• 제목/요약/키워드: NOx Emission Factor

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서울지역 대형연소시설에서의 질소산화물 배출계수 산정 (The Evaluation of NOx Emission Factor from Large Combustion Facilities in Seoul)

  • 조기찬;최종욱;박후경;유병태
    • 환경위생공학
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    • 제15권4호
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    • pp.78-83
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    • 2000
  • The emission factor of nitrogen oxides(NOx) was evaluate to clarify the characteristics of NOx emitted from seven large combustion facilities in seoul area. The emission factors of NOx at A-1 and A-2 facilities of internal combustion engine were 66.957kgNOx/ton and 20.913kgNOx/ton, respectively. The emission factor of A-1 facility was higher than that of A-2 facility even same internal combustion engine, because A-1 facility adopted SCR(selective catalystic reactor) for reduction of NOx emission factor of A-2, A-4, and A-7 power generation boiler facilities were 4.300kgNOx/ton, 2.460kgNOx/ton and 1.796kgNOx/ton, respectively. The capacity of A-2 facility was about two times than that of A-4 and A-7. These emission factors were lower than those at facilities in other areas of korea, because of using low NOx burner of power generation boiler. The emission factors of NOx at A-3 and A-6 incinerator facilities were 0.147kgNOx/ton and 0.221kgNOx/ton which were lower than other facilities, respectively, because these facilities incinerate municipal solid waste of low heating value and uwe SCR for reducing NOx concentration.

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천연가스 사용 난방 및 산업보일러의 NOx와 CO 배출계수 산정 연구 (A Study on Estimation of NOx and CO Emission Factor from Industrial and Commercial LNG Boilers)

  • 장영기;최상진;김관;송기봉;김호정;정봉진
    • 한국대기환경학회지
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    • 제20권5호
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    • pp.615-623
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    • 2004
  • This study was conducted for developing the emission factors of nitrogen oxide(NOx) and carbon monoxide (CO) from the combustion boilers burning liquefied natural gas (LNG). These emission factors were compared with those of U.S. EPA and European Environment Agency (EEA). NOx and CO concentration in the flow gas were measured using Kane-May, KM9106 and Thermo Environmental Instruments Inc., 42C-HL. Measurement were conducted at thirty industrial and commercial LNG boilers. Emission factors were calculated on the basis of fuel consumption (kg-pollutant/㎥-fuel burned). NOx concentration at industrial boiler was 14~125 ppm and it was measured as 35~125 ppm at commercial boiler. NOx emission factors of industrial boiler and commercial boiler were 1.84kg/$m^3$ and 2.09kg/$m^3$, respectively. NOx emission factor of commercial boiler was higher than that of industrial boiler. The NOx emission factors estimated in this study were lower than those of U.S. EPA and higher than those of EEA. Average CO emission factor of industrial boiler was 0.65 kg/$m^3$ and at commercial boiler it was 0.70kg/$m^3$, CO emission factor at industrial boiler was lower than that at commercial boiler.

서울지역 대형연소시설에서의 질소산화물 제거효율과 배출계수 산정 (Evaluation of NOx Reduction Efficiency and Emission Factor from Large Combustion Facilities in Seoul)

  • 신진호;오석률;김정영;전재식;신정식
    • 환경위생공학
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    • 제18권2호
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    • pp.27-33
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    • 2003
  • This survey was performed to investigate the NOx emission factors at 3 Municipal Solid Waste Incinerators(MSWI) and 5 Power generation boilers in Seoul. The NOx concentrations were measured before and after control systems. The results were as follows. 1) The NOx reduction efficiencies of Selective Catalytic Reduction (SCR) using ammonia as reducing agent ranged from 53.7% to 89.9%. The NOx reduction efficiencies of SCR using methanol as reducing agent, Non- Selective Catalytic Reduction (NSCR) using ethanol as reducing agent and low-NOx burner were 20.8%, 29.1% and 24.7%, respectively. 2) The NOx emission factors at A-1, A-2 and A-3 facilities of MSWI were 0.786, 0.127 and 0.594 kg Nox/ton fuel, respectively. The factors of A-1 and A-3 facilities were higher than the average value of Korea. 3) The NOx emission factors at B-1, B-2, B-3, B-4 and B-5 facilities of Power generation boiler were 2.109, 0.726, 4.106, 8.378 and 5.168 kg Nox/ton fuel, respectively. The factors of B-4 and B-5 facilities were higher than the average value of Korea.

