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Characteristics of Expanded Graphite Filled Conductive Polymer Composites for PEM Fuel Cell Bipolar Plates

  • Oh, K.S.;Heo, S.I.;Yun, J.C.;Yang, Y.C.;Han, K.S.
    • Advanced Composite Materials
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    • v.17 no.3
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    • pp.259-275
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    • 2008
  • This study aims to optimize the mechanical and electrical properties of electrically conductive polymer composites (CPCs) for use as a material of bipolar plates for PEM fuel cells. The thin CPCs consisting of conductive fillers and polymer resin were fabricated by a preform molding technique. Expanded graphite (EG), flake-type graphite (FG) and carbon fiber (CF) were used as conductive fillers. This study tested two types of CPCs, EG/FG filled CPCs and EG/CF filled CPCs, to optimize the material properties. First, the characteristics of EG/FG filled CPCs were investigated according to the FG ratio for 7 and $100{\mu}m$ sized FG. CPCs using $100{\mu}m$ FG showed optimal material properties at 60 wt% FG ratio, which were an electrical conductivity of 390 S/cm and flexural strength of 51 MPa. The particle size was an important parameter to change the mechanical and electrical behaviors. The flexural strength was sensitive to the particle size due to the different levels of densification. The electrical conductivity also showed size-dependent behavior because of the different contributions to the conductive network. Meanwhile, the material properties of EG/CF filled CPCs was also optimized according to the CF ratio, and the optimized electrical conductivity and flexural strength were 290 S/cm and 58 MPa, respectively. The electrical conductivity of this case decreased similarly to the EG/FG filled case. On the other hand, the behavior of the flexural strength was more complicated than the EG/FG filled case, and the reason was attributed to the interaction between the strengthening effect of CF and the deterioration of voids.

Intracisternal Administration of Voltage Dependent Calcium Channel Blockers Attenuates Orofacial Inflammatory Nociceptive Behavior in Rats

  • Won, Kyoung-A.;Park, Sang-H.;Kim, Bo-K.;Baek, Kyoung-S.;Yoon, Dong-H.;Ahn, Dong-K.
    • International Journal of Oral Biology
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    • v.36 no.2
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    • pp.43-50
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    • 2011
  • Voltage dependent calcium channel (VDCC), one of the most important regulator of $Ca^{2+}$ concentration in neuron, play an essential role in the central processing of nociceptive information. The present study investigated the antinociceptive effects of L, T or N type VDCC blockers on the formalin-induced orofacial inflammatory pain. Experiments were carried out on adult male Sprague-Dawley rats weighing 220-280 g. Anesthetized rats were individually fixed on a stereotaxic frame and a polyethylene (PE) tube was implanted for intracisternal injection. After 72 hours, 5% formalin ($50 \;{\mu}L$) was applied subcutaneously to the vibrissa pad and nociceptive scratching behavior was recorded for nine successive 5 min intervals. VDCC blockers were administered intracisternally 20 minutes prior to subcutaneous injection of formalin into the orofacial area. The intracisternal administration of 350 or $700{\mu}g$ of verapamil, a blocker of L type VDCC, significantly decreased the number of scratches and duration in the behavioral responses produced by formalin injection. Intracisternal administration of 75 or $150 \;{\mu}g$ of mibefradil, a T type VDCC blocker, or 11 or $22\; {\mu}g$ of cilnidipine, a N type VDCC blocker, also produced significant suppression of the number of scratches and duration of scratching in the first and second phase. Neither intracisternal administration of all VDCC blockers nor vehicle did not affect in motor dysfunction. The present results suggest that central VDCCs play an important role in orofacial nociceptive transmission and a targeted inhibition of the VDCCs is a potentially important treatment approach for inflammatory pain originating in the orofacial area.

Development and Evaluation of Injury Prevention Education Proposal for Elementary School Children (학령기 아동의 사고예방 교육안 개발 및 평가)

  • Lee Jung-Eun;Kim Ji-Hyun;Kim Shin-Jeong
    • Child Health Nursing Research
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    • v.8 no.4
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    • pp.365-380
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    • 2002
  • This study was to develop and evaluate injury prevention education proposal which will helpful and can be utilized directly on the first line spot for elementary school children. Education proposal development and evaluation process was 1) Construction of 10-times education proposal contents proper to schooler 2) Testify validity through 3 pediatric nursing professor and 4 elementary school nurse 3) Pretest was done from March, 2002 to July on 3-6th grade 313 elementary school students 4) Through correction and revision after pretest evaluation meeting, final injury prevention education proposal was developed 5) After 10-times injury education, evaluation was carried out about the degree of help in education contents and general constitution of injury education to total subjects of educated children. Injury prevention education proposal consists of 10 times and each subjects are followings. 1st is 「introduction of injury prevention education and the importance of injury prevention」 2nd is「safety in and around home」, 3rd is 「injury prevention in school」, 4th is 「prevention of violence」, 5th is 「motor vehicle safety」, 6th is 「water safety」, 7th is 「prevention of fire and burns」, 8th is 「toy and product safety」, 9th is 「sports and recretional activities safety」and the final 10th is 「injury prevention caused by animals」. In the evaluation, the degree of help in education contents showed it helped to children averaged 1.66 and general constitution showed averaged 2.17 that children satisfied about developed injury prevention proposal. This study expected to provide systematic and concrete guidance in injury prevention education for elementary school children.

