• 제목/요약/키워드: NOx formation characteristics

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고압 분위기하에 분사된 메탄가스 제트의 자연발화 및 화염전파 특성 해석 (Numerical Analysis for Autoignition Characteristics of Turbulent Gaseous Jets in a High Pressure Environment)

  • Kim, Seong-Ku;Yu, Yong-Wook;Kim, Yong-Mo
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2002년도 제24회 KOSCO SYMPOSIUM 논문집
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    • pp.24-32
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    • 2002
  • The autoignition and subsequent flame propagation of initially nonpremixed turbulent system have been numerically analyzed. The unsteady flamelet modeling based on the RIF (Representative Interactive Flamelet) concept has been employed to account for the influences of turbulence on these essentially transient combustion processes. In this RIF approach, the partially premixed burning, diffusive combustion and formation of pollutants(NOx, soot) can be consistently modeled by utilizing the comprehensive chemical mechanism. To treat the spatially distributed inhomogeneity of scalar dissipation rate, the multiple RIFs are employed in the framework of EPFM(Eulerian Particle Flamelet Model) approach. Computations are made for the various initial conditions of pressure, temperature, and fuel composition. The present turbulent combustion model reasonably well predicts the essential features of autoignition process in the transient gaseous fuel jets injected into high pressure and temperature environment.

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고압 분위기하에 분사된 메탄가스 제트의 자연점화 및 화염전파 특성 해석 (Numerical analysis for Autoignition Characteristics of Turbulent Gaseous Jets in a High Pressure Environment)

  • 김성구;유용욱;김용모
    • 한국자동차공학회논문집
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    • 제10권5호
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    • pp.81-89
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    • 2002
  • The autoignition and subsequent flame propagation of initially nonpremixed turbulent system have been numerically analyzed. The unsteady flamelet modeling based on the RIF (representative interactive flamelet) concept has been employed to account for the influences of turbulence on these essentially transient combustion processes. In this RIF approach, the partially premixed burning, diffusive combustion and formation of pollutants(NOx, soot) can be consistently modeled by utilizing the comprehensive chemical mechanism. To treat the spatially distributed inhomogeneity of scalar dissipation rate, the multiple RIFs are employed in the framework of EPFM(Eulerian particle flamelet model) approach. Computations are made for the various initial conditions of pressure, temperature, and fuel composition. The present turbulent combustion model reasonably well predicts the essential features of autoignition process in the transient gaseous fuel jets injected into high pressure and temperature environment.

백금 촉매에 의해 안정화된 메탄의 연소 특성 (Catalytically Stabilized Combustion Characteristics of Methane on Platinum Catalyst)

  • 황철홍;정영식;이창언
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2000년도 제20회 KOSCO SYMPOSIUM 논문집
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    • pp.152-161
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    • 2000
  • The catalytically stabilized combustion of $CH_4$-air mixture on platinum catalyst was investigated numerically using a 2-D boundary layer model with detailed heterogeneous and homogeneous chemistries. The actual surface site density of monolith coated with platinum was decided by the comparison with experimental data. The comparisons were made between results for cases where only heterogeneous chemistry was allowed and both heterogeneous and homogeneous chemistries were allowed. It was found that the homogeneous reaction in the monolith had little effect on the change of temperature profile, methane conversion rate and light off location. The contributions of each reactions related with CO formation were discussed on the surface. The effects of operation conditions such as equivalence ratio, temperature, velocity and pressure at the entrance were studied. In thermal combustor, CO and NOx was produced less than 1 ppm at the exit and the production of $N_{2}O$ was more dominant than that of NO.

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자동차용 M-90 스파크 점화기관의 배기가스 정화특성 (Exhaust gas purification characteristics of M-90 fueled SI engine for passenger car)

  • 김재휘;홍영표
    • Journal of Advanced Marine Engineering and Technology
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    • 제20권4호
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    • pp.43-49
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    • 1996
  • With the recent interest in methanol as a SI engine fuel, aldehyde emissions have become a greater concern. A M-90 fueled passenger car was operated in a chassis dynamometer using FTP 75 driving cycle to examine formaldehyde emissions. Formation process of aldehyde and methods to reduce them are discussed in this paper for a SI-engine passenger car operating by M-90. Aldehyde emissions have been found to be 3 to 7 times higher from M-90 than from gasoline, while CO, NOx, THC are as low or lower than gasoline. Noble metal compositions appeared to play a role in formaldehyde and unburned methanol emission performance. For example, catalyst Pd showed better reduction of both formaldehyde and methanol than catalyst Pt. however, emission rates of formaldehyde and methanol for catalyst Pt were relatively similar to catalyst Pt/Rh.

