• Title/Summary/Keyword: N/C ratio

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GaN Thin Flims Grown by CVPE(Chloride Vapor Phase Epitaxy) Method (CVPE(Chloride Vapor Phase Epitaxy)법에 의한 GaN 박막성장 연구)

  • 오태효;박범진
    • Korean Journal of Crystallography
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    • v.8 no.2
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    • pp.81-88
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    • 1997
  • We investigated the CVPE grown of GaN thin films on (0001) sapphire using the $GaCl_3$ and $NH_3$ as source gases. The growth temperatures are ranged 970 to $1040^{\circ}C$ with the various flow rate ratio of source gases. The nitridation treatment was performed using the $NH_3$ gas before the GaN deposition. The optimal growth conditions were determined to be; growth temperature of $1040^{\circ}C$, III/V flow rate ratio of 2, nitridation time of 3 min. The FWHM at the (0002) peak from the XRD analysis was shown to be 0.32 deg. for the sample grown under those conditions. The growth rate was about $40{\mu}m/hr$ at $1040^{\circ}C$.

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Optimum Mixing Ratio of Bulking Agent for Garbage Composting (음식쓰레기 퇴비화시 bulking agent의 적정 첨가량 결정에 관한 연구)

  • Shin, Hang-Sik;Hwang, Eung-Ju;Jeong, Yeon-Koo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.2 no.1
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    • pp.75-86
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    • 1994
  • Garbage composting was studied in a controlled batch reactor with the addition of cooked rice as a biodegradable carbon source to find the effect of C/N ratio control on composting. And composting of bulking agents such as sawdust and wheat straw were tested with the addition of ammonium sulfate as a nitrogen source. As expected, biodegradation of the garbage having low C/N ratio was improved to some extent when foreign carbon was added. But bulking agents used in this study exerted slightly biodegradable carbon potential, indicating that the estimation of the dose of additional carbon considering desirable C/N ratio was not reasonable when lignocellulosic bulking material was added to garbage. It was found that the optimum moisture content increased with sawdust addition meaning the C/N ratio increment. Considering the above results, it was suggested that 78g sawdust per 100g garbage should be mixed to make C/N ratio to 25 and moisture content to 56% for effective composting of the garbage studied in this paper.

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Assessment on Stabilization of Open-dumping Landfill Gas - A Case Study of Salmi Landfill - (사용종료된 비위생매립지의 매립가스 안정화 평가 - 살미매립지 사례연구 -)

  • Hong, Sang-Pyo;Kim, Kwang-Yul
    • Journal of Environmental Impact Assessment
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    • v.14 no.6
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    • pp.365-375
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    • 2005
  • For managing and utilizing a closed municipal solid waste landfill site in environmentally secure conditions, it is necessary to verify the stabilization level of landfill gas(LFG) and waste. For assessing LFG and waste stabilization of an open-dumping municipal solid waste landfill (Salmi Landfill) which is located at the vicinity of Chungju Reservoir which flows into Paldang Reservoir that has been used for Seoul Metropolitan water supplies, the history and the surrounding characteristics of the landfill site were surveyed. In this study, waste and LFG samples obtained from landfill site were physically and chemically analyzed, and then the analysis results were evaluated on the basis of 'The Criteria of Landfill Waste Stabilization(CLWS)' that were promulgated by Korean Ministry of Environment. Based on LFG composition of Salmi landfill, $CH_4$ was as high as 68%. In CLWS regulation, the stabilization criteria of $CH_4$ should be lower than 5%, and the criteria of C/N ratio should also be lower than 1/10. The result showed that C/N ratio of landfilled waste ranged 17.4~24.7. From this results, it was concluded that the LFG and C/N ratio stabilization level of this landfill based on the CLWS were still actively proceeding.

The Decomposition of Leaf Litters of Some Tree Species in Temperate Deciduous Forest in Korea II. Changes in Nutrient Content During Litter Decomposition

  • Yang, Keum-Chul;Shim, Jae-Kuk
    • The Korean Journal of Ecology
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    • v.26 no.6
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    • pp.313-319
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    • 2003
  • Dry weight loss and nutrient release from leaf litter for six tree species were studied using litter bag methods. The litter bags were incubated for f6 months on the forest floor in temperate deciduous forest in Mt. Cheonma, located at the middle part of Korean Peninsula. The changes in nutrient content and the rate of dry weight loss in leaf litter varied with litter types. The litter of Pinus densiflora showed the lowest rate of mass loss (k=0.33), nitrogen concentration (0.89%) and ash concentration (2.50%), while showed the highest C/N ratio (63.40). On the other hand, the litter of Acer pseudo-sieboldianum showed the fastest rate of mass loss (k=0.82), the highest nitrogen concentration (1.11%), and the lowest C/N ratio (49.40). During the decomposition, nitrogen, phosphorus and calcium in the leaf litters showed relatively slow decreasing pattern compared to other elements (carbon, potassium, magnesium, manganese and sodium), but potassium and sodium decreased at early stage of the decomposition for all leaf litters. Differences in annual decomposition rates of litter among species were consistent with the particular chemical characteristics of their leaf litters. The initial concentration of nitrogen was positively correlated with litter decomposition rate for six species, while litter decomposition rate of six species was negatively correlated with C:N ratio of initial leaf litters.

