• 대한기계학회논문집B
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• 제35권8호
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• pp.789-798
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• 2011

본 연구에서는 디젤엔진에서 배출되는 질소산화물의 저감을 위한 후처리장치인 LNT(Lean NOx Trap, 흡장형 De-NOx 촉매)의 특성을 파악하였다. 먼저 희박한 배출가스 상태에서의 질소산화물 중 산화질소에 대한 촉매의 기본적인 흡장성능을 알아본 후, 다양한 환원제를 분사하여 인위적으로 배출가스를 농후한 상태를 만들었다. 농후한 상태에서는 희박한 상태에서 촉매 내에 흡장되어 있던 산화질소가 촉매의 환원반응에 의해서 질소로 전환된 후 촉매후단부에서 산화질소 배출농도를 측정하였다. 본 연구에서 사용된 LNT(Lean NOx Trap)시편은 실제 디젤 차량에서 사용되는 LNT 촉매로부터 Reactor에 장착될 수 있도록 작은 사이즈로 절단 및 가공된 후, SUS304의 stainless 재질로 재가공 처리한 후에 Micro bench-flow reactor에 장착하였다. 분사된 피드가스성분들은 실제 배출가스의 분위기를 만들기 위해서 각각 3가지의 가열성분, 비가열 성분으로 나누어 분사된다. 이러한 조건들에서 다양한 반응온도와 공간속도를 반응변수로 하여 LNT(Lean NOx Trap)의 흡장성능과 환원제종류에 따른 산화질소의 배출특성을 파악하였다.

• 한국에너지공학회:학술대회논문집
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• 한국에너지공학회 2006년도 에너지.가스.기후변화학회 연합춘계학술대회 및 특별심포지움
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• pp.412-419
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• 2006

지구온난화의 주원인인 이산화탄소 배출 규제에 대응하기 위한 온실가스 감축 기술개발의 노력이 전 세계적으로 진행되고 있다. 따라서 본 연구에서는 배기가스 중에 $CO_{2}$를 고효율 저비용으로 회수할 수 있는 회수처리기술의 일환으로 효율성과 경제성에 맞추어, 산화제로 공기대신 순산소를 사용하는 $CO_{2}$ 재순환 산소연소 가열로시스템에 관한 실험을 수행하였다. 가재 가열용 연소로 시뮬레이터 및 화염 가변형 버너를 이용하여 $CO_{2}$ 재순환에 따른 로내 온도특성, 압력변화 그리고 배기가스특성을 비교 파악하였다. 실험결과, 배기가스의 대부분은 $CO_{2}$와 $H_{2}O$로 구성되었고, 반복재순환시 배기가스 중의 $H_{2}O$를 응축 분리시켜 고농도($90{\sim}95%$)의 $CO_{2}$를 얻을 수 있었다. 또한 온도를 제어할 수 있는 가능성을 보였고 NOx 배출도 100PPM 이하로 감소시킬 수 있었다.

• Journal of Advanced Marine Engineering and Technology
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• 제30권1호
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• pp.93-101
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• 2006

This research makes a new attempt to apply the activated seawater by electrolysis in the development of two-stage wet scrubber system to control the exhaust gas of large marine diesel engines. First, with using only seawater that is naturally alkaline (pH typically around 8.1). the $SO_2\;and\;SO_3$ are absorbed by relatively high solubility compared to other components of exhaust pollutants, and PM (Particulate Matter) is removed through direct contact with sprayed seawater droplets. Besides, the electrolyzed alkaline seawater by electrolysis, which contains mainly NaOH together with alkali metal ions $(i.e.\;Na^+,\;Mg^{2+},\;Ca^{2+})$, is used as the absorption medium of NOx and $CO_2$. Especially, to increase NOx absorption rate into the alkaline seawater. nitric oxide (NO) is adequately oxidized to nitrogen dioxide $(NO_2)$ in the acidic seawater, which means both volume fractions are adjusted to identical proportion. The results found that the strong acidic seawater was a valid oxidizer from NO to $NO_2$ and the strong alkaline seawater was effective in $CO_2$ absorption In the scrubber test, the SOx reduction of nearly $100\%$ could be achieved and also led to a sufficientPM reduction. Hence, the author believes that applying seawater and its electrolyte would bring the marine air pollution control system to an economical measure. Additionally it is well known that NOx and SOx concentration has a considerable influence on the $N_2O$ emission of green house gas. Although the $N_2O$ concentration exhausted from diesel engines is not as high, the green house gas effect is around 300 times greater than an equivalent volume of $CO_2$. Therefore, we investigated the $N_2O$ removal efficiency with using the electrolyzed seawater too. Finally this research would also plan to treat the effluent by applying electro-dialysis and electro-flotation technique s in the future.

• 환경영향평가
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• 제16권1호
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• pp.1-13
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• 2007

This study was carried out to estimate the emission reduction rates for the regional allowable emissions by special measures to achieve the target air quality in Seoul Metropolitan Area (SMA). A modeling system was designed to validate the details in enforcement regulations set up by local governments based on the current status and plans for air quality improvement. Modeling system was composed of meteorological model (MM5), emission model (SMOKE), and air quality model (CMAQ). Predicted results by this system show quiet well not only daily air pollutants concentration but also the tendencies of wind direction, wind speed and temperature. To achieve the target air quality in Seoul Metropolitan Area (SMA), emission allowances are estimated by seasons and regions. Referring to the base year 2002, it was estimated that emission reduction rates to achieve the intermediate goal in 2007 were 14.2% and 16.6% for NOx and $PM_{10}$, respectively. It was also estimated that 52% of NOx and 48% of $PM_{10}$ reductions from the base year 2002 would be required to accomplish the air quality improvement goal of 22 ppb for $NO_2$, and $40mg/m^3$ for $PM_{10}$ in year 2014. To improve $NO_2$ and $PM_{10}$ concentration through emissions reduction policies, it was found that emissions reduction for the on-road mobile sources would be the most effective in SMA.