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반응물 분사조건에 따른 무화염 연소특성 연구 (Combustion Characteristics of Flameless Combustion by Reactants Injection Conditions)

  • 홍성원;이필형;황상순
    • 한국연소학회지
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    • 제18권2호
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    • pp.8-16
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    • 2013
  • The flameless combustion has been considered as one of the promising combustion technology for high thermal efficiency, reducing NOx and CO emissions. In this paper, the effect of air and fuel injection condition on formation of flameless combustion was analyzed using three dimensional numerical simulation. The results show that the high temperature region and the average temperature was decreased due to increase of recirculation ratio when air velocity is increased. The average temperature was also affected by entrainment length. Generally mixing effect was enhanced at low entrainment length and dilution was dominated at high entrainment length. This entrainment length was greatly affected by air and fuel injection velocity and distance between air and fuel. It is also found that the recirculation ratio and dilution effect were generally increased by entrainment length and the recirculation ratio, mixing and dilution effect are the significant factor for design of flameless combustion system.

EXPERIMENTAL STUDY ON THE STRATIFIED COMBUSTION CHARACTERISTICS ACCORDING TO COMPRESSION RATIO AND INTAKE TEMPERATURE IN A DIG ENGINE

  • Lee, C.H.;Lee, K.H.
    • International Journal of Automotive Technology
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    • 제7권6호
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    • pp.675-680
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    • 2006
  • In the direct injected gasoline engine, atomized spray is desired to achieve efficient mixture formation needed to good engine performance because the injection process leaves little time for the evaporation of fuels. Therefore, substantial understanding of global spray structure and quantitative characteristics of spray are decisive technology to optimize combustion system of a GDI engine. The combustion and emission characteristics of gasoline-fueled stratified-charge compression ignition(SCCI) engine according to intake temperature and compression ratio was examined. The fuel was injected directly to the cylinder under the high temperature condition resulting from heating the intake port. With this injection strategy, the SCCI combustion region was expanded dramatically without any increase in NOx emissions, which were seen in the case of compression stroke injection. Injection timing during the intake temperature was found to be an important parameter that affects the SCCI region width. The mixture stratification and the fuel reformation can be utilized to reduce the required intake temperature for suitable SCCI combustion under each set of engine speed and compression ratio conditions.

부산지역 광화학 오존 생성 regime 분석 - 수도권과 비교연구 (Ⅳ) (Analysis of Photochemical Ozone Formation Regime in Busan - Comparative Study on Busan vs. Seoul Metropolitan Area(Ⅳ))

  • 백승희;이효정;김철희
    • 한국환경과학회지
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    • 제32권5호
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    • pp.285-301
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    • 2023
  • This study analyzed characteristics of ozone (O3) formation regimes in Busan over a period of recent five years (2015~2019) and compared the findings with those obtained in Seoul. We employed four observed variations: early morning commuting-hour (i.e., 06:00-09:00 LST) nitrogen dioxide (NO2), peak-hour (i.e., 12:00-16:00 LST) O3, 8-hour average O3 (MDA8 O3), and △O3 (=O3_max- O3_min) in Busan and Seoul. In addition, the NO2-O3 relation was assessed to interpret which of NOx-limited or volatile organic compound (VOC)-limited was dominant. In Busan, the annual mean O3 concentration was relatively higher than in Seoul, whereas there were fewer high-concentration days. The Pearson correlation coefficients (R) between Early morning-hour NO2 and the Peak-hour O3 was positive (but close to zero) in Busan and negative in Seoul. Likewise, the R between the Early morning-hour NO2 and the △O3 showed a relatively considerable positive correlation (R=+0.4~0.5)(R=+0.4~0.5) in Busan, while a weak positive correlation (R=+0.1~0.2) in Seoul. From this result, it can be inferred that the O3 formation regime in Busan was intrepreted to be nearly neutral or relatively closer to the NOx-limited regime than Seoul, while Seoul to the VOC-limited regime. The study findings imply that O3 control strategies should be applied differently in Busan and Seoul. The results here were inferred from surface NO2 and O3 observations, and the varification studies based on in-situ VOCs measurements would be needed.

