• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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• pp.57.1-57.1
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• 2010

Development of low cost hybrid functional nano-structured materials has great interest to enhance sensitivity of dye-sensitized solar cells and reduction of the production cost. In this talk we will discuss about using different processes to modify functional characteristics of photoelectrode and investigate effects of chemical modification without significant structural variation on to enhance performance of DSSCs. Efficient electron transportation between dye molecules and photoelectrode has been obtained by appropriate chemical modification and efficiency of DSSC has been significantly improved. A comparative analysis on effects of surface functional and electron states of photoelectrode on VOC and JSC has been also carried out to discuss effects of composite materials on physical structure and electronic properties to correlate enhanced performance of these devices.

• 한국표면공학회지
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• 제42권2호
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• pp.73-78
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• 2009

Quinary Ti-Al-Si-C-N films were successfully synthesized on SUS 304 substrates and Si wafers by a hybrid coating system combining an arc ion plating technique and a DC reactive magnetron sputtering technique. In this work, the effect of Si content on the microstructure and mechanical properties of Ti-Al-C-N films were systematically investigated. It was revealed that the microstructure of Ti-Al-Si-C-N coatings changed from a columnar to a nano-composite by the Si addition. Due to the nanocomposite microstructure of Ti-Al-Si-C-N coatings, the microhardness of The Ti-Al-Si-C-N coatings significantly increased up to 56 GPa. In addition the average friction coefficients of Ti-Al-Si-C-N coatings were remarkably decreased with Si addition. Therefore, Ti-Al-Si-C-N coatings can be applicable as next-generation hard-coating materials due to their improved hybrid mechanical properties.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2004년도 춘계 학술발표회 제16권1호
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• pp.292-295
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• 2004

Recently, polymer-clay hybrid materials have received considerable attention from both a fundamental research and application point of view. This organ-inorganic hybrid, which contains a nanoscale dispersion of the layered silicates, is a material with greatly improved thermal and mechanical characteristics. Two classes of nanocomposites were synthesized using an unsaturated polyester resin as the matrix and sodium montmorillonite as well as an organically modified montmorillonite as the reinforcing agents. X -ray diffraction pattern of the composites showed that the interlayer spacing of the modified montmorillonite were exfoliated in polymer matrix. The mechanical properties also supported these findings, since in general, tensile strength, modulus with modified montmorillonite were higher than the corresponding properties of the composites with unmodified montmorillonite. Adding organically modified clay improved the tensile strength of unsaturated polyester by $22\%$ and the tensile modulus of unsaturated polyester was also improved by $34\%$.

• Macromolecular Research
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• 제15권3호
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• pp.211-215
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• 2007

Hybrid thin film nanostructures composed of metal nanoparticles (NPs) and self-assembled polymer films with different spatial distributions of NPs were analyzed by optical waveguide spectroscopy (OWS). Specifically, the dielectric constants were calculated using effective medium theory for the incorporation of 1 vol% Au NP into the block copolymer (BCP) films having a cylindrical nanodomain morphology. Three cases were considered: uniform distribution of NPs in the film; selective distribution of NPs only in the cylindrical domains; and segregation of NPs to the center of the cylindrical domains. The optical waveguide spectra derived from the calculated dielectric constants demonstrate the feasibility of experimentally distinguishing the composite nanostructures with different inner morphologies in the hybrid metal NP-BCP nanostructures, by the measurement of the dielectric constants using OWS.

• 공업화학
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• 제23권1호
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• pp.53-58
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• 2012

투명한 플라스틱 필름의 표면경도를 향상시키기 위하여 유-무기 하이브리드 코팅 용액을 졸-겔 공정을 이용하여 합성하였다. 무기성분으로 콜로이드 실리카와 유기성분으로 PMMA, 유-무기 성분 간의 결합력을 향상시켜 하이브리드 코팅 층의 특성을 더욱 향상시키기 위하여 실란커플링제로서 vinyl trimethoxy silane (VTMS)과 [3-(metha cryloyloxy)] propyl trimethoxy silane (MAPTMS)를 이용하였고, 알콕시 실란의 종류, 콜로이드 실리카/PMMA의 함량비 등의 반응조건에 따라 콜로이드 실리카/PMMA 졸을 합성하였다. 이러한 졸을 PET 필름에 바코팅시키고, 열경화 시켜 하드코팅막을 제조하여 물리적 화학적 특성을 조사하였다. PMMA에 비해서 하이브리드 형태에서 코팅 막의 연필경도와 기재와의 부착력이 우수하였다.

