• Title/Summary/Keyword: NO flux

Search Result 669, Processing Time 0.03 seconds

Estimation and Characteristics of Atmospheric Deposition Flux of Polycyclic Aromatic Hydrocarbons (PAHs) into the Masan and Haengam Areas of Korea (마산과 행암 지역으로 유입되는 다환방향족탄화수소(PAHs)의 대기 침적 플럭스 산정과 특성)

  • Lee Su-Jeong;Moon Hyo-Bang;Choi Min-kyu
    • Journal of Environmental Science International
    • /
    • v.15 no.2
    • /
    • pp.121-131
    • /
    • 2006
  • Atmospheric bulk (wet and dry) samples were monthly collected in Masan and Heangam areas of Korea, to assess the deposition flux and seasonal variation of polycyclic aromatic hydrocarbons (PAHs). Deposition fluxes of PAHs in bulk samples were determined using gas chromatography coupled to mass spectrometer detector (GC/MSD). Particle deposition fluxes from Masan and Haengam areas varied from 13 to $87\;g/m^2/year$ and from 5 to $52\;g/m^2/year$, respectively. PAHs deposition fluxes in atmospheric bulk samples in Masan and Haengam areas ranged from 135 to $464\;{\mu}g/m^2/year$ and from 62.2 to $194\;{\mu}g/m^2/year$, respectively. Atmospheric deposition fluxes of particles and PAHs in this study were comparable to or slightly lower values than those from different locations in Korea and other countries. PAHs profiles of atmospheric deposition bulk samples showed slightly different from two sampling areas, however the predominant species of PAHs were similar. Indeno (1,2,3-c,d)pyrene, benzo(g,h,i)perylene, phenanthrene compounds were the most detected PAHs in deposition bulk samples. Carcinogenic PAHs occupied the contribution of approximately $30-40\%$ of the total PAHs deposition fluxes. The non-metric multi-dimensional scaling (MDS) was used, to assess the differentiation of PAHs source between two sampling areas. The result suggests that PAHs contamination sources were different according to the location and season surveyed. There was no an apparent relationship between the PAHs deposition flux against temperature and rainfall amount, even though summer season with the highest temperature and the largest amount of precipitation showed the lowest PAHs deposition flux. Benzo(e)pyrene/benzo(a)pyrene ratio indicated that the photo-degradation process was one of important factors to the seasonal variation of PAHs with the lower deposition fluxes.

Problems of Stator Flux Estimation in DTC of PMSM Drives

  • Kadjoudj, M.;Golea, N.;Benbouzid, M.E.H
    • Journal of Electrical Engineering and Technology
    • /
    • v.2 no.4
    • /
    • pp.468-477
    • /
    • 2007
  • The DTC of voltage source inverter-fed PMSMs is based on hysteresis controllers of torque and flux. It has several advantages, namely, elimination of the mandatory rotor position sensor, less computation time, and rapid torque response. In addition, the stator resistance is the only parameter, which should be known, and no reference frame transformation is required. The DTC theory has achieved great success in the control of induction motors. However, for the control of PMSM drives proposed a few years ago, there are many basic theoretical problems that must be clarified. This paper describes an investigation into the effect of the zero voltage space vectors in the DTC system and points out that if using it rationally, not only can the DTC of the PMSM drive be driven successfully, but torque and flux ripples are reduced and overall performance of the system is improved. The implementation of DTC in PMSM drives is described and the switching tables specific for an interior PMSM are derived. The conventional eight voltage-vector switching table, which is namely used in the DTC of induction motors does not seem to regulate the torque and stator flux in a PMSM well when the motor operates at low speed. Modelling and simulation studies have both revealed that a six voltage-vector switching table is more appropriate for PMSM drives at low speed. In addition, the sources of difficulties, namely, the error in the detection of the initial rotor position, the variation of stator resistance, and the offsets in measurements are analysed and discussed.

