• Title/Summary/Keyword: NIR reflectance spectroscopy

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Nondestructive determination of humic acid in compost by NIRS

  • Seo, Sang-Hyun;Han, Xiao-Ri;Cho, Rae-Kwang;Park, Woo-Churl
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1623-1623
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    • 2001
  • Composting is a biological method used to transform the organic waste into stable, humified organic amendments. Humification is indicated as the key factor in improving the quality of compost, because of the importance of humic substances to soil ecology, fertility and structure, and their beneficial effects on plant growth The compost constituents vary widely, however, the degree of maturity is very important factor in compost quality. So this experiment carried out to determine the rapid estimation of the quality in cattle, pig, chicken and waste composts using near infrared reflectance spectroscopy(NIRS). Near infrared reflectance spectra of composts was obtained by Infra Alyzer 500 scanning spectrophotometer at 2-nm intervals from 1100 to 2500nm. Multiple linear regression(MLR) or partial least square regression (PLSR) was used to evaluate a NIRS method for the rapid and nondestructive determination of humic acid contents in composts. The results summarized that NIR spectroscopy can be used as a routine testing method to determine quantitatively the humic acid content in the compost samples ondestructively. Especially, we supposed that absorbance around 2300nm is related to humic acid as a factor of compost maturity. However the NIR absorption approach is empirical, it actually requires many combinations of samples and data manipulations to obtain optimal prediction.

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Prediction of Soluble Solids Content of Chestnut using VIS/NIR Spectroscopy

  • Park, Soo Hyun;Lim, Ki Taek;Lee, Hoyoung;Lee, Soo Hee;Noh, Sang Ha
    • Journal of Biosystems Engineering
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    • v.38 no.3
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    • pp.185-191
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    • 2013
  • Purpose: The present study focused on the estimation of soluble solids content (SSC) of chestnut using reflectance and transmittance spectra in range of VIS/NIR. Methods: Four species intact/peeled chestnuts were used for acquisition of spectral data. Transmittance and reflectance spectra were used to develop the best PLS model to estimate SSC of chestnut. Results: The model developed with the transmitted energy spectra of peeled chestnuts rather than intact chestnuts and with range of NIR rather than VIS performed better. The best $R^2$ and RMSEP of cross validation were represented as 0.54 and $1.85^{\circ}Brix$. The results presented that the reflectance spectra of peeled chestnuts by species showed the best performance to predict SSC of chestnut. $R^2$ and RMSEP were 0.55 and $1.67^{\circ}Brix$. Conclusions: All developed models showed RMSEP around $1.44{\sim}2.54^{\circ}Brix$, which is considered not enough to estimate SSC accurately. It was noted that $R^2$ of cross validation that we found were not high. For all that, grading of the fruits in two or three classes of SSC during postharvest handling seems possible with an inexpensive spectrophotometer. Furthermore, the development of estimation of SSC by each chestnut species could be considered in that SSC distribution is clustering in different range by species.

Noninvasive blood glucose monitoring system based on NIR spectroscopy with a contact pressure control device

  • Kang, Na-Roo;Baek, Ju-Hyun;Woo, Young-Ah;Kim, Hyo-Jin
    • Proceedings of the PSK Conference
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    • 2003.10b
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    • pp.67.3-68
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    • 2003
  • The purpose of this study is to improve repeatability of a non-invasive blood glucose measurement. The portable NIR system that was newly integrated by our lab includes a tungsten halogen lamp, a specialized reflectance fiber optic probe and a photo diode array type InGaAs detector, which was developed by a microchip technology based on the lithography. Reflectance NIR spectra of finger tip were recorded by using a fiber optic probe. The probe was fixed in the system and subjects put their finger on the probe head. (omitted)

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ESTIMATION OF SUGAR AND REDUCING SUGAR IN MOLASSES USING NEAR INFRARED REFLECTANCE SPECTROSCOPY

