• 한국산학기술학회논문지
• /
• 제16권10호
• /
• pp.7182-7188
• /
• 2015

최근 수기에 의한 맵핑 방식을 탈피하고자 고해상도 카메라, 레이저스캐너 등의 장비를 이용한 디지털 맵핑에 대한 관심이 높아지고 있으며 관련 연구도 보고된바 있다. 본 연구에서는 고해상도 화상기술이 연동된 레이저스캐너를 활용하여 굴진면의 공학적 특징 중 하나인 풍화도를 정량적으로 분석 및 산출하고자 실내 및 현장시험을 수행하였다. 레이저스캐너의 반사율(reflectance)값과 풍화도의 상관관계를 분석하고자 현장테스트를 통해 반사율에 영향을 미치는 인자를 파악하였다. 또한 반사율에 영향을 미치는 주요 인자 중 하나인 색상값(RGB value)에 대한 영향을 최소화하고자 실내테스트를 통해 보정식을 제안하였다. 본 연구에서 제안된 보정식은 실제 현장에서 취득한 스캐닝 데이터를 이용하여 보정 전과 후의 결과를 비교하여 검증하였다. 검증결과 보정 반사율 값을 통해 산정된 풍화도 index는 현장에서 관찰된 우세 풍화도 등급 및 풍화도 비율 등과 매우 유사한 결과를 보이는 것으로 확인되었다.

• 한국광학회지
• /
• 제14권3호
• /
• pp.266-271
• /
• 2003

수 $\mu\textrm{m}$ 이상의 두께를 가지는 비교적 두꺼운 박막의 경우 박막에 의한 간섭효과로 인하여 나타나는 반사율 스펙트럼에서의 진동주기로부터 막의 두께를 얻는다. 대개 빠른 데이터 처리를 위해서 고속 푸리에 변환(Fast Fourier Transformation, FFI)을 사용하여 진동주기(또는 진동수)를 구한다. 본 연구에서는 반사율 또는 투과율 스펙트럼을 빛의 에너지 축상에서 푸리에 변환하는 종래의 방법을 개선하여 박막의 굴절률 분산을 반영하는 수정된 고속 푸리에 변환 방법을 최초로 도입하였다. 이 새로운 방법은 굴절률 분산에서 유래하는 유효굴절률 결정에서의 오차를 줄여주고 푸리에 변환 피크의 폭 넓어짐을 막아줌으로써 막 두께 결정의 정밀도를 크게 향상시킨다. 수정된 고속 푸리에 변환방법을 80 $\mu\textrm{m}$의 덮게층과 13 $\mu\textrm{m}$의 사이층이 있는 시료의 반사 스펙트럼에 적용하여 고 타당성을 확인하였다.

• Food Science and Biotechnology
• /
• 제14권2호
• /
• pp.280-285
• /
• 2005

Applicability of near infrared reflectance spectroscopy (NIRS) was examined for quality control of red pepper powder in milling factories. Prediction of chemical composition was performed using modified partial least square (MPLS) techniques. Analysis of total 51 and 21 red pepper powder samples by conventional methods for calibration and validation, respectively, revealed standard error of prediction (SEP) and correlation coefficient ($R^2$) of moisture content, ASTA color value, capsaicinoid content, and total sugar content were 0.55 and 0.90, 8.58 and 0.96, 31.60 and 0.65, and 1.82 and 0.86, respectively; SEP and $R^2$ were low and high, respectively, except for capsaicinoid content. The results indicate, with slight improvement, on-line quality measurement of red pepper powder with NIRS could be applied in red pepper milling factories.

• Food Science and Biotechnology
• /
• 제18권1호
• /
• pp.60-65
• /
• 2009

Near infrared reflectance spectroscopy (NIRS) was used as a rapid and non-destructive method to determine the protein content in intact and ground seeds of pea (Pisum sativum L.) germplasms grown in Korea. A total of 115 samples were scanned in the reflectance mode of a scanning monochromator at intact seed and flour condition, and the reference values for the protein content was measured by auto-Kjeldahl system. In the developed ground and intact NIRS equations for analysis of protein, the most accurate equation were obtained at 2, 8, 6, 1 math treatment conditions with standard normal variate and detrend scatter correction method and entire spectrum (400-2,500 nm) by using modified partial least squares regression (n=78). External validation (n=34) of these NIRS equations showed significant correlation between reference values and NIRS estimated values based on the standard error of prediction (SEP), $R^2$, and the ratio of standard deviation of reference data to SEP. Therefore, these ground and intact NIRS equations can be applicable and reliable for determination of protein content in pea seeds, and non-destructive NIRS method could be used as a mass analysis technique for selection of high protein pea in breeding program and for quality control in food industry.

• 한국유기농업학회지
• /
• 제13권3호
• /
• pp.281-289
• /
• 2005

In order to find out an alternative way of analysis of food waste compost, the Near Infrared Reflectance Spectroscopy(NIRS) was used for the compost assessment because the technics has been known as non-detructive, cost-effective and rapid method. One hundred thirty six compost samples were collected from Incheon food waste compost factory at Namdong Indurial Complex. The samples were analyzed for nitrogen, organic matter (OM), ash, P, and K using Kjedahl, ignition method, and acid extraction with spectrophotometer, respectively. The samples were scanned using FOSS NIRSystem of Model 6500 scanning mono-chromator with wavelength from $400\~2,400nm$ at 2nm interval. Modified partial Least Squares(MPLS) was applied to develop the most reliable calibration model between NIR spectra and sample components such as nitrogen, ash, OM, P, and K. The regression was validated using validation set(n=30). Multiple correlation coefficient($R^2$) and standard error of prediction(SEP) for nitrogen, ash, organic matter, OM/N ratio, P and K were 0.87, 0.06, 0.72, 1.07, 0.68, 1.05, 0.89, 0.31, 0.77, 0.06, and 0.64, 0.07, respectively. The results of this experiment indicates that NIRS is reliable analytical method to assess some components of feed waste compost, also suggests that feasibility of NIRS can be Justified in case of various sample collection around the year.

