• Proceedings of the Korean Society of Marine Engineers Conference
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• 2006.06a
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• pp.21-22
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• 2006

디젤엔진에서 배출되는 배기가스 중의 주요 오염물질 중의 하나인 NOx(질소산화물)는 대부분 고온의 연소 과정에서 발생하고, 발생량은 연소온도에 따라 결정되는 것으로 알려져 있다. 또한 연료의 연소 중에 물이 첨가되면 연소공기의 비열 증가에 의하여 연소온도가 감소하여 NOx 발생량이 급격하게 감소하게 되는데, 연소실에 물을 첨가하는 방법으로는 유화연료, 직접물분사, 흡기가습 등이 있다. 이중 흡기가습은 구조가 간단하면서 NOx 저감효율이 가장 높은 것으로 알려져 있다. 본 연구는 당사 고유모델 중형엔진인 힘센엔진에 흡기가습 기술을 적용하여 연소성능 및 NOx 저감효과 등을 시험하고, 흡기가습 시스템의 상용화 모델 개발을 위한 기초 데이터를 확보하기 위해 수행되었다.

• Journal of the Korean Society for Marine Environment & Energy
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• v.7 no.2
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• pp.57-63
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• 2004

In this paper, the NOx emission and the reduction technologies of NOx emission for domestic marine diesel engine were investigated. At first, the present production status of domestic marine diesel engines was investigated. In the next, the NOx emission of domestic marine diesel engines was investigated. Finally, the present status of a reduction technologies of NOx emission was investigated. From this investigation, It could be founded that the domestic marine diesel engines satisfied the IMO current NOx regulations, however the higher technologies must be studied to prepare the more severe IMO regulations of the near future.

• Korean Chemical Engineering Research
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• v.47 no.1
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• pp.111-118
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• 2009

A hybrid SNCR/SCR plant was designed and manufactured, and experimented on the SNCR process in the first step to investigate the optimum operation conditions of SNCR, with the equivalence ratio of the reducing agent(NSR, 0.5~5.0), reaction temperature($850{\sim}1,100^{\circ}C$), nozzle type(wall nozzle, pipe nozzle), and nozzle position as variables. In the case of wall nozzles, the NOx reduction efficiency rapidly increased to 87% at 2.5 NSR and slowed down after this. Compared to the upward spray from the pipe nozzle, wall nozzles have narrower range of applicable reaction temperature. In the case of pipe nozzles, it rapidly increased to 77% at 1.5 NSR. But the pipe nozzle downward had no NOx reduction efficiency; on the contrary, NOx increased. When the reducing agent was sprayed upward from a pipe nozzle, the NOx reduction efficiency was 50~75% in the range of 0.5~1.5 NSR, and the NOx reduction efficiency was constant without fluctuations even in the change of reaction temperature from 890 to $1,000^{\circ}C$. When 5% urea solution was sprayed upward from the pipe nozzle, 200 ppm NOx decreased to approximately 60 ppm at 1.2 NSR, and the non-reacted $NH_3$ was 50~100 ppm. In this condition, we expect over 90% NOx reduction efficiency without additional supply of $NH_3$ to SCR at the back of SNCR.

• Journal of the Korea Convergence Society
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• v.10 no.4
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• pp.131-138
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• 2019

Diesel engines have important advantages over its gasoline counterpart including high thermal efficiency, high fuel economy and low emissions of CO, HC and $CO_2$. However, NOx reducing is more difficult on diesel engines because of the high $O_2$ concentration in the exhaust, marking general three way catalytic converter ineffective. Two method available technologies for continuous NOx reduction onboard diesel engines are Urea-SCR and LNT. The implementation of the Urea-SCR systems in design engines have made it possible for 2.5l and over engines to meet the tightened NOx emission standard of Euro-6. In this study, we investigate the characteristics of NOx reduction with respect to engine speed, load, types of catalyst and the $NH_3$/NOx ratio and present the conditions which maximize NOx reduction. Also we provide detailed experimental data on Urea-SCR which can be used for the preparation for standards beyond Euro-6.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.40 no.10
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• pp.637-644
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• 2016

The purpose of this study is to understand the characteristics of unburned carbon (UBC) and NOx emissions for pulverized coal when air staging combustion is applied. A two-staged drop tube furnace capable of applying air staging combustion was designed and installed. The combustion of sub-bituminous (Tanito) has been investigated. UBC and the NOx concentration were measured under various temperatures and stoichiometric ratios in unstaged and staged combustion. As a result, UBC decreased and the NOx concentration increased with an increase in stoichiometric ratio and temperature. In particular, the NOx reduction mechanism was activated when the temperature in the fuel rich zone increased. Both UBC and the NOx concentration decreased as the temperature increased in the fuel rich zone. A high NOx reduction effect was obtained, compared to the UBC increase, when the air staging technique was applied.

