• Title/Summary/Keyword: Moisture constant

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Electrochemical Synthesis of Ammonia from Water and Nitrogen using a Pt/GDC/Pt Cell (Pt/GDC/Pt 셀을 이용한 물과 질소로부터 전기화학적 암모니아 합성)

  • Jeoung, Hana;Kim, Jong Nam;Yoo, Chung-Yul;Joo, Jong Hoon;Yu, Ji Haeng;Song, Ki Chang;Sharma, Monika;Yoon, Hyung Chul
    • Korean Chemical Engineering Research
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    • v.52 no.1
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    • pp.58-62
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    • 2014
  • Electrochemical ammonia synthesis from water and nitrogen using a Pt/GDC/Pt cell was experimentally investigated. Electrochemical analysis and ammonia synthesis in the moisture-saturated nitrogen environment were performed under the operating temperature range $400{\sim}600^{\circ}C$ and the applied potential range OCV (Open Circuit Voltage)-1.2V. Even though the ammonia synthesis rate was augmented with the increase in the operating temperature (i.e. increase in the applied current) under the constant potential, the faradaic efficiency was decreased because of the limitation of dissociative chemisorption of nitrogen on the Pt electrode. The maximum synthesis rate of ammonia was $3.67{\times}10^{-11}mols^{-1}cm^{-2}$ with 0.1% faradaic efficiency at $600^{\circ}C$.

Effects of Aging and Soil Texture on Composting of Diesel-Contaminated Soil (디젤오염기간 및 토성이 오염토양 콤포스팅 처리에 미치는 영향)

  • Choi, Jung-Young;Namkoong, Wan;Park, Joon-Seok;Hwang, Eui-Young
    • Journal of the Korea Organic Resources Recycling Association
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    • v.10 no.2
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    • pp.132-139
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    • 2002
  • This study was carried out to investigate the effects of aging and soil texture on composting of diesel-contaminated soil. The soils used for this study were silt loam and sand. Target contaminant, diesel oil, was spiked at 10,000mgTPH/kg of dry soil. Aging times of diesel-contaminated soils were 15days and 60days, respectively. Fresh diesel-contaminated soil was also investigated. Moisture content was controlled to 70% of soil field capacity. Mix ratio of soil to sludge was 1:0.3 as wet weight basis. Temperature was maintained at $20^{\circ}C$ Volatilization loss of TPH was below 2% of initial concentration. n-Alkanes lost by volatilization were mainly by the compounds of C10 to C17. Diesel in contaminated soil was mainly removed by biodegradation mechanism. First order degradation rate constant of TPH in sandy soil was ranged from 0.081 to 0.094/day, which is higher than that in silt loam(0.056-0.061/day). From fresh to 60day-aged soils, there was little difference of TPH biodegradation rate between the soils. Carbon recovery ranged from 0.61 to 0.89. TPH degradation rate was highly correlated with $CO_2$ production rate.

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Quality Characteristics of Traditional Kochujang Adding Pear Juices during Fermentation (배즙을 첨가한 전통고추장의 숙성과정 중 품질특성)

  • Yoo, Mi-Young;Jung, Kwon-Hyug;Yang, Ji-Young
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.34 no.8
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    • pp.1226-1231
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    • 2005
  • In order to improve qualities of traditional kochujang, pear juice was added to kochujang, and the physicoche-mical and microbial characteristics of pear-added kochujang were investigated for 2 months of fermentation at 30$^{\circ}C$. Moisture contents of pear-added kochujangs increased except of 9$\%$ pear-added kochujang and crude protein contents of them decreased as the fermentation proceeded. Total sugar contents of pear-added kochujangs did not change during the fermentation period, and reducing sugar contents of them increased remarkably from early stage of fermentation. The pH of pear-added kochujangs decreased and titratable acidity of them increased during fermentation. Amino-nitrogen contents of pear-added kochujangs increased remarkable after 45 days of fermentation. Viable cells counts of yeasts in pear-added kochujangs increased to 2.2$\∼$2.9$\times$$10^{3}$CFU/g, and bacterial cell counts were in relatively constant range of 2.1$\∼$2.9$\times$$10^{7}$CFU/g at the late stage of fermentation. Color of pear-added kochujangs had no difference and 'a' value decreased slightly during fermentation. The result of sensory evaluation showed that 6$\%$ pear added kochujang were more acceptable than others.

