• Transactions of the Korean Society of Mechanical Engineers B
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• v.38 no.12
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• pp.963-969
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• 2014

Four coal sources that had different ash contents were evaluated in a drop tube furnace (DTF). Combustion experiments were conducted by using several sources with different particle sizes and excess air ratios under air-staging conditions to determine the optimized combustion conditions of high-ash coal, with an emphasis on the combustion efficiency and NOx emissions. The results show that the higher ash content results in a large amount of carbon remaining unburned, and that this effect is dominant when the largest particle size is used. Furthermore, the ash content of coal does affect the Char-NOx concentration, which decreases with the particle size. The results of this study suggest that an air-staged system can be useful to reduce the NOx emissions of high-ash coal and that control of the air stoichiometric ratio of the primary combustion zone (SR1) is effective for reducing NOx emissions, especially by considering unburned carbon contents.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.23 no.11
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• pp.1464-1472
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• 1999

Design and operation of $1MW_{th}$ pulverized coal combustion testing facility are described. Also the influence of air staging on NOx emission and burnout of coal flames was investigated in this facility. The test facility consisted of coal feeding system, firing system and flue gas treatment system. A top-fired externally air staging burner was adopted in order to avoid influence of gravity on the coal particles and for easy maintenance. Distribution of temperature and chemical species concentration of coal flames could be measured in vertical pass of furnace. Main fuel was pulverized (83.4% less than $80{\mu}m$) Australian high bituminous coal. From variety of test conditions, overall excess air ratio was selected at 1.2(20% excess air). Tho study showed that increasing the staged air resulted in lower NOx omission, and it was suggested to be more than 40% of the total combustion air for the substantial NOx reduction. Sufficient burnout was not achievable when NOx emission was less than 500ppm. Also, the amount of core air did not influence tho NOx reduction.

• Journal of Environmental Science International
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• v.13 no.6
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• pp.537-542
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• 2004

$V_{2}O_{5}/TiO_{2}$ catalysts promoted with Mn were prepared and tested for selective catalytic reduction of NOx in $NH_3.$ The effects of promoter content, degree of catalyst loading were investigated for NOx activity while changing temperatures, mole ratio, space velocity and $O_2$ concentration. Among the various $V-{2}O_{5}$ catalysts having different metal loadings, $V-{2}O_{5}$(1 wt.%) catalyst showed the highest activity(98%) under wide temperature range of $200-250^{\circ}C.$ When the $V-{2}O_{5}$ catalyst was further modified with 5 wt.% Mn as a promoter, the highest activity(90-47%) was obtained over the low temperature windows of $100-200^{\circ}C.$ From Mn-$V_{2}O_{5}/TiO_{2}$, it was found that by addition of 5 wt.% Mn on $V_{2}O_{5}/TiO_{2}$ catalyst, reduction activity of catalyst was improved, which resulted in the increase of catalytic activity and NOx reduction. According to the results, NOx removal decreased for 10%, but the reaction temperature down to $100^{\circ}C.$

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.15 no.7
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• pp.640-648
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• 2002

This study is to develop electromagnetic-catalyst application plasma reactors for indoor air purification. Nitrogen Oxide(NOx) removal characteristics are measured in the electromagnetic catalyst application plasma reactors with various parameters and the effect of catalyst or/and magnetic field are investigated on the NOx removal. And AC or DC high voltage is applied for corona discharge, flow rates are 150~1500 $\ell/min$ and NO initial concentration is about 10 ppm. $Mn0_2$ and $TiO_2$ catalysts to increase NOx removal rate are used. In the results, NOx removal rate by AC power is about 10 % higher than that by DC power under the experimental condition of 700 $\ell/min$, 5 magnets, $MnO_2$ and $Ti)_2$ catalysts. When magnet is applied to the reactor, NOx removal rate increased. Also, the reactor with $MnO_2$ and $Ti)_2$ catalyst and magnet have the best removal rate.

• Transactions of the Korean Society of Automotive Engineers
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• v.15 no.4
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• pp.54-60
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• 2007

A new method that optimizes a control of hydrocarbon (HC) addition to diesel exhaust gas for HC type DeNOx catalyst system has been developed. These catalysts are called as the HC-DeNOx catalyst in this paper. The system using HC-DeNOx catalyst requires a resonable quantity of hydrocarbons addition in the inlet gas of the catalyst, because the HC concentration in a diesel engine is so low that the HC is not sufficient for NOx conversion. Generally ambient temperature in the exhaust manifold is $250{\sim}350^{\circ}C$, so spray behavior in this case is different from that of any other condions. This research shows spray behavior of injected hydrocarbons in the transparent exhaust manifold.

