• Journal of the Korean Chemical Society
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• v.39 no.11
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• pp.856-862
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• 1995

The tungsten oxo-nitrosyl complexes (n-Bu4N)2[W5O12(NO)2{RC(NH2)NHO}2{RC(NH)NO}2] (R=(CH3)2CH, CH3CH2CH2, CH3SCH2) have been synthesized by the reactions of polyoxotungsten complex (n-Bu4N)2[W6O19] and tungsten dinitrosyl monomeric complex [W(NO)2(acac)(CH3CN)2](BF4) with butylamidoxime derivatives. The prepared complexes have been characterized by elemental analysis, infrared, UV-visible, 1H NMR and 13C NMR spectroscopy. The pentanuclear species was formed by the interaction of the electron-withdrawing {W(NO)2}2+ unit between the two dinuclear tungsten {W2O5}2+ cores. We can estimate to exist large proton interactions viewed from the four doublet in 1H NMR spectrum of (n-Bu4N)2[W5O12(NO)2{(CH3)2CHC(NH2)NHO}2{(CH3)2CHC(NH)NO}2]. We also drew informations of the two different coordination mode and symmetry of the complexes because two ligands appear in 13C NMR spectra instead of four. The {W(NO)2}2+ unit has been cis-form and C2v symmetry in geometric structure.

• Journal of Plant Biotechnology
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• v.50
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• pp.169-175
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• 2023

A plant regeneration system was developed through shoot organogenesis from in vitro leaf explants of Chrysanthemum morifolium 'Ohblang'. The effects of different concentrations of plant growth regulators and AgNO₃ on efficient shoot regeneration and inhibition of browning were evaluated in chrysanthemum. The explants were cultured on MS shoot induction medium supplemented with 12 combination treatments of 6-benzyladenine (BA) 0.5, 1.0 and 2.0 mg/L, and α-naphthaleneacetic acid (NAA) 0.2, 0.5, 1.0 and 2.0 mg/L in darkness for 6 weeks and cultured under a 16/8 h photoperiod for 6 weeks. The highest shoot regeneration was obtained from the explants cultured on the medium with 1.0 mg/L BA and 1.0 mg/L NAA. Based on this result, AgNO₃ was added to a shoot induction medium containing MS salts, vitamins, 1.0 mg/L BA, 1.0 mg/L NAA, 30 g/L sucrose, and 6 g/L agar to reduce browning of chrysanthemum leaf explants. In the control treatment without AgNO₃, leaf explants turned brown at the cut edge; however, browning was not observed in AgNO₃ treatments. Shoot organogenesis was higher at low concentrations of AgNO₃ and decreased with an increase in AgNO₃ concentration. The explants cultured on shoot induction medium (MS salts, vitamins, 1.0 mg/L BA, 1.0 mg/L NAA) with 1 mg/L of AgNO₃ produced the highest shoot regeneration with 2.6 shoots per explants and a browning index of 0.7. When the regenerated shoots were detached from the explants and cultured on MS medium, the shoots were elongated and rooted successfully.

• Journal of Korean Society of Water and Wastewater
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• v.23 no.4
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• pp.439-446
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• 2009

This study was performed to evaluate SND(simultaneous nitrification and denitrification)efficiency, nitrogen removal efficiency and filtration function of non-woven fabric by using submerging MBR packed with granular sulfur covered with non-woven fabric filter. Synthetic wastewater was used as influent wastewater. Concentration of $NH_4{^+}-N$ in influent was maintained about 40 mg/L and the experiment was performed in four phases according to the flow rate. Nitrogen loading rate divided four phases ranging from $0.04 kg\;NH_4{^+}-N/m^3-day$ to $0.16 kg\;NH_4{^+}-N/m^3-day$. As a result, the maximum $NH_4{^+}-N$ removal rate was accomplished at $0.142 kg\;NH_4{^+}-N/m^3-day$ in nitrogen loading of $0.147 kg\;NH_4{^+}-N/m^3-day$. Nitrification efficiency was higher than 95% in all phases. $NO_3{^-}-N$ loading rate was adjusted ranging from $0.22 kg\;NO_3{^-}-N/m^3-day$ to $0.89 kg\;NO_3{^-}-N/m^3-day$. The maximum $NO_3{^-}-N$ removal rate was accomplished up to $0.71 kg\;NO_3{^-}-N/m^3-day$ in $NO_3{^-}-N$ loading of $0.89 kg\;NO_3{^-}-N/m^3-day$. The maximum $NO_3{^-}-N$ removal efficiency was 95% in $NO_3{^-}-N$ loading of $0.22 kg\;NO_3{^-}-N/m^3-day$. T-N removal rate was 90% and concentration of T-N in effluent was 3.7 mg/L in T-N loading rate of $0.039 kg\;NO_3{^-}-N/m^3-day$. In this study, TMP in reactor with and without non-woven fabric filter were observed to define fouling of hollow-fiber membrane module. Reaching time to standard washing pressure(22 cm Hg) of two reactors were 29 days with non-woven fabric But the reactor without non-woven fabric reached standard washing pressure only after 4 days. Accordingly, non-woven fabric was demonstrated the superiority as a filtration ability. With high nitrogen removal rate and decreasing of fouling of membrane, MBR packed with granular sulfur covered with non-woven fabric filter submerging in activated sludge aeration tank can be used as an advanced treatment process.

