• 폴리머
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• 제25권5호
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• pp.691-698
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• 2001

에폭시 (diglycidyl ether of bisphenol A: DGEBA), 경화제 (dicyandiamide; DICY), 촉매 (benzyl dimethyl amine : BDMA), 그리고 유기치환된 실리케이트 (organically modified mica type silicate: OMTS)를 용융법 및 용액법을 이용해 나노복합체를 제조하였고, $170^{\circ}C$에서 시간에 따라 경화 반응을 진행하면서 X선 회절분석기 (XRD)와 소각 X선 산란장치 (SAXS)를 이용하여 구조 변화를 관찰하였다. 용융법으로 제조된 치료의 경우 박리된 구조를 관찰할 수 없었으나 용액법에 의해 제조된 경우 박리된 구조를 관찰할 수 있었다. 이는 OMTS 층 내ㆍ외부의 경화 속도차이 때문인 것으로 생각된다. 박리된 에폭시 나노복합체의 OMTS 첨가량에 따른 기계적 물성을 동적기계적 분석기 (DMA)를 이용해 측정한 결과 OMTS의 첨가량이 증가할수록 모둘러스는 증가하였으나 유리전이온도는 큰 차이가 없었다. OMTS 첨가량에 따른 열적 성질을 열중량분석기(TGA)와 한계산소지수 (LOI)를 이용해 측정한 결과 OMTS양이 증가할수록 OMTS 판의 차단효과로 인해 열분해 시작 온도와 LOI 값이 증가하였다.

• 한국전기화학회:학술대회논문집
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• 한국전기화학회 2003년도 연료전지심포지움 2003논문집
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• pp.83-88
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• 2003

PtRu alloy and $PtRu-WO_3$ nanocomposite thin-film electrodes for methanol electrooxidation were fabricated by means of a sputtering method. The structural and electrochemical properties of well-defined PtRu alloy thin-film electrodes were characterized using X-ray diffraction, Rutherford backscattering spectroscopy. X-ray photoelectron spectroscopy, and electrochemical measurements. The alloy thin-film electrodes were classified as follows: Pt-based and Ru-based alloy structure. Based on structural and electrochemical understanding of the PtRu alloy thin-film electrodes, the well-controlled physical and (electro)chemical properties of $PtRu-WO_3$, showed superior specific current to that of a nanosized PtRu alloy catalyst, The homogeneous dispersion of alloy catalyst and well-formed nanophase structure would lead to an excellent catalytic electrode reaction for high-performance fuel cells. In addition, the enhanced catalytic activity in nanocomposite electrode was found to be closely related to proton transfer in tungsten oxide using in-situ electrochemical transmittance measurement.

• Advances in nano research
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• 제7권3호
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• pp.181-190
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• 2019

The thermal buckling temperature values of the graded carbon nanotube reinforced composite shell structure is explored using higher-order mid-plane kinematics and multiscale constituent modeling under two different thermal fields. The critical values of buckling temperature including the effect of in-plane thermal loading are computed numerically by minimizing the final energy expression through a linear isoparametric finite element technique. The governing equation of the multiscale nanocomposite is derived via the variational principle including the geometrical distortion through Green-Lagrange strain. Additionally, the model includes different grading patterns of nanotube through the panel thickness to improve the structural strength. The reliability and accuracy of the developed finite element model are varified by comparison and convergence studies. Finally, the applicability of present developed model was highlight by enlighten several numerical examples for various type shell geometries and design parameters.

• Structural Engineering and Mechanics
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• 제87권2호
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• pp.129-136
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• 2023

In this paper, dynamic buckling of truncated conical shell made of carbon nanotubes (CNTs) composite is studied. In aerospace industries, this category of structures is utilized extensively due to wide range of engineering applications. To calculate the effective material properties of the nanocomposite, The Mori-Tanaka model is applied. Also, the motion equations are derived with the assistance of the first order shear deformation theory (FSDT), Hamilton's principle and energy method. Besides, In order to solve motion equations and analyze dynamic instability region (DIR) of the structure, mixed model of differential quadrature method (DQM) and Bolotin's method is used. Moreover, investigation of the different parameters effects such as geometrical parameters and volume fraction of CNTs on the analysis of the DIR of the structure is done. In accordance with the obtained results, the DIR will occur at higher frequencies by increasing the volume fraction of CNTs.