  • Mehrotra, Ranjana;Gupta, Alka;Tewari, Jagdish;Varma, S.P.
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1258-1258
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    • 2001
  • Estimation of sugar and reducing sugar content in molasses is very important task in sugar refineries. Conventional methods of determination of sugar content in molasses samples are highly time consuming and employ hazardous chemicals. Due to the physical properties of molasses, probability of error in conventional analytical techniques is high. These methods have proven to be inefficient for a process control in any sugar industry. Hence development of a rapid, inexpensive, physical and also accurate method for sugar determination in molasses will be highly useful. Near Infrared spectroscopy is being widely used worldwide as an analytical technique in food industry. The technique offers the advantage of being non-destructive and rapid. The present paper highlights the potential of near infrared reflectance spectroscopy as a rapid and automated analytical technique for determination of sugar and reducing sugar content in molasses. A number of molasses samples were collected during and after the sugar season from Havana Sugar Industry, Havana. The samples were chosen so as to obtain a wide range of concentration of sugar and reducing sugars. This was done in order to achieve a good calibration curve with widely spread data points. These samples were scanned in the region of 1100 - 2500 nm in diffuse reflectance mode. An indigenous ELICO NIR spectrophotometer, modified according to the requirements of sugar industry was used for this purpose. Each sample was also analyzed simultaneously by standard chemical methods. Chemical values were taken as reference for near infrared analysis. In order to obtain the most accurate calibration for the set of samples, various mathematical treatments were employed. Partial Least Square method was found to be most suitable for the analysis. A comparison is made between the actual values (chemical values) and the predicted values (NIR values). The actual values agree very well with the predicted values showing the accuracy of the technique. The validity of the technique is checked by predicting the concentration of sugar in unknown molasses samples using the calibration curve. The present investigation assesses the feasibility of the technique for on-line monitoring of sugars present in molasses in sugar industries.

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Analysis on Food Waste Compost by Near Infrared Reflectance Spectroscopy(NIRS) (Near Infrared Reflectance Spectroscopy(NIRS)에 의한 음식물 쓰레기 퇴비 분석에 관한 연구)

  • Lee Hyo-Won;Kil Dong-Yong
    • Korean Journal of Organic Agriculture
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    • v.13 no.3
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    • pp.281-289
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    • 2005
  • In order to find out an alternative way of analysis of food waste compost, the Near Infrared Reflectance Spectroscopy(NIRS) was used for the compost assessment because the technics has been known as non-detructive, cost-effective and rapid method. One hundred thirty six compost samples were collected from Incheon food waste compost factory at Namdong Indurial Complex. The samples were analyzed for nitrogen, organic matter (OM), ash, P, and K using Kjedahl, ignition method, and acid extraction with spectrophotometer, respectively. The samples were scanned using FOSS NIRSystem of Model 6500 scanning mono-chromator with wavelength from $400\~2,400nm$ at 2nm interval. Modified partial Least Squares(MPLS) was applied to develop the most reliable calibration model between NIR spectra and sample components such as nitrogen, ash, OM, P, and K. The regression was validated using validation set(n=30). Multiple correlation coefficient($R^2$) and standard error of prediction(SEP) for nitrogen, ash, organic matter, OM/N ratio, P and K were 0.87, 0.06, 0.72, 1.07, 0.68, 1.05, 0.89, 0.31, 0.77, 0.06, and 0.64, 0.07, respectively. The results of this experiment indicates that NIRS is reliable analytical method to assess some components of feed waste compost, also suggests that feasibility of NIRS can be Justified in case of various sample collection around the year.

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Development of Calibration Model for Firmness Evaluation of Apple Fruit using Near-infrared Reflectance Spectroscopy (사과 경도의 비파괴측정을 위한 검량식 개발 및 정확도 향상을 위한 연구)

