• Bulletin of the Korean Chemical Society
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• v.33 no.5
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• pp.1443-1444
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• 2012

• Economic and Environmental Geology
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• v.13 no.2
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• pp.117-127
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• 1980

Molybdenum as by-products of Sangdong tungsten mine occurrs in the form of molybdenite in quartz vein. The molybdenum contents of scheelite in Sangdong ore bodies ranges from trace to 8%, therefore the scheelites show variable fluorescence colores under ultra-violet lamp (short wave). The fluorescence color are in order high content of molybdenum, yellow, white and blue. The yellow fluorescing scheelite is dominant in upper ore vein, otherwise the blue fluorescent variety is dominant in lower ore vein. The fluorescence color of scheelite in the main ore vein show zonal distribution becoming progressively more blue outerwards, contrary more yellow innerwards, and even in single scheelite crystal, simillar zonal pattern is observed, too. Molybdenite occurrs as flakes or elongated blades at the margins of the quartz vein only molybdenite bearing quartz veins but also other sulfides mineral bearing quartz veins have mainly blue flourescing scheelites. We suggest that the molybdenum contents of the early stage ore solution are progressively decreased by a subsequent crystallization of the yellow fluorescing scheelites.

• YAKHAK HOEJI
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• v.18 no.3
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• pp.190-196
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• 1974

A new colorimetric method established for the determination of ampicillin was based on the reductions of phosphomolybdic acid by ampicillin to be resutled in a molybdenum blue which showed a mezimal absorbance at 770nm. The pH effects on a molybodenum blue solution was dependent significantly on temeprature, but the wave-length shift was not effected by the molybdenum blue.

• Journal of the Korean Chemical Society
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• v.8 no.3
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• pp.113-120
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• 1964

The critical examination of the spectrophotometric method for determining microgram quantities of phosphate by the n-butyl acetate extraction as molybdophosphoric acid and subsequent development of the molybdenum blue has been made. In this procedure from 2 to 8 ${\mu}g$. of phosphate-phosphorus can be determined under optimum conditions. The final concentration of ammonium molybdate and the final acidity of perchloric acid for the formation of heteropoly acid are suitable to be ranges of 0.5 to 1.1% and 0. 5 to 1. 1 N respectively, and subsequently extracted with 10 ml. of n-butyl acetate. The extract is developed to molybdenum blue with 5.0 ml. of 1. 3% stannous chloride in 1N hydrochloric acid. The color is stable for at least one hour in the use of perchloric acid for the condensation. In order to determination of submicrogram amounts of phosphate, the sensitivity of the molybdenum blue method is hardly sufficient, a sensitive and stable molybdenum(V)-thiocyanate complex method has been investigated. By the procedure less than 1.2 ${\mu}g$. of phosphate-phosphorus can be determined with an accuracy of less than 5% the relative error. The molybdenum(Ⅵ) extracted by the above procedure is reduced to molybdenum(V) in the extract directly with a solution of 4 to 10% of stannous chloride, 0.5 to 1.5 mM of copper, and 0.1 to 0.9 N of perchloric acid as final concentration in 4.3 to 6.3 N of hydrochloric acid or 9.0 to 13.0 N of sulfuric acid by heating for one minute in boiling water, after cooling, the molybdenum(V)-thiocyanate complex color is developed by adding 6.0 M ammonium thiocyanate solution making the final concentration to be in a range of 0.4 to 0.9 M. This procedure the very sensitive, reliable, and stable can be applied to determining submicrogram amounts of phosphate in natural waters with a precision of 1.6 ${\times}\;10^{-2}$ the standard deviation as absorbance.

• 한국정보디스플레이학회:학술대회논문집
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• 2007.08b
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• pp.1411-1414
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• 2007

We have developed a top-emitting white organic electroluminescent device (TWOLED) incorporating a low-reflectivity molybdenum (Mo) anode and doped transport layers as well as a dual-layer architecture of doped blue and yellow emitters with the same blue host. The EL efficiency and operational lifetime of TWOLED can be enhanced by a factor of 1.2 and 3.4 than that of standard TWOLED, respectively, with a co-doping technology in yellow emitter by doping another blue dopant. The enhancement in device performances can be attributed to improve the energy transfer efficiency from blue host to yellow dopant through a blue dopant as medium in yellow emitter.