• Journal of the Korean Applied Science and Technology
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• v.35 no.3
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• pp.876-885
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• 2018

Utilization of spent RHDM(Residue Hydrodemetallation) catalyst as de-NOx SCR(Selective Catalytic Reduction) catalyst was studied by conducting by heptane cleaning and high-temperature roasting for removal of deposited carbon and sulfur. Followed by oxalic acid leaching was carried out for controlling excess vanadium deposited on spent RHDM catalyst in search of appropriate vanadium loadings for the best SCR performance and the leaching conditions are 5~15wt% concentration of oxalic acid and 5min leaching time at $50^{\circ}C$ with the ultra-sonic agitator. De-NOx activities of prepared and commercial SCR catalyst were measured by the atmospheric SCR catalyst performance test unit, their residual content were also carried out by ICP, C&S Analysis and XRF. Acid leaching (AL-10) catalyst showed the highest de-NOx efficiency of all prepared catalysts and the de-NOx efficiency over wash coated catalyst(WC-AL-10) was equivalent to that of commercial SCR catalyst. Therefore the possibility of using as SCR catalyst for each application by adjusting treatment conditions of spent RHDM catalyst was found and further research will be needed in detail for the its commercialization.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2003.05a
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• pp.38-40
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• 2003

본 연구에서 적용한 저 NOx 연소법의 NOx 저감 효과를 비교해 보면 다단 연소법이 지연연소 효과와 국부적인 최고 화염온도 감소, 고온부에서의 산소농도 감소효과 등이 동시에 나타나 저 과잉공기 연소법, 배기가스 재순환법, 이단 연소법 보다 더 큰 NOx 저감효과를 얻을 수 있음을 알 수 있었다. 다만, 총 공급공기 량에 대한 분할 공급공기량의 비가 일정수준 이상으로 커지면 CO 발생량 증가로 효율저하 등의 문제점이 우려되므로 연소상태를 저하시키지 않는 공급비를 산정하는 것이 중요할 것으로 생각된다.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 1999.10a
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• pp.473-474
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• 1999

일반적으로 NOx배출은 연소과정에 의해 강력하게 지배되고 있으며, NOx 저감 기술은 1970년대 후반부터 많은 연구들이 수행되어, 그 이론들이 확립되고 있다. 석탄 연소시스템에서는 공기 다단(air staging, OFA), 연료다단(fuel staging, reburning) 및 배기가스 재순환(FGR) 등이 대표적인 NOx 저감 기술이며 [1∼4], 그 중 배기가스 재순환법은 저산소 배기가스를 연소용 공기에 재혼입시키므로써 NO의 생성속도를 저하시켜 NOx를 저감시키는 기법이다.(중략)

• Korean Chemical Engineering Research
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• v.44 no.5
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• pp.540-546
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• 2006

Effects of organic and inorganic additives on the SNCR reaction of NOx were investigated in a pilot scale flow reactor with a variation of operating parameters. NOx reduction efficiency increased with the increase of a residence time and an initial NOx concentration. NOx reduction reaction by urea solution started to appear about 850 and then reached to maximum value around $970^{\circ}C$. NOx reduction efficiency also increased with the increase of NSR (Normalized Stoichiometric Ratio) up to 2.0. Addition of ethanol and phenol as an organic additives shifted the optimum temperature window to lower region with decreasing the maximum NOx reduction efficiency. This might be due to the side reaction of hydrocarbon in ethanol structure. NaOH addition widened the temperature window and enhanced the NOx reduction efficiency about 10％ due to the chain reaction of NaOH and the reduction of $N_2O$.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2002.11a
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• pp.155-160
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• 2002

연소시 발생하는 오염물질 중 NOx는 심각한 대기오염의 원인이 되는 것으로 알려져 있어, 각종 연소기 등에서 발생하는 NOx 저감을 위한 연구가 중요하게 대두되었다. 특히 확산화염은 예혼합화염 및 부분예혼합화염에 비해 NOx, Soot 등 오염물질이 발생할 가능성은 높으나 화염 안정성이 좋아 산업용 연소기에 많이 이용되고 있어 보다 다양한 NOx 저감 기술의 필요가 요구되고 있다.(중략)