• Journal of the Semiconductor & Display Technology
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• v.22 no.3
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• pp.46-51
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• 2023

We investigated the MoS₂ thin film layer by thermolytic deposition and applied it to the silicon solar cells. MoS₂ thin films were made by two methods of dipping and spin coating of (NH₄)₂MoS₄ precursor solution. We implemented two types of substrates of microtextured and nano-microtextured 6-in. Si pn junction wafers. The fabricated MoS₂ thin film layer was analyzed, and solar cells were fabricated by applying the standard silicon solar cell process. The MoS₂ thin film layer of sulfur-deficient form was deposited on the n-type emitter layer, and electrons, which are minority carriers, were well transported at the interface and exhibited photovoltaic solar cell characteristics. The cell efficiencies were achieved at 5% for microtextured wafers and 2.56% for nano-microtextured wafers.

• Tribology and Lubricants
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• v.12 no.3
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• pp.107-114
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• 1996

MoS$_{2}$ bonded film was applied to reduction gears, and its lubricating properties were experimentally evaluated in terms of the power transmission efficiency and the frictional noise with a dynamo-typed gear test rig. Tests were performed in both oil lubrication and dry condition where the rotating velocity and loading torque were varied. In dry condition, MoS$_{2}$ bonded films effected the power transmission efficiency to increase about 5%, and the frictional noise level to decrease about 6 dB under the test operating conditions. It well proved that MoS$_{2}$ bonded films were a very effective solid lubricant for reduction gears. In oil lubricating conditions, the frictional properties of the coated gears were mainly governed by the lubricating oil, and lubricating effects of MoS2 bonded films were not evident. The result suggested that lubricating effect of MoS$_{2}$ bonded films would be limited to prevent a damage of reduction gears in the initial run when they were used in oil lubrication conditions.

• Proceeding of EDISON Challenge
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• 2014.03a
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• pp.439-441
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• 2014

단층 $MoS_2$는 현재 트랜지스터나 LED등에 활용을 연구중인 물질이다. 단층 $MoS_2$의 밴드구조는 약 1.8eV의 직접 밴드갭을 보이는 반도체로 알려져있다. 이 물질을 소자에 활용할 때 고유의 1.8 eV 직접 밴드갭을 이용한다. 다양한 분야에 소자로 응용되기 위해서는 밴드갭을 조절이 필요하다. 그래서 $MoS_2$의 밴드갭을 조절하는 연구가 행해져 왔는데 그 중 하나가 수소흡착 방법이다. 수소를 단층 $MoS_2$에 흡착시키면 금속 밴드구조를 보인다고 알려져 있다. 본 연구에서는 DFT (Density Functional Theory) 계산을 통하여 밴드갭을 조절하는 다른 방법 중에 하나인 역학적인 힘에 의해 전기적인 특성의 변화에 대한 기초연구를 진행하였다. 단층 $MoS_2$에 in-plane 방향으로 isotropic strain을 주었을 때 밴드갭이 0.68 eV에서 1.89 eV까지 변하는 것을 확인했다. 우리는 단층 $MoS_2$는 약간의 strain에도 밴드갭크기가 다소 많이 변할 뿐만 아니라 직접 밴드갭이 간접 밴드갭으로 변하는 것을 보였다. 심지어 10%정도 strain을 주면 금속으로 변할 것으로 예상된다. 밴드갭이 변하는 성질을 이용하여 센서등 여러 어플리케이션에 단층 $MoS_2$를 활용할 수 있을 것으로 예상된다.

