• Title/Summary/Keyword: MoM

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Magnetic Properties of ${\alpha}-Fe$ Based Nd-Fe-B Melt-Spun Alloys (${\alpha}-Fe$ 기 Nd-Fe-B 급속응고합금의 자기특성)

  • 조용수;김윤배;박우식;김희태;김창석;김택기
    • Journal of the Korean Magnetics Society
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    • v.4 no.2
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    • pp.122-125
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    • 1994
  • The magnetic properties of Nd-Fe-B alloys of containing 4 at.% Nd have been studied for the development of new type rare-earth magnets. The amorphous phase of a melt-spun $Nd_{4}Fe_{85.5}B_{10.5}$ alloy is transformed into the phases which have a small amount of $Nd_{2}Fe_{14}B_{1}$ in ${\alpha}-Fe$ matrix by annealing above their crystallization temperature. The addition of Mo, Nb, V or Cu to $Nd_{4}Fe_{85.5}B_{10.5}$ alloy results in the reduction of grain size and the sub¬sequent improvement of the coercivity. The coercivity of $Nd_{4}Fe_{82}B_{10}M_{3}Cu_{1}$(M = Mo, Nb, V) alloys increases in the order of M = V < Nb < Mo and shows the highest value of 2.7 kOe when M = Mo. On the other hand, the rem¬anence of these alloys shows the opposite trend and the rn>st improved value of 1.35 T is observed when M = V.

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A Rice Blast Fungus Alpha-N-Arabinofuranosidase B Elicits Host Defense in Rice

  • Kim, Sun-Tae
    • 한국균학회소식:학술대회논문집
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    • 2015.11a
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    • pp.23-23
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    • 2015
  • Rice blast disease caused by M. oryzae is the most devastating fungal disease in rice. During the infection process, M. oryzae secretes a large number of glycosyl hydrolase (GH) proteins into the apoplast to digest host cell wall and assist fungal ingress into host tissues. In this study, we identified a novel M. oryze arabinofuranosidase B (MoAbfB) which is secreted during fungal infection. Live-cell imaging exhibited that fluorescent labeled MoAbfB was highly accumulated in fungal invasive structures such as appressorium, tips of penetration peg, biotrophic interfacial complex (BIC), as well as invasive hyphal tip. Deletion of MoAbfB mutants extended biotrophic phase followed by enhanced disease severity, whereas, over-expression of OsMoAbfB mutant induced rapid defense responses and enhanced rice resistance to M. oryzae infection. Furthermore, exogenous treatment of MoAbfB protein showed inhibition of fungal infection via priming of defense gene expression. We later found that the extract of MoAbfB degraded rice cell wall fragments could also induce host defense activation, suggesting that not MoAbfB itself but oligosaccharides (OGs) derived from MoAbfB dissolved rice cell wall elicited rice innate immunity.

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Metal-Dinitrosyl Complexes(III) : Synthesis and Structural Study of Homo-, Hetero-dinuclear Molybdenum and Tungsten Complexes, $[Cl(phen)(NO)_2M({\mu}-pyz)M'(NO)_2(phen)Cl][ClO_4]_2 $(phen = 1,10-phenanthroline, pyz = pyrazine) (금속-디니트로실 착물 (제 3 보) : 몰리브덴과 텅스텐의 호모 및 헤테로 이핵 착물, $[Cl(phen)(NO)_2M({\mu}-pyz)M'(NO)_2(phen)Cl][ClO_4]_2 (phen=1,10-phenanthroline,\;pyz=pyrazine)$의 합성 및 구조에 대한 연구)

  • Sang-Oh Oh;Seong-Jong Mo
    • Journal of the Korean Chemical Society
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    • v.37 no.7
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    • pp.655-661
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    • 1993
  • The neutral monomeric compounds $[Mo(NO)_2Cl_2(phen)]$ and $[W(NO)_2Cl_2(phen)]$ (phen= 1,10-phenanthroline) have been prepared by reactions of polymeric compounds $[{Mo(NO)_2Cl_2}n],\;[{W(NO)_2Cl_2}n]$ with chelate ligands. Additions of one equivalent of silver(I) perchlorate to these cis-dinitrosyl compounds in acetone solution produce $[Mo(NO)_2(phen)(S)Cl][ClO_4]\;and\;[W(NO)_2(phen)(S)Cl][ClO_4]$ (S = acetone). The homo- and hetero-dinuclear complexes, $[Cl(phen)(NO)_2M(pyz)M'(NO)_2(phen)Cl][ClO_4]_2$ (M = Mo, W) and $[Cl(phen)(NO)_2M(pyz)M'(NO)_2(phen)Cl][C1O_4]_2$ (M = Mo, M' = W) have been prepared by these monocationic complexes with pyrazine ligand respectively. These complexes characterized by elemental analysis, $1^H-\;and\;^{13}C-NMR$, infrared, and UV-visible spectroscopy are reported. The spectral data indicate that homo- and hetero-dinuclear complexes were symmetrical structures of $C_{2v}$.

