• Title/Summary/Keyword: ND4

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Effect of Nd Doping on the Electrical Conductivity and Lattice Parameters of barium-Lead Titanate (Nd첨가가 Barium-Lead Titanate의 전기전도도와 격자상수에 미치는 영향)

  • Tadashi NAKANO;;Hiroaki YANAGIDA
    • Journal of the Korean Ceramic Society
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    • v.22 no.4
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    • pp.15-20
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    • 1985
  • $(Ba_{0.5} Pb_{0.5})_{1-x} Nd_x TiO_3$ 중의 $_x(Nd$의 양)를 변화시키면서 격자상수와 전기전도도를 측정하였다 c축과 a축의 비(c/a) 의 극대값은 실온에 있어서 전기전도도의 극대값과 일치하였다. 이것은 Nd원자의 치환위치와 강유 전성의 변화에 의한 것으로 고찰되었다 Curie 온도이하에서는 Nd 첨가량의 증가에 따라 전기전도도의 활성화에너지가 증가하는 경향을 나타내었다 이것은 입경의 감소에 따른 Spontaneous polarization의 저하가 원인으로 고찰되었다 첨가량의 역학을 입계의 potential barrier의 높이와 관련지어 논하였다.

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Magnetic Properties and Microstructure of Nanocrystalline NdFeB Magnets Fabricated by a Modified Hot Working Process

  • Kim, Hyoung-Tae;Kim, Yoon-Bae;Jeon, Woo-Yong;Kim, Hak-Shin
    • Journal of Magnetics
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    • v.7 no.4
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    • pp.138-142
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    • 2002
  • Magnetic properties, microstructure and texture of NdFeB magnets fabricated by a modified hot working process from commercial melt-spun powders (Magnequench; MQPA, MQPB and MQPB+) have been investigated. The hot-pressed isotropic magnet made from MQPA powder, which contains higher Nd content than that of MQPB or MQPB+, shows higher coercivity. The magnet also shows homogenous and fine grains with higher coercivity for higher consolidation pressure. The hot-deformed MQPA magnet shows a strong anisotropy along the press direction with homogeneous platelet Nd$_2$Fe$_{14}$B grains of 50∼100nm in thickness and 200∼500nm in length. The hot-deformed MQPB+ magnet, however, shows low remanence and low coercivity. The microstructure of the magnet consists of two areas; undeformed Nd$_2$Fe$_{14}$B grains and well-aligned but large grains with 3∼4 $\mu$m in length. Low Nd content attributes to the formation of the two different area.

INFLUENCE OF B AND Nd CONTENT ON THE MAGNETIC PROPERTIES OF ${\alpha}-Fe$ BASED NdFeB MAGNETS WITH ULTRAFINE GRAINS

  • Cho, Y.S.;Kim, Y.B.;Park, W.S.;Kim, C.S.;Kim, T.K.
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.427-431
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    • 1995
  • The influence of Nd and B contents on the magnetic properties and structures of ${\alpha}-Fe$ based Nd-(Fe,Co)-B-Mo-Cu alloys was investigated. $Nd_{4}{(Fe_{0.9}Co_{0.1})}_{92-x}B_{x}Mo_{3}Cu_{1}$ and $Nd_{x}{(Fe_{0.9}Co_{0.1})}_{86-x}B_{10}Mo_{3}Cu_{1}$ amorphous alloys prepared by rapid solidification process were crystallized to form nanocrystalline structure. The increase of B content in $Nd_{4}{(Fe_{0.9}Co_{0.1})}_{92-x}B_{x}Mo_{3}Cu_{1}$ nanocrystalline resulted in the change of stucture of soft phase in the sequence of ${\alpha}-Fe$->${\alpha}-Fe+Fe_{3}B$->$Fe_{3}B$. The coercivitis of the alloys were increased with increasing B content and was 263 kA/m at x=18. On the contrary, the remanence has shown an opposite trends. The increase of Nd content in $Nd_{x}{(Fe_{0.9}Co_{0.1})}_{86-x}B_{10}Mo_{3}Cu_{1}$ nanocrystalline containing ${\alpha}-Fe$ as main phase had no effect on the structure and improved coercivity up to 256 kA/m. However, the remanence was decreased from 1.4 T to 1.15 T according to the increase of Nd content.

