• Title/Summary/Keyword: Nanohybrid

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Aging Properties from Forest-fire Simulated Acceleration of Porcelain Insulators for Transmission Line (송전용 애자의 산불 복합가속열화 특성)

  • Han, Se-Won;Choi, In-Hyuk;Lee, Dong-Il;Lee, Won-Kyo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.114-114
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    • 2010
  • 산불에 노출되는 경우 열충격으로 작용하는 패턴과 특성을 검토하여 가속열화시험에 반영하는 것이 필요하다. 본 연구에서는 산불환경을 모의하여 복합열화시험을 실시하기위해 복합가속열화 챔버를 구축하였다. 온도는 주로 $200^{\circ}C$에서 최대 $1000^{\circ}C$까지 변화를 주면서 예비시험과 본시험 실하였다.

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CLINICAL EFFICACY EVALUATION OF O/W EMULSION CONTAINING INDOLE-3-ACETIC ACID WITH THE FUNCTION OF ANTI-WRINKLE

  • Yang, Jae-Hun;Lee, Sun-Young;Han, Yang-Su;Jung, Hye-Sun;Kim, Ju-Ho;Park, Kwon-Ho;Choy, Jin-Ho
    • Proceedings of the SCSK Conference
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    • 2003.09b
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    • pp.219-238
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    • 2003
  • Indole-3-acetic acid (IAA) molecule has been successfully encapsulated in biocompatible inorganic matrix in order for the cosmetic application such as superfacial fine line reduction. The encapsulation was realized through chemical reaction involving simultaneous formation of inorganic lattice and 1M giving rise to an 1M-inorganic nanohybrid (IAA-brid) which shows excellent storage stability and sustained releasing property of indole-3-acetic acid. The clinical efficacy of essence cream containing IAA-brid as anti-wrinkle formulation was also carefully evaluated by measuring the roughness of the skin replica before and after treatment. Upon administration of the cream on the eye-area, the fine-line is drastically reduced.

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Electrical and optical studies of organic light emitting devices using Ag and $SiO_2$ / poly(p-phenylene vinylene)(PPV) nanocomposites

  • Lee, Cho-Young;Park, Hyung-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.367-367
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    • 2007
  • Polymer/nanoparticle hybrids have been increasingly studied because of their enhanced properties for organic light emitting devices (OLEDs). In this study, we made poly(p-phenylene vinylene) (PPV) nanohybrid films by incorporation of Ag and $SiO_2$ nanoparticles into the PPV. A possible interaction between nanoparticles was investigated and especially we focused whether there is a change in the interaction between $SiO_2$ or Ag nanoparticles and matrix or not. The current characteristics of PPV nanohybrid films were analyzed by I-V and EL measurements. The optical properties were also investigated by UV-Vis spectroscopy and photoluminescence measurements.

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Molecular Layer Deposition of Organic/Inorganic Nanohybrid Dielectrics for OTFTs

  • Lee, Byeong-Hun;Lee, Gwang-Hyeon;Im, Seong-Il;Seong, Myeong-Mo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.56-56
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    • 2010
  • We report a low-temperature fabrication of organic/inorganic nanohybrid dielectrics for organic thin film transistors. The self-assembled organic layers (SAOLs) were grown by repeated sequential adsorptions of C=C-terminated alkylsilane and metal (Al or Ti) hydroxyl with ozone activation, which was called "molecular layer deposition (MLD)". The $TiO_2$ and $Al_2O_3$ inorganic layers were grown by ALD, which relies on sequential saturated surface reactions resulting in the formation of a monolayer in each sequence and is a potentially powerful method for preparing high quality multicomponent superlattices. The MLD method combined with ALD (MLD-ALD) was applied to fabricate SAOLs-$Al_2O_3$-SAOLs-$TiO_2$ nanohybrid superlattices on polymer substrates at relatively low temperature. The MLD method is an ideal fabrication technique for various flexible electronic devices.

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Comparative study of surface roughness between several finishing and polishing procedures on ormocer-based composite resin and nanohybrid composite resin (복합 레진에서 마무리 방법에 따른 표면 거칠기 비교)