Rheological Properties of Gelatinized Model Foods (모형식품의 리올로지 특성)

  • Chun, Ki-Chul;Park, Young-Deok;Chang, Kyu-Seob
    • Korean Journal of Agricultural Science
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    • v.22 no.1
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    • pp.103-109
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    • 1995
  • The model foods were prepared by simulating mositure, protein and starch, and they were heated for 30 mins, at $80^{\circ}C$ and then cooled at $25^{\circ}C$ in water bath. Their rheological properties were investigated by the use of Brookfield wide-gap rotational viscometer at $30{\sim}60^{\circ}C$, and the rotation speed ranged from 0.6 to 6 rpm and solid content ranged from 8% to 11%, the results obtained were as follows. 1. All the model foods ($P_1S_3$, $P_2S_2$, $P_1S_1$, $P_2S_1$, $P_3S_1$, $P_4S_0$) exhibited pseudoplastic behaviors with yeild stress and were thixotropic foods which showed time - dependent structural decays, but the starch food of 8 ~ 11 % solid content did not show the flow behavior. 2. The correlation between the rheological parameters and the protein content of model foods in various moisture content did not appeared a constant relationship. 3. The change of shear stress against shear rate in high starch foods was larger than that in high protein foods and the structure at initial shear time was decayed with a quatic equation according to the Tiu's Model and structural decay was in parallel with the increase of shear rate. 4. The temperature dependency of the apparent viscosity of $P_1S_2$, and $P_2S_1$ was fully expressed by Arrhenius equation and activation energies of their food were 2.35 and $1.34Kcal/g{\cdot}mol$, respectively.

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Studies on Optimum Cooking Conditions for Commercial Continuous Rice Cooker (대량연속취반장치에서 최적 취반조건 연구)

  • Lee, Eun-Young;Jung, Jin-Hoon;Shin, Hae-Hun;Lee, Seok-Hoon;Pyun, Yu-Ryang
    • Korean Journal of Food Science and Technology
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    • v.32 no.1
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    • pp.90-96
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    • 2000
  • The optimum cooking conditions for large scale continuous gas cooker were studied with three varieties of rice. Optimum soaking time for the cooker was estimated to be 30 min at cooking temperature above $20{\circ}C$, while 60 min at cooking temperature below $10{\circ}C$. The ratio of water-to-milled rice giving the best eating quality was founded to be $1.41{\sim}1.48$, and corresponding moisture content of cooked rice ranged from 60 to 62% for different rice varieties. The optimum ratio of water to milled rice. (Chucheong) decreased from 1.50 to 1.37 with increase in the amount of milled rice from 4.0 to 6.5 kg in a cooking vessel. However, actual water uptake by rice (g water absorbed per g rice) on cooking was nearly constant value of 1.13, which means that evaporated water during cooking increases with decreasing the amount of rice in a cooking vessel.

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The Diffusion of Boron from Borate Rod through Pinus densiflora and Pinus koraiensis (소나무와 잣나무에서 붕산염 막대로부터 붕소의 확산)

  • Oh, Choong-Sup;Kim, Jae-Jin;Kim, Gyu-Hyeok
    • Journal of Conservation Science
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    • v.7 no.2
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    • pp.60-67
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    • 1998
  • The effects of moisture content (MC) and diffusion period on the diffusion of boron from borate rod through Pinus densiflora and P. koraiensis were investigated as a preliminary research of integrated remedial treatment for heritage wooden structures using borate rod. After equilibrating MCs of samples (15, 25, and 40%), borate rod (1,000 mg) was inserted into the sample, and stored for diffusion of boron at room temperatures ($23^{\circ}C$) for 2, 4, 8, and 12 weeks. Wafers were serially cut at constant intervals from rod treatment point and the boron penetration through longitudinal and transverse direction was measured by staining with boron indicator. For boron diffusion, MC above fiber saturation point was needed, and the diffusion rates increased with time. The fastest rates of diffusion were observed in longitudinal direction, followed by the radial and then the tangential direction. The rates of diffusion in all directions were the fastest in P. koraiensis. In P. densiflora, the diffusion rates through heartwood was faster than that in sapwood in longitudinal direction and vice versa in transverse direction. Based on the best result of this study, optimal space between rod insertion points could be recommended as follows; approximately 120 mm for P. koraiensis and heartwood of P. densiflora, 60 mm for sapwood of P. densiflora in longitudinal direction, and approximately 30 mm for all species tested in transverse direction. However, the effect of rod size and long-term exposure for diffusion on boron movement should be fully investigated for the accurate evaluation of optimal space between rod holes.

