• Title/Summary/Keyword: N,N-dimehylaniline

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Photochemical Reactions of Some Carbonyl Compounds with N, Nv-Dimethylaniline: Formation of $\beta- and \gamma-Hydroxynmines$

  • Kim, Sung-Sik;Change, Ji-Ae;Mah, Yoon-Jung
    • Journal of Photoscience
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    • v.9 no.1
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    • pp.5-7
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    • 2002
  • Direct irradiation of carbonyl compounds such as some aldehydes, ketones and anthraquinone in N,N-dimethylamiline(DMA), without using other solvents, gave $\beta$-hydroxyamines as the major products. Irradiation of anthrone and DMA in methanol afforded ${\gamma}$-hydroxyamine. The structure of the photoproduct was confirmed by treatment with an acid to give a bicyclic compound.

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