• 제목/요약/키워드: NaOH concentration

검색결과 918건 처리시간 0.033초

염색 전처리조의 NaOH 자동 농도 제어 시스템의 개발 (Development of Automatic Concentration Control System for NaOH in Dyeing Pretreatment Bath)

  • 김한도
    • 한국염색가공학회지
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    • 제15권4호
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    • pp.39-42
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    • 2003
  • Automatic concentration control system for pretreatment of dyeing was set up with adaptive control system supported by Fuzzy logic for the high speed successive pretreatment of fabric. Concentration of pretreatment bath was determined by the conductivity due to the ionized NaOH. Usability of this system was also evaluated with 30wt% of NaOH (conductivity of 0.25 S/cm) as an initial concentration. Conductivity fluctuated between 0.31 and 0.17 S/cm. This range accorded with the 21-35wt% of NaOH concentration.

농도제어장치를 이용하여 면직물 전처리 공정에서 발생하는 가성소다 폐액의 재활용에 관한 연구 - 재활용 가성소다에 의한 면직물의 정련성 - (A Study on Recycling NaOH from Pre-treatment Process with Concentration Control System - Scouring Ability of Cotton Fabric Treated with Recycled NaOH -)

  • 이언필
    • 한국의류산업학회지
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    • 제6권3호
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    • pp.393-398
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    • 2004
  • This research offers recycling method of NaOH from mercerizing process of cotton fabric. The measuring system of NaOH concentration was designed for the mercerizing process and tested for various conditions which can be occurred in factory. The accuracy of the system was varied as the testing condition was changed. As the concentration of sulfuric acid used for titrating NaOH decreased, the accuracy of measuring system increased. The concentration of NaOH for waste water collected from mercerizing process was measured by 5.2%. As the ratio of newly mixed NaOH increased, moisture regain. water absorbency and whiteness of the specimen increased. The bending rigidity(B) and shear rigidity(G) decreased, as the ratio of newly mixed NaOH increased.

개질 비대칭 폴리에테르이미드막을 통한 물-이소프로판올 혼합물의 투과증발 분리: 투과증발 특성에 미치는 표면층 개질에 사용된 NaOH 농도의 영향 (Pervaporation Separation of Water-isopropanol Mixtures Through Modified Asymmetric Polyetherimide membranes: the Effect of NaOH Concentration for the Modification of Skin Layers on the Pervaporation Characteristics)

  • 김상균;제갈종건;이규호
    • 공업화학
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    • 제10권2호
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    • pp.319-323
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    • 1999
  • 비대칭 폴리에테르이미드막을 상전이 방법으로 제조하였고, 표면층 개질에서 NaOH 농도의 영향과 그에 따른 물/이소프로판올 혼합물 투과증발 분리에 대하여 연구하였다. 실험결과, 개질 용액의 농도가 증가할수록 폴리에테르이미드의 이미드 그룹이 가수분해에 의해서 쉽게 폴리아믹산 구조로 변하여 치밀층의 두께가 증가하였다. 따라서 사용된 NaOH 농도가 증가할수록 전반적인 투과도는 감소하였고, 선택도는 증가하였다. 그러나 NaOH 용액의 농도가 너무 높은 경우, 선택도가 오히려 감소하고 투과도는 증가되었다. 이러한 결과로부터, 비대칭 폴리에테르이미드막의 투과거동이 NaOH 농도에 크게 의존한다는 것을 알 수 있었다. 또한, NaOH로부터 개질된 막들의 투과증발 운전온도가 증가할수록 투과도와 선택도가 모두 증가되었다.