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Thin Layer Drying Model of Sorghum

  • Kim, Hong-Sik;Kim, Oui-Woung;Kim, Hoon;Lee, Hyo-Jai;Han, Jae-Woong
    • Journal of Biosystems Engineering
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    • v.41 no.4
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    • pp.357-364
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    • 2016
  • Purpose: This study was performed to define the drying characteristics of sorghum by developing thin layer drying equations and evaluating various grain drying equations. Thin layer drying equations lay the foundation characteristics to establish the thick layer drying equations, which can be adopted to determine the design conditions for an agricultural dryer. Methods: The drying rate of sorghum was measured under three levels of drying temperature ($40^{\circ}C$, $50^{\circ}C$, and $60^{\circ}C$) and relative humidity (30%, 40%, and 50%) to analyze the drying process and investigate the drying conditions. The drying experiment was performed until the weight of sorghum became constant. The experimental constants of four thin layer drying models were determined by developing a non-linear regression model along with the drying experiment results. Result: The half response time (moisture ratio = 0.5) of drying, which is an index of the drying rate, was increased as the drying temperature was high and relative humidity was low. When the drying temperature was $40^{\circ}C$ at a relative humidity (RH) of 50%, the maximum half response time of drying was 2.8 h. Contrastingly, the maximum half response time of drying was 1.2 h when the drying temperature was $60^{\circ}C$ at 30% RH. The coefficient of determination for the Lewis model, simplified diffusion model, Page model, and Thompson model was respectively 0.9976, 0.9977, 0.9340, and 0.9783. The Lewis model and the simplified diffusion model satisfied the drying conditions by showing the average coefficient of determination of the experimental constants and predicted values of the model as 0.9976 and Root Mean Square Error (RMSE) of 0.0236. Conclusion: The simplified diffusion model was the most suitable for every drying condition of drying temperature and relative humidity, and the model for the thin layer drying is expected to be useful to develop the thick layer drying model.

Development of Standard Analysis Methods for Physical Properties on Korean Bedsoil 2. Water content, Water retention, Saturated hydraulic conductivity (우리나라 상토의 물리적 표준분석법 설정 연구 2. 수분함량, 보수력, 포화수리전도도)

  • Kim, Lee-Yul;Jung, Kang-Ho;Ro, Hee-Myong
    • Korean Journal of Soil Science and Fertilizer
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    • v.35 no.6
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    • pp.335-343
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    • 2002
  • Methods of bedsoil analysis were difficult to be applied universally because use and material of bedsoil are diverse from country to country. Korean Standard Methods for Bedsoil Analysis was developed to measure the water content, water retention, and saturated hydraulic conductivity. Fifty-three samples for horticultural bedsoil and nine samples for paddy rice bedsoil in the current market were collected. Water content of bedsoil was determined using gravimetric method through $105^{\circ}C$ oven-dry for 16 hours, but different calculations between horticultural and paddy rice bedsoils were chosen according to different predominant component, plant residue or mineral. Water content percentage of horticultural bedsoil was calculated as [(weight of sample before oven-dry - weight of sample after oven-dry)/(weight of sample before oven-dry)]${\times}100$, while that of paddy rice bedsoil as [(weight of sample before oven-dry - weight of sample after oven-dry)/(weight of sample after oven-dry)]${\times}100$. Water retention was measured at water potential -0.5, -1, -3, -5, -7, -10 kPa by Sandbox method and saturated hydraulic conductivity was measured by constant head method using acryl cylinder (${\Phi}5cm{\times}L\;20cm$). By new 'Korean Standard Methods of Bedsoil Analysis', the average water content of horticultural bedsoil was obtained 46.34%(w/w) and that of paddy rice bedsoil 16.89%. For horticultural bedsoil, easily available water(EAW), water buffering capacity(WBC), and optimal matric potential(OMP) was estimated at 28.4%, 7.01%, and -5.60 kPa, respectively. Optimal moisture content was 44.41% and average saturated hydraulic conductivity for bedsoils was estimated at $28.4cm\;min^{-1}$.

