• Title/Summary/Keyword: Multicomponent Mixture

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Modeling of Multicomponent Mixture Separation Processes Using Hollowfiber Membrane (중공사막을 이용하는 다성분 혼합물 분리공정의 모델링)

  • Kim, Sin-Ah;Kim, Jin-Kuk;Lee, Young Moo;Yeo, Yeong-Koo
    • Korean Chemical Engineering Research
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    • v.53 no.1
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    • pp.22-30
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    • 2015
  • So far, most of research activities on modeling of membrane separation processes have been focused on binary feed mixture. But, in actual separation operations, binary feed is hard to find and most separation processes involve multicomponent feed mixture. In this work models for membrane separation processes treating multicomponent feed mixture are developed. Various model types are investigated and validity of proposed models are analysed based on experimental data obtained using hollowfiber membranes. The proposed separation models show quick convergence and exhibit good tracking performance.

Numerical modelling for multicomponent diffusion in laminar hydrogen jet flame by using opensource OpenFOAM (오픈 소스 OpenFOAM을 이용한 층류 수소 제트 화염장 내의 다종 확산 수치해석 모델 개발)

  • Kim, Gunhong
    • 한국연소학회:학술대회논문집
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    • 2012.11a
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    • pp.335-338
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    • 2012
  • The present study focuses mainly on modeling the ordinary diffusion flux of species. According to CHEMKIN, both the mixture-averaged approach, Fick's formula, and the full multicomponent approach are implemented in the framework of opensource OpenFOAM. Also the Stefan-Maxwell approach is coded and validated together against measurements of laminar hydrogen jet flame. In the case of viscosity and conductivity of mixture, the mixture-averaged approach is applied and thermal diffusion is not considered in this work. Results show that there are no distinct deviations in three different approaches of diffusion of species in the present hydrogen flame condition.

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Transient Multicomponent Mixture Analysis Based On an ICE Numerical Technique for the Simulation of an Air Inggess Accident in an HTGR

  • Lim, Hong-Sik;No, Hee-Cheon
    • Nuclear Engineering and Technology
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    • v.36 no.5
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    • pp.375-387
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    • 2004
  • This paper presents a transient multicomponent mixture analysis tool developed to analyze the molecular diffusion, natural convection, and chemical reactions related to air ingress phenomena that occur during a primary-pipe rupture of a high temperature gas-cooled reactor (HIGR). The present analysis tool solves the one-dimensional basic equations for continuity, momentum, energy of the gas mixture, and the mass of each gas species. In order to obtain numerically stable and fast computations, the implicit continuous Eulerian scheme is adopted to solve the governing equations in a strongly coupled manner. Two types of benchmark calculations were performed with the data of prerious Japanese inverse U-tube experiments. The analysis program, based on the ICE technique, runs about 36 times faster than the FLUENT6 for the simulation of the two experiments. The calculation results are within a 10% deviation from the experimental data regarding the concentrations of the gas species and the onset times of natural convection.

Multidimensional Gas Chromatography-A Powerful Tool for the Analysis of Multicomponent Mixtures

  • Kim, Kyoung-Su
    • Preventive Nutrition and Food Science
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    • v.1 no.1
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    • pp.127-133
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    • 1996
  • The development of high resolution capillary columns and a large variety of different detectors led to a strong position of gas chromatography in instrumental analysis. Every effort has been made to solve sophisticated separation problems by column switching. Nowadays, several systems are commercially available for this purpose. The principle and the capabilities of multidimensional gas chromatography(MDGC) are illustrated by different applications in the field of modern flavor and essential oil research.

