• Journal of the Korean Electrochemical Society
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• v.12 no.1
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• pp.75-80
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• 2009

The effect of polyoxometalate monolayers on the electrodeposition of Au nanoparticles (AuNPs) on glassy carbon (GC) surfaces was examined by electrochemical and scanning electron microscope techniques. The presence of $SiMo_{12}O^{4-}_{40}$-layers resulted in average particle sizes of ca. 60 nm, which is larger than AuNPs deposited on bare GC surfaces. AuNPs electrodeposited on $SiMo_{12}O^{4-}_{40}$-modified GC surfaces for 20 s exhibited the best electrocatalytic activity for oxygen reduction. This system exhibited similar or slightly better efficiency for oxygen reduction than a bare Au electrode. Rotating disk electrode experiments were also performed and revealed that the catalytic reduction of oxygen on AuNPs deposited on $SiMo_{12}O^{4-}_{40}$-modified GC electrodes is a two-electron process.

• Journal of Industrial Technology
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• v.29 no.B
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• pp.229-232
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• 2009

We prepared gold nanoparticles (Au NPs) by reduction-oxidation reaction between $HAuCl_4$ and trisodium citrate and measured the size and morphology of Au NPs by TEM for various molar ratios of $HAuCl_4$ to citrate and for various concentrations of $HAuCl_4$. UV-vis spectroscopy was used to characterize the optical properties of Au NPs. Au NPs in the size range from 14.3 nm to 20.3 nm were prepared with monodisperse distribution.

• Journal of The Korean Society of Agricultural Engineers
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• v.53 no.4
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• pp.29-37
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• 2011

Effect of rice straw mat and wood shaves on the reduction of runoff and nonpoint source (NPS) pollution loads from field plots were experimentally studied. Three runoff plots of $5{\times}22$ m in size and 3 % in slope were prepared on a loamy sand field. Each plot was equipped with a flume to measure runoff and collect water samples. Experimental treatments of surface cover were bare, wood shaves (1,000 kg/ha) and rice straw mat cover (3,000 kg/ha). Under radish was cultivation. During the growing season of the radish, three rainfall-runoff events were monitored. Effect of wood shaves and straw mat cover on runoff reduction was 4~30 % and 33~75 % respectively compared to control. The effect on NPS pollution reduction was 36.8 and 64.3 % in BOD, 41.1 and 80.8 % in SS, 34.0 and 56.1 % in TP and 28.0 and 56.6 % in TN respectively. It was analyzed that the reduction of runoff and NPS pollution were mainly contributed by the decrease of rainfall energy impact and flow velocity and the increase of infiltration due to the surface cover materials. Rice straw mat showed very stable soil cover while large portion of wood shaves were lost during heavy storm events. It was concluded that straw mat was an efficient cover material to reduce NPS pollution from upland fields.

• KCID journal
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• v.21 no.1
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• pp.99-108
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• 2014

This study investigated the effects of NPS(non point source) pollution reduction of sediment traps through field experiments. Various sizes of 4 sediment traps were applied in a upland field located in Gunwi and assessed the infiltration and storage effects as well as NPS pollution reduction effects of this technique. The characteristics of deposited soil in the sediment traps were also analyzed including distribution of particle size, soil texture, and chemical properties. The results showed that slightly different composition of soil particle size from each sediment trap with high proportion of 0.15mm and 0.25mm ranges of soil particle diameters, while the loamy sand is the main types of deposited soils in the sediment traps. Decreased NPS pollution were observed from the water quality analysis of the samples taken from the sediment traps. Further research need to be proceeded continuously to improve this technique in order to utilize on upland fields for management of agricultural NPS pollutions.