• 한국염색가공학회지
• /
• 제28권2호
• /
• pp.63-69
• /
• 2016

Poly(butylene terephthalate)(PBT) surface was modified by UV/ozone irradiation and the effect of UV energy on the surface properties of the irradiated PBT films were characterized by the reflectance, surface roughness, contact angles, ESCA, and ATR analyses of the film surface. The surface reflectance, at the short wavelength of visible spectrum of particularly 400nm, decreased with increasing UV energy. And the irradiation roughened the film surface uniformly in the nano scale. The maximum surface roughness increased from 110nm for the unirradiated sample to 303nm at the UV energy of $10.6J/cm^2$. The surface energy of PBT film increased from $50.5mJ/m^2$ for the unirradiated PBT to $58.8mJ/m^2$ at the irradiation of $21.2J/cm^2$. The improvement in hydrophilicity was caused by the introduction of polar groups containing oxygens such as C-O and C=O bonds resulting in higher $O_{1s}/C_{1s}$. The increased dyeability of the modified film to cationic dyes may be resulted from the photochemically introduced anionic and dipolar dyeing sites on the PBT films surfaces.

• 한국염색가공학회지
• /
• 제18권6호
• /
• pp.49-56
• /
• 2006

Surface treatment using UV irradiation was carried out to improve optical properties of polarizing films. The effects of UV energy of the UV-treated PVA films were investigated by measuring reflectance, surface roughness, contact angles, ESCA, and ATR. Reflectance decreased at wavelength of 450 nm or less and surface roughness increased with increasing UV energy. Water contact angle increased in the irradiated PVA films and surface energy decreased with increase in w energy. An analysis showed that the OH groups were broken and some new groups were introduced such as C=C and C=O bonds together with increased $O_{1s}/C_{1s}$, resulting in the observed surface modification effect. Surface modified PVA polarizing films showed improvement in light transmittance of polarizing films at high wavelength region without deteriorating polarization efficiency, which was not affected by UV irradiation sequence during manufacturing processes such as coloring and drawing.

• Bulletin of the Korean Chemical Society
• /
• 제35권2호
• /
• pp.392-396
• /
• 2014

New organic-inorganic composite of 2,4-dihydroxybenzophenone (BP-1) encapsulation into dodecylbenzenesulfonate (DBS) modified layered double hydroxide (LDH) was successfully prepared. The surface, structural, thermal and absorption properties of the BP-1/DBS-LDH nanohybrid was characterized by BET analysis, scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TG) and diffuse reflectance UV-Vis absorbance spectra (DRUV-vis). The interlayer configuration of composite and the adsorption mechanism of BP-1 on MgAl-DBS-LDH were discussed. It was suspected that DBS anions located in the form of monolayer arrangement with a $75^{\circ}$ anti parallel angle between dodecylbenzenesulfonate chain axis. The diffuse reflectance UV-Vis absorbance results revealed that the UV absorbing wavelength of BP-1/DBS-LDH evidently extends to about 400 nm, which shows that the BP-1/DBS-LDH has the potential application as a UV absorber.

• Macromolecular Research
• /
• 제12권6호
• /
• pp.608-614
• /
• 2004

Isotactic polypropylene (PP) surfaces were modified with argon and oxygen plasmas using a radio­frequency (RF) glow discharge at 240 mTorr and 40 W. The changes in topography and surface structure were investigated by atomic force microscopy (AFM) in conjunction with specular reflectance of infrared (IR) microspectroscopy. Under our operating conditions, the AFM image analysis revealed that longer plasma treatment resulted in significant ablation on the PP surface, regardless of the kind of plasma employed, but the topography was dependent on the nature of the gases. Specular reflectance IR spectroscopic analysis indicated that the constant removal of surface material was an important ablative aspect when using either plasma, but the nature of the ablative behavior and the resultant aging effects were clearly dependent on the choice of plasma. The use of argon plasma resulted in a negligible aging effect; in contrast, the use of oxygen plasma caused a noticeable aging effect, which was due to reactions of trapped or isolated radicals with oxygen in air, and was partly responsible for the increased surface area caused by ablation. The use of oxygen plasma is believed to be an advantageous approach to modifying polymeric materials with functionalized surfaces, e.g., for surface grafting of unsaturated monomers and incorporating oxygen-containing groups onto PP.

• 한국작물학회지
• /
• 제51권spc1호
• /
• pp.304-309
• /
• 2006

Near infrared reflectance spectroscopy (NIRS) was used to develop a rapid and nondestructive method for the determination of fatty acid composition in sesame (Sesamum indicum L.) seed oil. A total of ninety-three samples of intact seeds were scanned in the reflectance mode of a scanning monochromator, and reference values for fatty acid composition were measured by gas-liquid chromatography. Calibration equations were developed using modified partial least square regression with internal cross validation (n=63). The equations obtained had low standard errors of cross-validation and moderate $R^2$ (coefficient of determination in calibration). Prediction of an external validation set (n=30) showed significant correlation between reference values and NIRS estimated values based on the SEP (standard error of prediction), $r^2$ (coefficient of determination in prediction) and the ratio of standard deviation (SD) of reference data to SEP. The models developed in this study had relatively higher values (more than 2.0) of SD/SEP(C) for oleic and linoleic acid, having good correlation between reference and NIRS estimate. The results indicated that NIRS, a nondestructive screening method could be used to rapidly determine fatty acid composition in sesame seeds in the breeding programs for high quality sesame oil.