Nitrate Flux at the Sediment-Water Interface in the West-Nakdong River Estuary (서낙동강 하구에서 퇴적물과 강물 경계면을 통한 질산염의 플럭스)

  • Lee, Tae-Hee;Lee, Tong-Sup
    • Ocean and Polar Research
    • /
    • v.26 no.4
    • /
    • pp.635-646
    • /
    • 2004
  • Chronic outbreaks of green tide in the Nakdong estuary toll a heavy socioeconomic cost. The paper investigates the influence of sediments on the nitrogen eutrophication, being claimed as the primary cause of green tide. To measure the flux of nitrate at the sediments-water interface, sediment cores were taken in Jan., Mar., May and Sep., 2000 at Noksan located in the West-Nakdong river estuary. The dissolved oxygen was profiled and then the pore water was extracted in situ. Core samples were analyzed for their textural characteristics. Cores were incubated by a novel technique to measure the fluxes of nitrate $(NO_3^-)$ and ammonia $(NH_4^+)$ at the sediment-water interface. The dissolved oxygen was depleted usually within several millimeters in the top sediments. Nitrate started to decrease drastically at the layer where dissolved oxygen was nearly depleted. Nitrate was also exhausted within several centimeters, followed by ammonia build up rapidly. The flux at the sediments-water interface calculated from the pore water concentrations revealed that nitrate was removed from the water column into the sediments. The sediment incubation experiment confirmed the above result. On the other hand ammonia were released from the sediment to the water column. As the incubation went on, however, the nitrate concentration in the overlying water was dropped below that of a top sediment. Then the flux is reversed, i.e., nitrate was released from the sediments to the water column. The implication is that the sediment can supply nitrate to the water column if it falls below a certain level. Thus it is likely that sediments in the eutrophicated river buffers the nitrate concentration in the water column, which leads to a prolonged green tide.

Percutaneous Absorption and Model Membrane Variations of Melatonin in Aqueous-based Propylene Glycol and 2-Hydroxypropyl-$\beta$-cyclodextrin Vehicles

  • Lee, Beom-Jin;Cui, Jing-Hao;Keith A. Parrott;James W.Ayres;Robert L.Sack
    • Archives of Pharmacal Research
    • /
    • v.21 no.5
    • /
    • pp.503-507
    • /
    • 1998
  • Percutaneous absorption and model membrane variations of melationin (MT) in aqueous-based propylene glycol and $2-hydroxypropyl-{\beta}-cyclodextrin $vehicles were investigatted. the excised hairless mouse skin (HMS) and two synthetic ethylene vinyl acetate (EVA) and microporous polyethylene (MPE) were selected as a model membrane. the solubility of MT was determined by phase equilibrium study. the vertical $Franz{\circledR}$ type cell was used for diffusion study. The concentration of MT was determined using reverse phse HPLC system. The MT solubility was the highest in a mixture of PG and $2-HP{\beta}CD$. The percutaneous absorption of MT through excised HMS increased as the solubility increased. However, the permeability coefficient decreased and then slightly increased in mixture of PG and $2-HP{\beta}CD$. On the other hand, both flux and permeability coefficient through EVA membrane decreased as the solubility increased. No MT was detected over 12 h after starting diffusion through MPE membrane. The flux of MT was dependent on the type of membrane selected. Flux of MT was greatest in excised HMS followed by EBA and MPE membrane. Flux of MT through EVA membrane was 5-20 times lower when compared to excised HMS. Interestingly, volumes of donor phase when MPE membrane was used, significantly increased during the study period. the HMS might be applicable to expect plasma concentration of MT in human subjects based on flux and pharmacokinetic parameters as studied previously. the current studies may be applied to deliver MT transdermally using aqueous-based vehicles and to fabricate MT dosage forms.

  • PDF

Surface Treatment of Air Gap Membrane Distillation (AGMD) Condensation Plates: Techniques and Influences on Module Performance

  • Harianto, Rachel Ananda;Aryapratama, Rio;Lee, Seockheon;Jo, Wonjin;Lee, Heon Ju
    • Applied Science and Convergence Technology
    • /
    • v.23 no.5
    • /
    • pp.248-253
    • /
    • 2014
  • Air Gap Membrane Distillation (AGMD) is one of several technologies that can be used to solve problems fresh water availability. AGMD exhibits several advantages, including low conductive heat loss and higher thermal efficiency, due to the presence of an air gap between the membrane and condensation wall. A previous study by Bhardwaj found that the condensation surface properties (materials and contact angle) affected the total collected fresh water in the solar distillation process. However, the process condition differences between solar distillation and AGMD might result in different condensation phenomena. In contrast, N. Miljkovic showed that a hydrophobic surface has higher condensation heat transfer. Moreover, to the best of our knowledge, there is no study that investigates the effect of condensation surface properties in AGMD to overall process performance (i.e. flux and thermal efficiency). Thus, in this study, we treated the AGMD condensation surface to make it hydrophobic or hydrophilic. The condensation surface could be made hydrophilic by immersing and boiling plate in deionized (DI) water, which caused the formation of hydrophilic aluminum hydroxide (AlOOH) nanostructures. Afterwards, the treated plate was coated using hexamethyldisiloxane (HMDSO) through plasma-enhanced chemical vapor deposition (PECVD). The result indicated that condensation surface properties do not affect the permeate flux or thermal efficiency significantly. In general, the permeate flux and thermal efficiency for the treated plates were lower than those of the non-treated plate (pristine). However, at a 1 mm and 3 mm air gap, the treated plate outperformed the non-treated plate (pristine) in terms of permeate flux. Therefore, although surface wettability effect was not significant, it still provided a little influence.