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사급암모늄염/수산화나트륨용액에서 폴리에스테르 직물의 알칼리처리에 관한 연구 (A Study on Polyester Fabric treated with Quarternary Ammonium Salt and Alkali)

  • 류효선
    • 대한가정학회지
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    • 제25권4호
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    • pp.9-18
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    • 1987
  • This study is conducted to investigate the influence of addition of quarternary ammonium salt(cetyl trimethyl ammonium bromide: CTAB) when polyester(PET) fabric is treated with sodium hydroxide(NaOH), depending on experimental variables such as CTAB concentration, NaOH concentration, time & temperature, and the change in physical & chemical properties of alkaline-hydrolyzed PET fabrics depending on their weight loss. The results are as follows: 1. By adding CTAB in aqueous NaOH, the weight loss of PET fabric is increased remarkably and until the concentration of CTAB is reached at its cmc, and the higher the concentration of CTAB are, the more weight loss on PET fibrics are. 2. The addition of CTAB in aqueous NaOH is most effective at lower NaON concentration(2%) among various NaOH concentration, on increasing the amount of weight loss, while there are almost similar results through various treatment time and temperature. 3. As the amount of weight of weight loss on PET fabric is increased, the increase of void space in the PET yarn, of softness & dyeability of PET fabric and the decrease of tensile strength are found. On the other hand, the moisture regain shows a little increase by alkaline-hydrolysis on PET fabric while vertical absorption test & water retention value are not sufficiently sensitive to distinguish between the hydrophillicity of untreated and treated PET fabric. The shrinkage of PET fabric is induced by swelling in hot aqueous NaOH regardless of NaOH concentration & addition of CTAB.

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알칼리 용액에서 알루미늄 재활용 캔을 이용한 수소생산에 미치는 환경 인자의 영향 (Effects of Environmental Variables on Hydrogen Generation from Alkaline Solutions using used Aluminum Cans)

  • 윤귀섭;박찬진
    • 한국수소및신에너지학회논문집
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    • 제22권1호
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    • pp.29-34
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    • 2011
  • This study examined the effect of environmental variables, such as the NaOH concentration and solution temperature, on the rate of hydrogen generation from NaOH solutions through the corrosion of used aluminum cans as a potential candidate material for the safe and economic production of hydrogen. Corrosion of the used aluminum cans was promoted by increasing the NaOH concentration and solution temperature because of the loss of aluminum passivity. The measured rate of hydrogen generation from the NaOH solutions increased with increasing NaOH concentration due to the catalytic activity of NaOH in the hydrolysis process. However, at higher solution temperatures, the rate of hydrogen generation rate was less affected by the NaOH concentration than that at lower temperature.

생활(生活) 폐기물(廢棄物) 소각재(燒却材) 슬래그를 이용(利用)한 메조포러스 실리카 합성(合成) : NaOH 농도(濃度)의 영향(影響) (Synthesis of Mesoporous Silica Using Municipal Solid Waste Incinerator Ash Slag : Influence of NaOH Concentration)

  • 한요셉;정종훈;박재구
    • 자원리싸이클링
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    • 제19권1호
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    • pp.40-48
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    • 2010
  • 생활 폐기물 소각재 슬래그를 출발원료로한 메조포러스 실리카의 합성에 미치는 NaOH 영향에 대해 조사하였다. 기계적 분쇄를 통해 활성화된 소각재 슬래그에 대한 추출 공정은 농도가 다른 NaOH 용액을 이용한 알칼리 처리로 수행하였다. 분쇄시간 그리고 NaOH 용액 농도가 증가 할수록 소각재 슬래그로부터 추출되는 Si 추출량은 증가하였다. 합성된 메조포러스 실리카의 물리적 특성(기공크기, 비표면적 그리고 총 기공부피)은 BET, SEM, TEM 그리고 small-angle XRD 분석을 통하여 평가하였다. 합성된 메조포러스 실리카는 대략 7 nm 기공크기의 hexagonal 구조를 가진 SBA-15로 판명되었다. NaOH 용액 농도가 증가됨에 따라 합성된 메조포러스 실리카는 비표면적 및 기공 부피도 증가하였다. 반면, 거의 동일한 Si 이온 농도로 제조된 메조포러스 실리카의 경우, 3M NaOH로 제조된 샘플에 비해 4M NaOH로 제조된 샘플의 비표면적 및 기공 부피가 감소하였다. 이는 과량의 Na 이온이 mesophase 형성을 방해하여 미반응되어 남아있는 Si 이온이 합성되어진 mesophase의 벽 두께를 증가시키는 것으로 확인되었다.