• Clean Technology
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• v.26 no.4
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• pp.251-256
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• 2020

The biocompatibility and plasmonic properties of Au nanoparticles make them useful for photothermal therapy, drug delivery, imaging, and many other fields. This study demonstrated a novel, facile, economic, and green synthetic method to produce gold nanoparticles. Gold nanoparticles (AuNPs) with spherical and triangular shapes were effectively synthesized using only Schisandra chenesis fruit extract as the capping and reducing agent. The shape of the AuNPs could be engineered simply by adjusting the molar concentration of HAuCl4 in the reaction mixture. The as-synthesized AuNPs were characterized using UV-VIS spectroscopy, transmission electron microscopy (TEM), X-ray diffraction (XRD), dynamic light scattering (DLS), and energy dispersive X-ray analysis (EDXA). This study revealed that by using the HAuCl4 concentration in the AuNP synthesis, the shape and size of the AuNPs could be controlled by the concentration of HAuCl4 and Schisandra chinensis fruit extract as a surfactant. The as-synthesized AuNPs samples had sufficient colloidal stability without noticeable aggregation and showed the predominant growth of the (111) plane of face-centered cubic gold during the crystal growth. The catalytic efficiency of the AuNPs synthesized using Schisandra chenesis fruit extract was examined by monitoring the catalytic reduction of 4-nitrophenol to 4-aminophenol using Ultraviolet-visible spectroscopy (UV-Vis spectroscopy). The synthesized AuNPs showed good catalytic activity to reduce 4-nitrophenol to 4-aminophenol, revealing their practical usefulness.

• Bulletin of the Korean Chemical Society
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• v.33 no.12
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• pp.3987-3992
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• 2012

Silver nanopowders were prepared from silver 2-ethylhexylcarbamate (Ag-EHCB) complexes by simple thermal reduction at $85^{\circ}C$ without any reducing agent in organic solvent. 2-Ethylhexylammonium 2-ethylhexylcarbamate (EHAEHC) was investigated in terms of their abilities to stabilize the silver nanoparticles (Ag-NPs) and its subsequent effects on the preventing aggregation between Ag-NPs. Conditions (concentration of stabilizer and reaction time) used to reduce Ag-EHCB complex were systematically varied to determine their effects on the sizes of Ag-NPs. The formation of the stabilized Ag-NPs were easily monitored by UV-vis spectroscopy and characterized by TGA, TEM, SEM and XRD. When EHAEHC was used as a stabilizer, Ag-NPs of 10-30 nm in diameter were easily obtained in high yield. Silver patterns were obtained from a silver nano-paste by heat treatment at $200^{\circ}C$ in air and were found to have resistivity values of $2.9{\times}10^{-8}\;{\Omega}{\cdot}m$.

• Journal of Korean Society on Water Environment
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• v.28 no.3
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• pp.436-443
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• 2012

This research was focused on the effect of rice straw and rice straw mat on the reduction of upland field non-point source (NPS) pollution discharges. Six experimental plots of $5{\times}22m$ in size and 3% in slope prepared on gravelly sandy loam soil were treated with control, rice straw cover and rice straw mat cover. Radish in Spring growing seasons were cultivated. NPS pollution discharge was monitored and compared with respect to the treatments. The surface cover rate of rice straw and rice straw mat right after the treatments was 64.7% and 73.7%, respectively. Rainfall of the 16 monitored events ranged from 12.8 mm to 538.2 mm. Runoff coefficient of the events was 0.01~0.67 in control plot, 0~0.63 in rice straw plot and 0~0.45 in rice straw mat plot. The reduction of runoff compared to the control plot was 5.4~99.7% in rice straw plot and 32.9~100% in rice straw mat plot. The reduction of NPS pollution load was 52.0% for SS, 28.5% for T-N and 35.2% for T-P in rice straw plot and 79.8% for SS, 68.3% for T-N and 53.3% for T-P in rice straw mat plot. This research revealed that rice straw mat cover on the soil surface could not only increase the crop yield and farmer's income but also reduce the NPS pollution loads significantly.

