• 한국재료학회:학술대회논문집
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• 한국재료학회 2003년도 추계학술발표강연 및 논문개요집
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• pp.132-132
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• 2003

Second-order nonlinear optical(NLO) materials have been extensively studied for applications in photonic devices, such as frequency doubling and electro-optical(EO) modulation, because of their large optical nonlinearity, excellent processibility, low dielectric constant, and high laser damage thresholds. The poling behaviour of NLO chromophore in organic/inorganic matrixes showed the randomization of poled NLO chromophore in the absence of poling Held. The liquid crystal molecules in a droplet showed a long-range orientational order along a director. Therefore, liquid crystal effects on poling behaviour of NLO chromophore dispersed in organically modified inorganic sol-gel materials were investigated. Using sol-gel process for the development of NLO material has received increasing attention, Organically modifked inorganic NLO sol-Eel materials are obtained via incorporation of the organic NLO active chromophore into an alkoxysilane based inorganic network. One of the most important thing in this works was that tetraethoxysilane(TEOS) and methyltrimathoxysilane(HTMS) were used as precursor followed by hydrolysis and condensation without using any acidic catalyst during the process. The NLO chromophores in the liquid crystal nanodomains were well mixed with I/O hybrid matrix, deposited on transparent ITO-coated glasses. The poling behaviour of liquid crystal effects of NLO chromophore dispersed in I/O hybrid matrix were investigated by UV-vis spectroscopy. Size distribution and morphology of the NLO chromophores doped in the liquid crystal nanodomains dispersed in I/O hybrid matrix were investigated by SEM.

• Bulletin of the Korean Chemical Society
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• 제17권1호
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• pp.11-15
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• 1996

A series of poly(1,4-phenylene terephthalates) with pendant NLO chromophores was prepared by the solution polycondensation of 2,5-NLO chromophore substituted terephthalic acid with hydroquinone. The polymers obtained gave satisfactory NMR and elemental analysis results when taking into account their expected structures and the inherent viscosity value proved the polymeric character of all polymers. DSC, optical polarizing microscopy and WAXS studies revealed that none of these polymers exhibited liquid crystalline mesophases. Preliminary results on NLO properties of these polymers showed a surprisingly large second harmonic signal relative to a Y-cut quartz plate.

• 한국전기전자재료학회논문지
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• 제23권6호
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• pp.491-496
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• 2010

The relaxation behavior of aligned electric dipoles in a mixed polymer of P2ANS with P(VDF-TrFE) is studied with optical second harmonic generation (SHG). In this work, a macroscopic noncentrosymmetry of the spin coated film was achieved by an electrical poling. The relaxation of induced polar order of nonlinear optic(NLO) chromophores after poling leads to an insufficient long-term stability of NLO properties. In this work, we develop a new technique to suppress such kind of dipole relaxation in a poled polymer. We found that the poled dipoles in a NLO polymer were effectively immobilized by the internal electric field created by a thermally annealed ferroelectric polymer. The long-term stability in a mixed system of NLO polymer/ferroelectric polymer was successively accomplished by a series of thermal treatments applied to the mixed polymer system at a temperature of $140^{\circ}C$ for at least 1hour after poling.

• 대한전자공학회논문지TC
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• 제45권12호
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• pp.105-113
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• 2008

유비쿼터스 사회에서는 사용자의 요구를 충족시키기 위하여 사용자가 갖고 있는 기기에 대한 정밀한 위치측정을 필요로 한다. 위치 측정은 송수신기간에 신호의 전송을 기반으로 한 거리측정을 통해 이뤄지기 때문에 위치측정의 오차는 거리측정의 오차로부터 발생한다. 신호가 전송되는 기기 간에 장애물이 존재하게 되면 LoS(Line of Sight)신호 성분이 줄어들게 되어 NLoS(Non-Line of Sight) 채널이 발생하게 되고 정확한 시점에서 신호를 검출할 수 없게 되어 거리오차가 발생하게 된다. 일반적인 위치측정 알고리즘은 참조기기(Reference Device)의 거리측정 성능에 관계없이 참조기기와 목표기기(Target Device)간의 거리측정 값을 위치 계산에 그대로 사용하기 때문에 거리측정 값으로부터 발생되는 오차가 위치 계산에 더해지게 된다. 따라서 본 논문에서는 각 참조기기가 속해 있는 채널특성을 판별하고 NLoS채널로부터 계산된 거리와 LoS채널로부터 계산된 거리를 다른 비율로 적용하여 위치측정의 오차를 줄이는 Iterative Calculation 기법을 제안한다. 참조기기는 수신된 신호의 Kurtosis, Mean, Excess Delay, RMS Delay spread를 통해 NLoS와 LoS 채널을 구분한다. 이를 통해 구분된 채널마다 각기 다른 비율로 랜덤 거리를 계산된 거리에 더하여 위치를 계산하는 것을 반복적으로 수행한 뒤 평균값을 계산하여 확률적으로 존재할 가능성이 높은 목표기기의 위치를 찾아감으로써 NLoS채널로부터 계산된 거리오차가 위치측정에 미치는 영향을 줄이는 방법을 제안하고 시뮬레이션을 통해 기존의 방식과 비교했을 때 성능향상을 확인하였다.

