• Title/Summary/Keyword: Nano- and microstructure

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Effect of Powder Synthesis Processing on the Microstructure and Electrical Conductivity of Sintered $CNTs/Fe/Al_2O_3$ Nanocomposites

  • Choa, Yong-Ho;Yoo, Seung-Hwa;Yang, Jae-Kyo;Park, Jin-Woo;Oh, Sung-Tag;Kang, Kae-Myung;Kang, Sung-Goon
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1087-1088
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    • 2006
  • The microstructure and electrical conductivity of CNTs dispersed $Al_2O_3$ nanocomposites depending on the powder processing and CNTs content were demonstrated. The composite powders with homogeneous dispersion of CNTs could be synthesized by a catalytic route for direct formation of CNTs on nano-sized Fe dispersed $Al_2O_3$ powders. The sintered nanocomposite using the composite powder with directly synthesized CNTs showed homogeneous microstructure and enhanced elelctrical conductivity. The influence of powder processing on the properties of sintered nanocomposites was discussed by the observed microstructural features.

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Multiple Scale Processes in Microstructural Evolution: Case Study of Self-Reinforced β-Si3N4

  • Becher, Paul F.
    • Journal of the Korean Ceramic Society
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    • v.53 no.6
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    • pp.575-580
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    • 2016
  • Microstructural design of ceramics has generally focused on information gathered at the micro- and macro-scales and related this to how specific properties could be improved. Ceramic processing serves as the key to optimizes the final microstructure. However, the advent of nano-scale microstructures and highly advanced characterization tools are forcing us to develop new knowledge of what is occurring not just at the micro-scale but also at the atomic level. Thus we are now beginning to be able to address how microstructure is influenced by events at the atomic scale using atomic scale images and data. Theoreticians have joined us in interpreting the mechanisms involved in the "microstructural" evolution at multiple scales and how this can be used to enhance specific properties of ceramics. The focus here is on delving into the various layers the "microstructure" in order understand how atomic-scale events influence the structure and properties of ceramics.

Properties of Working Electrodes with Nano YBO3:Eu3+ Phosphor in a Dye Sensitized Solar Cell

  • Noh, Yunyoung;Choi, Minkyoung;Kim, Kwangbae;Song, Ohsung
    • Journal of the Korean Ceramic Society
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    • v.53 no.2
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    • pp.253-257
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    • 2016
  • We added 0 ~ 5 wt% $YBO_3:Eu^{3+}$ nano powders in a scattering layer of a working electrode to improve the energy conversion efficiency (ECE) of a dye sensitized solar cell (DSSC). FESEM and XRD were used to characterize the microstructure and phase. PL and micro Raman were used to determine the fluorescence and the composition of $YBO_3:Eu^{3+}$ phosphor. A solar simulator and a potentiostat were used to confirm the photovoltaic properties of the DSSC with $YBO_3:Eu^{3+}$. From the results of the microstructure and phase of the fabricated $YBO_3:Eu^{3+}$ nano powders, we identified $YBO_3:Eu^{3+}$ having particle size less than 100 nm. Based on the microstructure and micro Raman results, we confirmed the existence of $YBO_3:Eu^{3+}$ in the scattering layer and found that it was dispersed uniformly. Through photovoltaic properties results, the maximum ECE was shown to be 5.20%, which can be compared to the value of 5.00% without $YBO_3:Eu^{3+}$. As these results are derived from conversion of light in the UV range into visible light by employing $YBO_3:Eu^{3+}$ in the scattering layer, these indicate that the ECE of a DSSC can be enhanced by employing an appropriate amount of $YBO_3:Eu^{3+}$.

The Effects of Sintering Temperature Influence on the Mechanical Property and Microstructure of Dental Zirconia Block (치과용 지르코니아 블록의 소결온도가 기계적 특성과 미세구조에 미치는 영향)

  • Jo, Jun-Ho;Seo, Jeong-Il;Bae, Won-Tae
    • Journal of Technologic Dentistry
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    • v.36 no.1
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    • pp.9-15
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    • 2014
  • Purpose: Generally dental technicians clinically decide the sintering temperature of zirconia artificial teeth to match the color of the teeth. However, the sintering temperature influence the microstructure and mechanical strength of ceramic body. In this study, to evaluate the free choice of sintering temperature which leads to color the problems in zirconia false teeth, the variation of microstructure, mechanical strength, and colortone of zirconia ceramics according to the change of sintering temperature was investigated. Methods: Bar type specimens were prepared from commercial zirconia blocks by cutting and polishing into $0.8cm(L){\times}1.0cm(W){\times}4.8cm(H)$. Specimens were fired from 1,400 to $1,700^{\circ}C$ at $50^{\circ}C$ intervals and held for 1hour at highest temperature. Apparent porosity, water absorption, firing shrinkage, bulk density, bend strength, whiteness were tested. Microstructures were observed by SEM. Results: When fired above $1450^{\circ}C$, all specimens showed 0% apparent porosity and water absorption, 20% firing shrinkage, and $6.1g/cm^3$ bulk density regardless of firing temperatures. SEM photomicrographs showed grain growth of zirconia occurred above $1,600^{\circ}C$. Whiteness was also largely changed above this temperature. Maximum bend strength of 1,05MPa was obtained at $1,550^{\circ}C$. Bend strength lowered slightly above this temperature and showed $950{\ss}\acute{A}$ at $1,700^{\circ}C$. Conclusion: In order to fit the colortone of zirconia artificial teeth, arbitrary choice of firing temperature higher than $1,500^{\circ}C$, up to $1,700^{\circ}C$ did not influence the mechanical strength.

Investigation About Surface Microstructure of Aluminum with Change of Voltage, a Period of Treatment and Density of Electrolyte in Micro-Arc Oxidation Treatment (MAO(Micro-Arc Oxidation) 공정 중 인가 전압, 반응 시간, 전해액 농도에 따른 알루미늄의 표면 미세조직 평가)

  • Yeo, In-Chul;Kang, In-Cheol
    • Journal of Powder Materials
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    • v.18 no.6
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    • pp.575-582
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    • 2011
  • MAO(Micro-Arc Oxidation) method was used to make $Al_2O_3$ surface on 6063 Al specimen. This study was focused on an influence of voltage, density of electrolyte and a period of treatment on the change of surface microstructure by using SEM(Scanning Electron Microscope), EDS(Energy Dispersive X-ray Spectroscopy). The microstructure shows higher roughness and thicker oxidized layer with increase of voltage and maintaining period of treatment. The density of electrolyte affected a formation of more dense surface and increase of a oxidized layer.

Fabrication of Nanocomposite Powders by Sonochemical Method

  • Hayashi, Yamato;Sekino, Tohru;Niihara, Koichi
    • Journal of Powder Materials
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    • v.8 no.3
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    • pp.207-209
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    • 2001
  • Nano particles have recently been a major research interest, motivated by their unusual physical and chemical properties. Such particles can be synthesized using physical and chemical methods. The physical methods need expensive installation like vacuum induction furnace, whereas in chemical methods the process in generally very simple and low cost. In this study, simple and new fabrication process by using ultrasound was investigated to prepare the nano-sized metal particles on various powders at room temperature.

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