Weight Loss and Nutrient Dynamics during Leaf Litter Decomposition of Quercus mongolica in Mt. Worak National Park

  • Mun, Hyeong-Tae
    • Journal of Ecology and Environment
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    • v.32 no.2
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    • pp.123-127
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    • 2009
  • Weight loss and nutrient dynamics of Quercus mongolica leaf litter during decomposition were investigated from December 2005 through August 2008 in Mt. Worak National Park as a part of National Long-Term Ecological Research Program in Korea. The decay constant (k) of Q. mongolica litter was 0.26. After 33 months decomposition, remaining weight of Q. mongolica litter was 49.3$\pm$4.4%. Initial C/N and C/P ratios of Q. mongolica litter were 43.3 and 2,032, respectively. C/N ratio in decomposing litter decreased rapidly from the beginning to nine months decomposition, and then showed more or less constant. C/P ratio increased to 2,407 after three months decomposition, and then decreased steadily thereafter. N and P concentration increased significantly during decomposition. N immobilization occurred from the beginning through 18 months decomposition, and mineralization occurred afterwards in decomposing litter. P immobilized significantly from fifteen months during decomposition. K concentration decreased rapidly from the beginning to six months decomposition. However it showed an increasing pattern during later stage of decomposition. Remaining K decreased rapidly during early stage of decomposition. There was no net K immobilization. Ca concentration increased from the beginning to twelve months decomposition, and then decreased rapidly till twenty one months elapsed. However, it increased again thereafter. Ca mineralization occurred from fifteen months. Mg concentration increased during decomposition. There was no Mg immobilization during litter decomposition. After 33 months decomposition, remaining N, P, K, Ca and Mg in Q. mongolica litter were 79.2, 110.9, 36.2, 52.7 and 74.4%, respectively.

The effect of reactive gases on the propertise of TiCN layer synthesized by Arc Ion plating process (Arc Ion Plating 방식에 의한 TiCN 증착시 반응가스가 코팅층에 미치는 영향)

  • Seo, Chang-Min;Kim, Chang-Geun;;Yu, Im-Jun
    • Journal of Ocean Engineering and Technology
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    • v.11 no.3
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    • pp.56-68
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    • 1997
  • This work was intended to study the effect of a partial pressure ratio and a total pressure of reactive gases on the properties of TiC$_{x}$N$_{1-x}$ . coated layer. In this regard, various TiC$_{x}$N$_{1-x}$ coatings were synthesized with C2112 and N2 Mixture gas of different compositions by Arc Ion Plating process which has been highlighted for an industrial purpose. It was revealed from colors and X-ray diffraction patterns that the concentration of carbon of a TiC$_{x}$N$_{1-x}$ coating increases with a partial pressure ratio (PC$_{2}$H$_{2}$/PN$_{2}$) as well as a total pressure Of $C_{2}$H$_{2}$ and N$_{2}$ mixture gas. Accordingly, the hardness of TiC$_{x}$N$_{1-x}$ coated layer increased but the adhesion to the substrate of SKH 51 was degraded. On the other hand, the deposition rate was independent of a partial pressure ratio and a total pressure of mixture gas. It was found that a uniform gas distribution is critical for an industrial application since the composition of a coating depends strongly on the location of a substrate inside of the furnace. As a result of milling tests with different TiC$_{x}$N$_{1-x}$ coated end mills, the one which has a low carbon concentration was better than others studied in this work.d in this work.

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Ginseng authenticity testing by measuring carbon, nitrogen, and sulfur stable isotope compositions that differ based on cultivation land and organic fertilizer type

  • Chung, Ill-Min;Lee, Taek-Jun;Oh, Yong-Taek;Ghimire, Bimal Kumar;Jang, In-Bae;Kim, Seung-Hyun
    • Journal of Ginseng Research
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    • v.41 no.2
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    • pp.195-200
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    • 2017
  • Background: The natural ratios of carbon (C), nitrogen (N), and sulfur (S) stable isotopes can be varied in some specific living organisms owing to various isotopic fractionation processes in nature. Therefore, the analysis of C, N, and S stable isotope ratios in ginseng can provide a feasible method for determining ginseng authenticity depending on the cultivation land and type of fertilizer. Methods: C, N, and S stable isotope composition in 6-yr-old ginseng roots (Jagyeongjong variety) was measured by isotope ratio mass spectrometry. Results: The type of cultivation land and organic fertilizers affected the C, N, and S stable isotope ratio in ginseng (p < 0.05). The ${\delta}^{15}N_{AIR}$ and ${\delta}^{34}S_{VCDT}$ values in ginseng roots more significantly discriminated the cultivation land and type of organic fertilizers in ginseng cultivation than the ${\delta}^{13}C_{VPDB}$ value. The combination of ${\delta}^{13}C_{VPDB}$, ${\delta}^{15}N_{AIR}$, or ${\delta}^{34}S_{VCDT}$ in ginseng, except the combination ${\delta}^{13}C_{VPDB}-^{34}S_{VCDT}$, showed a better discrimination depending on soil type or fertilizer type. Conclusion: This case study provides preliminary results about the variation of C, N, and S isotope composition in ginseng according to the cultivation soil type and organic fertilizer type. Hence, our findings are potentially applicable to evaluate ginseng authenticity depending on cultivation conditions.