Estimation of Surface Fluxes Using Noah LSM and Assessment of the Applicability in Korean Peninsula (Noah LSM을 이용한 지표 플럭스 산정 및 한반도에서의 적용성 검토)

  • Jang, Ehsun;Moon, Heewon;Hwang, Seok Hwan;Choi, Minha
    • Journal of Wetlands Research
    • /
    • v.15 no.4
    • /
    • pp.509-518
    • /
    • 2013
  • Understanding of the exchange between the water and energy which is happening between the surface and atmosphere is the basic of studying water resources. To study these, lots of researches using Noah Land Surface Model(LSM) are in progress. Noah LSM is based on energy and water balance equation and simulates various hydrological factors. There are diverse researches with Noah LSM are ongoing in overseas, on the other hand not enough study has been done. Especially there is almost no study using uncoupled Noah LSM in Korea. In this study we used data from Korea Flux Tower in Haenam(HFK) and Gwangneung(GDK) as forcing data to simulate the model and compared its result of net radiation, sensible heat flux and latent heat flux with the observation data to assess the applicability of Noah LSM in Korea. Regression coefficients of the comparison results of Noah LSM and observation show good agreement with the value of 0.83~0.99 at Haenam and 0.64~0.99 at Gwangneung which means Noah LSM can be trusted.

Iontophoretic Delivery of Levodopa: Permeation Enhancement by Oleic Acid Microemulsion and Ethanol (Levodopa의 이온토포레시스 경피전달: 올레인산 아이크로에멀젼 및 에탄올의 투과증진)

  • Jung, Shin-Ae;Gwak, Hye-Sun;Chun, In-Koo;Oh, Seaung-Youl
    • Journal of Pharmaceutical Investigation
    • /
    • v.38 no.6
    • /
    • pp.373-380
    • /
    • 2008
  • In order to develop optimal formulation and iontophoresis condition for the transdermal delivery of levodopa, we have evaluated the effect of two permeation enhancers, ethanol and oleic acid in microemulsion, on transdermal delivery of levodopa. In vitro flux studies were performed at $33^{\circ}C$, using side-by-side diffusion cell and full thickness hairless mouse skin. Current density applied was $0.4\;mA/cm^2$ and current was off after 6 hours application. Levodopa was analysed by HPLC at 280 nm. The o/w microemulsions of oleic acid in buffer solution (pH 2.5 & 4.5) were prepared using oleic acid, Tween 80 and ethanol. The existence of microemulsion regions were investigated in pseudo-ternary phase diagrams. Contrary to our expectation, cumulative amount of levodopa transported from microemulsion (pH 2.5) for 10 hours was similar to that from aqueous solution in all delivery methods (passive, anodal and cathodal). When pH of the micro-emulsion was pH 4.5, cumulative amount of levodopa transported for 10 hours increased about 40% (anodal) to 50% (cathodal), when compared to that from aqueous solution. Flux from pH 4.5 microemulsion showed higher value than that from pH 2.5 in all delivery methods. These results seem to indicate that electroosmosis plays more dominant role than electrorepulsion in the flux of levodopa at pH 2.5. The effect of ethanol on iontophoretic flux was studied using pH 2.5 phosphate buffer solution containing 3% or 5% (v/v) ethanol. Flux enhancement was observed in passive and anodal delivery as the concentration of the ethanol increased. Without ethanol, cathodal delivery showed higher flux than anodal delivery. Anodal delivery increased the cumulative amount of levodopa transported 1.6 fold by 5% ethanol after 10 hours. However, in cathodal delivery, no flux enhancement of levodopa was observed during current application and only marginal increase in cumulative amount transported after 10 hours was observed by 5% ethanol. These results seem to be related to the decrease in dielectric constant of the medium and the lipid extraction of the ethanol, which decrease the electroosmotic flow, and thus decrease the flux. Overall, the results provide important insights into the role of electroosmosis and electrorepulsion in the transport of levodopa through skin, and provide some useful informations for optimal formulation for levodopa.

