• Title/Summary/Keyword: Mn/S ratio

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Effects of Systematic Variation Application of Fe, Mn, Cu, and Zn on These Relative Contents, Uptake Amounts, and Mutual Ratios in Orchardgrass and White Clover (Fe, Mn, Cu, Zn의 Systematic Variation 시비가 Orchardgrass 및 White Clover중 이들의 상대 함량, 탈취량 및 상호비율에 미치는 영향)

  • Jung, Yeun-Kyu
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.24 no.4
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    • pp.281-292
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    • 2004
  • This pot experiment was conducted to investigate the effects of systematic variation appling of Fe, Mn, Cu, and Zn on forage performance of orchardgrass and white clover, The treatments of systematic variation were 0/100. 25/75, 50/50. 75/25, and $100/0\%$ in the Fe/Cu, Mn/Zn, and Fe+Cu/Mn+Zn trials, respectively. The treatments of Fe/Mn/Cu/Zn trial were $70\%$ in main-element and $10\%$ in other 3sub-elements. 1 . General differences had been showed in the relative contents, uptake amounts, and mutual ratios of Fe, Mn, Cu, and Zn between orchardgrass and white clover. The effects of Fe application on the all traits were generally insignificant. The Mn and Cu applications, however, showed consistent differences in the all traits. At the high relative content of Mn in the forages influenced by the Mn application, the relative contents of Fe, Cu and Zn were greatly decreased without the significant differences in common content. 2. The increase of uptake amount of each micronutrient was not positively correspond to the yield increase. In some cases, the uptake amount of micronutrient was greatly increased without the significant increase of yield. At the Mn application, the Mn uptake amount was relatively much more increased than increase of the yield. The uptake amount of each element was significantly increased by the application with Mn and Cu. However, it was not in the case of Fe and Zn. 3. The mutual ratios of micronutrients were more influenced by the applications of Mn and Cu, especially Mn, than those by the applications of Fe and Zn. In the Fe/cu trial, the ratios of Fe/Cu showed 6.0~ 10.5 in orchardgrass and 10.2~ $16.4\%$ level of difference in white clover. In the Fe+Cu/Mn+Zn trial, the ratios of Mn/Cu, Mn/Zn, and Fe/Mn were greatly influenced by the treatments. It has been also found that the poor growth of white clover was caused by the unbalanced ratios of Fe/Mn, and it tended to be enhanced by the good applications and mutual ratios of other elements.

A computational estimation model for the subgrade reaction modulus of soil improved with DCM columns

  • Dehghanbanadaki, Ali;Rashid, Ahmad Safuan A.;Ahmad, Kamarudin;Yunus, Nor Zurairahetty Mohd;Said, Khairun Nissa Mat
    • Geomechanics and Engineering
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    • v.28 no.4
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    • pp.385-396
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    • 2022
  • The accurate determination of the subgrade reaction modulus (Ks) of soil is an important factor for geotechnical engineers. This study estimated the Ks of soft soil improved with floating deep cement mixing (DCM) columns. A novel prediction model was developed that emphasizes the accuracy of identifying the most significant parameters of Ks. Several multi-layer perceptron (MLP) models that were trained using the Levenberg Marquardt (LM) backpropagation method were developed to estimate Ks. The models were trained using a reliable database containing the results of 36 physical modelling tests. The input parameters were the undrained shear strength of the DCM columns, undrained shear strength of soft soil, area improvement ratio and length-to-diameter ratio of the DCM columns. Grey wolf optimization (GWO) was coupled with the MLPs to improve the performance indices of the MLPs. Sensitivity tests were carried out to determine the importance of the input parameters for prediction of Ks. The results showed that both the MLP-LM and MLP-GWO methods showed high ability to predict Ks. However, it was shown that MLP-GWO (R = 0.9917, MSE = 0.28 (MN/m2/m)) performed better than MLP-LM (R =0.9126, MSE =6.1916 (MN/m2/m)). This proves the greater reliability of the proposed hybrid model of MLP-GWO in approximating the subgrade reaction modulus of soft soil improved with floating DCM columns. The results revealed that the undrained shear strength of the soil was the most effective factor for estimation of Ks.

Crystal Structure and Electrical Transport Characteristics of ${La_{1-x}}{Sr_x}{MnO_{3-{\delta}}}$(0.19$\leq$x$\leq$0.31) Thin Films (${La_{1-x}}{Sr_x}{MnO_{3-{\delta}}}$(0.19$\leq$x$\leq$0.31) 박막의 결정구조 및 전기전도 특성)

  • Heo, H.;Lim, S.J.;Cho, N-H.
    • Korean Journal of Materials Research
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    • v.10 no.6
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    • pp.437-444
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    • 2000
  • We investigated the effect of substrate temperature, chemical composition and post-deposition heat-treatment on the crystal structure and electrical transport of $La_{1-x}Sr_xMnO_{3-{\delta}}$(0.19${\leq}x{\leq}$0.31) thin films. As-prepared $La_{1-x}Sr_xMnO_{3-{\delta}}$ films grown at $500^{\circ}C$ by sputter techniques were found to have the pseudo-tetragonal system(a/c=0.97) and a highly preferential <001> orientation. The films were changed to be of the cubic system by post-deposition annealing at around $900^{\circ}C$. A main target of $La_{0.67}Sr_{0.33}MnO_3$ as well as auxliary targets of $La_{0.3}Sr_{0.7}MnO_3$ ceramics were co-sputtered to control the chemical composition of the film. The Sr content(x) of the film ranged from 0.19 to 0.31, depending on the number of the auxiliary target. When x increased from 0.19 to 0.31, the electrical resistivity of the film decreased and the transition temperature between metal and semiconductor shifted to higher temperature. With a magnetic field of 0.18 T, the magneto-resistance ratio (MR(%) = (${\rho}_o-{\rho}_H/{\rho}_H$) of the $La_{0.69}Sr_{0.31}MnO_3$ thin film was about 390%.

