• 제목/요약/키워드: Nano solution

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나노트로닉스-나노테크놀로지에서 엔지니어의 역할 (Nanotronics-The Role of the Engineer in Nano-Technology.)

  • Stout, K.J.;Johnson, A.
    • 한국정밀공학회지
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    • 제15권10호
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    • pp.15-26
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    • 1998
  • The role of the Engineer in the era of nano-technology is explored, a trend in manufacture which is expected to yield a $20-30 billion per annum business throughout the world by the year 2020. The engineers who will be working in this subject will be required to have broadly based experience, over a range of traditional disciplines, such as physics. electronics, software engineering, control and mechanical engineering. As well as having an appreciation of other disciplines such as air conditioning, vibration analysis and its minimisation, the selection of materials for maximum stability and minimal thermal distortion as well as an understanding of ultra precision design and nano tribology. In other words the engineer who is to be successful in this new and emerging field, will have to be broader based than engineers of the past, where it was traditional to break up the elements of a discipline to smaller subsets. But as nano-technology advances and the subject brings about the evolution of nanotronics to provide a successful solution to emerging problems, it will be essential for a breed of engineers to develop who can consider the subject in a holistic manner. This paper therefore considers the emergence of nano-technology, predicts the subsets of the development and places them in context of the new engineer which will be required in increasing numbers. The paper summarises the skills of the proposed nanotronics engineer and provides a basis for their training and development.

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Surface Control of Planarization Layer on Embossed Glass for Light Extraction in OLEDs

  • Cho, Doo-Hee;Shin, Jin-Wook;Moon, Jaehyun;Park, Seung Koo;Joo, Chul Woong;Cho, Nam Sung;Huh, Jin Woo;Han, Jun-Han;Lee, Jonghee;Chu, Hye Yong;Lee, Jeong-Ik
    • ETRI Journal
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    • 제36권5호
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    • pp.847-855
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    • 2014
  • We developed a highly refractive index planarization layer showing a very smooth surface for organic light-emitting diode (OLED) light extraction, and we successfully prepared a highly efficient white OLED device with an embossed nano-structure and highly refractive index planarization layers. White OLEDs act as an internal out-coupling layer. We used a spin-coating method and two types of $TiO_2$ solutions for a planarization of the embossed nano-structure on a glass substrate. The first $TiO_2$ solution was $TiO_2$ sol, which consists of $TiO_2$ colloidal particles in an acidic aqueous solution and several organic additives. The second solution was an organic and inorganic hybrid solution of $TiO_2$. The surface roughness ($R_a$) and refractive index of the $TiO_2$ planarization films on a flat glass were 0.4 nm and 2.0 at 550 nm, respectively. The J-V characteristics of the OLED including the embossed nano-structure and the $TiO_2$ planarization film were almost the same as those of an OLED with a flat glass, and the luminous efficacy of the aforementioned OLED was enhanced by 34% compared to that of an OLED with a flat glass.

Bone-like Apatite Formation on Ti-6Al-4V in Solution Containing Mn, Mg, and Si Ions after Plasma Electrolytic Oxidation in the SBF Solution

  • Lim, Sang-Gyu;Choe, Han Cheol
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2017년도 춘계학술대회 논문집
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    • pp.157-157
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    • 2017
  • Titanium and its alloys that have a good biocompatibility, corrosion resistance, and mechanical properties such as hardness and wear resistance are widely used in dental and orthopedic implant applications. They can directly connect to bone. However, they do not form a chemical bond with bone tissue. Plasma electrolytic oxidation (PEO) that combines the high voltage spark and electrochemical oxidation is a novel method to form ceramic coatings on light metals such as titanium and its alloys. This is an excellent reproducibility and economical, because the size and shape control of the nano-structure is relatively easy. Silicon (Si), manganese (Mn), and magnesium (Mg) has a useful to bone. Particularly, Si has been found to be essential for normal bone, cartilage growth and development. Manganese influences regulation of bone remodeling because its low content in body is connected with the rise of the concentration of calcium, phosphates and phosphatase out of cells. Insufficience of Mn in human body is probably contributing cause of osteoporosis. Pre-studies have shown that Mg plays very important roles in essential for normal growth and metabolism of skeletal tissue in vertebrates and can be detected as minor constituents in teeth and bone. The objective of this work was to study nucleation and growth of bone-like apatite formation on Ti-6Al-4V in solution containing Mn, Mg, and Si ions after plasma electrolytic oxidation. Anodized alloys was prepared at 270V~300V voltages. And bone-like apatite formation was carried out in SBF solution for 1, 3, 5, and 7 days. The morphologies of PEO-treated Ti-6Al-4V alloy in containing Mn, Mg, and Si ions were examined by FE-SEM, EDS, and XRD.