선박엔진의 NOx 배출량 산정 (Estimation of Exhaust NOx Emission for Marine Engines)

  • 김대식;엄명도
    • Journal of Advanced Marine Engineering and Technology
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    • 제24권4호
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    • pp.441-445
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    • 2000
  • Considering international status of our country as world class ship builder and geographical characteristics encircled by sea in three facets, controlling of air pollutants emission from marine engines becomes more and more important issue in recent days. Implementation of immediate pollutants emission control regulation and standardization of test and certification procedure are required to reduce air pollution from marine engines. But cost increments due to additional equipment of emission control device and development and certification test expenses as well as depreciation of fuel economy should be considered. To satisfy those air pollution reduction and economic requirements, we should make our own interpretation of IMO standard and implementation schedule depending on our country's status. For this purpose we measured NOx emission from small and middle class marine engines to calculate emission factor and total pollutant emission in our country. With the comparison and analysis of other countries emission control regulation we proposed basic data of total emission from marine engine and future emission control standard in our country. According to our estimation, 62% of total NOx emission of marine engines comes from fishing boat and 38% from commercial vessels. The portion of NOx emission from marine engine is 18.6% of whole country NOx emission. Due to the voyage characteristics of middle and large vessel and necessity of international harmonization of marine engine pollutants emission control standard, it is inevitable to adopt IMO standard for middle and large marine engines. But considering technological and cost effect of fishing boat operating in near sea, it is resonable to set a standard within 80% of measured value at the moment and gradually implement the same IMO standard in near future.

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A Study on the Enhancement of Inventories for Precursors (NOx, SOx) Released from Open Burning of Agricultural Waste Vinyl Causing the Secondary Generation of Particulate Matters

  • Kim, Tae-Han;Choi, Boo-Hun
    • 인간식물환경학회지
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    • 제24권2호
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    • pp.195-207
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    • 2021
  • Background and objective: While response measures to particulate matters in rural areas are limited due to poor inventory record keeping in the agricultural sector, it is necessary to control agricultural waste vinyl and the emission of precursors released from open burning and the secondary generation of particulate matters. Currently, the open burning emission calculation method uses the definition prescribed in CAPSS by the National Institute of Environmental Research. Methods: This study presented an open burning emission calculation formula for agricultural waste vinyl, which is included as agricultural waste. As for activity data, the open burning ratio of agricultural waste vinyl, and the annual incineration volume provided in the Status Survey by the Ministry of Agriculture, Food, and Rural Affairs were applied. The emission factor was generated through incineration tests on three agricultural plastic film samples collected by the Korea Environment Corporation. Results: Among precursors, SOx and NOx were selected and their emission features were monitored with incineration experiment infrastructure based on the EPA 5G method. The highest emission concentration by agricultural waste type was concentrated in the first and second quarters. As for emission factor of SO2, it was calculated at 98.25 g/kg for mulching-use LDPE, 52.31 g/kg for greenhouse-use LDPE, and 14.40 g/kg for HDPE. As for NOx, it was calculated at 18.21 g/kg for mulching-use LDPE, 16.49 g/kg for greenhouse-use LDPE, and 10.67 g/kg for HDPE. Conclusion: This test confirmed the incineration features of PE-based plastics, ascertained the SOx emission factor that had not been included in open burning in the past, and established that low NOx emission concentration is interfered by soil mixed with livestock excretions. The findings from this study are expected to contribute to improving the system for controlling air pollutants in rural environments.