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A Study on Fuel Economy Determination of Natural Gas Vehicle Using Carbon Balance Method (탄소평형법을 적용한 천연가스 자동차의 연비 산출 방법 고찰)

  • Han, JeongOk;Chae, JungMin;Lee, DongWon
    • Journal of the Korean Institute of Gas
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    • v.21 no.6
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    • pp.1-7
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    • 2017
  • This study is aimed to investigate the US code and European code on the evaluation of fuel economy of natural gas vehicles and deduce the formula suitable for domestic natural gas fuel. The fuel consumption formula have been derived by carbon balance relation between fuel composition and exhaust emission. The US code does not limit the composition of the test gas, but European code should be used the reference gases such as G20 and G23. In the case of NGV using domestic city gas, it is confirmed that the fuel economy determined by European code is 12% worse than that of US code because of difference of test gas. Also, a method of determining the fuel properties from the calorific value is proposed to evaluate the fuel economy of natural gas vehicles.

Crack and Cutting Resistance Properties of Natural Rubber(NR) Compounds with Silica/Carbon Black Dual Phase Filler (Silica/Carbon Black이 충전된 NR 가황물의 내Crack 및 내Cutting 특성)

  • Son, Woo-Jung;Cho, Ur-Ryung;Kim, Won-Ho
    • Elastomers and Composites
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    • v.37 no.2
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    • pp.86-98
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    • 2002
  • The application of silica/carbon black dual phase fillers to natural rubber(NR) compound was investigated. When the amounts of filler content were restricted to 60phr, the optimum ratio of dual phase fillers were 25phr/35phr of silica/carbon black. It was found that these new fillers give better overall performance in comparison with carbon black in tear strength, crack resistance, and cutting resistance. Also the thermal degradation resistance of NR vulcanizates which were filled with dual phase fillers was better than that of the carbon black. Dual phase fillers filled NR vulcanizates showed better viscoelastic properties, like tan${\delta}$, for the wet skid resistance and rolling resistance of motor vehicle tires.

Oral and maxillofacial injuries in children: a retrospective study

  • Mukhopadhyay, Santanu;Galui, Sauvik;Biswas, Raju;Saha, Subrata;Sarkar, Subir
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.46 no.3
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    • pp.183-190
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    • 2020
  • Objectives: The purpose of this retrospective epidemiological study was to determine the etiology and pattern of maxillofacial injuries in a pediatric population. Materials and Methods: Data for pediatric maxillofacial trauma patients aged 12 years and younger who were registered at the Department of Pediatric and Preventive Dentistry, Dr. R. Ahmed Dental College and Hospital, Kolkata, India, were reviewed and examined. Patients who were treated between October 2016 and September 2018 were analyzed according to age, sex, cause of injury, frequency and site of facial fractures, and soft tissue injuries. The chi-square tests were carried out for statistical analyses with a significance level of 5%. Results: Of 232 patients with a mean age of 6.77±3.25 years, there were 134 males (57.8%) and 98 females (42.2%). The overall male to female ratio was 1.39:1. The most common causes of injuries were falls (56.5%) and motor vehicle accidents (16.8%). Incidence of falls decreased significantly with age (P<0.001). Dentoalveolar injuries (61.6%) and soft tissue injuries (57.3%) were more common than facial fractures (42.7%). Mandibular fractures (82.8%) were the most common facial fractures, and perioral or lip injuries were the most prevalent injuries in our patient population. There was a positive association between facial fractures and soft tissue injury (P<0.01) (odds ratio 0.26; confidence interval 0.15-0.46). Conclusion: Falls were the leading cause of maxillofacial trauma in our sample of children, and the most common site of fractures was the mandible.

Torque Predictive Control for Dynamic Performance Improvement of Clamping Force in EMB for Railroad Cars (철도 차량용 EMB의 클램핑 포스 과도응답 향상을 위한 토크 예측 제어)

  • Jang, Yoon;Bak, Yeongsu;Lee, Kyo-Beum
    • Journal of IKEEE
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    • v.21 no.3
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    • pp.174-184
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    • 2017
  • This paper proposes a torque predictive control for dynamic performance improvement of clamping force in electro-mechanical brake (EMB) for railroad cars. In general, pneumatic braking system (PBS) is used for railroad cars. It is sensitive depending on environmental changes and it has increasing idle running time because of slow dynamic response. Additionally, the PBS has low braking efficiency in case braking torque more than standard value is applied to the brake system such as emergency braking. In order to overcome these disadvantages of the PBS, the EMB is used for the railroad cars. The EMB for railroad cars has advantages that increasing the fuel efficiency and design flexibility because it is able to decrease vehicle weight of railroad cars and secure space for design. In this paper, control method for dynamic performance improvement of clamping force in EMB for railroad car is proposed. The effectiveness of the proposed control method is verified by the simulation results.