• Journal of the Korean Society of Food Science and Nutrition
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• v.21 no.1
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• pp.109-116
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• 1992

Kimchi is a very popular traditional fermented vegetable in Korea, however, contaminations of $NO_3$, $NO_2$ and nitrosamines in Kimchi were suspected. In this review, ingredients used in manufacturing Kimchi, kinds of Kimchi, microorganisms involved the fermentation and nutritional values of Kimchi are introduced. The quantitated levels of $NO_3$, $NO_2$ and secondary amines in the ingredients of Kimchi, and the changes of the contents of $NO_3$, $NO_2$ and nitrosamines during Kimchi fermentation were shown. The level of $NO_3$ during Kimchi fermentation reduced greatly, and the content of $NO_2$ was also trace amounts. NDMA is a major nitrosamine found in Kimchi, but the levels were trace or not detected.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2002.11a
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• pp.429-429
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• 2002

This study examines the influence of long-range transport of dust particles and air pollutants on photochemistry of OH and NO$_3$ at Jeju Island (33.17$^{\circ}$ N, 126.10$^{\circ}$ E) during the Asian dust-storm (ADS) period in April 2001. The atmospheric concentrations of criteria pollutants (O$_3$, NO$_2$, CO) and sulfur species were measured at a ground station on Jeju Island, Korea as part of the ACE-Asia intensive operation. Three ADS events were observed during the periods of 10-12, 13-14, and 25-26 April, respectively. The concentrations of the criteria pollutants (i.e., $O_3$, NO$_2$, and SO$_2$) were not significantly different from those during the non-Asian-dust-storm (NADS) period. Average OH and NO$_3$ levels at Jeju Island during the study period (ADS and NADS) were estimated to be 4-10 $\times$ 10$^{5}$ moleculescm$^{-3}$ and 2-4 pptv, respectively. Two main sources of OH radical were the primary production from the reaction of water vapor ($H_2O$) and O(1D) radicals and the reaction of HO$_2$ with NO. CO was a dominant sink of OH during the ADS period: whereas NO$_2$ was the most important during the NADS period. for NO$_3$ radical, a reaction of NO$_2$ with $O_3$ was the most important atmospheric source; while $N_2$O$_{5}$ uptake on dust particles was the most dominant sink during the ADS period.

• Korean Journal of Organic Agriculture
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• v.5 no.1
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• pp.149-165
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• 1996

In order to get some basic datas on environmental friendly funtion against soil and water pollution and safe vegetable production by organic farming, chemical characteristics of soils cultivated by the conventional farming, greengouse cultivation and organic farming and acumulation of NO3--N in chinese cabbage and lettuce were analysed. The highest value of NO3--N in 0-30cm subsoil of organic farming was found among the 3 different farming systems, and it was 3.6 and 6.6 times higher than those of conventional farming in chinese cabbage and lettuce respectively. P2O5 also show high accumulation in the rhizosphere of organic farming compared to convnetional farming. The accumulation of NO3--N and P2O5 in the rhizosphere of organic farming were simial to those of greenhouse cultivation. The NO3- accumulation in chinese cabbage and lettuce by organic farming reach 3224ppm in chinese cabbage and 2543ppm in lettuce and it were 4.7 and 6.4 times higher than those of convnetional farming. It is urgently necessary to introduce the basic standard of IFOAM, EU and FAO/WHO Codex on organic agriculture into korean organic agriculture for operation of environmental friendly system and production of safe vegetable in terms of NO3-.

