• Journal of Powder Materials
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• v.17 no.4
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• pp.312-318
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• 2010

High speed steels (HSS) were used as cutting tools and wear parts, because of high strength, wear resistance, and hardness together with an appreciable toughness and fatigue resistance. Conventional manufacturing process for production of components with HSS was used by casting. The powder metallurgy techniques were currently developed due to second phase segregation of conventional process. The powder injection molding method (PIM) was received attention owing to shape without additional processes. The experimental specimens were manufactured with T42 HSS powders (59 vol%) and polymer (41 vol%). The metal powders were prealloyed water-atomised T42 HSS. The green parts were solvent debinded in normal n-Hexane at $60^{\circ}C$ for 24 hours and thermal debinded at $N_2-H_2$ mixed gas atmosphere for 14 hours. Specimens were sintered in $N_2$, $H_2$ gas atmosphere and vacuum condition between 1200 and $1320^{\circ}C$. In result, polymer degradation temperatures about optimum conditions were found at $250^{\circ}C$ and $480^{\circ}C$. After sintering at $N_2$ gas atmosphere, maximum hardness of 310Hv was observed at $1280^{\circ}C$. Fine and well dispersed carbide were observed at this condition. But relative density was under 90%. When sintering at $H_2$ gas atmosphere, relative density was observed to 94.5% at $1200^{\circ}C$. However, the low hardness was obtained due to decarbonization by hydrogen. In case of sintering at the vacuum of $10^{-5}$ torr at temperature of $1240^{\circ}C$, full density and 550Hv hardness were obtained without precipitation of MC and $M_6C$ in grain boundary.

• Composites Research
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• v.12 no.5
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• pp.31-39
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• 1999

Glass-fiber reinforced polymeric composites provide the desitable properties of high stiffness and strength as well as specific weight. Hence, they have become some of the most important materials in several industries. These composites can be grouped into thermoplastic and thermoset composites, with thermoplastic composites having several advantages over thermoset composites in mechanical properties and processing. As a result, the study of the material behavior and forming techniques of such composites has attracted considerable attention in recent years. When the continuous fiber-reinforced polymeric composites are molded by flow molding, the molded parts leads to be nonhomogeneity and anisotropic because of the separation and orientation of fibers. As the characteristics of the products are greatly dependent on the separation, it is very important to clarify the separation in relarion to molding conditions, fiber mat structures and mold geometry. In this study, the effects of the mold geometry and the fiber mat structure on the compression moldability are studied using the cup-type molding.

• Korean Chemical Engineering Research
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• v.58 no.1
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• pp.44-51
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• 2020

The basic catalyst 1-benzyl-3-methyl-imidazolium hexafluoroantimonate (BMH) was synthesized and analyzed by FT-IR and ¹H-NMR. A crystalized biphenyl-based epoxy was synthesized by using tetramethyl biphenol (TMBP) and epichlorohdrine. In order to consider the curing tendency of the synthesized BMH, the mass ratio was changed to 0.5, 1.0, 2.0 wt.% under heated conditions and the curing tendency was analyzed by differential scanning calorimeter (DSC). As a result, the BMH catalyst showed a fast curing result in the stepwise heating pr℃ess of the biphenol-A epoxy and the cationic polymer. From these results, the BMH catalyst showed excellent thermal stability as a potential heat curing catalyst. In addition, we considered the application possibility of epoxy molding compound (EMC) which required a skeleton structure and a high heat resistance because the synthesized biphenyl epoxy had a characteristic of rapidly lowering viscosity at a constant temperature and a rigid skeleton structure of biphenol. As a result, it was confirmed that the TMBP-based epoxy developed in this study was composed of a crystalline structure, and a curing reaction was observed with a Novolac resin at a high temperature. In the presence of a catalyst, a curing reaction was observed around 150 ℃ and thus TMBP-based epoxy was successfully applied as a raw material of EMC.

• Journal of Applied Reliability
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• v.7 no.4
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• pp.173-181
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• 2007

Out door exposure to daylight and weather climate conditions can cause adverse effect on the properties of automotive plastic materials. The effects of sunlight exposure, especially ultra violet (UV) radiation, can break down the chemical bonds in a polymeric material. This degradation process is called photo-degradation and ultimately leads to color changes, cracking, chalking, the loss of physical properties and deterioration of other properties. To explore the effect of sunlight exposure on the automotive materials, this study investigated photo-oxidation degree and surface property change of molding parts by analytical methods. For the further study, accelerated weathering test methods are proposed, which can correlate with out door weathering, to predict long term performance of automotive plastic materials.

