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Characterization of Tribocorrosion Behaviour of CoCr Alloy by Electrochemical Techniques in Several Corrosive Media

  • Escudero, M.L.;Diaz, I.;Martinez Lerma, J.F.;Montoya, R.;Garcia-Alonso, M.C.
    • Corrosion Science and Technology
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    • v.17 no.2
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    • pp.68-73
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    • 2018
  • Substitution of hip and knee joints by CoCr alloys is in great demand due to their high wear resistance and good biocompatibility. Understanding of tribocorrosion in joint replacements requires study of variables such as coefficient of friction and the choice of a proper corrosive medium in wear-corrosion tests carried out in the lab. The objective of this study was to characterize tribocorrosion behaviour of CoCr alloy with low (LCCoCr) and high carbon (HCCoCr) contents in several corrosive media: NaCl, Phosphate Buffer Solution (PBS), and PBS with hyaluronic acid (PBS-HA). Tribocorrosion tests were carried out on a pin-on-disk tribometer with an integrated electrochemical cell. A normal load of 5N was applied on the alumina ball counterpart at a rotation rate of 120 rpm. Coefficient of friction (COF) was measured and tribocorrosion behaviour was characterized by in situ application of electrochemical techniques. HCCoCr alloy immersed in PBS-HA showed the best tribocorrosion behaviour with the lowest COF. In this case, in situ measurement of corrosion potential and the impedance data under wear corrosion process showed an active state while passive film was continuously destroyed without possibility of regeneration.

A Study on Rotary Bending Fatigue Strength of the $CO_2$ Gas Welded Joint in Air and Sea Water ([$CO_2$] 용접이음재의 대기 및 해수중에서의 회전굽힘 피로강도에 관한 연구)

  • S.W. Kang;S.Y. Lee
    • Journal of the Society of Naval Architects of Korea
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    • v.37 no.2
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    • pp.118-126
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    • 2000
  • TMCP steel has been widely used to construct ships and offshore structures. When it comes to ship and offshore structures, corrosion fatigue damages caused by sea water and fatigue occurred by wave-induced forces usually go on occurring simultaneously. So the fatigue life in corrosion environment is decreased markedly in comparison with that in air. The fatigue crack in corrosion easily initiates on welded joints of structure like as the fatigue crack in air. Therefore it is very important to study the fatigue properties of those of their welded joints as well as steel plates. In this study, rotary bending fatigue tests have been performed to investigate fatigue crack initiation and behavior of fatigue crack growth on CO2 gas weld HAZ of TMCP steel. The fatigue test used the specimens with various stress concentration factors in air and 3% NaCl solution

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Study on the Salt Tolerance of Rice and Other Crops in Reclaimed Soil Areas 12. On the Salt Tolerance of the Rice Seeldings Grown under the Land and Water Conditions in the Reclaimed Salty Areas (간척지에서 수도 및 기타작물의 내염성에 관한 연구 12. 육묘와 수묘의 염분간척지에서의 내염성에 관하여)

  • 임형빈
    • Journal of Plant Biology
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    • v.13 no.4
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    • pp.23-31
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    • 1970
  • The rice variety, Kwanok, was reared in the water and land beds and transplanted to the reclaimed soil area, having an average salt concentration of 0.39%. Two levels of the moderate and late season cultures with 4 treatments were used. The K and Si contents of the stem part of land bed seedlings were somewhat smaller, but total carbohydrate remarkably larger, the C/N ratio was accordingly greater than water bed seedlings. The rooting ability of land bed seedlings was vigorous markedly in culture solutions, to which added various concentrations of NaCl, The rooting ability of each seedling water not much declined in theculturing solution of up to 9.4mmhos/cm, (0.6%) of salt concentration, but it was drastically declined in the salt concentration over that. It seemed that the critical salt concentration for the rooting rice plant. The land bed seedlings in each salty condition markedly decreased compared with the water bed seeldings in transpiration rate and it showed a stronger drought resistance and contained a large amount of chlorophyll at transplanting stage, and also showed higher stability of chlorophyll at rooting stage in the salt treatment. The number of panicles, panicle weight, number of grains per panicle and ratio of matured grains of the rice plant grown by the land bed seedlings were much greater and 1,000 grain weight was less than from water bed seedlings. The cultural practices with the land bed seedlings increased the rough rice yields by 15% and 11%, respectively, compared with the yields of the moderate and late season cultures by water bed seedlings.

