• Macromolecular Research
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• v.17 no.9
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• pp.688-696
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• 2009

In this study, a new class of polyurethane (PU) nanofibers containing silver (Ag) nanoparticles (NPs) was synthesized by electrospinning. A simple method that did not depending on additional foreign chemicals was used to self synthesize the silver NPs in/on PU nanofibers. The synthesis of silver NPs was carried out by exploiting the reduction ability of N,N-dimethylformamide (DMF), which is used mainly to decompose silver nitrate to silver NPs. Typically, a sol-gel consisting of $AgNO_3$/PU was electrospun and aged for one week. Silver NPs were created in/on PU nanofibers. SEM confirmed the well oriented nanofibers and good dispersion of pure silver NPs. TEM indicated that the Ag NPs were 5 to 20 nm in diameter. XRD demonstrated the good crystalline features of silver metal. The mechanical properties of the nanofiber mats showed improvement with increasing silver NPs content. The fixedness of the silver NPs obtained on PU nanofibers was examined by harsh successive washing of the as-prepared mats using a large amount of water. The results confirmed the good stability of the synthesized nanofiber mats. Two model organisms, E. coli and S. typhimurium, were used to check the antimicrobial influence of these nanofiber mats. Subsequently, antimicrobial tests indicated that the prepared nanofibers have a high bactericidal effect. Accordingly, these results highlight the potential use of these nanofiber mats as antimicrobial agents.

• Journal of The Korean Society of Agricultural Engineers
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• v.53 no.2
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• pp.67-74
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• 2011

This research focused on the investigation of runoff and nonpoint sources (NPS) pollution characteristics from small soil box plots treated by livestock waste composts. An indoor rainfall simulation was performed over the plots for 60 minutes. Simulated rainfall intensities were 32.4, 43.2, 50.3 and 57.1 mm/hr respectively. Slope of soil box plots was $10^{\circ}$ and $20^{\circ}$, respectively. Rainfall simulation replicated 5 times and the experiment was conducted every four days five times. As the slope of soil box increased, NPS pollution loads increased. And as rainfall intensity was increased from 32.4 to 57.1 mm/hr, NPS pollution loads gradually increased, too. Discharge of NPS pollution loads was the largest in the first simulation and thereafter decreased gradually. Discharged BOD load to the total applied load from $10^{\circ}$ plots, ranged 0.2 to 0.7 %, was 8.4 to 50.0 % lower than slope $20^{\circ}$ plots. When the application rate increased twice, the increase of pollution load was between 1.7~5.7 times. Analysis of Pearson's correlation coefficient showed that organic matter content in pig compost and NPS pollution loads were correlated well. While under liquid compost application, the correlation coefficients between them were not good. It was concluded that application of livestock resources need to consider long-term weather forecast and if necessary, NPS reduction measures must be preceded in order to reduce NPS pollution discharge.

• Journal of Korean Society of Rural Planning
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• v.24 no.4
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• pp.37-46
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• 2018

The nonpoint pollution source (NPS) is irregular in the amount of generated and runoff. About 70% of the water pollution sources in Korea are NPS. Most of the rural areas are small towns with less than 50 families. This is where sewerage supply is poor. This is where the domestic swage of the house flows directly into the small stream. This study investigated the amount and concentration of domestic swage. And investigated NPS for public officials. We have suggested an improvement plan here. Local government officials lack the concept of NPS. Rural residents also do not know about NPS. Therefore, we proposed NPS public relations and education linked to public administration. This is an extension of the national budget and interest. The domestic swage is discharged at about 272 liters per day in a house. We proposed the introduction of small facilities. If the capacity remains, it is suggested to link to cattle shed, pigsty and so on. The BOD, COD, TN, TP, and SS concentrations were all high. This suggested a reduction in concentration in combination with natural water. Finally, NPS facilities were proposed to be put into rural areas. And it was determined that continuous monitoring was necessary. The results of this study were expected to be applied to NPS management.