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Determination of Trace Mo(VI) in Seawater Samples by Ion Pair Formation and Solvent Extraction (이온쌍 형성-용매추출에 의한 해수 중 극미량 Mo(VI)의 정량)

  • Kim, Young-Sang;Nho, Seung-Gu;Choi, Jong-Moon
    • Analytical Science and Technology
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    • v.6 no.3
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    • pp.329-334
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    • 1993
  • The formation of Mo(VI)-alizarin red S chelate ion its extraction into an organic solvent by ion-pairing for the separarive determination of trace Mo(VI) in natural water was applied in seawater samples. Removed Fe(III) and Zn(II), and Cu(II) by precipitating with anthranilic acid at pH 4.0 and 2.0, seawater 100mL was sampled in 250mL separatory funnel. After Mo(VI)-ARS chelate ion was formed by adding 0.01M alizarin red S solution 1.0mL to the water sample of pH 4.6, 0.6% aliquat-336 chloroform solution 10mL was added and the solution was vigorously shaked for about 30 seconds to form the ion-pair between Mo(VI)-ARS and aliquat-336 perfectly. The solution was stood for about 30 minutes. And the organic phase was taken for the absorbance measurement of the ion-pair at 520nm. The content of Mo(VI) was obtained from the standard calibration curve. Several extraction conditions such as pH, adding amounts of alizarin red S and aliquat-336, and shaking and standing times were optimized and the interferences and release of concomitant ions was also studied. This procedure was applied to the analysis of Eastern and Yellow seawaters. It could be confirmed from the recoveries of over 85% in samples spiked with a given amount of Mo(VI) that this method was also quantitative in the determination of trace Mo(VI) in a seawater.

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Implementation of a RangeBased MoM under Regional Registration (지역등록기법 기반 RangeBased MoM)

  • Song, SungHak;Yoo, Chyuck
    • Proceedings of the Korea Information Processing Society Conference
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    • 2004.05a
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    • pp.1393-1396
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    • 2004
  • 모바일 환경에서 멀티캐스트를 구현하는 방법으로 대표적인 방법으로는 원격가입(MIP-RS)와 양방향 터널링(MIP-BT)이 있으며 이의 단점을 보완한 MoM이 제안되었다. 하지만 터널링 경로가 최적으로부터 멀어지는 현상을 처리하지 못함에 따라 이를 해결하기 위해 터널링 범위에 제한을 가하는 RB MoM이 제안되었다. RB MoM의 경우 터널링 경로의 조절은 가능할 수 있었으나 이동호스트의 이동에 따른 HA 등록 등과 같은 등록메시지의 양은 줄일수는 없었다. 따라서 본 논문에서는 RB MoM의 장점인 터널링 경로 조절기능을 살리면서 이동호스트의 이동에 따른 등록메시지를 줄이고 GFA의 터널링 부하를 분산시키기 위해 멀티캐스트 터널링 범위에 제한을 둔 지역등록 기법을 제안하였다.

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Evaluation of Monkman-Grant Parameters for Type 316LN and Modified 9Cr-Mo Stainless Steels

  • Kim, Woo-Gon;Kim, Sung-Ho;Ryu, Woo-Seog
    • Journal of Mechanical Science and Technology
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    • v.16 no.11
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    • pp.1420-1427
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    • 2002
  • The Monkman-Grant (M-G) and its modified parameters were evaluated for type 316LN and modified 9Cr-Mo stainless steels prepared with minor element variations. Several sets of creep data for the two alloy systems were obtained by constant-load creep tests in 550~650$\^{C}$ temperature range. The M-G parameters, m, m', C, and C' were proposed and discussed for the two alloy systems. The m value of the M-C relation was 0.90 in type 316LN steel and 0.84 in modified 9Cr-Mo steel. The m' value of the modified relation was 0.94 in type 316LN steel and 0.89 in 9Cr-Mo steel. Although creep fracture modes and creep properties between type 316LN and modified 9Cr-Mo steels showed a basic difference, the M-G and its modified relations demonstrated linearity quite well. The m' of modified relation almost overlapped regardless of the creep testing conditions and chemical variations in the two alloy systems, and the parameter m' was closer to unity than that of the M-G relation.

Dimerization of Aquooxomolybdenum (V) ion in Acid Media (I). Dehydrogenation of Bridging Hydroxide of $Mo_2O_4(OH)_{2(aq)}^{4+}$ (산성용액에서 아쿠오옥소몰리브덴 (V) 이온의 이합화 반응 (I). 이합체 착물의 두다리인 히드록소의 탈수소화 반응)

  • Chang-Su Kim;Chann-Woo Kim;Chang-Yong Kwon;Moon-Pyoung Yi
    • Journal of the Korean Chemical Society
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    • v.29 no.5
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    • pp.510-515
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    • 1985
  • Color of $MoO_{(aq)}^{3+}$ in concentrated methanesulfonic acid (∼10M) changes dark green due to the formation of $Mo_2O_2(OH)_{2(aq)}^{4+}$ dimer. This color is similar to that shown by addition of water to that shown by addition of water to green $MoO_{(aq)}^{3+}$ solution in 15-16M methanesulfonic acid. The molar extinction coefficient of monomer in 15M methanesulfonic acid is about 20 at 415nm. Rate constants are independent on the aquomolybdenum (V) and hydrogen ion concentration under the condition of this experment. Bridging hydroxides of $Mo_2O_2(OH)_{2(aq)}^{4+}$ are dehydrogenated at the less concentration of ∼6 M for HPTS and ∼10M for $CH_3SO_3H$. The structure of both the yl-oxygens and the bridging oxygens of final product is identified to (*image)unit.