A Flexible Multi-body Dynamic Model for Analyzing the Hysteretic Characteristics and the Dynamic Stress of a Taper Leaf Spring

  • Moon Il-Dong;Yoon Ho-Sang;Oh Chae-Youn
    • Journal of Mechanical Science and Technology
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    • v.20 no.10
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    • pp.1638-1645
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    • 2006
  • This paper proposes a modeling technique which is able to not only reliably and easily represent the hysteretic characteristics but also analyze the dynamic stress of a taper leaf spring. The flexible multi-body dynamic model of the taper leaf spring is developed by interfacing the finite element model and computation model of the taper leaf spring. Rigid dummy parts are attached at the places where a finite element leaf model is in contact with an adjacent one in order to apply contact model. Friction is defined in the contact model to represent the hysteretic phenomenon of the taper leaf spring. The test of the taper leaf spring is conducted for the validation of the reliability of the flexible multi-body dynamic model of the taper leaf spring developed in this paper. The test is started at an unloaded state with the excitation amplitude of $1{\sim}2mm/sec$ and frequency of 132 mm. First, the simulation is conducted with the same condition as the test. Then, the simulations are conducted with various amplitudes in a loaded state. The hysteretic diagram from the test is compared with the ones from the simulation for the validation of the reliability of the model. The dynamic stress analysis of the taper leaf spring is also conducted with the developed flexible multi-body dynamic model under a dynamic loading condition.

Estimation of Source Apportionment of Ambient PM2.5 at Western Coastal IMPROVE Site in USA (미국 서부 해안 IMPROVE 측정소에 대한 대기 중 PM2.5의 오염원 기여도 추정)

  • Hwang, In-Jo;Kim, Dong-Sool;Hopke, Philip K.
    • Journal of Korean Society for Atmospheric Environment
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    • v.24 no.1
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    • pp.30-42
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    • 2008
  • In this study, the chemical compositions of $PM_{2.5}$ samples collected at the Redwood National Park IMPROVE site in California from March 1988 to May 2004 were analyzed to provide source identification and apportionment. A total of 1,640 samples were collected and 33 chemical species were analyzed by particle induced X-ray emission, proton elastic scattering analysis, photon induced X-ray fluorescence, ion chromatography, and thermal optical reflectance methods. Positive matrix factorization (PMF) was used to develop source profiles and to estimate their mass contributions. The PMF modeling identified five sources and the average mass was apportioned to motor vehicle (35.8%, $1.58\;{\mu}g/m^3$), aged sea salt (23.2%, $1.02\;{\mu}g/m^3$), fresh sea salt (21.4%, $0.94\;{\mu}g/m^3$), wood/field burning (16.1%, $0.71\;{\mu}g/m^3$), and airborne soil (3.5%, $0.15\;{\mu}g/m^3$), respectively. To analyze local source impacts from various wind directions, the CPF and NPR analyses were performed using source contribution results with the wind direction values measured at the site. These results suggested that sources of $PM_{2.5}$ are also sources of visibility degradation and then source apportionment studies derived for $PM_{2.5}$ are also used for understanding visibility problem.

A Study on Accident Prevention through Analysis of Industrial Drone Accidents and Their Causes (산업용드론 재해발생 특성과 원인분석을 통한 재해예방에 관한 연구)

  • Byun, Hyung Shik;Rhim, Jong Kuk
    • Journal of the Korean Society of Safety
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    • v.34 no.6
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    • pp.88-95
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    • 2019
  • It has been only a few years since drones have been introduced to Korea, and as the use of drones has increased in industrial sites as well as in hobby activities, accidents such as workers' body parts coming into contact with rotating propellers have been occurring since 2016. Industrial accident cases are being filed. In the case of a remote control vehicle, if you release the remote controller in the event of an abnormal situation, it stops in place and no further danger occurs but in case of drones flying over the sky is different. Sudden motor stops during flight, uncontrolled changes in flight posture, loss of radio waves, loose propeller, etc, numerous factors can lead to accidents due to unintentional movements. Therefore, drone operators need safety knowledge as well as high knowledge about drones. However, drones with a weight of less than 12 kg can fly without a pilot's certification, and therefore, a minimum accident prevention measure is required. 10 accidents approved as industrial accidents since 2016, 23 accidents surveyed by general drone operator, 40 accidents surveyed by the Korean Consumer Resources Unfortunately for the purpose of writing this paper, drones are a new species and do not have many parameters for analysis but my experience has shown that the type of disaster does not deviate significantly. In addition, there is no paper that analyzes drone related industrial accidents not only in Korea but also in other countries. However, even if you watch an overseas drone accident video through YouTube, it is not much different from the case that occurs in Korea. I hope that this study will be of little help to all the drone pilots as well as the work safety of industrial drones used in industrial sites.