Studies on the Modelling of Controlled Environment in Leaf Vegetable Crops (엽채류의 환경제어 모델 연구 I. 야온 및 양액내 $\textrm{NO}_3\;^-$: $\textrm{NH}_4\;^+$비가 백경채 및 탑채의 생육에 미치는 영향)

  • 박권우;신영주;이용범
    • Journal of Bio-Environment Control
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    • v.1 no.1
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    • pp.21-27
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    • 1992
  • The effects of different night temperatures and NO$_3$$^{[-10]}$ : NH$_4$$^{+}$ ratios in nutrient solution on the growth and quality of Chinese white cabbage(B. chinensis L. var. chinensis) and Chinese flat cabbage(B. chinensis L. var. rosularis) were studied. The results were summarized as follows. 1. Fresh weight was increased higher in night temperature 15$^{\circ}C$ than 5, 1$0^{\circ}C$, but content of vitamin C and dry weight ratio were increased as night temperature was lower. 2, The growth of Chinese white cabbage and Chinese flat cabbage was bad extremely in NO$_3$$^{[-10]}$ : NH$_4$$^{+}$(0 : 8), and the others were little different 3. In nutrient solution, the higher NO$_3$$^{[-10]}$ -N concentration was, the more content of vitamin C, and the higher NH$_4$$^{+}$-N concentration was, the more dry weight ratio.ratio.

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Effect of C/N Ratio on the Production of Poly(3-hydroxyalkanoates) by the Methylotroph Paracoccus denitrificans

  • Kim, Byung-Ki;Yoon, Sung-Chul;Nam, Jae-Do;Lenz, Robert-W.
    • Journal of Microbiology and Biotechnology
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    • v.7 no.6
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    • pp.391-396
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    • 1997
  • Two series of carbon sources, linear primary $C_1$~$C_9$ alcohols and linear $C_2$~$C_{10}$ monocarboxylic acids were tested for PHA synthesis in Paracoccus denitrificans. The results showed that the growth-associated synthesis of PHA could be referred only to the carbon sources with odd number of carbon except methanol. For all carbon sources with even number of carbon, nitrogen limitation was required to induce PHA synthesis in P. denitrificans. Poly(3-hydroxyvalerate)[P(3HV)] homopolymer was synthesized from $C_5$, $C_7$, and $C_9$ while growing in the presence of nitrogen, but the nitrogen depletion in the later growth period incorporated 3-hydroxybutyrate(3HB) unit into the polymer chain. The optimum C/N ratio for P(3HV) homopolymer production was found to be 10 when the strain was grown on 10 ml/l of valeric acid for 96 h. P. denitrificans synthesized P(3HB-co-3HV) copolymers from n-hexanoic and n-octanoic acid. The microstructural characterics of the P(3HB-co-3HV) copolymer from n-propanol was investigated using $^13C$-nuclear magnetic resonance spectroscopy, showing a structural heterogeneity.

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New and Regenerated Production Based on Nitrogen in the southern Part of the Yellow Sea in Late April, 1993. (1993년 4월말 황해 남부 해역의 질소 신생산(新生産)과 재생산(再生産))

  • YANG, SUNG RYULL;SHIN, KYOUNG SOON;YANG, DONG-BEOM
    • 한국해양학회지
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    • v.29 no.3
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    • pp.258-268
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    • 1994
  • Nitrogenous new production and regenerated production were measured in the southern part of the Yellow Sea (Hwanghae) using a stable isotope /SUP 15/N nitrate and ammonia between April 25∼30, 1993. Nitrogen production varied between 155 and 688 mg N m/SUP -2/ d/SUP -1/, which belongs to meso to eutrophic area values. This is equivalent to 881∼3909 mg C m/SUP -2/ d/SUP -1/, assuming the Redfield ratio for C:N of 5.7:1 (by weight). the f0ratio which is the fraction of new production from primary production, varied between 0.12 and 0.26, indicating that 74 to 88% of primary production was supported by the regeneration of nutrients within the euphoric zone. This low f0ratio is the characteristics of the oligo- to mesotrophic area. Contrary to the expected, the ambient nutrient concentration was not an important factor for controlling productivity in this area during the study period. The difference in productivity among stations was mainly due to the variations in phytoplankton biomass in different water masses.

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