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Grain Size Dependence of Soft Magnetic Properties in $Fe_{68.5}Co_5M_3Cu_1Si_{13.5}B_9(M=Nb, Mo, Mn, Cr)$ Nanocrystalline Alloys ($Fe_{68.5}Co_5M_3Cu_1Si_{13.5}B_9(M=Nb, Mo, Mn, Cr)$계 초미세결정립합금의 결정립 크기에 따른 자기적 특성의 변화)

  • 조용수;김택기
    • Journal of the Korean Magnetics Society
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    • v.1 no.2
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    • pp.37-41
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    • 1991
  • Amorphous $Fe_{68.5}Co_5M_3Cu_1Si_{13.5}B_9(M=Nb, Mo, Mn, Cr)$ alloys were prepared by using rapidly quenching techinque and were annealed above their crystallization temperatures. Coercive force, initial permeability and AC power loss of the annealed $Fe_{68.5}Co_5M_3Cu_1Si_{13.5}B_9(M=Nb, Mo, Mn, Cr)$ alloys have been studied systematically. Nanocrystallines are formed in the annealed alloys which include Mo and Nb. Remarkably improved soft magnetic properties are obtained in the alloys whose average grain size is around 10 nm. However, soft magnetic properties of the alloys are degraded when grain size is less than IOnm or larger than 15nm. It is considered that the degradation of soft magnetic properties in the alloys whose average grain size is less than 10 nm is due to the Fe-rich amorphous phase retained at grain boundary during the initial crystallization process.

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Sonochemical Synthesis of Fullerene Oxides $[C_{70}O_n](n=1{\sim}2)$ Using Metal Hexacarbonyl Complexes $M(CO)_6$ (M=Cr, Mo, W) Under Air Atmosphere (공기 중에서 금속 헥사카르보닐 착물 $M(CO)_6$ (M=Cr, Mo, W)를 이용한 폴러렌 산화물 $[C_{70}O_n](n=1{\sim}2)$의 초음파화학 합성)

  • Ko, Weon-Bae;Park, Young-Hwan
    • Elastomers and Composites
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    • v.40 no.3
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    • pp.174-180
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    • 2005
  • Sonochemical synthesis of fullerene oxides $[C_{70}O_n](n=1{\sim}2)$ by fullerene$[C_{70}]$ and metal hexacarbonyl complexes $M(CO)_6$(M=Cr, Mo, W) took place under air atmosphere. The reactivity of fullerene$[C_{70}]$ and several metal hexacarbonyl complexes $M(CO)_6$(M=Cr, Mo, W) under same ultrasonic condition increased in the order of $Mo(CO)_6$ > $W(CO)_6$ > $Cr(CO)_6$. The MALDI-TOF-MS, UV-visible spectra, and HPLC analysis confirmed that the products of sonochemical reaction were $[C_{70}O_n](n=1{\sim}2)$.

Solvent Extraction of Trace Mo(VI) in Natural Water Samples by Chelation and Ion-pairing (킬레이트 및 이온쌍 형성을 이용한 자연수 중 극미량 Mo(VI)의 용매추출)

  • Kim, Young-Sang;Nho, Seung-Gu;Choi, Jong-Moon;Choi, Hee-Seon
    • Analytical Science and Technology
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    • v.6 no.3
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    • pp.289-296
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    • 1993
  • The formation of Mo(VI)-alizarin red S chelate ion and its extraction into an organic solvent by ion-pairing were studied for the separative determination of trace Mo(VI) in natural water samples. Natural water 100mL was sampled in 250mL separatory funnel. After Mo(VI)-ARS chelate ion was formed by adding 0.01M alizarin red S solution 0.5mL to the water sample of pH 4.0, 0.2% aliquat-336 chloroform solution 10mL was added and the solution was vigorously shaked for about 30 seconds to from the ion-pair between Mo(VI)-ARS and aliquat-336, completely. The solution was stood for about 90 minutes. And the organic phase was taken for the absorbance measurement of the ion-pair at 520 nm. The content of Mo(VI) in sample was obtained from the standard calibration curve. Several extraction conditions such as pH, adding amounts of alizarin red S and aliquat-336, and shaking and standing times were optimized. This procedure was applied to the analysis of river and tap waters. It could be confirmed from the recoveries of over 99% in samples spiked with a given amount of Mo(VI) that this method was quantitiative in the determination of trace Mo(VI) in a natural water.

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