• Journal of Sensor Science and Technology
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• v.19 no.3
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• pp.176-183
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• 2010

It is considered that the urea injection DeNOx SCR(selective catalytic reduction) system is the only promising method to satisfy the worldwide NOx emission standards. As for the theoretical aspect, reactants of NO and $NO_2$ with $NH_3$ produce $H_2O$, $N_2$ and $O_2$ which do not harm human beings and environmental as well. The realization of maximum NOx conversion (without using a post oxidation catalyst) is only possible with closed loop controlled urea dosing. It means built-in $NH_3$ gas sensor have to be developed for detecting accurate $NH_3$ concentration for the feedback system. Using YSZ(yttria-stabilized zirconia) as a solid state electrolyte and $In_2O_3$ as a sensing material, this paper aims to study dependable $NH_3$ gas sensor for the promising solution of DeNOx technology, which have a reproducible electric output signal, a high sensitivity and fast response.

• Journal of Korean Society of Environmental Engineers
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• v.33 no.5
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• pp.325-331
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• 2011

A numerical analysis of reactive flow in a MILD(Moderate and Intense Low oxygen Dilution) combustor is accomplished to elucidate the characteristics of combustion phenomena in the furnace with the change of fuel and air nozzle position and air mass flow rate. For the case with the fuel nozzle located near center position of combustor, the reaction zone started at the fuel nozzle and had inclined shape toward combustor wall when the air mass flow rate was relatively smaller. On the other hand, the end of reaction zone moved toward center of combustor from combustor wall when the air flow rate was relatively larger. For the case with the air nozzle located near center position of combustor, the reaction zone started at the fuel nozzle and had inclined shape toward combustor wall when the air mass flow rate was relatively small, which was similar as the previous case with smaller air mass flow rate. On the other hand, the end of reaction zone moved toward combustor wall when the air flow rate was relatively larger. The maximum temperature increased as the air mass flow rate increasing for both cases, and the concentration of thermal NOx increased also from the previous reason of temperature characteristics. The concentration of NOx for the case with the air nozzle located near center position of combustor was considerably smaller than that for the case with the fuel nozzle located near center position of combustor. From the present study, the case with the air nozzle located near center position of combustor and theoretical air flow rate was the most effective condition for the NOx reduction and perfect combustion.

• Journal of the Korean Applied Science and Technology
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• v.32 no.2
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• pp.296-301
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• 2015

The experiment was performed for in order to remove NOx which is generated in the Ship's engine. it was performed test in order to remove NOx which is generated in the Ship's engine. It was used as the oxidizing agent sodium chlorite. Use the oxidizer is nitrogen monoxide was oxidized to nitrogen dioxide. and was tested pH adjustment to increase the efficiency of oxidizing. An aqueous solution of sodium hydroxide was used for the nitrogen dioxide absorbent. Low concentration of the solution, it showed a high efficiency. improves the absorption efficiency by add additives.

• Proceedings of the IEEK Conference
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• 1998.10a
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• pp.601-604
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• 1998

NOX detecting gas sensors using TiO2 doped tungsten oxide semiconductor were prepared and their electrical and sensing characteristics have been investigated. In normal air condition, the sensors of WO3, TiO2 doped WO3 show grain boundary heights of 0.34 eV, 0.25 eV, respectively. The grain boundary barrier energy variation was increased by doping TiO2 into large variation of resistance to NOX gases. And doping the TiO2 4 wt.%, the particle size of WO3 polycrystal films showed higher sensitivity and better sorption characteristics to NOX gas than the pure WO3 films material in air at operating temperature of $350^{\circ}C.$ The TiO2 doped WO3 semiconductor gas sensor shows nano-sized particle size and good sensitivity to sub-ppm concentration of NOX.

• 한국연소학회:학술대회논문집
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• 1999.10a
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• pp.201-207
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• 1999

The combustion characteristics for the low NOx 50 kW-class gas turbine combustor have been experimentally investigated. In order to achieve the premixing and the lean burn combustion, the geometries of the primary zone including premixed chamber were modified from conventional combustor. The centerline profiles of CO and NO concentration, and temperature were measured for the premixed combustors with or without dilution holes in the liner. The effects of the pilot fuel injection rate and air dilution on flame stabilization and pollutant (CO, NO) emission are discussed in detail.