• Transactions of Materials Processing
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• v.17 no.7
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• pp.496-500
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• 2008

Plastics is commonly used in consumer electronics because of it is high strength per unit mass and good productivity. But plastic parts are usually distorted after injection molding due to the residual stress after filling, packing, cooling process, and etc. And plastic material is to be deteriorated according to various temperature conditions and operating time, which can be characterized by stress relaxation and creep. The viscoelastic behavior of plastic materials in time domain can be expressed by the Prony series of the commercial code, ABAQUS. In the paper, the process to predict the post deformation under cyclic thermal loadings was suggested. The process was applied to the real panel, and the deformation predicted by the analysis was compared with that of real test, which showed the possibility of applying the suggested process to predict the post deformation of plastic product under thermal loadings.

• Journal of Surface Science and Engineering
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• v.35 no.3
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• pp.113-120
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• 2002

Injection molded plastic parts have many surface defects. These include a weld line, sink mark, flow mark, gloss, shading, scratching etc. Because these surface faults are not aesthetically acceptable, plastic parts are produced through painting or texturing. The purpose of this paper is to develop paintless molded parts using a flow control method. Computer aided injection mold filling simulations were used in order to minimize the number of defects from injection molding. Based on the numerical results, FR(Flame Retardant) HIPS was developed and the guidelines for part design, mold design, and the processing conditions were established. The effects of cost savings, improvements in productivity, and recycling were considered by reducing the number of surface faults and eliminating the painting process.

• Journal of the Korean Society for Precision Engineering
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• v.15 no.12
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• pp.97-105
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• 1998

The fiber oriented condition inside fiber reinforced composite material is a basic factor of mechanical properties of composite materials. It is very important to meausure the fiber orientation angle for the determination of molding conditions, mechanical characteristics, and the design of composite materials. In the work, the fiber orientation distribution of simulation figure plotted by PC is measured using image processing in order to examine the accuracy of intersection counting method. The fiber orientation function measured by intersection counting method using image processing is compared with the calculated fiber orientation function. The results show that the measured value of fiber orientation function using intersection counting method is lower than the calculated value, because the number of intersection between the scanning line and the fiber with smaller fiber aspect ratio is counted less than with larger fiber aspect ratio.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 1995.10a
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• pp.659-663
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• 1995

The fiber oriented conditied inside fiber reinforced composite material is a basic factor of mechanical properties of composite materials. It is very important to measure the fiber orientation angel for the determination of molding conditions, mechanical charactistics, and the design of composite materials. In the work, the fiber orientation distribution of simulation figure plotted by PC is measured using image processing in order to examine thr accuracy of intersection counting method. The fiber orientation function measured by intersection countingmethod using image processing is compared with the calculated fiber orientation function. The results show that the measured value of fiber orientation function using intersection counting method is lower than the calculated value, because the number of intersection between the secant line and the fiber with smaller fiber aspect ratio is counted less than with larger fiber aspect ratio.

• Tribology and Lubricants
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• v.5 no.2
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• pp.94-100
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• 1989

Friction and Wear behavior of continuous graphite fiber composites was studied for different fiber orientations against the sliding direction. The effect of fiber orientation on friction and wear of the composite and on the deformation of the counterface was investigated experimentally. Pin on disk type testing machine was built and employed to generate the friction and wear data. A graphite fiber composite plate was produced by the bleeder ply molding in an autoclave and machined into rectangular pin specimens with specific fiber orientations, i.e., normal, transverse, and longitudinal directions. Three different wear conditions were employed for two different periods of time, 24 and 48 hours. The wear track of the worn specimens and the metal counterface was examined with a scanning electron microscope (SEM) to observe the damaged fibers on the surface and wear film generation on the counterface. Wear mechanism of the composite during sliding wear is proposed based on the experimental results.

• Transactions of Materials Processing
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• v.15 no.1 s.82
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• pp.42-46
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• 2006

For mass production, usually injection mold has multi-cavity which is filled through geometrical balanced runner system. Despite geometrical balanced runner system, filling imbalances between cavity to cavity have always been observed. These filling imbalances are one of the most significant factors to affect quality of plastic parts. Filling imbalances are results from non-symmetrical shear rate distribution within melt when it flows through tile runner system. It has been possible to decrease filling imbalance by optimizing processing conditions, but it has not completely eliminated this phenomenon during injection molding processing. This paper presents a solution for these filling imbalances by using Runner Core pin (RC pin). The Runner Core pin which is developed in this study creates a symmetrical shear distribution within runner. As a result of using Runner Core pin, a remarkable improvement in reducing filling imbalances was confirmed.