• Title/Summary/Keyword: Mn-Zn

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Effect of oxygen defects on luminescent characteristics of ZnGa_2O_4$:Mn phosphors (산소 결함이 ZnGa_2O_4$:Mn형광체 발광 특성에 미치는 효과)

  • 박용규;한정인;곽민기;한종근;주성후
    • Electrical & Electronic Materials
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    • v.9 no.10
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    • pp.1040-1046
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    • 1996
  • Low voltage phosphor, ZnGa$_{2}$O$_{4}$:Mn, was synthesized and sintered at the high temperature in Ar or vacuum. By XRD analysis, it is confirmed that poly crystalline ZnGa$_{2}$O$_{4}$:Mn solid solution was formed. From EPMA analysis of the samples prepared in Ar and vacuum, the change of oxygen content was investigated and as a result, it was observed that the oxygen amounts were reduced in ZnGa$_{2}$O$_{4}$:Mn prepared in vacuum. It caused the deficiency in oxygen amounts in the phosphor and then consequently, it results in the formation of the energy level near 513 nm. It contributes to the improvement of the brightness of ZnGa$_{2}$O$_{4}$:Mn.

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Effects of Combined Micronutrient(Fe, Mn, Cu, Zn, Mo and B) Application on Forage Traits in Pure and Mixed Swards of Orchardgrass and White Clover IV. Changes in the contents of micronutrients in forage plants (Orchardgrass 및 White Clover의 단파 및 혼파 재배에서 미량요소(Fe, Mn, Cu, Zn, Mo, B)의 조합시비가 목초의 여러 특성에 미치는 영향 IV. 목초 중 미량요소(Fe, Mn, Cu, Zn, Mo, B)의 함량 변화)

  • Jung, Yeun-Kyu
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.24 no.1
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    • pp.11-20
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    • 2004
  • This pot experiment was conducted to investigate the effects of combined micronutrient application($T_1$;control, $T_2$; Fe, $T_3$; Fe+Mn, $T_4$: Fe+Mn+Cu, $T_5$ ; Fe+Mn+Cu+Zn, $T_6$ ; Fe+Mn+Cu+Zn+Mo, $T_7$ ;Fe+Mn+Cu+Zn+Mo+B) on forage performance of pure and mixed cultures of orchardgrass and white clover. This 4th part was related to the changes in the contents of micronutrients(Fe, Mn, Cu, Zn, Mo, and B) in forages. The results obtained are summarized as follows: 1. General differences have been showed in the contents of micronutrients based on the treatments, forage species, pure/mixed culture, cutting order, and additional fertilization, especially N. Compared to pure culture, orchardgrass showed relatively high contents of Mn and Zn, and low contents of B and Fe in mixed culture. White clover, however, tended to be exactly opposed to the above trends. The contents of Cu and Mo did not show any differences between pure and mixed cultures. 2. In relative comparison, the $T_7$ influenced negatively on the contents of Cu, Zn, and Mo in orchardgrass. The $T_7$ also influenced negatively on the contents of Mo in white clover. However, the $T_7$ influenced positively on the contents of Mn in orchardgrass, and also influenced positively on the contents of Fe, Mn, and Cu in white clover. Because of the antagonism between Fe and Mn, the Fe contents in both forages were significantly decreased by the $T_3$. Under the various conditions, the differences among Fe contents tended to be more significant in white clover than in orchardgrass. 3. At the $T_6$ and $T_7$, the Mo contents in both forages tended to be relatively high. The Mo contents, however, were somewhat decreased by the $T_7$ 7/. The Mo-toxicity, which was caused by the high Mo-contents, tended to be diminished, and was likely to be prevented by the optimum B/Mo ratio and B application($T_7$ ).

Microwave Absorber Prepared by Using the Wasted Mn-Zn Ferrite and the Cement (Mn-Zn ferrite 廢棄物과 시멘트를 이용한 電波吸收體)

  • 조완식;김종오
    • Resources Recycling
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    • v.9 no.6
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    • pp.31-35
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    • 2000
  • The complex permeability, the complex permittivity and the reflection loss are investigated in the composite microwave absorbers which are mixed with the wasted Mn-Zn ferrite and the industrial cement. The cement has larger the complex permittivity than that of the rubber. The complex permittivity is decreasing with the increment of the mixing ratio of Mn-Zn ferrite to cement (F/C in weight) and the complex permeability is increasing with the increment of F/C. The maximum reflection loss is above -40 dB at all samples. The matching frequency is in the range of 1.3 GHz to 2.9 GHz and is decreasing with the increment of F/C from 1 to 3. The matching thickness is increasing with the increment of F/C. The wasted Mn-Zn ferrite and the cement is very useful material for the composite microwave absorber.

