• Title/Summary/Keyword: Multiple-ion

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Analysis of orbit control for allocation of small SAR satellite constellation (초소형 SAR 위성군의 배치를 위한 궤도 제어 분석)

  • Song, Youngbum;Son, Jihae;Park, Jin-Han;Song, Sung-Chan;Oh, Hyun-Ung
    • Journal of Aerospace System Engineering
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    • v.16 no.5
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    • pp.8-16
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    • 2022
  • This paper presents the orbital control for positioning micro synthetic aperture radar (SAR) satellites for all-weather monitoring around the Korean Peninsula. In Small SAR technology experimental project (S-STEP) developed in Korea, multiple satellites are placed at equal intervals in multiple orbital planes to secure an average revisit period for the region around the Korean Peninsula. Satellites entering the same orbital plane use ion thrusters to control their orbits and the separation velocity from the launch vehicle to distribute them evenly across the orbit. For an orbital that places the satellites equally spaced in the same orbital plane, the shape of the satellite constellation is formed by adjusting the difference in drift rates between the satellites. This paper presents, different types of satellite constellations, and the results of satellite constellation placement according to launch strategies are presented. In addition, a method and limitations in shortening the duration of orbital deployment are presented.

Synthesis and Fluoride Binding Properties of Tris-pyridinium Borane

  • Lee, Kang Mun;Kim, Yejin;Do, Youngkyu;Lee, Junseong;Lee, Min Hyung
    • Bulletin of the Korean Chemical Society
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    • v.34 no.7
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    • pp.1990-1994
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    • 2013
  • A novel multi-cationic borane, tri-N-methylpyridinium substituted triarylborane, $[BAr^N_3]I_3$ ($[2]I_3$) ($Ar^N=4-(4-C_5H_4N-Me)-2,6-Me_2-C_6H_2$) was prepared from the corresponding neutral tris-pyridyl borane, $BAr_3$ (2a) ($Ar=4-(4-C_5H_4N)-2,6-Me_2-C_6H_2$). The crystal structure of 2a determined by X-ray diffraction study reveals the presence of tri-coordinate boron center with peripheral pyridyl moieties. The fluoride ion affinity of the cationic borane, $[2]I_3$ was investigated by UV-vis absorption titrations and was compared with that of neutral 2a. While 2a binds fluoride with the binding constant of $1.9{\times}10^2\;M^{-1}$ in $THF/H_2O$ (9:1 v/v) mixture, $[2]I_3$ shows a very high binding constant ($K=1.0{\times}10^8\;M^{-1}$) that is greater by six orders of magnitude than that of 2a in the same medium. This result indicates that the fluorophilicity of triarylborane can be drastically enhanced by multiple pyridinium substitutions.

Efficiency enhancement of spray QD solar cells

  • Park, Dasom;Lee, Wonseok;Jang, Jinwoong;Yim, Sanggyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.420.1-420.1
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    • 2016
  • Colloidal quantum dot (CQD) is emerging as a promising active material for next-generation solar cell applications because of its inexpensive and solution-processable characteristics as well as unique properties such as a tunable band-gap due to the quantum-size effect and multiple exciton generation. However, the most widely used spin-coating method for the formation of the quantum dot (QD) active layers is generally hard to be adopted for high productivity and large-area process. Instead, the spray-coating technique may potentially be utilized for high-throughput production of the CQD solar cells (CQDSCs) because it can be adapted to continuous process and large-area deposition on various substrates although the cell efficiency is still lower than that of the devices fabricated with spin-coating method. In this work, we observed that the subsequent treatment of two different ligands, halide ion and butanedithiol, on the lead sulfide (PbS) QD layer significantly enhanced the cell efficiency of the spray CQDSCs. The maximum power conversion efficiency was 5.3%, comparable to that of the spin-coating CQDSCs.