• Korean Journal of Materials Research
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• v.32 no.1
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• pp.30-35
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• 2022

The development of advanced materials to improve the efficiency of photoelectrochemical (PEC) water splitting paves the way for widespread renewable energy technologies. Efficient photoanodes with strong absorbance in visible light increases the effectiveness of solar energy conversion systems. MoS₂ in a two-dimensional semiconductor that has excellent absorption performance in visible light and high catalytic activity, showing considerable potential as an agent of PEC water splitting. In this study, we successfully modulated the MoS₂ morphology on indium tin oxide substrate by using the metalorganic chemical vapor deposition method, and applied the PEC application. The PEC photocurrent of the vertically grown MoS₂ nanosheet structure significantly increased relative to that of MoS₂ nanoparticles because of the efficient transfer of charge carriers and high-density active sites. The enhanced photocurrent was attributed to the efficient charge separation and improved light absorption of the MoS₂ nanosheet structure. Meanwhile, the photocurrent property of thick nanosheets decreased because of the limit imposed by the diffusion lengths of carriers. This study proposes a valuable photoelectrode design with suitable nanosheet morphology for efficient PEC water splitting.

• Applied Chemistry for Engineering
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• v.30 no.2
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• pp.133-140
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• 2019

Two-dimensional (2D) ultrathin molybdenum dichalcogenides $MoS_2$ has gained a great deal of attention in energy conversion and storage applications because of its unique morphology and property. The 2D $MoS_2$ nanosheets provide a high specific surface area, 2D charge channel, sub-nanometer thickness, and high conductivity, which lead to high electrochemical performances for energy storage devices. In this paper, an overview of properties and synthetic methods of $MoS_2$ nanosheets for applications of supercapacitors and rechargeable batteries is introduced. Different phases triangle prismatic 2H and metallic octahedral 1T structured $MoS_2$ were characterized using various analytical techniques. Preparation methods were focused on top-down and bottom-up approaches, including mechanical exfoliation, chemical intercalation and exfoliation, liquid phase exfoliation by the direct sonication, electrochemical intercalation exfoliation, microwave-assisted exfoliation, mechanical ball-milling, and hydrothermal synthesis. In addition, recent applications of supercapacitors and rechargeable batteries using $MoS_2$ electrode materials are discussed.

• Bulletin of the Korean Chemical Society
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• v.19 no.11
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• pp.1211-1216
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• 1998

Bis(diethyldithiocarbamato)ioxomolybdenum(VI), cis-MoO2(S2CNEt2)2, 1, reacted with chlorotrimethylsilane (Me33SiCl) to give a seven-coordinate, pentagonal bipyramidal complex MoOC12(S2CN]Et2)2, 3, in which the oxo ligand is trans to the chloride ligand and the two chloride ligands are mutually cis. The monooxo molybdenum complex bis(diethyidithiocarbamato)oxomolybdenum(IV), MoO(S2CNEt2)2, 2, reacted with phenyl isocyanate (PhNCO) to give an Mo dimer MO2{μ-N(CONPh)Ph}(μ-NPh)(NPh)2(S2CNEt2)2, 4, which contains an Mo-Mo bond, two diethyldithiocarbamato ligands, two terminal imido (NPh) ligands, and two bridging hnido (NPh) ligands. One of the two bridging NPh ligands seemed to have been attacked by the electrophilic phenyl isocyanate carbon, which suggests that the bridging imido NPh ligand is more nucleophilic than the terminal one. Crystallographic data for 3: monoclinic space group P21/c, a=8.908(l) Å, b=17.509(3) Å, c=12.683(2) Å, β=110.15(1)°, Z=4, R(wR2)=0.0611(0.1385). Crystallographic data for 4-THF: orthorhombic space group P212121, a=17.932(4) Å, b=22.715(5) Å, c=11.802(3) Å, Z=4, R(wR2)=0.0585(0.1286).

