• Title/Summary/Keyword: NBR

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On the Pyrolysis of Polymers III. Identification of Gases from Rubber Pyrolysis by Gas Chromatography (高分子物質의 熱分解에 關한 硏究 (第3報) 合成고무類의 熱分解生成物의 Gas Chromatography에 의한 檢索과 合成고무 確認에의 利用)

  • Chwa-Kyung Sung
    • Journal of the Korean Chemical Society
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    • v.7 no.2
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    • pp.115-121
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    • 1963
  • Aliphatic hydrocarbon gases from rubber pyrolysis have been identified by gas chromatography with tetraethyleneglycol dimethylether column. Rubbers used in this work are polyisoprene, SBR, NBR, polybutadiene, buthyl rubber, polychloroprene and polyurethane rubber. The chromatogram is characteristic for each polymer. Author proposes a method of identification of synthetic rubbers by gas chromatograph of pyrolyzed gas. Sample is pyrolyzed at $450^{\circ}C$ under nitrogen or more effectively helium and gaseous portion, which eliminated liquid condensate, is passed to the column. The appearance of exclusively large peak of isoprene, isobutylene and carbon dioxide shows the presence of polyisoprene, polyisobutylene and polyurethane, respectively. Large peak of butadiene will appear in case of polybutadiene, SBR and NBR, but SBR can be identified through the styrene peak in gas chromatogram of liquid pyrolyzate and NBR can be identified by the evolution of hydrogen cyanide during pyrolysis. Polychloroprene is identified by the evolution of hydrogen chloride. This method could be applied to the identification of copolymer or polymer blend.

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Studies on the Physical Properties and Application of EPDM-Polymer Blends. Part 4. Physical Properties for EPDM-NBR Blends (EPDM과 각종(各種)Polymer의 Blend에 의(依)한 성능변화(性能變化) 및 그 응용(應用)에 관(關)한 연구(硏究)(제4보(第4報)) EPDM과 Acrylonitrile-Butadiene Rubber의 Blend에 대(對)하여)

  • Kim, Joon-Soo
    • Elastomers and Composites
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    • v.7 no.1
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    • pp.45-52
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    • 1972
  • As a series of the studies of EPDM-Polymer blends, the experiments are concentracted to the investigation of the physical properties of the EPDM-NBR blends. The results are shown as follows; 1. As EPDM addition ratio is increased, the physical properties such as resistance to ozone and aging have also improved, on the other hand, elongation and abrasion resistance decreased. 2. Tear strength is less influenced by blending and character after aging exhibited the same result. 3. Tensile strength decreased with increase in EPDM contents, especially the ratio of EPDM/NBR are 50/50 and 75/25.

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Improvement of Abrasion Resistance and Friction of Rubber Blend Composition

  • Lee, Jong-Hwan;Lee, Jieun;Han, Tak Jin;Jeong, Hye Min
    • Elastomers and Composites
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    • v.55 no.3
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    • pp.161-166
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    • 2020
  • On the basis of the use of shoes, the outsole, which is mainly made of rubber, has various characteristics. The most important of these characteristics is abrasion resistance and friction. Generally, the abrasion resistance can be improved by adding more reinforcing filler such as silica to the rubber; however, the friction force drops. Owing to these problems, rubber having excellent abrasion resistance and rubber having excellent frictional force are blended. In this study, various characteristics, including wear resistance and friction, were evaluated by blending NBR/SBR or NBR/BR mixture with high wear resistance and CIIR with high friction. The CIIR was increased up to 60 phr, whereas the friction wear characteristics were rapidly changed in the NBR/CIIR blend ratio from 75:15 to 60:30.

Effect of TESPT Silane Coupling Agent on Mechanical Properties of Precipitated Silica Filled NBR Compound for Oil Seal (TESPT 실란커플링제가 침전 실리카로 보강된 오일씰용 NBR복합소재의 기계적 물성에 미치는 영향)

  • Lee, Young-Seok;Hwang, Ki-Seob;Lee, Jong-Cheol;Kim, Tae-Geun;Ha, Ki-Ryong
    • Elastomers and Composites
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    • v.46 no.1
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    • pp.45-53
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    • 2011
  • The effect of the silane coupling agent, bis(triethoxysilypropyl)tetrasulfide (TESPT), on mechanical properties of a silica-filled NBR compound for oilseal was investigated. Curing behavior and crosslinking density of the compounds were measured using ODR (oscillating disk rheometer) and swelling ratio in toluene. UTM (universal testing machine) and shore A hardness tester were used in order to study the characteristics of mechanical properties of original vulcanizates and aged ones with heated air and ASTM No. 3. oil. Recovery of elasticity which influences the performance and service life of oilseal was investigated by giving bending deformation to vulcanizates in aging condition. After bending aging test, recovery distance was measured and calculated angle of recovery from it. TR (temperature retraction) test was performed on these vulcanizates to determine the low temperature recovery behavior. Wear resistance was measured by Taber type abrasion tester. In addition, SEM was used to characterize the morphology of the worn surface of vulcanizates. The result showed that addition of TESPT into silica-filled compound improves not only compound flow-ability, interaction between NBR and silica and crosslinking density, but also hardness, 100% modulus, recovery of elasticity, wear resistance, heat resistance and ASTM No.3 oil resistance of vulcanizates.

Preparation and Properties of NBR-Clay Hybrids (NBR-Clay 하이브리드의 제조 및 물성)

  • 김영진;남상용
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05b
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    • pp.131-132
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    • 2004
  • 클레이는 1 나노미터 정도의 두께를 가지는 실리케이트층으로 이루어져 있으며, 이러한 클레이를 고분자 사이에 나노미터 단위로 분산시키는 기술에 대한 연구가 활발하게 이루어져오고 있다. 최근에는 Nylon-6에 유기화된 클레이를 분산시키는 연구에 대한 결과가 발표된 바 있다. 클레이를 사용한 나노복합체의 개발은 제품의 경량화를 위한 노력과 더불어 이루어져왔으며, 특히 최근에 급격히 발전하고 있는 나노기술에 힘입어서 나노복합체의 개발위주로 이루어지고 있다.(중략)

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