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Development of a Nd;YAG Welding System and Its Applications (Nd:YAG 레이저 응접기의 국산화개발 및 응용)

  • 김철종;이종민
    • Proceedings of the Optical Society of Korea Conference
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    • 1989.06a
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    • pp.107-115
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    • 1989
  • A 200 W industrial Nd:YAG laser was developed and its weding applications were investigated. The important factors in designing of an industrial Nd:YAG laser were analyzed and special sedign features were explained. Also, the performance of laser weldings of Zircaloy-4, stainless steel and fine thermocouples was presented.

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Desensitizing Effects of a Nd:YAG Laser Irradiation on Hypersensitive Dentine (지각과민치아에 대한 Nd:YAG 레이저 조사의 효과)

  • Jung, Sung-Yong;Kim, Kyoung-Hee;Ko, Myong-Yun;Ahn, Yong-Woo;Park, Jun-Sang
    • Journal of Oral Medicine and Pain
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    • v.30 no.4
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    • pp.465-473
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    • 2005
  • The purpose of this study was to evaluate the desensitizing effects of a Nd:YAG laser (Sunlase, SUNRISE Technologies, Inc., USA) irradiation on cervically exposed hypersensitive dentine. 45 patients was irradiated with pulsed Nd:YAG laser (1.5 W, 20 Hz, 75 mJ/pulse, 4 minutes) as the experimental group, 27 patients was mock irradiated as the control group. The degree of sensitivity to the thermal and tactile stimuli were determined qualitatively with an evaporative stimulus defined as two times air blast at a distance of 3 mm from each site to be tested and with a mechanical stimulus as a slightly scratching the cervical site with a dental explorer. A qualitative registration of the degree of discomfort was determined according to a numerical pain scale(NPS) in an 11-point scale in which 0= "no pain" and 10="most excruciating pain imaginable". Recordings were assessed before treatment, immediately after, 1 and 2 weeks after treatment. Pain tolerance threshold and pulp vitality were evaluated with electric pulp tester before and immediately after treatment. 1. Desensitizing of hypersensitive dentine with Nd:YAG laser irradiation was more effective than that with mock irradiation. 2. The placebo effect of mock irradiation was recognized for severe sensitive teeth($NPS\;{\geqq}\;6$), but not for moderate sensitive teeth(NPS < 6). 3. Laser irradiation did not affect the pain tolerance threshold and pulp vitality of the hypersensitive teeth. 4. Desensitizing effect of laser irradiation for the hypersensitive teeth had been continuing at least 2 weeks. It was concluded that desensitizing of hypersensitive dentine with a Nd:YAG laser is effective and the maintenance of the positive result was more prolonged than the placebo effect.

Melt Textured Growth and Superconducting Properties of RE3+ Elements Doped YBCO Superconductors (RE3+원소가 첨가된 YBCO고온초전도체의 용융성장 및 초전도 특성)

  • 김소정
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.3
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    • pp.231-237
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    • 2003
  • RE(Nd, Sm) elements doped (RE/Y)$_{1.8}$B $a_{2.4}$C $u_{3.4}$$O_{7-x}$ [(RE/Y)1.8] high $T_{c}$ superconductors were directionally grown by Top Seed Melt Growth(TSMG) process in air atmosphere. The (001)melt-textured N $d_{1.8}$B $a_{2.4}$C $u_{3.4}$ $O_{7-X}$(Nd1.8) seed crystals were used for achieving the c-axis alignment large grains perpendicular to surface of the samples. The (RE/Y)1.8 SEM micrographs of the melt-textured (RE/Y)1.8 samples revealed that the nonsuperconducting (RE/Y)211 inclusions are uniformly distributed in the superconducting (RE/Y)123 matrix except the region very close to the Nd seed crystal. The microstructure and superconducting properties were investigated by XRD, SEM, TEM and SQUID magnetometer. The Melt-textured (RE/Y)1.8 samples showed an onset $T_{c}$=91K and sharp superconducting transition. Also, the magnetization value of the (RE/Y)1.8 samples were compared with those of Y1.8 sample at 77 K. 77 K. 77 K. 77 K.K.