• Journal of the Korean institute of surface engineering
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• v.39 no.2
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• pp.70-75
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• 2006

As technology advances, there is a demand for development of hard, solid lubricant coating. (Ti,Cr)N-$MoS_2$, films were deposited on SKD 11 tool steel substrate by co-deposition of $MoS_2$, with (Ti,Cr)N using a D.C. magnetron sputtering process. The influence of the $N_2/Ar$ gas ratio, the deposition temperature, the amount of $MoS_2$ in the films, and the bias voltage on the mechanical and the structural properties of the films were investigated. Wear tests were performed on the films deposited in various conditions.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.222.2-222.2
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• 2016

트랜지스터 응용 등에 관한 연구가 활발해 지면서 에너지 밴드갭이 0 eV에 가까운 그래핀 이외의 밴드 갭 조절이 가능한 MoS2 (molybdenum disulfide), BN (boron nitride), Bi2Te3 (bismuth telluride), WS2 (tungsten disulfide) 등과 같은 이차원 Transition Metal DiChalcogenides (TMDC) 물질이 반도체 물질로 각광받고 있다. 특히 MoS2의 경우 단결정 덩어리 상태에서는 약 1.3 eV의 밴드갭을 가지나 두께가 줄어들어 두 층일 경우에는 약 1.65 eV, 단일층이 되면 약 1.9 eV의 밴드갭을 가져 박막 층수에 따라 에너지 밴드갭 조절이 가능한 것으로 알려져있다. 하지만 두께 조절이 가능하면서 대면적, 고품질을 가지는 MoS2 박막 합성은 아직 제한적이라 할 수 있으며 새로운 방법 및 물질에 대한 연구가 지속적으로 이루어 지고 있다. 따라서 본 연구에서는 다양한 층수를 지니는 MoS2 합성을 위해 나노 두께의 MoS2 박막을 CF4 plasma 를 이용하여 layer etching 진행하고 CF4 plasma 100초 etching 진행한 2 layer 두께의 MoS2를 기준으로 H2S plasma를 이용하여 treatment 진행하였다. 물리적, 화학적 분석은 Raman spectroscopy, XPS(X-ray Photoelectron Spectroscopy), AFM (Atomic Force Microscopy) 등을 이용해 진행하였고 이를 통해 MoS2 layer 감소 및 damage recovery 등을 확인하였다.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2004.11a
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• pp.60-65
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• 2004

[ $MoS_2S$ ] is a well-known metal sulfide applied as solid lubricants and an additive to prolong the life of sintered bearings under severe conditions. However, the high price of $MoS_2S$ limited its wide application. This study is aimed to investigated the possibility for application to solid lubricants for $Cu_2S$ as a substitute of v. Bronzes added $Cu_2S$ and $MoS_2S$ are produced by powder metallurgy in this study, and then evaluated their friction and wear properties. The sliding wear test using pin-on-disc type machine, was conducted at several sliding speeds for three type test pieces, bronze and bronzes added $Cu_2S/MoS_2$. Addition of $Cu_2S$ to bronze leads to relatively good friction and wear properties, although it is not so good as addition of $MoS_2S$. But the properties of bronze added $Cu_2S/MoS_2$ would be not suitable for the condition under the high sliding speed.

• Bulletin of the Korean Chemical Society
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• v.34 no.10
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• pp.3033-3038
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• 2013

Nanoscale Chevrel $Mo_6S_8$ powders are synthesized by molten salt synthesis. Synthesized $Mo_6S_8$ powders have different mean particle sizes which are dependent on a ratio of salt to precursor. The particle sizes of $Mo_6S_8$ powders changes along with the ratio increase. $Mo_6S_8$ (6:1) demonstrates the best electrochemical characteristics among the synthesized $Mo_6S_8$ powders although the $Mo_6S_8$ (4:1) has the smallest particle size. $Mo_6S_8$ (6:1) shows a reversible capacity of 83.9 $mAhg^{-1}$, which is 27.5% and 33% improved value over $Mo_6S_8$ (2:1) and $Mo_6S_8$ (4:1) at a current density of 0.2C, respectively. The superior electrochemical properties of $Mo_6S_8$ (6:1) are attributed to the balanced particle size which provides proper contact area with electrolyte and the shortened $Mg^{2+}$ diffusion length. The $Mo_6S_8$ (4:1) has the smallest particle size but further reduction of particle size from $Mo_6S_8$ (6:1) is not advantageous.