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Characterization of Nanopores on Micropillars Pt Electrodes for Non-Enzymatic Electrochemical Sensor Applications

  • Park, Dae-Joon;Lee, Yi-Jae;Park, Jae-Yeong
    • JSTS:Journal of Semiconductor Technology and Science
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    • 제7권3호
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    • pp.161-165
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    • 2007
  • In this paper, mesoporous Pt on micro pillars Pt electrode is newly designed, fabricated, and characterized on silicon substrate for non-enzymatic electrochemical sensor micro-chip integrated with CMOS readout circuitry. The fabricated micro/nano Pt electrode has cylindrical hexangular arrayed nano Pt pores with a diameter of 3.2 nm which is formed on top of the micro pillars Pt electrode with approximately $6{\mu}m$ in diameter, $6{\mu}m$ in space, and $50{\mu}m$ in height. The measured current responses of the fabricated plane Pt, mesoporous Pt, and mesoporous Pt on the micro pillar Pt electrodes are approximately $9.9nA/mm^2,\;6.72{\mu}A/mm^2,\;and\;7.67{\mu}A/mm^2$ in 10mM glucose solution with 0.1M phosphate buffered saline (PBS) solution, respectively. In addition, the measured current responses of the fabricated plane Pt, mesoporous Pt, and mesoporous Pt on the micro pillar Pt electrodes are approximately $0.15{\mu}A/mm^2,\;0.56{\mu}A/mm^2,\;and\;0.74{\mu}A/mm^2$ in 0.1mM ascorbic acid (AA) solution with 0.1M phosphate buffered saline (PBS) solution, respectively. This experimental results show that the proposed micro/nano Pt electrode is highly sensitive and promising for CMOS integrated non-enzymatic electrochemical sensor applications. Since the micro-pillar Pt electrode can also be utilized with a micro-fluidic mixer in the sensor chip, the sensor chip can be much smaller, cheaper, and easier to be fabricated.

나노사이즈 불화탄소수지 용액 농도에 따른 GDL 발수 코팅 (Water Repellent Coating of GDL with Different Concentration of Nano-sized PTFE Solution)

  • 정문국;송기세;조태환;최원경
    • 한국수소및신에너지학회논문집
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    • 제20권4호
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    • pp.323-330
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    • 2009
  • Efficiency of a fuel cell is determined by the generated water. If water is not removed sufficiently, water will be accumulated at GDL, which causes flooding. Therefore, water control is regarded as a crucial factor to sustain fuel ell performance. In this study, PTFE coating on the surface of carbon paper was carried out to establish optimum process for hydrophobic treatment of GDL. Carbon paper was immersed at different concentrations of nano-sized PTFE coating solution. Their characteristics were analyzed systematically by FE-SEM, water contact angle, cyclic voltamogam, XRD and FT-IR. The quantitative correlation between the amount of coated-PTFE on a carbon paper and concentration of coating solution was carefully investigated. It is suggested that the amount of PTFE-coating on a carbon paper can be managed by means of controling concentration of coating solution.

전착법을 이용한 메조포러스 니켈 필름의 제조와 특성 분석 (Preparation and Characterization of Mesoporous Ni Film Made by Electroplating Method)

  • 이지훈;백영남;김영석;신승한
    • 한국표면공학회지
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    • 제40권1호
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    • pp.16-22
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    • 2007
  • Recently, mesoporous metallic materials are becoming more and more important in various applications like catalysts, electrochemical detectors, batteries, and fuel cells because of their high surface area. Among the various methods for manufacturing mesoporous structure, surfactant templating method followed by electroplating has been tried in this study. A mesoporous metallic film was prepared by electrodeposition from electroplating solution mixed with surfactant template. Nonionic type lyotropic liquid crystalline surfactant, Brij56, and nickel acetate based solution were selected as a template material and electroplating solution, respectively. To determine the content of surfactant forming a hexagonal column structure, the phase diagram of electroplating solution and surfactant mixture has been exploited by polarized optical microscopy equipped with heating and cooling stage. Nickel films were electroplated on Cu foil by stepwise potential input method to alleviate the concentration polarization occurred during the electroplating process. TEM and XRD analyses were performed to characterize the size and shape of mesostructures in manufactured nickel films, and electrochemical characterization was also carried out using cyclic voltammetry.

용액연소합성에 의한 나노크기 물라이트 분말의 제조 (Preparations of Nano-scale Mullite Powder from Solution Combustion Synthesis)

  • 이상진;윤존도;권혁보;전병세
    • 한국재료학회지
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    • 제11권9호
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    • pp.797-801
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    • 2001
  • In this study, the solution combustion method was employed to synthesize stoichiometric mullite, and hence the attrition process was employed to prepare ultrafine mullite particles with nano size. The thermal decomposition behavior and partial pressure of equilibrium species of both oxidizer and fuel were considered during solution combustion process. The synthesized product was mullite phase with 40 nm crystalline size, and the alumina contents of the product by TEM/EDS quantity analysis was 3.12$\pm$04 mole. The result showed that the synthesized mullite was almost close to the it's stoichiometric composition. For attrition process, the dispersion behavior of the mullite suspension was controlled and was comminuted with the condition of 800 rpm for 4 hours using 0.3 mm zirconia ball media. As a result of comminution, the mean particle size was 80 nm.