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Silencing of CaCDPK4 ( Capsicum annuum Calcium Dependent Protein Kinase) and ItsOrtholog, NbCDPK5 Induces Cell Death in Nicotiana benthamiana

  • Eunsook Chung;Kim, Young-Cheol;Oh, Sang-Keun;Younghee Jung;Kim, Soo-Yong;Park, Doil
    • Proceedings of the Korean Society of Plant Pathology Conference
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    • 2003.10a
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    • pp.77.1-77
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    • 2003
  • We have isolated a full-length cDNA clone, CaCDPK4 encoding a typical calcium-dependent protein kinase (CDPK) from hot pepper cDNA library. Genomic southern blot analysis showed that it belongs to a multigene family, but represents a single copy gone in hot pepper genome. RNA expression pattern of this gene revealed that it is induced by infiltration of Xanthomonas axonopodis pv. glycines Bra into hot pepper leaves but not by water deficit stress. However, high salt treatment of NaCl (0.4 M) solution to hot pepper plants strongly induced CaCDPK4 gene. In addition, this gene is weakly responsive to the exogenous application of salicylic acid or ethephon. Biochemical study of the GST-CaCDPK4 recominant protein showed that it autophosphorylates in vitro and the presence of EGTA, a calcium chelater, eliminates the kinase activity of the recombinant protein. As a way to identify the in vivo function of CaCDPK4 in plants, VIGS (Virus-Induced Gene Silencing) was employed. Agrobacterium-mediated TRV silencing construct containing the kinase and calmodulin domain of CaCDPK4 resulted in cell death of Nicotiana benthamiana plants. A highly homologous H benthamiana CDPK gene, NbCDPK5, to CaCDPK4 was cloned from N. benthamiana cDNA library. VIGS of NbCDPK5 also resulted in cell death. The molecular characterization of this cell death phenotype is being under investigation.

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Characteristics of Nano-Size Au Fine Particles Doped TiO2 Thin Films by Sol-Gel Method (졸-겔법에 의한 나노크기 Au 미립자 분산 TiO2 박막의 특성)

  • Park, Min-Jung;Koo, Se-Na;Lee, Kyoung-Seok;Mun, Chong-Soo
    • Journal of the Korean Ceramic Society
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    • v.43 no.2 s.285
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    • pp.114-120
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    • 2006
  • Nano-size Au particle doped $TiO_2$ films were prepared with $Ti(OC_3H_7^i)_4$, polyvinylpyrrolidone(PVP), $HAuCl_4$ and $C_3H_7OH$ etc. by sol-gel method. $TiO_2$ gel films were obtained by the dip-coating method on the $SiO_2$ glass substrates, and then heat-treated at $700^{\circ}C$ for 10 min. The thickness of $TiO_2$ films were $0.7\~1.8\;{\mu}m$. It was found that the thickness of films prepared from PVP containing solution was about $2\~8$ times higher values than that of thin films without PVP. The size of Au particles doped in the films were about $350\~750\;nm$. Nano-size Au particle dispersed $TiO_2$ films showed high absorption peak at visible region 450nm, which made them good candidates for non-linear optical materials and photo-catalytic materials. The contact angle of $TiO_2$ film for water was $12.5^{\circ}$, and therefore it is clear that $TiO_2$ films have very high hydrophilic properties and the self-cleaning effects.

Extraction and Separation of Protein-bound Polysaccharide Produced by Coriolus versicolor (Fr) Quel (구름버섯 배양액으로부터 단백다당류의 추출 및 정제방법)

  • Park, Kyung-Sook;Lee, Jae-Yang;Lee, Sang-Jik;Kim, Seon-Hee;Lee, Jae-Sung
    • The Korean Journal of Mycology
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    • v.20 no.1
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    • pp.72-76
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    • 1992
  • The extraction and separation methods of protein-bound polysaccharides from the mycelium and culture broth of Coriolus versicolor (Fr) Quel were investigated. The use of 2% solution of surface active agent Triton X-100, was effective for extraction of the protein-bound polysaccharides from the mycelium. For the separation and partial purification of the protein-bound polysaccharides, the column chromatography using DEAE-Cellulose and DEAE-Sephadex proved to be effective.

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Studies on the Kimchi Pasteurization -Part 1. Method of Kimchi Pasteurization with Chinese Cabbage Kimchi and its Effect on the Storage- (김치의 순간살균방법(瞬間殺菌方法) -제1보(第-報). 배추 김치의 순간살균방법(瞬間殺菌方法)과 살균효과(殺菌效果)-)

  • Lee, Nam-Jin;Chun, Jae-Kun
    • Applied Biological Chemistry
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    • v.24 no.4
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    • pp.213-217
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    • 1981
  • A Kimchi pasteurizer consisting of preheating, holding, cooling and liquid separation sections was built with copper tubing coil and glasses. The liquid portion of a Chiness Cabbage Kimchi prepared with 3% NaCl solution was preheated and held for 3 minutes at sterilization temperature. Thereafter it was cooled momentarily and recombined with the untreated solid part of Kimchi At four different temperatures of $68^{\circ}$, $75^{\circ}$, $81^{\circ}$ and $85^{\circ}C$ Kimchi was sterilized and examined for the sterilization effects by measuring acid and pH changes of the Kimchi when stored at $15^{\circ}C$. The shelf-life of sterilized Kimchi was prolonged by two folds compared with the untreated one. When Kimchi was sterilized at different maturing stages. the less cured one prolonged its shelf-life more effectively.