• Journal of Radiation Industry
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• v.7 no.2_3
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• pp.141-147
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• 2013

The simple and facile radiation technique of the preparation of antibacterial biodegradable polymer films containing silver nanoparticles (Ag NPs) was described. The biodegradable poly(butylene adipate-co-terephthalate) (PBAT) films containing silver trifluoroacetate (Ag TFA) were prepared by a solvent casting method, and then the films were irradiated by electron beams at the various doses ranging from 20 to 200 kGy to form Ag NPs in the biodegradable polymers. The results of UV-vis and FE-SEM/EDX analyses revealed that the Ag NPs were successfully formed in the PBAT matrix during the electron beam irradiation, and their amounts were dependant on the absorbed dose and Ag TFA concentrations. Furthermore, on the basis of the results of the antibacterial test through disk diffusion and colony counting test, the irradiated PBAT/Ag TFA films exhibited the antibacterial property due to the formation of Ag NPs.

• Advances in nano research
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• v.7 no.4
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• pp.233-240
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• 2019

The present research work reports in-vitro anti-cancer activity of biologically synthesized ZnO nanoparticles (ZnO NPs) against human carcinoma cells viz SCC-40, SK-MEL-2 and SCC-29B using Sulforhodamine-B (SRB) Assay. ZnO NPs were synthesized by a unique and novel biological route using Temperature-gradient phenomenon where the extract of combination of Catharanthus roseus (L.) G. Don (C. roseus), Azadirachta indica (A. indica), Ficus religiosa (F. religiosa) and NaOH solution were used as synthesis medium. The morphology of the ZnO NPs was characterized by Transmission Electron Microscopy (TEM). TEM images reveal that particle size of the samples reduces from 76 nm to 53 nm with the increase in reaction temperature and 68 nm to 38 nm with the increase in molar concentration of NaOH respectively. XRD study confirms the presence of elements and reduction in crystallite size with increase in reaction temperature and NaOH concentration. The diffraction peaks show broadening and a slight shift towards lower Bragg angle ($2{\theta}$) which represents the reduction in crystallite size as well as presence of uniform strain. The FTIR spectra of the extract show transmittance peak fingerprint of Zn-O bond and presence of bioactive molecules These NPs exhibit inhibition greater than 50% for SCC-40, SK-MEL-2 and SCC-29B cell lines and more than 50% cell kill for SCC-29B cells at concentrations < $80{\mu}g/ml$. Nanoparticles with smallest size have shown better anti-cancer activity and peculiar cell-selectivity. The combination of extracts of these plants with ZnO NPs can be used in targeted drug delivery as an effective anti-cancer agent, a potential application in cancer treatment.

• Proceedings of the KSR Conference
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• 2008.06a
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• pp.147-150
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• 2008

Changes in land uses at urbanizing areas are causing flooding, increase in NPS pollutants. Thus, Low Impact Development (LID) concept is now being employed in urban planning for sustainable development. Compared with the conventional BMPs, the LID is a new concept in urban planning to minimize the impacts of urbanization for site-specific LID IMPs. The objective of this study is to analyze the efficiency of LID adoption in study watershed in peak rate runoff and runoff volume reduction perspectives. The analysis revealed that the peak rate runoff and runoff volume decreased significantly with the LID adoption. This indicates that the Bimodal tram route with grass installed at the center of the road will contribute reduction in surface runoff and peak rate runoff, and also in NPS pollutant generation from the Bimodal tram route.

• Journal of Korean Society on Water Environment
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• v.31 no.2
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• pp.166-180
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• 2015

Pollutant in watersheds comes from two major sources which are NPS (nonpoint source pollution) and PS (point source pollution). Most of the pollutant can be treated by wastewater treatment plants. However, wastewater treatment plants may not be an appropriate practice to improve water quality for the watersheds with large portion of NPS pollutant and NPS pollution from direct runoff and baseflow has different characteristics. Therefore the practices to improve water quality need to be comprehensive for pollutants by both direct runoff and baseflow. Riparian buffer, one of practices to manage pollutant in watershed, has been applied to reduce pollutant not only from direct runoff but also baseflow. In this study, the scenarios for pollutant reduction by wastewater treat plants and the nitrogen reduction by riparian buffer were simulated using SWAT-REMM to suggest an effective plan for pollutant reduction from baseflow. Riparian buffer provided nitrogen reduction of 0.2~75.0% in YbB watershed and 38.0~47.0% in GbA watershed. The result indicates that riparian buffer is effective to reduce the pollutant especially from baseflow, and it suggested as suitable for the a watershed which WWTP discharge is not capable to reduce enough pollutant.