Study on a Phosphorylation of Rare Earth Nuclide (Nd) in LiCl-KCl-NdCl3 System using Li3PO4-K3PO4 (LiCl-KCl-NdCl3계에서 Li3PO4-K3PO4를 이용한 희토류 핵종(Nd) 인산화에 관한 연구)

  • Eun, Hee-Chul;Kim, Jun-Hong;Choi, Jung-Hoon;Cho, Yung-Zun;Lee, Tae-Kyo;Park, Hwan-Seo;Park, Geun-Il
    • Journal of Advanced Engineering and Technology
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    • v.6 no.2
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    • pp.125-129
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    • 2013
  • In the pyrochemcial process of spent nuclear fuel, it is necessary to separate rare earth nuclides from LiCl-KCl eutectic waste salt for radioactive waste reduction. This paper presents the phosphorylation of neodymium chloride in LiCl-KCl-NdCl3 system using Li3PO4-K3PO4 as a phosphorylation agent in a chemical reactor with pitched blade impellers. The phosphorylation test was performed changing operation temperature, stirring rate, and amount of phosphorylation agent. Neodymium chloride was effectively converted into neodymium phosphate (NdPO4). It was confirmed that more than 99 wt% of neodymium can be separated from LiCl-KCl-NdCl3 system using a phosphorylation method l

A New Method to Determine the Spin Rorientation Angle of Cone Anisotropy from Polcrystalline Magnetization Curves: Anisotropy from Polycrystalline Magnetization Curves Application to $Nd_2Fe_{14}B$ (다결정 자화곡선을 이용한 콘이방성물질의 스핀재배열각 결정법 : $Nd_2Fe_{14}B$에의 적용)

  • ;Jin Han-min
    • Journal of the Korean Magnetics Society
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    • v.8 no.3
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    • pp.144-149
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    • 1998
  • A new method to calculate the spin reorientation angle of cone anisotropy from magnetization curves of magnetically aligned powder is suggested. The spin reorientation angle of polycrystalline $Nd_2Fe_{14}B$ determined by this method coincided with the results obtained from torque magnetometry or magnetization measurements on single crystal. The underestimation of about 9% is expected if the basal plane anisotropy is neglected in determination of the spin reorientation angle of $Nd_2Fe_{14}B$ at 4.2 K.

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The Output Characteristics of a Fiber-Coupled Laser-Diode Pumped Ceramic Nd:YAC Laser Due to Thermal Lensing Effect (광섬유 연결 반도체레이저 여기 세라믹 Nd:YAG 레이저에서 열렌즈 효과에 의한 출력특성)

  • Ok, Chang-Min;Kim, Byung-Tai;Kim, Duck-Lae
    • Korean Journal of Optics and Photonics
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    • v.17 no.5
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    • pp.455-460
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    • 2006
  • The output characteristics of a ceramic Nd:YAC laser pumped by a fiber-coupled laser diode was investigated. An efficiency and a slope efficiency of 33.8 % and 39.3 % respectively were obtained, under an output coupler reflectance of 90.4 %. The laser power has decreased suddenly due to the thermal tensing effect more than 6 W pumping powers.

Grain growth and superconducting properties of melt-processed (Y-Sm-Nd)-Ba-Cu-O composite oxides

  • Kim, So-Jung
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.15 no.4
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    • pp.141-144
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    • 2005
  • [ $(Y_{0.5}Sm_{0.25}Nd_{0.25})Ba_2Cu_3O_y$ ] [(YSN)-123] high $T_c$ composite superconductors with $CeO_2$ addition were systematically investigated by top seeded melt growth (TSMG) process in air atmosphere. A melt textured $NdBa_2Cu_3O_y$ (Nd-123) single crystal was used as a seed for achieving the c-axis alignment large grains perpendicular to the surface of (YSN)-123 composite oxides. The size of $(Y_{0.5}Sm_{0.25}Nd_{0.25})_2BaCuO_5$ [(YSN)211] nonsuperconducting inclusions of the melt textured (YSN)-123 samples with $CeO_2$ addition were remarkably reduced and uniformly distributed within the (YSN)123 superconducting matrix except in the region very close to the Nd-123 seed crystal. The sample showed a sharp superconducting transition of 91 K.