• Proceedings of the KIEE Conference
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• 2004.11a
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• pp.220-222
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• 2004

The piezoelectric ceramics for a step-up piezoelectric transformer are desired large electromechanical coupling factor, high mechanical quality factor and good characteristic resonance frequency. In this study, the empirical formula of specimens is used $0.9Pb(Zr_xTi_{1-x})O_3-0.1Pb(Mn_{1/3}Nb_{1/3}Sb_{1/3})O_3$ (PZT-PMNS). The piezoelectric and dielectric characteristic are investigated by sintering temperature and value of x as functions of $Ti^{2+}$, $Zi^{2+}$ mol rate. MPB(morphotropic phase boundary) is defined in the x=0.522. Because it is appeared to the best piezoelectric and dielectric characteristic in the x=0.522, it can be application of step-up transformer.

• Proceedings of the KIEE Conference
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• 1999.07d
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• pp.1713-1716
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• 1999

PSN-PT 2성분계 압전세라믹스의 상도로부터 유전적, 압전적 특성이 양호한 MPB (Morphotropic phase boundary)부근의 조성을 선택하여 도너 도펀트인 $Nb_2O_5$와 억셉터 도펀트인 $Fe_2O_3$를 각각 $0{\sim}9wt%$ 첨가하여 유전특성을 비교, 연구해보았다 시편모두 $1250^{\circ}C$이상에서 이론밀도의 96%이상의 값을 얻을 수 있었고 상온, 1kHz에서 $Fe_2O_3$의 경우 0.1wt% 첨가된 시편에서 ${\varepsilon}_r=2054$의 최대 비유전율이 나타났으며, 0.7wt% 첨가된 시편에서는 $tan{\delta}$=0.49%의 최소 유전 손실값을 얻었다. 도펀트가 첨가됨에 따라 ${\varepsilon}_r$는 점점 감소하는 경향을 보였으며 큐리온도 Tc는 $Fe_2O_3$의 경우에서 더 큰 값이 나타났다. $Nb_2O_5$의 경우 도펀트의 증가에 따라 완만한 Relaxor의 형태로 나타났다.

• Proceedings of the KIEE Conference
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• 2004.07c
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• pp.1612-1614
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• 2004

The piezoelectric ceramics for AE-sensor are desired large electromechanical coupling factor, high mechanical quality factor and good characteristic resonance frequency. In this study, the empirical formula of specimens is used 0.9Pb$(Zr_xTi_{1-x})O_3-0.1Pb(Mn_{1/3}Nb_{1/3}Sb_{1/3})O_3$ (PZT-PMNS). The piezoelectric and dielectric characteristic are investigated by sintering temperature and value of x as functions of $Ti^{2+},\;Zi^{2+}$ moi rate. MPB(morphotropic phase boundary) is defned in the x=0.522. Because it is appeared to the best piezoelectric and dielectric characteristic in the x=0.522, it can be application of AE sensor. PZT-PMNS ceramics without pre-amplifier and filter are tested for AE-signal of PD and arc detecting. The detection characteristic is evaluated wave form, frequency distribution.

• Proceedings of the KIEE Conference
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• 2001.11a
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• pp.100-102
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• 2001

In this paper, the piezoelectric and dielectric properties of $Pb(Zr_xTi_{1-x)O_3$ - $Pb(Co_{1/3}Nb_{1/3})O_3)$ piezoelectric ceramics have been investigated as a function of Zr/Ti mole ratio. From the results, when Zr/Ti mole ratio is 49/51, electromechanical coupling coefficient($k_p$), piezoelectric strain constant($d_{33}$) mechanical quality factor($Q_m$), and Permittivity(${{\varepsilon}_{33}}^T/{\varepsilon}_0$) is 64[%], 469[PC/N], 360 and 2000, respectively. Morphotropic Phase Boundary is Zr/Ti mole ratio(49/51) from XRD analysis. Also. From SEM observation, when sintering temperature is 1150[$^{\circ}C$], grain size is about $1{\sim}2[{\mu}m]$ and maximum sintering density is 7.85[$g/cm^3$].

• Proceedings of the KIEE Conference
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• 1997.07d
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• pp.1326-1329
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• 1997

In this paper, PNN-PZN-PZT ceramics were fabricated with various mole ratio of the PZT[$Pb(Zr_{1/2}Tid_{1/2})O_3$]. PNN [$Pb(Ni_{1/3}Nb_{2/3})O_3$] and PZN[$Pb(Ni_{1/3}Nb_{2/3})O_3$ powders prepared by double calcination and PZT powders prepared by molten-salt synthesis method. The formation rate of perovskite phase in PNN-PZN-PZT ceramics could be obtained about 92% at PZT 0.3 mole ratio. The relative permittivity of specimen with PZT 0.3 mole ratio was shown 5,320 and appeared the relaxor ferroelectric feature. The maximum piezoelectric coefficient $d_{31}$ to be used for evaluation the displacement of piezoceramics in PNN-PZN-PZT ceramics was $324{\times}10^{-12}$(C/V) at the vicinity of morphotropic phase boundary and was larger than that of solid PZT ceramics($120{\times}10^{-12}C/V$).