• 한국연소학회:학술대회논문집
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• 한국연소학회 제26회 KOSCO SYMPOSIUM 논문집
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• pp.241-246
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• 2003

Numerical simulations are performed at atmospheric pressure in order to understand the effect of additives on flame speed and the NOx formation in freely propagating $H_{2}/O_{2}/N_{2}$ flames with oxygen enrichments. A chemical kinetic mechanism is developed, which involves 26 gas-phase species and 99 reactions. Under several equivalence ratios and oxygen enrichments, flame speeds are calculated and compared with those obtained from the experiments, the results of which is in good agreement. As hydrogen chloride as additive is added into $H_{2}/O_{2}/N_{2}$ flames with low oxygen enrichments, its chemical effect causes the decrease of flame speed, radical concentration, and the NO production rate. It is found that the chemical effect of additive has much more influence on the reduction of EINO than its physical effect. However, in flames with very high flame temperature the physical effect rather than the chemical effect becomes more important on the reduction of EINO.

• 한국분무공학회지
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• 제23권3호
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• pp.128-135
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• 2018

In this study, the following conclusions could be obtained from the analysis of emissions contribution rates and features for contaminated emissions by 13,456 gasoline vehicles passed in the vehicle load test (ASM-idle) under the inspection year 2013 to 2017. It was confirmed that the contamination of the CO, HC, NOx by the displacement is reduced on over 3L engine. As a result of comparing the exhaust gas in the low speed idle mode and the AS2525 mode, the exhaust gas in the low speed idle mode was measured high. It is estimated that if ISG function is applied, emissions from idle condition will be reduced. NOx emissions were reduced when the engine power was above 200HP. It has been confirmed that the amount of exhaust emissions are significantly reduced for vehicles manufactured after 2004. As a result of analyzing the exhaust gas according to the season, it is judged that there is a correlation between HC and NOx according to the ambient temperature. The concentration of exhaust emission in vehicles with high accumulated distance increases, which is considered to be the result of aging of the vehicle.

• 동력기계공학회지
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• 제17권6호
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• pp.130-135
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• 2013

It is a research about the change in reduction efficiency and performance resulting from installation of the EGR cooler, which is the core technology reducing NOx in response to standards been tightened of exhaust controls for off-road vehicle. It can reduce NOx by altering combustion temperature and oxygen concentration by recycling high-temperature exhaust gas. The target engine was large diesel engine for construction machine through by which we were able to verify a rate of change in output and capabilities for a heat-exchange within cooler itself depending on the existence of EGR cooler system. We have acquired a emission reduction technology for a construction machine by testing the reduction performance and rate of change in output.

• 한국자동차공학회논문집
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• 제22권1호
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• pp.157-164
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• 2014

Dual fuel combustion strategy with di-methl ether (DME) and gasoline was tested in a compression ignition engine. Characteristics of combustion and emissions were analyzed with the variation of engine operating parameters such as fuel proportion, DME injection timing, intake oxygen concentration, DME injection pressure and so forth. Gasoline was injected into the intake manifold to form the homogeneous mixture with intake charge and DME was injected directly into the cylinder at the late compression stroke to ignite the homogeneous gasoline-air mixture. Dual fuel combustion strategy was advantageous in achievement of higher thermal efficiency and low NOx emission compared with DME single fuel combustion. Higher thermal efficiency was attributed to the lower heat tranfer loss from the decreased combustion temperature since the amount of lean premixed combustion was increased with the larger amount of gasoline proportion. Lower NOx emissions were also possible by lowering the combustion temperature.

• 한국연소학회지
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• 제12권4호
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• pp.39-46
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• 2007

The technique of $NH_3$ SCR (selective catalytic reduction) assisted by plasma oxidation has been applied to a 2,000 cc diesel engine. The present combined $deNO_x$ process consists of two steps. The first step is that about 50% of emitted NO from the engine is oxidized to $NO_2$ in a plasma oxidation process. The second step is that NO and $NO_2$ are simultaneously reduced to $N_2$ in the $NH_3$ SCR process. The engine test results showed that the $deNO_x$ rates of the present combined process are higher than those of conventional SCR process by 20%. Such a high performance of the combined process is noticeable especially, when the exhaust temperature are relatively low, i.e., $170-220^{\circ}C$. To provide a feasibility of the present technique the effects of operating conditions, such as an electrical input energy, an exhaust gas temperature, an initial NO concentration, and the amount of hydrocarbon addition, were discussed.

• 한국분무공학회지
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• 제8권3호
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• pp.41-48
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• 2003

This work was performed to investigate the distribution of the fuel droplet size around the bluff-body and the combustion characteristics. The bluff-body is used fur the purpose of increasing the combustion efficiency by stabilizing the flame. Diameters of the bluff-body in this experiment are 6, 8, and 10mm and the impingement angles are $30^{\circ},\;60^{\circ}\;and\;90^{\circ}$. The measurement points were at the distances of 20 and 30 mm axially from the nozzle. The geometry of the bluff-body influenced the spray shape and the combustion characteristics. The SMD was acquired by image processing technique (PMAS), and the mean temperatures were measured by thermocouple. In the condition of ${\theta}=60^{\circ}$, the values of SMD are not greatly varied compared to the other conditions. As the angle of bluff-body was increased, the high temperature region was wider along radial direction. When the air-fuel ratio was larger than 5.2, the NOx concentration was decreased, and an increase in the diameter of the bluff-body decreased the NOx of emission.