• Structural Engineering and Mechanics
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• 제68권3호
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• pp.359-368
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• 2018

This paper deals with the dynamic stability of nanocomposite pipes conveying pulsating ferrofluid. The pipe is reinforced by carbon nanotubes (CNTs) where the agglomeration of CNTs are considered based on Mori-Tanaka model. Due to the existence of CNTs and ferrofluid flow, the structure and fluid are subjected to axial magnetic field. Based on Navier-Stokes equation and considering the body forced induced by magnetic field, the external force of fluid to the pipe is derived. For mathematical modeling of the pipe, the first order shear deformation theory (FSDT) is used where the energy method and Hamilton's principle are used for obtaining the motion equations. Using harmonic differential quadrature method (HDQM) and Bolotin's method, the motion equations are solved for calculating the excitation frequency and dynamic instability region (DIR) of the structure. The influences of different parameters such as volume fraction and agglomeration of CNTs, magnetic field, structural damping, viscoelastic medium, fluid velocity and boundary conditions are shown on the DIR of the structure. Results show that with considering agglomeration of CNTs, the DIR shifts to the lower excitation frequencies. In addition, the DIR of the structure will be happened at higher excitation frequencies with increasing the magnetic field.

• Structural Engineering and Mechanics
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• 제73권5호
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• pp.555-563
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• 2020

The objective of present paper is assessment of dynamic buckling behavior of an embedded sandwich microplates in thermal environment in which the layers are reinforced through functionally graded carbon nanotubes (FG-CNTs). Therefore, mixture rule is taken into consideration for obtaining effective material characteristics. In order to model this structure much more realistic, Kelvin-Voigt model is presumed and the sandwich structure is rested on visco-Pasternak medium. Exponential shear deformation theory (ESDT) in addition to Eringen's nonlocal theory are utilized to obtain motion equations. Further, differential cubature method (DCM) as well as Bolotin's procedure are used to solve governing equations and achieve dynamic instability region (DIR) related to sandwich structure. Different parameters focusing on volume percent of CNTs, dispersion kinds of CNTs, thermal environment, small scale effect and structural damping and their influences upon the dynamic behavior of sandwich structure are investigated. So as to indicate the accuracy of applied theories as well as methods, the results are collated with another paper. According to results, presence of CNTs and their dispersion kind can alter system's dynamic response as well.

• Steel and Composite Structures
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• 제48권4호
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• pp.419-428
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• 2023

In this paper, dynamic and static bending of ball modelled by nanocomposite microbeam by nanoparticles seeing agglomeration is presented. The structural damping is considered by Kelvin-Voigt model. The agglomeration effects are assumed using Mori-Tanaka model. The football ball is modeled by third order shear deformation theory (TSDT). The motion equations are derived by principle of Hamilton's and energy method assuming size effects on the basis of Eringen theory. Using differential quadrature method (DQM) and Newmark method, the static and dynamic deflections of the structure are obtained. The effects of agglomeration and CNTs volume percent, damping of structure, nonlocal parameter, length and thickness of micro-beam are presented on the static and dynamic deflections of the nanocomposite structure. Results show that with increasing CNTs volume percent, the maximum dimensionless dynamic deflection is reduced about 17%. In addition, assuming CNTs agglomeration increases the dimensionless dynamic deflection about 14%. It is also found that with increasing the CNTs volume percent from 0 to 0.15, the static deflection is decreased about 3 times due to the enhance in the stiffness of the structure. In addition, with enhancing the nonlocal parameters, the dynamic deflection is increased about 3.1 times.