Interactions and Changes between Sapflow Flux, Soil Water Tension, and Soil Moisture Content at the Artificial Forest of Abies holophylla in Gwangneung, Gyeonggido (광릉 전나무인공림에서 수액이동량, 토양수분장력 그리고 토양함수량의 변화와 상호작용)

  • Jun, Jaehong;Kim, Kyongha;Yoo, Jaeyun;Jeong, Yongho;Jeong, Changgi
    • Journal of Korean Society of Forest Science
    • /
    • v.94 no.6
    • /
    • pp.496-503
    • /
    • 2005
  • This study was conducted to investigate the influences of sapflow flux on soil water tensions and soil moisture content at the Abies holophylla plots in Gwangneung, Gyeonggido, from September to October 2004. The Abies holophylla had been planted in 1976 and thinning and pruning were carried out in 1996 and 2004. Sapflow flux was measured by the heat pulse method, and soil water tension was measured by tensiometer at hillslope and streamside. Time domain reflectometry probes (TDR) were positioned horizontally at the depth of 10, 30 and 50 cm to measure soil moisture content. All of data were recorded every 30 minutes with the dataloggers. The sapflow flux responded sensitively to rainfall, so little sapflow was detected in rainy days. The average daily sapflow flux of sample trees was 10.16l, a maximum was 15.09l, and a minimum was 0.0l. The sapflow flux's diurnal changes showed that sapflow flux increased from 9 am and up to 0.74 l/30 min. The highest sapflow flux maintained by 3 pm and decreased almost 0.0 l/30 mm after 7 pm. The average soil water tensions were low ($-141.3cmH_2O$, $-52.9cmH_2O$ and $-134.2cmH_2O$) at hillslope and high ($-6.1cmH_2O$, $-18.0cmH_2O$ and $-3.7cmH_2O$) at streamside. When the soil moisture content decreased after rainfall, the soil water tension at hillslope responded sensitively to the sapflow flux. The soil water tension decreased as the sapflow flux increased during the day time, whereas increased during the night time when the sapflow flux was not detected. On the other hand, there was no significant relationship between soil water tension and sapflow flux at streamside. Soil moisture content at hillslope decreased continuously after rain, and showed a negative correlation to sapflow flux like a soil water tension at hillslope. As considered results above, it was confirmed that the response of soil moisture tension to sapflow flux at hillslope and streamside were different.

Estimation of verticle fluxes of nitrogen compounds in tidal flats of the Keum river estuary (금강하구 갯벌내 질소화합물질의 연직적인 플럭스 평가)

  • Kim Do Hee;Yang Jae Sam
    • Journal of the Korean Society for Marine Environment & Energy
    • /
    • v.3 no.2
    • /
    • pp.3-10
    • /
    • 2000
  • The main purpose of this study were to estimate the benthic fluxes of dissolved inorganic nitrogen (DIN) from the sediment and denitrification rates in tidal flats of the Keum river estuary. Sediment specimens were collected by a core sampler from three stations along the Keum river estuary in April, August and December, 1999. The sediments were composed of 1.18 %, 29.34 % and 69.49 % of gravel and sand, sand and silt, respectively. The mean ignition loss of the sediment was found 6.7 % and its Oxidation Reduction Potential (ORP) was measured -12 mV. The total hydrogen sulfides was determined about 0.26 mg/gㆍdry. The estimated outflux of ammonium was found 11.2 m mole N/m²ㆍday from the sediment, whereas -1.09 m mole N/m²ㆍday of influx was obtained for nitrate and nitrite through the incubation experiment of sediment cores. Total DIN flux was 10.2 m mole N/m²ㆍday outflux from the sediment. From the incubation experiments executed with the flux studies, mean denitrification rate was found 30.6 m mole N₂/m²ㆍday measured by the direct assay of N₂ production technique. On the basis that DIN flux and denitrification rate in sediment of tidal flat of the Keum river estuary are may be effects to control the algal biomass in the coastal environment, it seems inevitable to pay more attention to investigate the flux of DIN and denitrification rate in tidal flat of the Keum river estuary.

  • PDF