Quality Characteristics of Ginger(Zingiber officinale Roscoe) as the Ripening Periods (생강(Zingiber officinale Roscoe)의 숙성기간에 따른 품질특성)

  • Lee, Myung-Hee;Kim, Kyung-Tack;Lee, Kyoung-Hae
    • Journal of Food Hygiene and Safety
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    • v.27 no.4
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    • pp.479-486
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    • 2012
  • This study was conducted to demonstrate quality characteristics of ginger by making aged ginger( AG) with two methods, the frist method was that ginger was aged at constant temperature and humidity chamber for the duration of 10, 20 and 30 days, and the other method was drying the ginger just after steaming it for 3 hours. As the age was being processed, the volume of ginger's appearance decreased rapidly and its color seemed to be darker because of the decrease in moisture. In the case of general components, the content of crude ash was depended on aged periods while the content of crude fat was independent with aged periods, and according to the content of crude protein, there was not any significant differences. The main valuable ingredient which is 6-gingerol showed the decreasing trend as it was exposed to heat with more time, and 6-shogaol which is also one of the main valuable ingredients showed high content at T-II(AG-10days). Free sugar and free amino acid of AG decreased as aged period goes by, and this study found that there were lots of essential amino acid (threonine, glutamic acid, alanine, valine, leucine and tyrosine) in ginger. The amount of unsaturated fatty acid of AG was significantly higher than the amount of saturated fatty acid of AG with the approximate ratio of 60:40, and the amount of free fatty acid of AG did not seem any big differences between AG and none AG. Considering both valuable ingredients and nutritive components, T-I (steamed ginger, SG) and T-II which was aged for 10 days were evaluated excellently.

Influence of Grass Cover on Water Use and Shoot Growth of Young 'Fuji'/M.26 Apple Trees at Three Soil Water Regimes in Double Pot Lysimeters (토양수분영역을 달리한 double pot-lysimeter에서 자라는 '후지'/M.26 사과나무의 수분이용과 신초 생장에 미치는 잔디피복의 영향)

  • Ro, Hee-Myong
    • Korean Journal of Soil Science and Fertilizer
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    • v.32 no.4
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    • pp.357-364
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    • 1999
  • This study measures the influence of grass cover on water use and shoot growth of apple trees growing under different soil water regimes in temperate climate conditions and evaluates monthly crop coefficients of such conditions during four months of the growing season in 1995. To do so, double pot lysimeter experiments of 3-year-old Fuji' apple (Males domestica Borkh.) trees under a transparent rain shield were designed and installed. Trees were triplicate under three soil water regimes: (A) drip-irrigation at -50 kPa of soil matric potential (IR50). (B) drip-irrigation at -80 kPa of soil matric potential (IR80), and (C) constant shallow water table at 0.45 m below the soil surface (WT45). In each treatment, two soil surface conditions were tested: the soil surface bare, and covered with turf grasses. Mean monthly water use increased with increasing soil matric potential for drip irrigation and was greatest in the WT45 treatment. Monthly crop coefficients increased linearly in time for drip-irrigated apple trees ($r^2$ values of $0.953^{***}$ for turf grass-covered system and of $0.862^{***}$ for bare surface system), while those obtained in the WT45 treatment fluctuated, Duncan's multiple range tests for shoot growth showed that grass-covered IR50 was most favorable to apple trees. while bare surface waterlogged situation was most adverse at least in part due to a lack of oxygen in the root zone. Mid-season leaf Kjeldahl-N was higher in drip-irrigated apple trees than in WT45 trees, while soil Kjeldahl-N was not different irrespective of treatments.

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