침지액의 NaOH와 NaCl의 농도 및 계란 침지기간이 계란 피단의 완성도에 미치는 영향 (Effect of Concentration of NaOH and NaCl in Dipping Solution and Dipping Period of Egg in Completeness of Egg Pidan)

  • 신택순;조성근;이홍구;조병욱;강한석;박현철;배석현;김윤석;김병우
    • 농업생명과학연구
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    • 제46권6호
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    • pp.117-126
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    • 2012
  • 본 실험은 계란의 과잉생산에 따른 여러 가지의 문제점을 해결하고 사육 농가의 소득을 증대하기 위해 계란으로 피단을 제조하는 방법을 실험하였다. NaOH의 농도를 3, 5, 7%로 기준하고 NaCl의 농도를 5, 10, 15, 20%로 기준하여 침지액을 제조하여 2일 간격으로 14일간 실험하였다. 침지액의 pH는 NaOH의 농도가 높을수록, 그리고 침지기간이 경과할수록 피단제조용 침지액의 pH는 증가하였고, NaCl의 농도가 높을수록 감소하는 경향이 나타났다. 난황의 pH는 NaOH의 농도가 진할수록 증가하였으나, NaCl의 농도에 따라서는 차이가 나타나지 않았다. NaOH와 NaCl의 농도가 높을수록 난황과 난백 침투속도는 빨라지는 것으로 나타났다. NaOH의 농도가 3%일 때 14일까지도 난백의 수양화가 되지 않았으나, 5%일 때는 11~12일째에, 7%일 때는 8~10일째에 각각 수양화가 발생하였다. 수양화가 되었을 때 난백의 pH는 11.8~12.0으로 조사되었다. NaOH의 농도가 3%일때는 12~14일 정도, 5%일 때는 10일 정도, 7%일 때는 6~7일 정도 침지 후 열처리를 하면 피단이 완성되었다. NaOH의 농도가 높을수록 침지기간 및 제조기간은 단축하였으나, 피단 난백의 수양화가 빠르게 진행되는 것이 큰 단점으로 나타났다. 따라서 NaOH가 3~5%정도가 알맞다고 생각되며, NaCl의 농도는 침지기간에는 무관하나 염도에 영향을 미치므로 5~10%정도 범위에서 조절하는 것이 적당하고 15~20%일 경우에는 염도가 높아 기호도가 떨어졌다.

견 피브로인의 알칼리 가수분해 (Hydrolysis of Silk Fibroin on Alkali Conditions)

  • 김남정;배도규
    • 한국잠사곤충학회지
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    • 제39권2호
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    • pp.197-202
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    • 1997
  • To hydrolyze silk fibroin was treated with NaOH solution on various concentrations and times. And it was examined that the addition effects of NaHSO3 solution on the solubility and colouring of silk fibroin. As obtained results are as follows; The more increasement of concentration and time of NaOH treatment, the more increasement of solubility but solubility was slight above 3% concentration of NaOH. Fibroin yield was decreased above 3% concentration. This was due to formation of peptide or amino acids below molecular weight 3,000. Most of molecular weight distribution came out to be under 3,000 in 2% concentration and 4hrs of NaOH treatment. The more increasement of adding concentration and 4hrs of NaOH treatment. The more increasement of adding concentration of NaHSO3, the more reduction of solubility but white index of powder increased. In the results of FT-IR spectras of silk fibroin powder obtained by various concentrations of NaHSO3 treatment, the absorbent peak at 3,400 cm-1 which was considered as -CH=N- (azomethine) was disappeared by the more addition of NaHSO3. It showed that absorbent peak of $\beta$-fibroin moved into low temperature region and transferred to $\alpha$- and random coil structure through the DSC experiment. In the results of amino acid analysis, alkali hydrolysis reduced the oxy amino contents acid like serine and tyrosine, but increased the glycine content by the more addition of NaHSO3.