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Comparison between Source-induced Dissociation and Collision-induced Dissociation of Ampicillin, Chloramphenicol, Ciprofloxacin, and Oxytetracycline via Mass Spectrometry

  • Lee, Seung Ha;Choi, Dal Woong
    • Toxicological Research
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    • v.29 no.2
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    • pp.107-114
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    • 2013
  • Mass spectrometry (MS) is a very powerful instrument that can be used to analyze a wide range of materials such as proteins, peptides, DNA, drugs, and polymers. The process typically involves either chemical or electron (impact) ionization of the analyte. The resulting charged species or fragment is subsequently identified by the detector. Usually, single mass uses source-induced dissociation (SID), whereas mass/mass uses collision-induced dissociation (CID) to analyze the chemical fragmentations Each technique has its own advantages and disadvantages. While CID is most effective for the analysis of pure substances, multiple-step MS is a powerful technique to get structural data. Analysis of veterinary drugs ampicillin, chloramphenicol, ciprofloxacin, and oxytetracycline serves to highlight the slight differences between SID and CID. For example, minor differences were observed between ciprofloxacin and oxytetracycline via SID or CID. However, distinct fragmentation patterns were observed for ampicllin depending on the analysis method. Both SID and CID showed similar fragmentation spectra but different signal intensities for chloramphenicol. There are several factors that can influence the fragmentation spectra, such as the collision energy, major precursor ion, electrospray mode (positive or negative), and sample homogeneity. Therefore, one must select a fragmentation method on an empirical and case-by-case basis.

Development and Validation of a Liquid Chromatography-Tandem Mass Spectrometry Method for the Determination of ε-Acetamidocaproic Acid in Rat Plasma

  • Kim, Tae Hyun;Choi, Yong Seok;Choi, Young Hee;Kim, Yoon Gyoon
    • Toxicological Research
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    • v.29 no.3
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    • pp.203-209
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    • 2013
  • A simple and rapid liquid chromatography-tandem mass spectrometry (LC-MS/MS) method was developed and validated for the quantification of ${\varepsilon}$-acetamidocaproic acid (AACA), the primary metabolite of zinc acexamate (ZAC), in rat plasma by using normetanephrine as an internal standard. Sample preparation involved protein precipitation using methanol. Separation was achieved on a Gemini-NX $C_{18}$ column ($150mm{\times}2.0mm$, i.d., 3 ${\mu}m$ particle size) using a mixture of 0.1% formic acid-water : acetonitrile (80 : 20, v/v) as the mobile phase at a flow rate of 200 ${\mu}l/min$. Quantification was performed on a triple quadrupole mass spectrometer employing electrospray ionization and operating in multiple reaction monitoring (MRM) and positive ion mode. The total chromatographic run time was 4.0 min, and the calibration curves of AACA were linear over the concentration range of 20~5000 ng/ml in rat plasma. The coefficient of variation and relative error at four QC levels were ranged from 1.0% to 5.8% and from -8.4% to 6.6%, respectively. The present method was successfully applied for estimating the pharmacokinetic parameters of AACA following intravenous or oral administration of ZAC to rats.

Electrical Power Subsystem Performance Evaluation of the GEO Satellite (정지궤도위성 전력계 성능 평가)

  • Koo, Ja Chun;Ra, Sung Woong
    • Journal of Korea Society of Industrial Information Systems
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    • v.19 no.1
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    • pp.31-41
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    • 2014
  • The satellite on geostationary orbit accommodates multiple payloads into a single spacecraft platform and launched in June 26, 2010. The Electrical Power Subsystem provides a fully regulated power bus at $50V_{DC}$ in sunlight and eclipse conditions. The electrical power required to the satellite is generated by a solar array wing and the energy is stored by a Li-Ion battery with a capacity of 192.5Ah. This paper selects the main design parameters, compares and analyzes with the results at ground test and in orbit operation to apply this performance evaluation of the Electrical Power Subsystem to next satellite design on geostationary orbit. The Electrical Power Subsystem is demonstrated nominal behavior without significant degradation through the performance evaluation from design to in orbit operation.