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열처리 카올린 분말의 알칼리활성화 반응에 미치는 가열온도의 영향 (Effect of the Heating Temperature on the Alkali-activation Reaction of Calcined Kaolin Powder)

  • 김성곤;송태웅
    • 한국세라믹학회지
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    • 제49권6호
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    • pp.601-607
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    • 2012
  • The alkali-activation reaction of two types of typical kaolin calcined at various lower temperatures was investigated at room temperature and at elevated temperatures. For the assessment of the reactivity, the temperature increase and the setting time of pastes prepared with calcined kaolin and sodium/potassium hydroxide solution were measured. Unlike raw kaolin, calcined kaolin samples prepared at various temperature showed an alkali-activation reaction according to the different aspects of the changes in the mineral phases. The reactivity with alkaline solutions was exceedingly activated in the samples calcined at $600-650^{\circ}C$, but the reactivity gradually decreased as the temperature increased in a higher temperature range, most likely due to the changes in the crystal structure of the dehydrated kaolin. The activation effect of the calcination treatment was achieved at reaction temperatures that exceeded $60^{\circ}C$ and was enhanced as the temperature increased. The reactivity of the calcined kaolin with an alkaline solution was more enhanced with the solution of a higher concentration and with a solution prepared from sodium hydroxide rather than potassium hydroxide.

분무열분해 공정에 의한 폐액으로부터 니켈 페라이트 나노 분말 제조 (Manufacture of Nano-Sized Ni-ferrite Powder from Waste Solution by Spray Pyrolysis Process)

  • 유재근;서상기;강성구;김좌연;박시현;김용수;최재하;손진군
    • 자원리싸이클링
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    • 제12권4호
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    • pp.20-29
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    • 2003
  • 본 연구에서는 새도우마스크 제조공정 중 발생되는 Fe-Ni 계 폐산용액을 효율적으로 재활용하기 위하여 폐산용액을 자체 제작한 분무열분해 system을 이용하여 분무열분해시킴에 의해 평균입도 100nm 이하의 니켈 페라이트($NiFe_2$$O_4$)나노 분발을 제조하였으며 반응온도, 용액의 농도 및 용액 유입속도의 반응인자들의 변화에 따른 생성된 분발의 특성변화를 파악하였다. 반응온도가 800∼$1100^{\circ}C$ 로 증가함에 따라 분무열분해 공정에 의해 생성된 분말의 평균입도가 현저히 증가하였고 점점 치밀한 조직을 나타내었으며 비표면적은 크게 감소하였다. 반응온도의 증가에 따라 니첼 페라이트 상의 생성비율 및 결정성이 증가하였다. 원료용액의 농도가 증가됨에 따라 분말의 평균입도는 점점 증가하고 비표면적은 감소하는 반면 입도분포는 더욱 불규칙하게 나타났다. 용액의 농도 증가에 따라 니켈 폐라이트 상의 생성비율 및 결정성은 현저히 증가하고 있었다. 용액의 유입속도 증가에 따라 분말들의 평균입도는 현저히 증가하고 비표면적은 감소하는 반면 입도분포는 불규칙하게 되며 조직의 치밀성도 감소하였다. 용액의 유입속도 감소에 따라 니켈 폐라이트 상의 결정성 및 생성비율이 현저히 증가하고 있었다.

스폰지 복제법을 이용한 Ag 코팅 BCP 지지체의 제조 및 평가 (Fabrication and Characterization of Ag-coated BCP Scaffold Derived from Sponge Replica Process)

  • 김민성;김영희;송호연;민영기;이병택
    • 한국재료학회지
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    • 제20권8호
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    • pp.418-422
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    • 2010
  • As a starting material, BCP (biphasic calcium phosphate) nano powder was synthesized by a hydrothermal microwave-assisted process. A highly porous BCP scaffold was fabricated by the sponge replica method using 60 ppi (pore per inch) of polyurethane sponge. The BCP scaffold had interconnected pores ranging from $100\;{\mu}m$ to $1000\;{\mu}m$, which were similar to natural cancellous bone. To realize the antibacterial property, a microwave-assisted nano Ag spot coating process was used. The morphology and distribution of nano Ag particles were different depending on the coating conditions, such as concentration of the $AgNO_3$ solution, microwave irradiation times, etc. With an increased microwave irradiation time, the amount of coated nano Ag particles increased. The surface of the BCP scaffold was totally covered with nano Ag particles homogeneously at 20 seconds of microwave irradiation time when 0.6 g of $AgNO_3$ was used. With an increased amount of $AgNO_3$ and irradiation time, the size of the coated particles increased. Antibacterial activities of the solution extracted from the Ag-coated BCP scaffold were examined against gram-negative (Escherichia coli) and gram-positive bacteria (Staphylococcus aureus). When 0.6 g of $AgNO_3$ was used for coating the Ag-coated scaffold, it showed higher antibacterial activities than that of the Ag-coated scaffold using 0.8 g of $AgNO_3$.