• Bulletin of the Korean Chemical Society
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• v.34 no.4
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• pp.1195-1198
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• 2013

Nickel hexacyanoferrate supported palladium nanoparticles (Pd-NiHCF NPs) were synthesized and studied for oxygen reduction reactions in direct methanol fuel cell. The NiHCF support was readily synthesized by a comixing of $Ni(OCOCH_3)_2$ and equimolar $K_3[Fe(CN)_6]$ solution into DI water under rigorous stirring. After the preparation of NiHCF support, Pd NPs were loaded on NiHCF via L-ascorbic acid reduction method at $80^{\circ}C$. Pd-NiHCF NPs were electrochemically active for oxygen reduction reaction in 0.1 M $HClO_4$ solution. X-ray absorption near edge structure analysis was conducted to measure the white line intensity of Pd-NiHCF to verify the OH adsorption. As a comparison, carbon supported Pd NPs exhibited same white line intensity. This study provides a general synthetic approach to easily load Pd NPs on porous coordination polymers such as NiHCF and can provide further light to load Pd based alloy NPs on NiHCF framework.

• Explosives and Blasting
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• v.22 no.2
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• pp.13-20
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• 2004

도심지 굴착과 같은 환경적 제약과 사회적 문제가 존재하는 현장에 대하여. 암반제거작업에 있어서 가장 경제적이고 효율적인 발파공법을 적용하기 위해서, 본 연구는 기존의 발파방진기술인 Line Drilling과 Presplitting의 상점을 살리면서, 단점을 보안한 새로운 발파방진 기술인 NPS(New Presplitting)발파법의 효과에 대하여 연구하였다. NPS 발파법의 분석은 안산암과 화강암, 화강편마암의 3종류의 암반을 대상으로 NPS 발파법의 열수를 1열, 2열, 3열, 4열을 적용하여 발파로 인한 진동을 NPS 발파법의 적용전과 후의 발파진동값을 기준으로 NPS 발파법의 전, 후 진동감쇠 효과를 비교하고, 동일 조건을 가정한 경제성을 살펴보았다. 그 결과 NPS 발파법의 3가지 암석에 대한 현장적용 결과 암종에 따른 NPS 발파공법의 진동감쇠효과의 변화보다, NPS 발파법의 적용 pattern에 대한 진동감쇠효과의 변화가 크게 나타났으며 NPS 발파공열이 2열일 때 감쇠범위는 40％∼80％로 가장 효율적으로 나타났으며 3열과 4열의 경우에도 진동감쇠효과는 있으나 그 효율이 크게 향상되지 않을 뿐 아니라 2열에 비하여 경제적으로 불리함을 알 수 있었다. 또한 NPS 발파법은 보안물과의 거리가 가까울수록 더 경제성이 큰 것으로 분석되었다.

• Journal of The Korean Society of Agricultural Engineers
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• v.57 no.2
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• pp.75-83
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• 2015

This study was aimed to estimate the total application cost and utilization of Turf grass VFS application through the field experiment. The experimental plots were constructed in an upland field of Iksan city within the Saemangeum watershed. Turf grass was transplanted at the down-slope edge of the pollution source area in each of the treated plots. Three rainfall events were monitored during the experiment period, and the rainfall-runoff relationships and NPS pollution reduction effects of the VFS systems were assessed. As results, the reduction ratio of runoff volume ranged 14.1~64.0 %, while the NPS pollution reduction ratio ranged 9.8~73.9 % for SS, 24.0~84.2 % for T-N, 31.6~80.9 % for T-P respectively. The total cost of VFS application was estimated by considering purchase cost of Turf grass sods and construction and maintenance costs of VFS system as well as the loss caused by giving up crop cultivation for the area needed to construct the VFS. The total cost of the VFS was estimated to be approximately \3,379,000/ha/year for the first year of application, and this cost could be decreased to \1,899,000/ha/year from the second year as the construction cost of VFS could no longer need to be counted afterwards. Apart from the NPS pollution reduction effects, the possible utilization of VFS was examined by detaching Turf grass within 40 % of VFS area for sale during spring time when the VFS systems fully covered. The benefit of selling the detached Turf grass sods was estimated as \1,260,000/ha/year, and also found that the VFS area successfully recovered by the time of the summer period. This benefit could attract farmers to adopt the VFS technique to manage agricultural NPS pollution.