• Journal of Microbiology and Biotechnology
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• 제32권4호
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• pp.531-540
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• 2022

Due to the high incidence of malignant melanoma, the establishment of in vitro models that recapitulate the tumor microenvironment is of great biological and clinical importance for tumor treatment and drug research. In this study, 3D printing technology was used to prepare GelMA/PEGDA composite scaffolds that mimic the microenvironment of human malignant melanoma cell (A375) growth and construct in vitro melanoma micro-models. The GelMA/PEGDA hybrid scaffold was tested by the mechanical property, cell live/dead assay, cell proliferation assay, cytoskeleton staining and drug loading assay. The growth of tumor cells in two- and three-dimensional culture systems and the anti-cancer effect of luteolin were evaluated using the live/dead staining method and the Cell Counting Kit-8 (CCK-8) method. The results showed a high aggregation of tumor cells on the 3D scaffold, which was suitable for long-term culture. Cytoskeleton staining and immunofluorescent protein staining were used to evaluate the degree of differentiation of tumor cells under 2D and 3D culture systems. The results indicated that 3D bioprinted scaffolds were more suitable for tumor cell expansion and differentiation, and the tumor cells were more aggressive. In addition, luteolin was time- and dose-dependent on tumor cells, and tumor cells in the 3D culture system were more resistant to the drug.

• Advances in nano research
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• 제14권2호
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• pp.201-210
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• 2023

A ZnO/poly (amide-imide) hybrid nanocomposite film with different weight percentages of Zinc oxide (ZnO) nanoparticles is synthesized and characterized in this paper. A two-step reaction successfully synthesized a new kind of heteroaromatic diamine with bulky pendant groups. In order to produce 3, 5-dinitro-3, 3-bis (4-(4-Nitrophenoxy) phenyl) -2- benzofuran-1-one, 3, 3'-bis (4-hydroxyphenyl) benzofuran-1-one and 3'-bis (4-hydroxyphenyl) benzofuran-1-one were combined with 3'-bis (3-hydroxyphenyl) benzofuran-1-one. The obtained dinitro was then reduced by zinc dust and hydrochloric acid. The reaction of 4, 4^* carbonyl diphthalic anhydride with amino acid L-alanine in acetic acid leads to the production of very high yields of chiral diacid monomer. As a result of the direct polymerization of these monomers, new optically active polymers were formed (amide-imide). In order to synthesize poly (amide-imide)/ZnO nanocomposites with different weight percentages (2, 4, 6, 8, and 10%), PAI and ZnO nanoparticles were combined using ultrasonication SEM, Fourier transform infrared spectroscopy, X-ray diffraction and thermal gravimetry were used to characterize the PAI films.

• Composites Research
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• 제29권6호
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• pp.353-357
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• 2016

B-stage 레진 필름에 탄소나노튜브(CNT) 등을 균일하게 분포시킨 뒤에 기타의 보강섬유 층과 함께 여러 겹으로 적층하여 하이브리드 형태의 복합재료를 만드는 방법은 유용하다. 본 연구에서는 CNT가 포함된 에폭시 레진으로부터 shear mixing 및 Three-roll mill 공정을 이용하여 B-stage 레진 필름을 제작하였다. 두 공정을 통해 형성된 CNT/레진 복합재 필름의분산도를 파단면의 SEM 관찰을통해분석하였다. 보다 효율적인 공정을 위해 Calendering pass 횟수에 따른 분산도를 평가하였다. Pass의 횟수에 따른 샘플을 제조하고 CNT 분산도는 SEM 이미지를 통해 확인하고, 전기 전도도 측정을 통해 분석하였다. 추가적으로 gap mode, force mode를 통해 제작한 각각의 샘플의 전기 전도도를 측정하여 CNT 분산도를 분석하였고 이를 통해 최적공정을 도출하였다.

• Composites Research
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• 제33권4호
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• pp.191-197
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• 2020

본 연구에서는 향상된 내구성을 가진 고효율 전자파차폐용 랜덤배향 시트 소재를 개발하기 위해 구리(Copper: Cu)와 니켈 (Nickel: Ni)이 코팅된 탄소섬유(Carbon fiber: CF)와 같은 하이브리드 소재를 습식공정을 통해 제조 하였다. 제조된 시트 소재는 69.4~93.0 dB의 높은 전자파 차폐효율을 보여주었다. 또한 하이브리드 금속으로 코팅된 Ni-Cu/CFs 시트는 Ni표면의 유효한 부식저항성과 기계적 저항성 때문에 가혹한 화학적/열적 환경하에서 매우 우수한 내구성을 보여주었다. 이와 관련하여 Ni-Cu/CF 시트는 Cu/CF 시트와 비교하여 1.7배 긴 수명을 가지는 것을 확인하였다.

• Composites Research
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• 제31권3호
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• pp.111-116
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• 2018

본 논문에서는 그래핀 표면에 무전해 도금을 통해 FeCoNi 자성 나노입자를 환원 성장시킨 후 이를 다양한 계면 활성제로 분산시켜 고분자 복합필름을 제조하였다. Pyridine 계면 활성제로 분산 시킨 후 제조한 복합필름은 가장 높은 분산성과 낮은 표면저항 값(351 Ohm/sq) 및 10 GHz 주파수에서 90% 이상의 전자파 차폐 능력을 보였다. 특히, 건조과정에서 pyridine의 증발은 내부 전도체 네트워크 형성과 분산성이 높은 필름 형성을 형성 할 수 있는 것으로 확인되었다.