• Steel and Composite Structures
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• 제35권1호
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• pp.77-92
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• 2020

The present paper outlined a procedure for geometrically nonlinear dynamic analysis of functionally graded graphene platelets-reinforced (GPLR-FG) nanocomposite cylinder subjected to mechanical shock loading. The governing equation of motion for large deformation problems is derived using meshless local Petrov-Galerkin (MLPG) method based on total lagrangian approach. In the MLPG method, the radial point interpolation technique is employed to construct the shape functions. A micromechanical model based on the Halpin-Tsai model and rule of mixture is used for formulation the nonlinear functionally graded distribution of GPLs in polymer matrix of composites. Energy dissipation in analyses of the structure responding to dynamic loads is considered using the Rayleigh damping. The Newmark-Newton/Raphson method which is an incremental-iterative approach is implemented to solve the nonlinear dynamic equations. The results of the proposed method for homogenous material are compared with the finite element ones. A very good agreement is achieved between the MLPG and FEM with very fine meshing. In addition, the results have demonstrated that the MLPG method is more effective method compared with the FEM for very large deformation problems due to avoiding mesh distortion issues. Finally, the effect of GPLs distribution on strength, stiffness and dynamic characteristics of the cylinder are discussed in details. The obtained results show that the distribution of GPLs changed the mechanical properties, so a classification of different types and volume fraction exponent is established. Indeed by comparing the obtained results, the best compromise of nanocomposite cylinder is determined in terms of mechanical and dynamic properties for different load patterns. All these applications have shown that the present MLPG method is very effective for geometrically nonlinear analyses of GPLR-FG nanocomposite cylinder because of vanishing mesh distortion issue in large deformation problems. In addition, since in proposed method the distributed nodes are used for discretization the problem domain (rather than the meshing), modeling the functionally graded media yields to more accurate results.

• Steel and Composite Structures
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• 제30권3호
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• pp.281-292
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• 2019

In this paper, analysis of critical fluid velocity and heat transfer in the nanocomposite pipes conveying nanofluid is presented. The pipe is reinforced by carbon nanotubes (CNTs) and the fluid is mixed by $AL_2O_3$ nanoparticles. The material properties of the nanocomposite pipe and nanofluid are considered temperature-dependent and the structure is subjected to magnetic field. The forces of fluid viscosity and turbulent pressure are obtained using momentum equations of fluid. Based on energy balance, the convection of inner and outer fluids, conduction of pipe and heat generation are considered. For mathematical modeling of the nanocomposite pipes, the first order shear deformation theory (FSDT) and energy method are used. Utilizing the Lagrange method, the coupled pipe-nanofluid motion equations are derived. Applying a semi-analytical method, the motion equations are solved for obtaining the critical fluid velocity and critical Reynolds and Nusselt numbers. The effects of CNTs volume percent, $AL_2O_3$ nanoparticles volume percent, length to radius ratio of the pipe and shell surface roughness were shown on the critical fluid velocity, critical Reynolds and Nusselt numbers. The results are validated with other published work which shows the accuracy of obtained results of this work. Numerical results indicate that for heat generation of $Q=10MW/m^3$, adding 6% $AL_2O_3$ nanoparticles to the fluid increases 20% the critical fluid velocity and 15% the Nusselt number which can be useful for heat exchangers.

• 멤브레인
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• 제23권2호
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• pp.151-158
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• 2013

EVA의 기체 분리 성질에 미치는 LDH의 영향을 알아보았다. Mg-Al LDH/EVA 나노복합막은 유기적으로 수정된 DS-LDH를 이용하여 용액 삽입법으로 제조되었다. DS-LDH는 LDH 층간에 DS 음이온을 삽입하여 제조하였다. 나노복합막의 구조는 XRD, FT-IR, SEM으로 알아보았다. DS-LDH가 EVA 내에 무질서하게 분산되었음을 XRD로부터 확인하였다. LDH가 3 wt% 첨가된 나노복합막에서 인장강도와 파단신율 모두 최댓값을 나타내었다. 열적 안정도 역시 EVA에 LDH가 첨가되면서 향상되었다. 1, 3, 5 wt%의 LDH를 함유한 LDH/EVA 나노복합막의 기체투과도는 $O_2$와 $CO_2$에 대하여 측정하였다. 3 wt% LDH를 함유한 경우 나노복합막의 $O_2$에 대한 투과도가 EVA막에서보다 53% 감소하였다. 하지만 $CO_2$ 투과도는 나노복합막의 기체 차단 특성에도 불구하고 LDH 내의 OH기와 $CO_2$ 간의 높은 친화력으로 인하여 기체투과도는 증가하였다.