• Asian Journal of Turfgrass Science
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• v.9 no.3
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• pp.207-212
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• 1995

This experiment was conducted to investigate the effect of the nitrogen fertilization levels on the content of $NH_4^+$-N in soil of 'Suffolk' Kentucky bluegrass and zoysiagrass. The results obtained are summarized as follows : 1.According to the nitrogen fertilization levels, the content of $NH_4^+$-N in soil of Kentucky blue-grass and zoysiagrass was not significantly different. The content of $NH_4^+$-N in soil of Kentucky bluegrass and zoysiagrass was highest in June and December and lowest in March and September. 2.The content of $NH_3^-$-N in soil was increased by increasing the nitrogen fertilization levels in both Kentucky bluegrass and zoysiagrass. However, the deeper the depth of soil the less the content of $NO_3^-$-N in soil. In 40~60cm soil depth, the content of $NO_3^-$-N in soil was lower than 10ppm in average. Even in June, which was the highest month of the content of $NO_3^-$-N in soil, the content of $NO_3^-$-N in soil was not overpassed the degree of 20ppm.

• Journal of The Korean Society of Grassland and Forage Science
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• v.17 no.3
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• pp.223-230
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• 1997

The experiments were undertaken to investigate the dynamics of $NO_3\;^-$ uptake at low temperature with forage rape(Bmssica napus), barle(Hordeum vulgare) and winter rye (Scale cereale). A net $NO_3\;^-$uptake and the contents of nitrogenous compound in tissues at low temperature ($5^{\circ}C$) were compared with normal temperature ($25^{\circ}C$).The net uptake of $NO_3\;^-$ by Brass ica nqus was the highest among three species at both temperature applied. During 9 hours after temperature treatment, $NO_3\;^-$ uptake of Brassica napus, Hordeum vulgm and Scale c e d e grown at $5^{\circ}C$ decreased to about 31, 50 and 27% compared with those grown at $25^{\circ}C$. $NO_3\;^-$ contents in roots were much sensitively affected by low temperature than those of leaves. Comparing with the plants grown at $25^{\circ}C$, $NO_3\;^-$ contents in roots of increased to 48.3, 38.7 and 53.5% repectively, for Brassica napus, Hordeum vulgare and Scale cereale during 9 days. A relatively less changes in the content of $NH_4\;^+$-N were observed according to the temperature treatment. The ontents of amino acids-N in leaves at $5^{\circ}C$ slightly decreased while that of roods remarkably increased compared with $25^{\circ}C$. Protein-N was the largest pool of nitrogen and its contents in leaves and roots showed a similar response on the temperature treatment. These results suggested that $NO_3\;^-$uptake was inhibited at low temperature. The dynamics of $NO_3\;^-$ uptake could be closely related to the increased concentration of $NO_3\;^-$ and amino acids in roots.

• Journal of Korean Society for Atmospheric Environment
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• v.18 no.5
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• pp.337-344
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• 2002

In this study, we analyzed the NO removal efficiency by the pulsed corona discharge process and investigated the effects of several process variables such as initial concentrations of NO, $H_2O$, and NH$_3$, applied voltage, pulse frequency, diameter of the discharge electrode, and residence time. The removal efficiency of NO increased by the addition of $H_2O$ or NH$_3$, but the changes of initial NH$_3$ and $H_2O$ concentrations did not affect the removal efficiency of NO significantly. With the increases of the applied voltage or the residence time, the removal efficiency of NO increased. In addition, with the increases of the pulse frequency of applied voltage, or the diameter of the discharge electrode, the removal efficiency of NO increased. The experimental results can be used as a basis to design the pulsed corona discharge process to remove NO$_{x}$, SO$_{x}$ and VOCs.OCs.

• Journal of Korean Society for Atmospheric Environment
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• v.20 no.3
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• pp.291-302
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• 2004

The CuO/$3AL_2O_3{\cdot}2SiO_2$ catalyst impregnated ceramic candle filters for nitrogen oxides removal were prepared by porous mullite($3AL_2O_3{\cdot}2SiO_2$) support and CuO catalyst deposited on this support to achieve uniformly dispersed CuO deposition, which are impregnated into the pores of available alumino-silicate ceramic candle filter. The CuO/3$AL_2O_3{\cdot}2SiO_2$ catalyst impregnated ceramic candle filters were characterized by XRD, BET, air permeability, pore size, SEM and catalytic tests in the reduction of NOx by NH$_3$. The observed effects of CuO/3$AL_2O_3{\cdot}2SiO_2$ impregnated ceramic candle filters in SCR reaction are as follows : (1) when the content of CuO catalyst increased further, activity of NO increased. (2) NO conversion at first increased with temperature and then decreased at high temperatures (above 40$0^{\circ}C$), possibly due to the occurrence of the ammonia oxidation reaction. (3) In pilot plant test for 3 months, NO conversion was greater than 90%.