  • 손미령;조래광
    • Food Science and Preservation
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    • v.6 no.1
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    • pp.29-36
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    • 1999
  • Using Fuji apple fruits cultivated in Kyungpook prefecture, the calibration model for firmness evaluation of fruits by near infrared(NIR) reflectance spectroscopy was developed, and the various influence factors such as instrument variety, measuring method, sample group, apple peel and selection of firmness point were investigated. Spectra of sample were recorded in wavelength range of 1100∼2500nm using NIR spectrometer (InfraAlyzer 500), and data were analyzed by stepwise multiple linear regression of IDAS program. The accuracy of calibration model was the highest when using sample group with wide range, and the firmness mean values obtained in graph by texture analyser(TA) were used as standard data. Chemometrics models were developed using a calibration set of 324 samples and an independent validation set of 216 samples to evaluate the predictive ability of the models. The correlation coefficients and standard error of prediction were 0.84 and 0.094kg, respectively. Using developed calibration model, it was possible to monitor the firmness change of fruits during storage frequently. Time, which was reached to firmness high value in graph by TA, is possible to use as new parameter for freshness of fruit surface during storage.

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NEAR INFRARED BIO-SPECTROSCOPY : APPROACHES FOR MEASUREMENTS IN CRITICAL CARE

  • Burns, David
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.2102-2102
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    • 2001
  • Near infrared, diffuse reflectance spectroscopy has shown significant potential for in vitro and in vivo assessment of metabolic status. However, the complexity of living samples can lead to ambiguous results. This presentation will focus on methods that provide controls for scattering and absorption estimation in tissue. For robust estimations, normalization procedures will be shown which can greatly improve interpretability of results. Normalization based on time, location and spectral property will be shown with data from models, tissue phantoms and in vivo measurements. In particular, interpretation of NIR spectra associated with major respiratory constituents will be examined. Measurement of constituents such as hemoglobin, myoglobin, tissue edema, and lactate will be shown. Results suggest that NIR may provide a valuable tool for physiological monitoring in critical care research and practice.

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Possible Use of NIR Spectroscopy for Soil Testing (토양검정에서 근적외 분광분석기의 이용 가능성)

  • Ryu, Kwan-Shig;Cho, Rae-Kwang;Park, Woo-Churl;Kim, Bok-Jin
    • Korean Journal of Soil Science and Fertilizer
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    • v.34 no.4
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    • pp.273-277
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    • 2001
  • Traditional methods of chemical analysis for the soil properties take time and produce harmful waste. The purpose of this research was to evaluate an NIR technique for measuring some soil properties that are rapid and accurate in soil fertility assessments. The NIR instrument (InfraAlyzer 500, Bran & Luebbe Co.) was used for obtaining spectral data from 140 finely ground soil for calibrations and validation estimating pH, CEC, extractable Ca, Mg, K, $SiO_2$, humic acid and EC. Partial least square regression analysis was used to develop a calibration of NIR spectroscopy method. The results indicated that NIR spectroscopy could be used as a routine nondestructive method quantitatively determining soil chemical properties quickly. However the NIR technique may require sample preparation to obtain even diffuse reflection spectra from the soil and data manipulations to obtain optimal predictions.

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IDENTIFICATION OF GEOGRAPHICAL ORIGIN AND VARIETY OF GREEN COFFEE BY NIR

  • Nzabonimpa, Rukundo;Prodolliet, Jacques;Vouilloz, Annick
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1151-1151
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    • 2001
  • The international coffee trade is conducted almost exclusively with green coffee. The main coffee producing countries include Brazil, Columbia, Indonesia, Mexico and the Ivory Coast. About 99 % of the coffee grown throughout the world belong to two coffee plant varieties that are commonly known as Arabica and Robusta. The quality of green coffee can be assessed according to several ISO standards (1,2,3,4,5). However, no official international standards for the authenticity of green coffee have been issued. It is important to know the country of origin of the coffee for the purposes of fair international trade. The geographic origin of the coffee is often stated on the label of coffee products such as speciality roasted and soluble coffees. Near Infrared Spectroscopy (NIR) is an accepted technique for quantitative analysis of various parameters in routine QC analysis of food products. It would appear to be a promising candidate as a tool for identification of green coffee origin and numerous feasibility studies have appeared in the literature on its use for soluble, roasted and green coffee variety identification as well as identification of arabica or robusta coffees. NIR spectrophotometers when configured in the reflectance mode are able to perform a complete profile of the NIR spectrum on whole beans. The data can then be interpreted by discriminant chemometrics data analysis. This is the approach used in the present study.

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