• 한국정보디스플레이학회:학술대회논문집
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• 2008.10a
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• pp.1350-1352
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• 2008

Research on down conversion phosphor materials is the key for the development of solid state lighting (SSL). Especially finding alternative red phosphor for white LEDs based on blue or NUV LEDs are important research task. Under this view, we have synthesized a series of $Eu^{3+}$ substituted $La_2W_{2-x}Mo_xO_9$ (x = 0 ~ 2, insteps of 0.1) red phosphor and characterized by X-ray diffraction (XRD) and photoluminescence. XRD results reveal a phase transition from triclinic to cubic structure for $x\;{\geq}\;0$. All the compositions show broad charge transfer band due to charge transfer from oxygen to tungsten/molybdenum and red emission due to $Eu^{3+}$ ions. Select compositions show high red emission intensity compared to the commercial red phosphor under NUV/blue ray excitation. Hence, this candidate can be possible red emitting phosphors for white LEDs.

• 한국정보디스플레이학회:학술대회논문집
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• 2009.10a
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• pp.820-822
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• 2009

Tandem white organic light emitting diodes (WOLEDs) are fabricated by using a transparent interconnecting layer of Al:LiF composite/molybdenum oxides ($MoO_3$). We demonstrate two types of tandem WOLEDs consisting of two color emissions (red and blue emission) and three color emissions (red, green and blue emission). Tandem WOLED consisting of three color emission shows higher external quantum efficiency and current efficiency.

• Bulletin of the Korean Chemical Society
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• v.34 no.8
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• pp.2348-2352
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• 2013

We report a simple electrochemical approach in fabricating multiple colored molybdenum (Mo) oxide bronzes on the surface of a Mo-quartz electrode. A three step electrochemical batch process consisting of linear sweep voltammetry and anodic oxidation followed by cathodic reduction in neutral $K_2SO_4$ electrolyte at different end potentials, viz. -0.62, -0.80 and -1.60 V (vs. $Hg/HgSO_4$) yielded red, blue and yellow colored bronzes. The samples produced were analyzed by XRD, EDS, and SIMS. The color variation was suggested to be associated with the cations intercalation into the oxide formed and the simultaneous structural changes that occurred during the cathodic reduction in neutral aqueous medium.

• Journal of the Korean Professional Engineers Association
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• v.3 no.10
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• pp.3-6
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• 1970

The scheelite occurred in Sang Dong mine are disseminated with a fine grain, and shelved pale blue or white color under the fluorescence. But among them, We can often observe the yellow fluorescent color mineral grains, which were called the powellite from the past time without any detail mineral study. I studied the characteristics of Sang-Dong scheelite and the so called powellite. In the result, the so called powellite is proved to be the molybdenum bearing scheelite in the view of specific gravity, index of refraction, chemical composition, other microscopic properties, and dressing. Such a scheelite is contained usually Zor 3% Mo, and oftenly 4 or 6% Mo, and fluorescent colors are pale yellow, leman yellow and chrome yellow.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1994.11a
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• pp.179-182
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• 1994

We have investigated the optical and electrochromic properties of molybdenum oxide(MoO$_3$) films by thermal evaporation. The MoO$_3$films deposited at substrate temperatures below 200$^{\circ}C$ are found to be amorphous and annealed films at temperature 300$^{\circ}C$ for 1 hour in air are crystalline. The optical energy gap calculated from the transmittance and reflectance spectra of MoO$_3$ films is near 2.75 eV and 3.25 eV for amorphous films and crystalline films, respectively. The MoO$_3$ thin films exhibit light blue to dark blue optical modulation on lithium intercalation and have a uniform transmittance modulation over a wavelength range of 300∼1100 nmcompared to tungsten oxide films.