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Spherical-shaped Zn2SiO4:Mn Phosphor Particles with Gd3+/Li+ Codopant (Gd3+/Li+ 부활성제가 첨가된 구형의 Zn2SiO4:Mn 형광체 입자)

  • Roh, Hyun Sook;Lee, Chang Hee;Yoon, Ho Shin;Kang, Yun Chan;Park, Hee Dong;Park, Seung Bin
    • Korean Chemical Engineering Research
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    • v.40 no.6
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    • pp.752-756
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    • 2002
  • Green-emitting $Zn_2SiO_4:Mn$ phosphors for PDP(Plasma Display Panel) application were synthesized by colloidal seed-assisted spray pyrolysis process. The codoping with $Gd^{3+}/Li^+$, which replaces $Si^{4+}$ site in the willemite structure, was performed to improve the luminous properties of the $Zn_2SiO_4:Mn$ phosphors. The particles prepared by spray pyrolysis process using fumed silica colloidal solution had a spherical shape, small particle size, narrow size distribution, and non-aggregation characteristics. The $Gd^{3+}/Li^+$ codoping amount affected the luminous characteristics of $Zn_2SiO_4:Mn$ phosphors. The codoping with proper amounts of $Gd^{3+}/Li^+$ improved both the photoluminescence efficiency and decay time of $Zn_2SiO_4:Mn$ phosphor particles. In spray pyrolysis, the post-treatment temperature is another factor controlling the luminous performance of $Zn_2SiO_4:Mn$ phosphors. The $Zn_{1.9}SiO_4:Mn_{0.1}$ phosphor particles containing 0.1 mol% $Gd^{3+}/Li^+$ co-dopant had a 5% higher PL intensity than the commercial product and 5.7 ms decay time after post-treatment at $1,145^{\circ}C$.

Study on the Manufacturing Process of Complex Oxide by Co-Roasting Process and Magnetic Properties Mn-Zn Ferrite (분무 배소법에 의한 복합산화물의 제조공정 및 Mn-Zn ferrite의 자기 특성에 관한연구)

  • 유재근;이경익;이성수
    • Resources Recycling
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    • v.8 no.4
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    • pp.45-56
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    • 1999
  • The purpose of tlus sludy was to preparc raw material powder for Mn-Zn iclrile, h m mined mill scale and fero-Mn, usins a co-spray roasting process The mill scale and ferra-Mn uscd in this raalins process was rcf~nedb y mesn-ns of a slxc~apl rxcss ~nvolvinm~a te~ialsc ontalning imp~u-ltleso r less than 100 pprn In this study an effeclive spray roaster system. wllich produces fme complex oxide powder, collects produccd ~owder.,m d prcvel~tse ~~llssiooifi HCI gas. was also manufactured. By means of spray~ngp urifcd raw malerial solu~lionl nln a manufacued high tcmpervture rumace. &-ferrite powder and a comnpleu o ~ d e powder of Fe,O; and M,x203 were manufactured. The chmcterlstics of the composllion. surface urca, and p'miicle size dismbulion or the produced powder were exmined. ptoduced powdcr was then ~ m e dwi tli ZnO powder. aid olher addilives of defined cornposnion, and Mn-Zn femite cares werc praiuccil by meuns of Sorlning and closely controlled sintering processes. The magpelic p~oprlieso f c olo~ss, initlal permeability. mauin~u~mnn agnehc flux. coz~civcr orcc and residual magnccic flux for the above cores we,= measured, and fmm Il~ase I-csulls the eflicacy of lhe co-spray roasling pncess to pl.ellare raw material powder lor Mn-Zn ferntc was established

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Effect of Zn and Mn on the Synthesis of Zn2SiO4:Mn2+ Phosphor by SHS (자전연소 합성법을 이용한 Zn2SiO4:Mn2+ 형광체 합성시 Zn 및 Mn의 영향)

  • Lee Jong Eun;Kim Byeong Beom;Lee Hyeok Hui;Won Chang Whan
    • Korean Journal of Materials Research
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    • v.14 no.12
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    • pp.889-892
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    • 2004
  • The synthesis of $Zn_{2}SiO_4:Mn^{2+}$ for PDP green phosphor by SHS(Self-propagating High temperature Synthesis method) was studied. The precursors were well mixed and cold compacted. And then, the green pellet was synthesized at high temperature through self-propagating high temperature zone. Because this reaction uses the heat resulted from the oxidation of Zn metal powder in this system, Zn/ZnO mole ratio is one of the most important reaction variable. Throughout several experiments, the optimal condition of Zn/ZnO mole ratio and Mn concentration are 1.2/0.8 and 0.05mo1e, respectively.