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The Arc Dispersion Properties by Switching of High Sensitivity Type RCD Contacts (고감도형 누전차단기 접점의 스위칭에 따른 아크 비산 특성)

  • Choi Chung-Seog;Kim Dong-Woo;Kim Young-Seok;Lee Ki-Yeon
    • Fire Science and Engineering
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    • v.19 no.2 s.58
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    • pp.63-68
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    • 2005
  • In this study, the arc dispersion properties were analyzed according to switching of high sensitive type Residual Current Protective Device(RCD) contacts. Arc dispersion and ignition process was taken by high speed imaging system(HSIS). In this experiment, electric lamps(60 W) and heaters(950 W) were connected in parallel as loads. In case of normal RCD, it took about 2.3(ms) from the generation of arc to the extinction of uc. When arc was dispersed in normal RCD, it did not ignite cotton. Whereas, in case of RCD deteriorated by NaCl solution, the range of arc dispersion was wider and the arc lasted for 3.3[ms] more compared to normal RCD. And the arc ignited cotton. In order to prevent accidents caused by RCD, we should be careful of environmental factors, such as dust and humidity, and the parts of RCD should be used as incombustible materials.

Longitudinal Alterations of Microarchitecture and Mineralization Distribution on Trabecular Bone Due to Metastatic Bone Tumor (전이성 골암에 의한 해면골의 미세구조와 골화 분포 변화)

  • Park, Sun-Wook;Jeon, Ok-Hee;Ko, Chang-Yong;Kim, Chi-Hyun;Kim, Han-Sung;Chun, Keyoung-Jin;Lim, Do-Hyung
    • Journal of Biomedical Engineering Research
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    • v.30 no.5
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    • pp.444-451
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    • 2009
  • Purpose: The aim of present study is to detect longitudinal alterations of mechanical characteristic determined by bone quality (microarchitecture and degree of mineralization) on femur trabecular bone due to metastatic bone tumor Materials and Methods: Each 6 female SD rats (12 weeks old, approximate 250g) were allocated in SHAM and TUMOR Group. W256 (Walker carcinosarcoma 256 malignant breast cancer cell) was injected into the right femur (intraosseous injection) in TUMOR Group, whereas 0.9% NaCl (saline solution) was injected in SHAM Group. The right hind limbs of all rats were scanned by in-vivo micro-CT to acquire structural parameters, bone mineral density, X-ray attenuation and bone mineralization distribution at 0 week and 4 weeks after surgery. Results: BMD, BV/TV and Tb.N of trabecular bone in TUMOR group were markedly decreased (26%, 11% and 23%) while those in SHAM group were significantly increased (34%, 48% and 11%) (p<0.05). BS/BV, Tb.Sp and SMI in TUMOR group were significantly increased (-16%, 38% and 2%) compared with those in SHAM group (-33%, 12% and -16%) (p<0.05). Additionally, bone mineralization in TUMOR group significantly decreased while those in SHAM group was significantly increased (p<0.05). Conclusion: It is identified that how much bone microarchitecture and mineralization are diminished due to the metastatic bone tumor. The results may be helpful to prediction of fracture risk by metastatic bone tumor.

Analysis for Cause of Corrosion and Gas Leakage on LP-Gas Cylinder (LP가스 용기의 부식 및 가스누출 원인 분석)

  • Choi S. C.;Jo Y. D.;Kweon J. R.;Kim J. Y.
    • Journal of the Korean Institute of Gas
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    • v.5 no.1
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    • pp.52-59
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    • 2001
  • Factors to cause accidents were investigated through a systematic analysis of leakage accidents in welded LP-gas cylinder between 199 and 1999. As a result It was showed that most of leakage accident occurred at the pin-hole due to the localized corrosion on welded zone in cylinder. Accordingly, in this paper, we suggested that the problems of heat treatment condition in two-piece welded cylinder and substitute proposal for preventing the tearing of T zone in three-piece welded cylinder. Furthermore, corrosion rate on the weldment and base metal of welded LP-gas cylinder was evaluated using the electrochemical tests in acid rain and $3.5\%NaCl$ solution, Also, the poor adhesion and defects of film which was produced by electrostatic powder spray painting, while the LP-gas cylinder was manufactured, were analyzed using SEM(Scanning Electron Microscopy). And we proposed a optimum coating thickness of the cylinder.

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