공기 다단공급식 미분탄 버너의 NOx 저감 특성 (NOx Reduction Characteristics of Air Staging Burner for Pulverized-coal Combustion)

  • 박주식;김성완;최상일
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2001년도 제23회 KOSCO SYMPOSIUM 논문집
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    • pp.153-160
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    • 2001
  • The combustion test used DTF was performed to obtain the characteristics of NOx emission and reduction. In this test, major factor of NOx emission was a stoichiometric air ratio. At the onset of combustion to be rich oxygen, NOx was produced rapidly. Optimum condition for NOx reduction was formed under about AR:0.7 in the combustion test of Alaska coal. Investigations were undertaken with 200KW(th) test combustor. In combustion test, the major variables were coal feed ratio of center/outer, stoichiometric air ratio at the onset of combustion. The lowest NOx emission, 182ppm(6% O2 base), was achieved at about AR:0.6 of the first combustion stage with low NOx burner. Also, unburned carbon content of char collected in this combustion condition was about 1wt%.

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철도디젤차량에서 배출되는 오염물질의 배출량 산정방법 개발 (Development of Estimation Methods of Pollutant Emissions from Railroad Diesel Rolling Stocks)

  • 박덕신;김동술
    • 한국대기환경학회지
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    • 제20권4호
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    • pp.539-553
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    • 2004
  • Up to the present time, many methods to estimate emissions from a particular diesel engines have wholly depended on the quantity of diesel fuel consumed. Then, the recommended emission factors were normalized by fuel consumption, and further total activity was estimated by the total fuel consumed. One of main purposes in the study is newly to develop emission factors for the railroad diesel rolling stock (RDRS) and to estimate a total amount of major gaseous pollutants from the RDRS in Korea. Prior to develop a Korean mode emission factor. the emission factor from the USEPA was simply applied for comparative studies. When applying the USEPA emission factors, total exhaust emissions from the RDRS in Korea were estimated by 28,117tons of NOx, 2,832.3tons of CO, and 1,237.5tons of HC, etc in 2001. In this study, a emission factor for the RDRS, so called the KoRail mode (the Korean Railroad mode) has been developed on the basis of analyzing the driving pattern of the Gyeongbu-Line especially for the line-haul mode. Explicitly to make the site specific emission factors, many uncertainty problems concerning weighting factors for each power mode, limited emission test, incomplete data for RDRS, and other important input parameters were extensively examined. Total exhaust emissions by KoRail mode in Korea were estimated by 10,960tons of NOx, and 4,622tons of CO, and so on in the year of 2001. The emissions estimated by the USEPA mode were 2.6 times higher for NOx, and 1.6 times lower for CO than those by the KoRail mode. As a conclusion, based on the emission calculated from both the USEPA mode and the KoRail mode, the RDRS is considered as one of the significant mobile sources for major gaseous pollutants and thus management plans an(1 control strategies for the RDRS must be established to improve air quality near future in Korea.

직접분사식 소형 디젤엔진의 배기배출물에 대한 인자분석적 고찰 (Factor Analysis on Exhaust Gas Emissions of Small DI Diesel Engine)

  • 장세호;김영식
    • 수산해양교육연구
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    • 제29권2호
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    • pp.586-592
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    • 2017
  • This study analyzed the effect of four control factors, RPM, load, EGR rate and cooling water temperature on the exhaust emissions of the small DI diesel engine. The amount of NOx and smoke emissions were measured through experiments for three levels of four control factors according to orthogonal array table, and the effect of four factors on NOx and smoke emissions was analyzed quantitatively. The main results obtained in this study are summarized as follows: 1. RPM, load and EGR rate have a great influence on NOx and smoke emissions, and the effect of cooling water temperature is negligible. 2. As RPM and load increases NOx emission increases and decreases sharply as the EGR rate increases. 3. Smoke emission decreases or increases randomly according to RPM and load, but increases sharply in proportion to the EGR rate. 4. EGR rate has the greatest effect on NOx and smoke emissions by more than 60% of contribution to variance, especially in the case of NOx emission, EGR rate represents a significant result even under the confidence level of 99% on ANOVA.