Coating Effects on Electromagnetic Wave Absorbers Prepared with Mn-Zn Ferrites

  • Song Jae-Man;Kim Dong-Il;Che Seung-Hun;Choi Yun-Seok;Kim Ki-Man;Rhyu Keel-Soo
    • Journal of electromagnetic engineering and science
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    • v.5 no.4
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    • pp.161-165
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    • 2005
  • We prepared Mn-Zn ferrite Electromagnetic(EM) wave absorbers. The Mn-Zn ferrite EM wave absorbers were coated with Sr ferrite powders and $Al(OH)_3$ powders. The coated Mn-Zn ferrite EM wave absorbers show improved absorption compared with non-coated Mn-Zn EM wave absorbers.

Dependence of luminescence property of ZnMgS:Mn thin film phosphor on RTA temperature (ZnMgS:Mn 박막 형광체의 RTA 온도 변화에 따른 발광 특성 의존성)

  • Lee, Dong-Chin;Yun, Sun-Jin;Jeon, Duk-Young
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.05a
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    • pp.102-105
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    • 2004
  • With varying rapid thermal annealing (RTA) temperature, luminescent properties of ZnMgS:Mn thin film sputter-deposited with one target were measured. Although all samples have the same composition, $Zn_{1-x}Mg_xS:Mn$ (x=0.25) can emit luminescence between 580 and 614 nm, which is controlled by only RTA temperature. It is understood that the energy band gap shift of ZnMgS:Mn thin film phosphor occurs with varying RTA temperature.

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Effects of the Columbite Precursors on Phase-Formation Characteristics, Microchemistry and Dielectric Properties of Pb(Zn, Mg)_{1/3}Nb_{2/3}O_3$ Ceramics (Pb(Zn, Mg)_{1/3}Nb_{2/3}O_3$계에서 Columbite Precursors의 화학적 특성이 상생성, 미세화학 및 유전특성에 미치는 영향)

  • 조성률;이규만;장현명
    • Journal of the Korean Ceramic Society
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    • v.30 no.9
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    • pp.723-730
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    • 1993
  • The mechanism of formation of perovskite phase and the dielectric properties of PZMN[Pb(Zn, Mg)1/3Nb2/3O3] ceramics were examined using two different types of the columbite precursors, (Mg, Zn)Nb2O6 (MZN) and MgNb2O6+ZnNb2O6 (MN+ZN). The formatin of perovskite phase in PbO+MN+ZN system is characterized by an initial rapid formation of Mg-rich perovskite phase, followed by a sluggish formation of Zn-rich perovskite phase. On the other hand, thepyrochlore/perovskite transformation in the PbO+MZN system proceeded uniformly with a spatial homogeneity. The degree of diffuseness of the rhombohedral/cubic phase transitionis higher in the PbO+MN+ZN system than in the PbO+MZN specimen, indicating a broadened compositional distributjion of the B-site catons (Nb+5, Zn+2, Mg+2) in the PbO+MN+ZN system.

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Luminescent characteristic of ZnS:Mn,Cu yellow phosphors for Light Emitting Diodes (백색 LED용 ZnS:Mn,Cu 황색 형광체의 발광 특성)

  • Lee, Ji-Young;Yu, Il
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.141-141
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    • 2010
  • ZnS:Mn yellow phosphors doped with Cu for white light emitting diodes were synthesized by solid state reaction method. Photoluminescence excitation spectra originated from $Mn^{2+}$ were ranged from 450 nm to 500 nm. The yellow emission at around 580 nm was associated with $^4T_1{\rightarrow}^6A_1$ transition of $Mn^{2+}$ ions in ZnS:Mn,Cu phosphors. The highest photoluminescence intensity of the phosphors under 405 nm excitation was obtained at Cu concentration of 0.02 mol%.

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