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.07a
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• pp.689-692
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• 2001

In this paper, the pizoelectric and dielectric properties of 0.95Pb(ZrxTil-x)O$_3$- 0.05Pb(Mn$\_$0.2/Fe$\_$0.4/W$\_$0.4/)O$_3$piezoelectric ceramics is investigated as a function of Zr/Ti mole ratio. Also, MPB(Morphotropic Phase Boundary) and optimal sintering temperature is studied using XRD and SEM. As a results, when Zr/Ti mole ratio is 52/48, electromechanical coupling factor, k$\_$p/, is 58[%], permittivity, $\varepsilon$$\^$T/$\_$33//$\varepsilon$0, is 1360 and piezoelectric strain constant, d$\_$33/ is 265[pC/N] and the piezoelectric and dielectric properties become maximum. Phase transition temperature of its ternary piezoelectric system is about 350[$^{\circ}C$]. From the XRD analysis, when Zr/Ti mole ratio is 52/48, tetragonal phase transits to rhombohedral phase. Also, From measuring results of the sintering density, when sintering temperature is 1050[$^{\circ}C$], sintering density become maximum and is about 7930[kg/㎥], and average grain size is about 2-3[$\mu\textrm{m}$].

• Proceedings of the Materials Research Society of Korea Conference
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• 2011.05a
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• pp.30.1-30.1
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• 2011

Multiferroic thin films with composition $0.9BiFeO_3-0.1Ba(Cu_{1/3}Nb_{2/3})O_3$ were epitaxially grown by pulsed laser deposition on $SrRuO_3(001)/SrTiO_3$ (000) substrate $0.9BiFeO_3-0.1Ba(Cu_{1/3}Nb_{2/3})O_3$, which is assumed to be morphotropic phase boundary (MPB), that showed superior dielectric, ferroelectric and magnetic properties in our study on polycrystalline films. The structures of epitaxially grown films were characterized by means of XRD. From P-E measurements, samples exhibited typical ferroelectric hysteresis loops and large remnant polarization, whose value is much larger than those of pure BFO film. The enhancement of dielectric, ferroelectric, magnetic properties was attributed to the structural distortion induced by the BCN addition and the high physical stress effect.

• Ceramist
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• v.23 no.1
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• pp.101-109
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• 2020

In this study, the phase transition behaviors of lead-free (Na_1/2Bi_1/2TiO₃)_(1-x)-(BaTiO₃)_x (NBT-BT) are investigated by using Brillouin spectroscopy. The elastic properties, sound velocity and absorption coefficient of NBT-BT are characterized as a function of temperature along different crystallographic axes. The temperature dependences of the elastic constants of NBT-BT near the morphotropic phase boundary are determined for the first time. The unpoled NBT-BT single crystals exhibits the typical relaxor behaviors, presenting broad acoustic and dielectric anomalies. The application of electric field induced discontinuous changes in the elastic properties at ~110℃, which indicates field-induced phase transition occurred. The electric field also changes the dielectric constant from more relaxor-like to ferroelectric-like dielectric behavior.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.15 no.10
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• pp.858-864
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• 2002

Aging stabilities of the operating frequency of piezoelectric devices such as filter, oscillator and discriminator are very important. In this study it was studied aging stabilities of the length-extensional vibration mode of Pb(Zr$\^$y/O$_3$+ x[wt%]Cr$_2$Co$_3$ ceramics. PZT ceramics in morphotropic phase boundary have higher aging rates of k$\_$31/ and resonance frequency than those in tetragonal phase or rhombohedral phase. Thermal aging moves the composition with maximum aging rate to Zr-rich side in Cr$_2$O$_3$ not added PZT system. In the PZT system, aging rates of k$\_$31/ and resonance frequency for first 30 days are bigger than those for the following 90 days. Thermal aging decrease those for first 30 days. Aging rate of resonance frequency of the ceramics with x=0.1, y=0.53 and x=0.3, y=0.53 increased by thermal aging.

• Journal of the Korean Ceramic Society
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• v.34 no.2
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• pp.175-180
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• 1997

새로운 복합페로브스카이트계 고용체 (1-x)Ba(Mg1/3Ta2/3)O3-xLa(Mg2/3Ta1/3)O3(x=0.0-1.0)를 설계하고 조성에 따른 고용체의 결정구조의 변화 및 MPB(Morphotropic Phase Boundary)를 분말 XRD를 이용하여 분석하였다. 초격자회절선의 변화로부터 MBT에 10mol%의 LMT를 치환함에 따라 1:2에서 1:1로의 규칙화타입의 전이가 일어남을 알 수 있었다. 면심입방정구조 영역(0.10.8조성의 경우, 주회절선의 피이크분리 및 새로운 회절선들로부터 격자비틀림의 형태가 단사정임을 알 수 있었다.