自動車에 의한 汚染物質 排出係數 및 排出量 算定에 관한 硏究 (Estimation of Emission Factor and Air Pollutant Emissions by Motor Vehicles)

  • 趙康來;金良均;董宗仁;嚴明道
    • 한국대기환경학회지
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    • 제3권1호
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    • pp.55-64
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    • 1987
  • Actual driving pattern of each motor vehicle type was measured and analyzed in Seoul area and vehicle emission rate was measured and traffic data were used to estimate vehicular emission factor and motor vehicle-related air pollutant emission. The analysis of contribution ratio of each vehicle type showed that LPG taxi's took 38.1% of total vehicular CO, gasoline passenger cars 37.5%, therefore, these cars are major sources of CO, gasoline passenger cars took 45.4% of total vehicular HC, motorcycles 25.3%, LPG taxi's 16.2%, so motorcycles can be said to play an important role in HC emission. For NOx, buses and trucks were thought to be major sources as buses took 36.8% and truck 26.4%. Diesel vehicles, on the other hand, took most $SO_2$ and particulate matter emission. Total emission from motor vehicles in Seoul was estimated to be 547 t/day of CO, 68t/day of HC, 163t/day of NOx, 18t/day of $SO_2$ and 19t/day of paticulate matter.

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고형연료제품 사용시설에서의 SNCR의 운전조건에 따른 NOx 배출특성 (NOx Emission Characteristics with Operating Conditions of SNCR in SRF Usage Facilities)

  • 서제우;김영희
    • 청정기술
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    • 제27권4호
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    • pp.350-358
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    • 2021
  • 본 연구결과에서 연소로 내 온도가 848.27 ~ 1,026.80 ℃ 범위로써 평균 976.61 ℃으로 나타났으며, 온도증가에 따라 NOx 농도는 증가하는 경향으로 나타났다. 요소 사용량은 291.00 ~ 693.00 kg d-1로 평균 542.34 kg d-1로 나타났으며, 요소 사용량의 증가에 따라 NOx 농도는 감소하는 경향으로 나타났다. 체류시간이 3.38 ~ 9.17 s로 평균 약 5.22 s로써 설계시 고려한 2 s이내 보다 약 2.61 배 크게 나타났다. 이는 SRF 투입량 허가조건인 1,950 kg h-1 대비 평균 SRF 투입량이 약 55.71%인 1,086 kg h-1로써 연소실 면적은 일정하나 SRF 연소량의 감소에 따라 배가스량 감소에 따른 체류시간이 증가하는 것으로 판단된다. O2/CO 비는 847.05 ~ 14,877.34로 평균 3,111.30으로 나타났고, O2/CO 비 증가에 따라 NOx 농도는 다소 증가하는 경향으로 나타났다. 온도증가와 O2/CO 비의 증가에 공기 중 질소 성분과의 연소반응이 증가하여 NOx 농도가 다소 증가하였으며, 요소 투입량 증가와 체류시간이 증가할수록 배가스의 NOx와의 반응량이 증가하여 처리 후의 NOx 농도는 다소 감소하는 경향으로 나타났다. TMS 자료에 의한 굴뚝 출구에서의 NOx 농도는 7.88 ~ 34.02 ppm으로 평균 19.92 ppm으로써 배출허용기준 60 ppm 이내로 배출되었다. NOx 배출계수는 1.058 ~ 1.795 kg ton-1으로써 평균 1.450 kg ton-1으로 나타났다. 본 연구결과 NOx 배출계수는 기타 고체연료인 최대 배출계수 5.830 kg ton-1 약 24.87%로 나타났으며, 기타 합성수지류와 기타 사업장폐기물의 배출계수인 1.817 kg ton-1, 3.322 kg ton-1 대비 각각 79.80%, 43.65%로 나타났다. 기 유사 연구결과인 NIER 고시(2005-9)의 RDF 배출계수인 1.400 kg ton-1과 유사하게 나타났으며, 최대로 나타난 SRF의 경우인 배출계수 13.210 kg ton-1에 비해 약 10.98%로 나타났다. 따라서 NOx의 배출계수는 편차가 크게 나타났다.