• Journal of The Korean Society of Agricultural Engineers
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• v.57 no.2
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• pp.27-36
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• 2015

The objective of this paper was to quantitatively analyze the effect of concentrated animal feeding operations (CAFO) NPS pollution on a small watershed water quality. Monitoring was conducted from March to October, 2013. Monthly flow rate and selected water quality at each monitoring site were measured during dry days. Rainy day monitoring also was conducted. Modeling was conducted to evaluate the effect of CAFO NPS pollution on the water quality at the watershed outlet. The highest and mean concentration of selected water quality indices during rainy days were higher than those in dry days in general. The highest TN concentration measured at the CAFP pollution discharge point was 237.831 mg/L. The results revealed that the CAFO NPS pollution sources could be equally blamed for the water quality degradation of the stream. However, the effect of the NPS pollution from CAFOs seemed not to be very influential to the watershed water quality at the outlet. SWAT modeling revealed that the TN load was reduced by 18.95 %, 23.39 % and 30.53 % at the watershed outlet if the TN load at the CAFO NPS pollution discharge point reduced by 20 %, 40 % and 60 %, respectively. It was thought that the natural attenuation processes played an important role. The modeling was based only on the assumption of the load reduction and not verified by the monitored data. Therefore, it was suggested that a long term monitoring studies for the evaluation of the impact of CAFO NPS pollution on the watershed water quality be conducted.

• Bulletin of the Korean Chemical Society
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• v.32 no.2
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• pp.613-619
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• 2011

Colloidal silver nanoparticles (AgNPs) have been commercialized as the typically stabilized form via the addition of a variety of surfactants or polymers. Herein, to examine the effects of stabilizing AgNPs in suspension, we modified the surface of bare AgNPs with four type of surfactants (NaDDBS, SDS, TW80, CTAB) and polymers (PVP, PAA, PAH, CMC). The modified AgNPs was applied to compare suspension stability and nanotoxicity test using Escherichia coli (E. coli) as a model organism. Modification of AgNPs surface using chemical stabilizer may be not related with molecular weight, but chemical structure such as ionic state and functional group of stabilizer. In this study, it is noteworthy that AgNPs modified with a cationic stabilizer (CTAB, PAH) were importantly toxic to E. coli, rather than anionic stabilizers (NaDDBS, SDS). Comparing similar anionic stabilizer, i.e., NaDDBS and SDS, the result showed that lipophilicity of chemical structure can affect on E. coli, because NaDDBS, which contains a lipophilic benzene ring, accelerated the cytotoxicity of AgNPs. Interestingly, none of the stabilizers tested, including biocompatible nonionic stabilizers (i.e., TW80 and cellulose) caused a reduction in AgNP toxicity. This showed that toxicity of AgNPs cannot be reduced using stabilizers.

• Journal of Environmental Science International
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• v.21 no.10
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• pp.1203-1212
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• 2012

Yongsan ward is located at central place connecting south and north ecology axis of seoul. Various environment-friendly Yongsan development could pose positive effects on NPS(non pollutant source) pollutant reductions and water quality improvement at Han-rive because BOD, T-N, and T-P NPS discharges took 90% of total pollutant from this area. In this study, direct runoff and NPS pollutant loads were evaluated before and after development using spatio-tamporal change in CN(curve number) and EMC(event mean concentration) data. It was found that direct runoff value is $23,584,724m^3$, and BOD, T-N and T-P loads are 104,456 kg/year, 111,483 kg/year and 7,500 kg/year under pre-development condition, respectively. Annual runoff, BOD, T-N and T-P reducing rate were 12.9%, 33.3%, 35.6% and 40.7% under integrated post-development condition, respectively. Based on the results obtained in this study, environment-friendly urban development could be achieved at Yongsan area.