Application of CRAMPS for a Phase Transition in H+-ion irradiated TlH2PO4

  • Kim, Se-Hun;Han, J.H.;Lee, Cheol-Eui;Lee, Kwang-Sei;Kim, Chang-Sam;Dalal, N.S.;Han, Doug-Young
    • Journal of the Korean Magnetic Resonance Society
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    • v.14 no.2
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    • pp.134-143
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    • 2010
  • We studied the hydrogen-bonded $TlH_2PO_4$ (TDP) ferroelectrics treated with the proton-beam bombardment. The TDP material was irradiated with 1-MeV proton beam at a dose of $10^{15}/cm^2$. In order to analyze the hydrogen environment in TDP, we carried out the $^1H$ high resolution nuclear magnetic resonance (NMR) - i.e., Combined Rotation And Multiple Pulse Spectroscopy (CRAMPS) measurement. The isotropic chemical shift of hydrogen indicates its displacive property is related to the $PO_4$ lattice deformation which occurs throughout the antiferroelectric-, the ferroelastic- and the paraelastic-phase transitions. The temperature dependence of $\sigma_{iso}$ reveals the electronic charge redistribution is induced by the proton-beam irradiation and the elastic property.

A Wrapper Model for Integrated Access to Biological Information Sources (생물 정보원에 대한 통합 접근을 위한 랩퍼 모델)

  • Park, Eun-Koung;Kang, Dong-Wan;Jung, Chai-Young;Bae, Jong-Min
    • The KIPS Transactions:PartD
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    • v.11D no.4
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    • pp.765-774
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    • 2004
  • In order to integrate heterogeneous biological information sources, it is necessary to define the view that represents unified viewpoint for the multiple sources by hiding heterogeneity of the data. We present an XML-based view definition model and show Its operating principles in designing the middleware system to integrate biological information sources. This model supports the user-defined XML view to increase flexibility in constructing the integration system and execute integrated queries on higher level ion. Based on the view-definition model, we present a wrapping model for relational database systems and web resources as well as an application program.

Cloning of Xenopus laevis TRPV2 by Gene Prediction

  • Lee, Jung Youn;Shim, Won Sik;Oh, Uhtaek
    • Genomics & Informatics
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    • v.3 no.1
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    • pp.24-29
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    • 2005
  • TRPV2 is a non-specific cation channel expressed in sensory neurons, and activated by noxious heat. Particularly, TRPV2 has six transmembrane domains and three ankyrin repeats. TRPV2 has been cloned from various species such as human, rat, and mouse. Oocytes of Xenopus laevis - an African clawed frog ­have been widely used for decades in characterization of various receptors and ion channels. The functional property of rat TRPV2 was also identified by this oocyte expression system. However, no TRPV2 orthologue of Xenopus laevis has been reported so far. Hence, we have focused to clone a TRPV2 orthologue of Xenopus laevis with the aid of bioinformatic tools. Because the genome sequence of Xenopus laevis is not available until now, a genome sequence of Xenopus tropicalis - a close relative species of Xenopus laevis - was used. After a number of bioinformatic searches in silico, a predicted full-length sequence of TRPV2 orthologue of Xenopus tropicalis was found. Based on this predicted sequence, various approaches such as RT-PCR and 5' -RACE technique were applied to clone a full length of Xenopus laevis TRV2. Consequently, a full-length Xenopus laevis TRPV2 was cloned from heart cDNA.

Properties of plasmas associated with fluctuations in the upstream of Earth's bow shock

  • Lee, En-Sang;Lin, Naiguo;Parks, George;Kim, Khan-Hyuk;Lee, Dong-Hun
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.1
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    • pp.96.1-96.1
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    • 2012
  • Various electromagnetic fluctuations are observed in the upstream of Earth's bow shock. Properties of plasmas are important in determining the development of the fluctuations. In this study we analyze the phase space distribution functions of plasmas measured by the Cluster spacecraft to understand how the fluctuations develop. Plasmas in the upstream of Earth's bow shock often consist of multiple components, especially when the fluctuations exist. In addition to the solar wind beams, backstreaming ion beams and diffuse ions are also often observed separately or simultaneously. The solar wind beams are not much perturbed even within the fluctuations. The diffuse ions are more than 10 times hotter than the solar wind beams and the backstreaming beams intermediate between them. The distribution functions of the diffuse and backstreaming ions are anisotropic to the magnetic field. Thus, they may be responsible for the fluctuations associated with temperature anisotropy. We will discuss about the thermalization processes and the relationship between the fluctuations and plasmas.

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