• Bulletin of the Korean Chemical Society
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• 제18권2호
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• pp.198-203
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• 1997

Two different carbazolylnitrostilbene chromophores with second-order nonlinear optical (NLO) activity were newly synthesized by the reaction of 9-(2-hydroxyethyl)-9H-carbazol-3-carbaldehyde with 4-nitrophenylacetonitrile or 4-nitrophenylacetic acid. The NLO monomers were obtained by reaction of these chromophores with methacryloyl chloride. The side-chain nonlinear optical polymers were synthesized by the copolymerization of NLO monomer with methylmethacrylate using a free radical initiator. The chemical structures of the polymers were identified by spectroscopic means and the polymer properties such as molecular weight, Tg, solubility, UV-visible absorption, and second-harmonic generation (SHG) coefficients were investigated.

• 한국항해항만학회:학술대회논문집
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• 한국항해항만학회 2021년도 추계학술대회
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• pp.37-38
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• 2021

해상에서의 통신은 파도의 움직임에 의해 내륙에서의 통신에 비해 어려움이 있다. 본 논문에서는 Bretschneider 스펙트럼 모델을 이용하여 Open-Ocean에서의 파도의 움직임을 모델링다. 내륙에 위치한 기지국과 내륙으로부터 일정 거리 떨어진 해상에 위치한 부표와의 해상통신 환경을 고려하였으며, 모델링한 파도의 움직임을 바탕으로 부표부터 기지국까지의 거리에 대한 각도와 기지국부터 Block되어 Non-Line of Site(NLoS)된 지점까지의 거리에 대한 각도를 비교함으로써 Continuous-LoS(CLoS)구간을 확보하기 위해 파고 대비 안테나의 높이를 변경하며 비교했다.

• Bulletin of the Korean Chemical Society
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• 제35권5호
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• pp.1391-1396
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• 2014

In the present study, ten metal free non-linear optical (NLO) compounds have been designed. These compounds have designed by structural modification of (2-cyano-5-(4-(phenyl(4-vinylphenyl)amino)phenyl) penta-2,4-dienoic acid (TC4). Density functional theory was used for structure optimization and determination of photo-physical properties. These compounds contain triphenylamine as electron-donor and cyanoacrylic acid as acceptor. Five ${\pi}$-spacers are used to connect the donor and acceptor. Two auxiliary donors are also used to assist the donor. Results of this study indicate that stronger electron-donating auxiliary groups and longer ${\pi}$-conjugation enhance NLO response. Major absorption peaks of all systems were in the visible region. These absorption peaks are associated with the ${\pi}-{\pi}^*$ transitions of the entire molecule. From calculations it is clear that all system will be good NLO material. The present calculations will provide new ways for experimentalists to synthesize high-performance NLO material.

• 한국고분자학회:학술대회논문집
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• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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• pp.165-165
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• 2006

We prepared nonlinear optical (NLO) polymers possessing thermal and temporal stability, which were based on the polyimides appended with NLO chromophores. NLO chromophores with a terminal hydroxyl group have been synthesized by coupling between aminobenzene or julolidine donor and phenylene bridge, and then subsequent coupling between the resulting product and tricyanofuran acceptor. The chromophores were chemically bonded to the polyimides backbone through Mitsunobu reaction. The NLO polymers showed $160-170^{\circ}C$ of Tgs and were thermally stable up to $200^{\circ}C$. We obtained optical quality films by spincoating and evaluated their electro-optical properties and temporal stability.

• 한국결정성장학회:학술대회논문집
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• 한국결정성장학회 1998년도 PROCEEDINGS OF THE 14TH KACG TECHNICAL MEETING AND THE 5TH KOREA-JAPAN EMGS (ELECTRONIC MATERIALS GROWTH SYMPOSIUM)
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• pp.3-5
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• 1998

The interest in the use of borate crystals in ultraviolet(UV) nonlinear optics(NLO) has increased because all solid-stste UV lasers obtained with NLO are in highly demand. Much effort has been spent on developing borates series, such as{{{{ { beta -BaB }_{2 } {O }_{4 }(BBO), {LiB }_{ 3}{O }_{5 }(LBO)}}}} and{{{{{ CsKiB}_{6 }{O }_{10 }(CLBO)}}}} in this decade. Recently another new borate crystals, {{{{{ YCa}_{4 }O({BO }_{3 })_{3}}}}} and{{{{{Gd }_{x }{Y }_{1-x }{Ca }_{4 }O({BO }_{ 3})({Gd }_{x }{Y }_{1-x }COB)}}}} have been developed by the present authors. Here, the growth and NLO properties of YCOB and {{{{ {Gd }_{ x} {Y }_{ 1-x} }}}}CO B crystal are reported and their properties discussed in relation to those of other nonlinear optical crystals, such as LBO.

• Bulletin of the Korean Chemical Society
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• 제23권7호
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• pp.964-970
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• 2002

We synthesized three kinds of chromophores incorporating aromatic quinoline unit as a $\pi-conjugated$ bridge in order to prepare more thermally stable nonlinear optical (NLO) chromophores than general stilbene unit. The NLO poly(methylmethacrylate) copolymer, polyimides, and polyester were successfully synthesized by these corresponding quinoline-based monomers. Their physical and optical properties were investigated by thermogravimetry, gel permeation chromatography, ultraviolet-visible spectroscopy, second harmonic generation (SHG) and electro-optic (EO) measurement. All the polymers exhibited better thermal stability,however their NLO activity was a little lower than that of general stilbene-based NLO polymers. Among three kinds of polymers, the PMMA copolymer with quinoline chromophores had the largest SHG coefficient d33 value of 27 pm/V (at 1.064 $\mu\textrm{m})$ and EO coefficient r33 value of 6.8 pm/V (at 1.3 $\mu\textrm{m}$).