) films with a thickness of $5{\sim}10{\mu}m$ at the morphotropic phase boundary were fabricated by aerosol-deposition (AD), and their phase evolution and electrical properties were investigated. The microstructure of the AD PZT films revealed nanosized grains with a low crystallinity and a dense structure at room temperature. The AD PZT films showed a mixture of tetragonal and rhombohedral phases. The post-annealing temperature was varied to study the phase transition behavior. The crystallinity of the AD PZT films was enhanced by annealing at 450, 550, and $650^{\circ}C$ for 2 h. At $650^{\circ}C$, the tetragonal and rhombohedral phases reacted to form a bridge phase between the two phases. The polarization-electric field hysteresis loops of the AD PZT film annealed at $650^{\circ}C$ exhibited a smaller cohesive field and a lower slim hysteresis than the films annealed at 450 and $550^{\circ}C$.

Synthesis and Characterization of TiO2/CuS Nanocomposite Fibers as a Visible Light-Driven Photocatalyst

  • An, HyeLan;Kang, Leeseung;Ahn, Hyo-Jin;Choa, Yong-Ho;Lee, Chan Gi
    • Journal of the Korean Ceramic Society
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    • v.55 no.3
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    • pp.267-274
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    • 2018
  • $TiO_2/CuS$ nanocomposites were fabricated by precipitation of nanosized CuS via sonochemical method on electrospun $TiO_2$ nanofibers, and their structure, chemical bonding states, optical properties, and photocatalytic activity were investigated. In the $TiO_2/CuS$ nanocomposite, the position of the conduction band for CuS was at a more negative than that of TiO; meanwhile, the position of the valence band for CuS was more positive than those for TiO, indicating a heterojunction structure belonging to type-II band alignment. Photocatalytic activity, measured by decomposition of methylene blue under visible-light irradiation (${\lambda}$ > 400 nm) for the $TiO_2/CuS$ nanocomposite, showed a value of 85.94% at 653 nm, which represented an improvement of 52% compared to that for single $TiO_2$ nanofiber (44.97% at 653 nm). Consequently, the photocatalyst with $TiO_2/CuS$ nanocomposite had excellent photocatalytic activity for methylene blue under visible-light irradiation, which could be explained by the formation of a heterojunction structure and improvement of the surface reaction by increase in surface area.