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Effect of NaOH Concentration on the PEO Film Formation of AZ31 Magnesium Alloy in the Electrolyte Containing Carbonate and Silicate Ions

  • Moon, Sungmo;Kim, Yeajin;Yang, Cheolnam
    • 한국표면공학회지
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    • 제50권5호
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    • pp.308-314
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    • 2017
  • Anodic film formation behavior of AZ31 Mg alloy was studied as a function of NaOH concentration in 1 M $Na_2CO_3$ + 0.5 M $Na_2SiO_3$ solution under the application of a constant anodic current density, based on the analyses of voltage-time curves, surface appearances and morphologies of the anodically formed PEO (plasma electrolytic oxidation) films. The anodic film formation voltage and its fluctuations became largely lowered with increasing added NaOH concentration in the solution. Two different types of film defects, large size dark spots indented from the original surface and locally extruded white spots, were observed on the PEO-treated surface, depending on the concentration of added NaOH. The large size dark spots appeared only when added NaOH concentration is less than 0.2 M and they seem to result from the local detachments of porous PEO films. The white spots were observed to be very porous and locally extruded and their size became smaller with increasing added NaOH concentration. The white spot defects disappeared completely when more than 0.8 M NaOH is added in the solution. Concludingly it is suggested that the presence of enough concentration of $OH^-$ ions in the carbonate and silicate ion-containing electrolyte can prevent local thickening and/or detachment of the PEO films on the AZ31 Mg alloy surface and lower the PEO film formation voltage less than 70 V.

규질 이암으로부터 제올라이트의 수열 합성에 관한 연구 (Hydrothermal Synthetic Study of Zeolites from Siliceous Mudstone)

  • 노진환
    • 한국광물학회지
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    • 제13권4호
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    • pp.171-185
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    • 2000
  • Siliceous mudstones are embedded on a large scale in the Tertiary formations of Pohang area. Some useful zeolites such as NsP, (Na, TMA)P, analcime and hydroxysodalite were synthesized from the siliceous mudstones by treating with the variety of solution, i.e ., NaOH, NaOH+NaCl, NaOH, NaOH+$NaAlO_2$and NaOH+TMAOH at the low-temperature hydrothermal system ranging 60~12$0^{\circ}C$. Major precursor of zeolites is found as opal-CT in the zeolite-forming reaction. Smectite, which is included in considerable amounts in the mudstone, appears to play a major role of Al-source in the zeolite synthesis. In comparison, chalcedonic quartz and mica are rather insoluble in alkaline solution, and thus, these are observed as major impurities in the reaction products. An addition of $NaAlO_2$to NaOH solution is effective for eliminating these impurities in the reaction procedure, through these are partly dissolved when elevating the reaction temperature, concentration, and time. Phase change from NaP to hydroxysodalite takes place at the NaOH concentrations of 3.0~4.0 M, and the reaction is not sensitive to the temperature shift. NaP is more stable at lower NaOH concentration and higher activity of $Na_{+}$ whereas analcime is sensitive to the temperature change and stable at higher than $100^{\circ}C$ and 2.0~4.0 M in NaOH concentration. For the pure NaP synthesis without any other products, the treatment of mudstones with 1:1 solution of NaOH and $NaAlO _2$ turns out to be quite effective. NaP was successfully synthesized together with analcime at $100^{\circ}C$ as well as lower concentrations of NaOH+NaCl solution. In addition, the organic type, (Na, TMA)P was formed together with smectite in the 1:1 solution of NaOH and TMAOH.

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