  • Jeong, Suk-In;Oh, Nam-Sik;Lee, Myung-Hyeon;Lee, En-Jung;Cho, Jung-Hyeon;Ji, Sung-Won
    • The Journal of Korean Academy of Prosthodontics
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    • v.46 no.2
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    • pp.105-115
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    • 2008
  • Statement of problem: Proper finishing and polishing enhance both the esthetics and the longevity of restored teeth. Blade finishing technique would be suited for smoothing and finishing. Evaluation of this technique are necessary. Purpose: The purpose of this study was to evaluate the blade finishing and polishing procedures on the surface profile and roughness of ormocer-based composite resin and nanohybrid composite resin. Material and methods: The material included a ormocer-based composite resin ($Admira^{(R)}$ & $Admira^{(R)}$ Flow); a nanohybrid composite resin ($Grandio^{(R)}$ & $Grandio^{(R)}$ Flow). One hundred forty specimens of each group were prepared using a mylar strip and randomly divied into blade finishing and rubber polishing groups (n=10). The average surface roughness (Ra) in micrometers was measured and the surface profile was examined by scanning electron microscopy (SEM) (Magnification ${\times}$ 200). The data were analyzed by Mann-Whitney Test at 0.05 significance level. Conclusion: The results of this study indicated that the mylar strip produced the smoothest surface on all materials and among the finishing-polishing methods was not significanct difference (P>0.05). Ormocer-based flowable composite resin performedthe lowest variability in initial surface roughness among the tested materials.

Repair bond strength of resin composite to three aged CAD/CAM blocks using different repair systems

  • Gul, Pinar;Altinok-Uygun, Latife
    • The Journal of Advanced Prosthodontics
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    • v.12 no.3
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    • pp.131-139
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    • 2020
  • PURPOSE. The purpose of this study is to evaluate the repair bond strength of a nanohybrid resin composite to three CAD/CAM blocks using different intraoral ceramic repair systems. MATERIALS AND METHODS. Three CAD/CAM blocks (Lava Ultimate, Cerasmart, and Vitablocks Mark II) were selected for the study. Thirty-two specimens were fabricated from each block. Specimens were randomly divided into eight groups for the following different intraoral repair systems: Group 1: control group (no treatment); Group 2: 34.5% phosphoric acid etching; Group 3: CoJet System; Group 4: Z-Prime Plus System; Group 5: GC Repair System; Group 6: Cimara System; Group 7: Porcelain Repair System; and Group 8: Clearfil Repair System. Then, nanohybrid resin composite (Tetric Evo Ceram) was packed onto treated blocks surfaces. The specimens were thermocycled before application of repair systems and after application of composite resin. After second thermal cycling, blocks were cut into bars (1 × 1 × 12 ㎣) for microtensile bond strength tests. Data were analyzed using two-way ANOVA and Tukey's HSD test (α=.05). RESULTS. Cimara System, Porcelain Repair, and Clearfil Repair systems significantly increased the bond strength of nanohybrid resin composite to all CAD/CAM blocks when compared with the other tested repair systems (P<.05). In terms of CAD/CAM blocks, the lowest values were observed in Vitablocks Mark II groups (P<.05). CONCLUSION. All repair systems used in the study exhibited clinically acceptable bond strength and can be recommended for clinical use.

INTERCALATIVE NANOENCAPSULATION OF COSMETIC INGREDIENTS INTO SKIN-FRIENDLY INORGNICS

  • Y. S. Han;Lee, S. Y.;J. H. Yang;J. H. Choy
    • Proceedings of the SCSK Conference
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    • 2003.09a
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    • pp.568-569
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    • 2003
  • Functional cosmetic ingredients such as L-ascorbic acid, retinoic acid, indole-3-acetic acid, salicylic acid, acidic dye(indigo carmine) are intercalatively encapsulated by skin-friendly metal hydroxides and oxides matrices. Such functional organic-inorganic nanohybrids are realized via chemical coprecipitation and surface coating reactions. The hetero-structural nature of these nanohybrids, their particle morphology and textural characterizations are mainly discussed on the basis of powder X-ray diffraction, electron microscopies, and high performance liquid chromatographic analyses. The cosmetic ingredients encapsulated in inorganics show greatly improved storage stability, sustained releasing property as well as higher transdermal transfer efficiency.

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Intercalation of Vitamer into LDH and Their Controlled Release Properties

  • Choy, Jin-Ho;Son, You-Hwan
    • Bulletin of the Korean Chemical Society
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    • v.25 no.1
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    • pp.122-126
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    • 2004
  • Biofunctional nanohybrids are synthesized from layered double hydroxide (LDH) and the vitamins such as ascorbic acid and topopherol acid succinate. Either ion exchange or copricipitaion leads to successful intercalation of the vitamins into gallery space of LDH that offers a new route to safe preservation of bioactivity as well as controlled release. Intercalations of vitamins are clearly reflected on the increase in the basal spacing of ZnAl-(Nitrate) LDH from 8.5 ${\AA}$ to 10.5 ${AA}$ for ascorbate, and 49.0 ${AA}$ for tocopherol acid succinate, respectively. No significant change in UV-Vis and IR absorption characteristics of the intercalated vitamins strongly supports the safe maintenance of their bioactivities without any deterioration of chemical and structural integrity. Furthermore, it is shown that the hybridized vitamins could be discharged in a controlled kinetics.