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Hot Petroleum Drying Method to the Preparation of Multicomponent Oxide Ceramic Material (다성분계 산화물의 요업재료 제조를 위한 석유 증발 건조 방법)

  • 변수일
    • Journal of the Korean Ceramic Society
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    • v.14 no.3
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    • pp.163-168
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    • 1977
  • As a wet chemical drying process "hot petroleum drying method" was applied and developed for preparing uniformly fine oxide powder with high purity and sinterreactivity. Using this method solution of sulfates was dried in hot petroleum bath (~17$0^{\circ}C$) to sulfate powder from which corresponding mullite doped by Fe3+ ion was formed. Particle size, shape, decomposition by heat, and phase identification of sulfate andoxide powders determined by DTA, TGA, X-ray diffraction, analysis and electron microscopy: sulfate powder prepared by this drying method is an intimate mixture of the amorphous form of uniformly and finely distributed spherical particles (0.05-0.1$\mu$). Mullitization with the sulfate powder occurs at 110$0^{\circ}C$ in air. The morphology of mullite particle made by firing the sulfate powder at 135$0^{\circ}C$ in oxygen atmosphere is granular of 0.1-0.3$\mu$ in size. This drying process proved to be a very effective method for preparing fine, homogeneous, and highly sinterreactive multicomponent oxide powder without conventional ceramic process of mixing, milling, and granulating. This process can be also applied for preparing electronic ceramic materials which are requisite for high purity and homogeneity.mogeneity.

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Ultraviolet Spectrophotometric Analysis of 2-Aminonaphtalene Sulfonic Acids (2 - 아미노나프탈렌술폰산류의 자외선분광 광도법에 의한 분석)

  • Sohn, Joo-Hwan;Kim, Joo-Youn
    • Journal of the Korean Applied Science and Technology
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    • v.3 no.2
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    • pp.23-28
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    • 1986
  • The sulfuric acid sulfonation mixtures of 2-aminonaphthalene, contained 2-aminonaphthalene, Dahl's acid, Broenner's acid, amino-F-acid and Baden acid, can be determined quantitatively by multicomponent spectrophotometric analysis. The analysis was performed in diluted sodium hydroxide aqueous solution and based on the ultraviolet absorption of the sodium salts of each isomers. The determination of quantity of each isomers was performed by subjection the absorbances of the unknown mixture and of its constituents, gathered at a large number of wavelengths, to a least square treatment by an electronic personer computer. This method provided a rapid analysis of such complex mixture, and the standard deviation was ${\pm}1.65$ mole %.

Prediction and Representation of Boiling Points for Combustible Solution of Quaternary Systems (4성분계 가연성 혼합용액의 끓는점 예측 및 표현)

  • 김문갑;하동명;이영세
    • Journal of the Korean Society of Safety
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    • v.13 no.4
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    • pp.192-198
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    • 1998
  • MRSM(modified response surface methodology)-2 model is presented for the prediction of boiling points in combustible solution of quaternary systems. This model requires only normal boiling points of pure substances and group-group parameters which are based on the group-group concepts without the use of experimental data under consideration. By means of this methodology, it is possible to predict the boiling points of the combustible mixture of quaternary systems by plotting of isothermal lines using computer graphics. The proposed methodology has been tested and compared successfully with reported boiling points in journals for the combustible solution of quaternary systems. It is hoped eventually that this methodology will permit prediction of the flash point and flammability limit for the combustible mixture of multicomponent systems.

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Powder Injection Molding of Alumina Parts Using a Binder System Based in Paraffin Wax and High Density Polyethylene

  • Thomas-Vielma, P.;Cervera, A.;Levenfeld, B.;Varez, A.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.207-208
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    • 2006
  • In this experimental work, the development of a multicomponent binder system based on high density polyethylene (HDPE) and paraffin wax for Powder Injection Molding of Alumina $(Al_2O_3)$ parts was carried out. The optimum composition of the injection mixture was established through mixing torque measurements and a rheological study. The maximum powder loading was 58 vol%. The miscibility of organic components and the optimum injection temperature was evaluated by thermal characterization of binder and feedstock. The thermal debinding cycle was developed on the basis of thermogravimetrical analysis of the binder. After sintering the densities achieved were closed to 98% of the theoretical one.

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