MILD 연소로에서 노즐의 위치와 유동 조건에 따른 유입량 특성에 관한 연구 (A Study on the Flow Entrainment Characteristics of a Coaxial Nozzle Used in a MILD Combustor with the Change of Nozzle Position and Flow Condition)

  • 심성훈;하지수
    • 대한환경공학회지
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    • 제34권2호
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    • pp.103-108
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    • 2012
  • 연소과정 중에 발생하는 질소산화물을 저감하는 기술인 MILD 연소로는 연소용 공기 및 연료로 고온의 배기가스가 유입되는 양에 따라 질소산화물 저감 특성이 많은 영향을 받는다. 일반적인 MILD 연소로는 연료와 연소용 공기는 수직 상향방향이고 배기가스는 수직하향 방향으로 흐르면서 배기가스가 유입되는데 이러한 형태보다 더욱 배기가스의 유입량을 증가시키기 위한 방법으로 동심원관형태의 MILD 연소로를 사용하고 있다. 본 연구에서는 바깥 원통의 배기가스 통로에서 안쪽 원통의 연소통로 사이에 연결관을 설치하고 배기가스를 유입하기 위한 공기노즐을 동심원관 형태로 설치하여 공기분사속도, 노즐 직경, 배기가스측 압력과 연소로측 압력 차이의 변화에 따른 유입량 특성을 수치해석을 통해 살펴봄으로써 MILD 연소로에서 더욱 적극적인 배기가스의 유입량 특성을 파악하는 것을 연구하였다. 공기노즐 분사속도의 증가에 따라 유입량은 속도의 제곱근에 비례하는 것을 알았고 배기가스 측과 연소로 측의 압력차의 크기에 선형적으로 감소하는 것을 관찰하였다. 공기노즐 출구 위치의 변화는 유입량 변화에 큰 영향이 없음을 알 수 있었다.

압축착화 엔진에서 함산소 혼합연료의 연소 및 미세입자 배출물 특성 (Combustion and Nano-particulate Emissions Characteristics of a Compression Ignition Engine Fueled with Oxygenated Blending Fuel)

  • 차준표;윤승현;전문수;이창식
    • 한국자동차공학회논문집
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    • 제17권5호
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    • pp.61-66
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    • 2009
  • An experimental investigation was conducted to analyze the effects of biodiesel-ethanol and biodiesel-diesel blended fuels on the characteristics of combustion and exhaust emissions, and size distributions of particulate matter in a single cylinder diesel engine. The three types of test fuel were biodiesel and two blended fuels which were added ethanol and diesel by 20 % volume based fraction into biodiesel, respectively. In this study, the injection rate, combustion pressure, exhaust emissions and size distributions of particulate matter were measured under various injection timings and injection pressures. The experimental results show that biodiesel-ethanol blended fuel has lengthened ignition delay and low combustion pressure in comparison with those of biodiesel and biodiesel-diesel blended fuel even if all fuels indicated similar trends of injection rate under equal injection pressures. In addition, the ethanol blended fuel significantly reduced nitrogen oxidies (NOx) and soot emissions. And then the size distribution of particulate matters shows that blended fuels restrain the formation of particles which were beyond the range of 150nm comparison with biodiesel fuel.

산화제 제어 확산화염의 화염구조 및 NO 생성 특성에 관한 수치해석적 연구 (Numerical Study on Flame Structure and NO Formation Characteristics in Oxidizer-Controlled Diffusion Flames)

  • 이창언;한지웅
    • 대한기계학회논문집B
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    • 제26권5호
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    • pp.742-749
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    • 2002
  • Numerical Study with detailed chemistry has been conducted to investigate the flame structure and NOx formation characteristics in oxygen -enhanced(CH$_4$/O$_2$-$N_2$) and oxygen-enhanced-EGR(CH$_4$/O$_2$-$CO_2$) counter diffusion flame with various strain rates. A small amount of $N_2$is included in oxygen-enhanced-EGR combustion, in order to consider the inevitable $N_2$contamination by $O_2$production process or air infiltration. The results are as follows : In CH$_4$/O$_2$-$CO_2$flame it is very important to adopt a radiation effect precisely because the effect of radiation changes flame structure significantly. In CH$_4$/O$_2$-$N_2$flame special strategy to minimize NO emission is needed because it is very sensitive to a small amount of $N_2$. Special attention is needed on CO emission by flame quenching, because of increased CO concentration. Spatial NO production rate of oxygen-enhanced combustion is different from that of air and oxygen-enhanced-EGR combustion in that thermal mechanism plays a role of destruction as well as production. In case CH$_4$/O$_2$-$CO_2$flame contains more than 40% $CO_2$it is possible to maintain the same EINO as that of CH$_4$/Air flame with accomplishing higher temperature than that of CH$_4$/Air flame. EINO decreases with increasing strain rate, and those effects are augmented in CH$_4$/O$_2$flame.