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Mineral Paragenesis and Chemical Composition of Sangeun Au-Ag Ore Vein, Korea (상은광산(常隱鑛山)의 Au-Ag 광맥(鑛脈)의 광물(鑛物) 공생(共生) 및 화학조성(化學組成))

  • Kim, Moon Young;Shin, Hong Ja;Kim, Jong Hwan
    • Economic and Environmental Geology
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    • v.24 no.4
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    • pp.347-361
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    • 1991
  • The Sangeun ore deposit is located in a volcanic belt within the Gyeongsang Basin in south western Korea. The ore deposit is of representative epithermal Au-Ag quartz vein type developed in lapilli tuff. This paper presents the mineralization with special emphasis on mineral zoning of the deposits. Principal points are summarized as follows: (1) Four stages of mineralization are recognized based on macrostructures. From ealier to later they are stage I(arsenopyrite-pyrite-quartz), stage II(Au-Ag bearing Pb-Zn-quartz), stage III(barren quartz), and stage IV(dickite-quartz). (2) Electrum principally occurs with arsenopyrite and galena in stage II, and has chemical compositions of 72.9-67.1 Ag atom %, and has Ag/Au ratio of 2.69-2.04. (3) Sphalerite varies in its FeS content according to the mineralization stages; 22.03-18.60 mole % FeS and 1.33-0.23 mole % MnS in stage IB, 16.11-8.64 mole % FeS and 1.33-0.23 mole % MnS in stage II. (4) Alteration zones of mineral assemblage, from the vein to the wall-rock, consist of sericite - quartz - pyrite, sericite - quartz - dickite, sericite - chlorite plagioclase respectively.

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Statistical Analysis on Water Quality Characteristics of Large Lakes in Korea (우리나라 주요 호소의 수질특성에 대한 통계적 분석)

  • Kong, Dongsoo
    • Journal of Korean Society on Water Environment
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    • v.35 no.2
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    • pp.165-180
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    • 2019
  • Water quality data of 81 lakes in Korea, 2013 ~ 2017 were analyzed. Most water quality parameters showed left-skewed distribution, while dissolved oxygen showed normal distribution. pH and dissolved oxygen showed a positive correlation with organic matter and nutrients, which appeared to be a nonsense correlation mediated by the algae. The ratio of $BOD_5$ and $COD_{Mn}$ to CBOD was 21 % and 52 % in the freshwater lakes, respectively. TOC concentration appeared to be underestimated by the UV digestion method, when salinity exceeds $700{\mu}S\;cm^{-1}$. In terms of nitrogen/phosphorus ratio, the limiting factor for algal growth seemed to be phosphorus in most of the lakes. Chlorophyll ${\alpha}$ increased acutely with decrease of N/P ratio. However, it seemed to be a nonsense correlation mediated by phosphorus concentration, since the N/P ratio depended on phosphorus. The N/P ratio of brackish lakes was lower than that of the freshwater, at the same concentration of phosphorus. It is worth examining denitrification that occurs, in bottom layer and sediment, during saline stratification. $Chl.{\alpha}$ concentration decreased in the form of a power function with increase of mean depth. The primary reason is that deep lakes are mainly at the less-disturbed upstream. However, it is necessary to investigate the effect of sediment, on water quality in shallow lakes. Light attenuation in the upper layer, was dominated by tripton (non-algal suspended solids) absorption/scattering (average relative contribution of 39 %), followed by CDOM (colored dissolved organic matter) (average 37 %) and $Chl.{\alpha}$ (average 21 %).

Piezoelectric Characteristics of Low-temperature Sintered PSN-PZT Ceramics as a Function of Zr/Ti Ratio (저온소결한 PSN-PZT 세라믹스의 Zr/Ti 비에 따른 압전특성)

  • 류주현;우원희;오동언;정영호;정광현;류성림
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.12S
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    • pp.1195-1199
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    • 2003
  • In this study, in order to develop the low temperature sintering ceramics for multilayer piezoelectric transformer, dielectric and piezoelectric properties of PSN-PZT[0.91Pb(Sb$\sub$1/2/Nb$\sub$1/2/)$\sub$0.03/(Zr$\sub$0.495/Ti$\sub$0.505/)$\sub$0.97/O$_3$-0.04Pb(Ni$\sub$1/2/W$\sub$1/2/)O$_3$+0.05BiFeO$_3$+0.3wt%MnO$_2$+0.6wt%CuO〕 ceramics were investigated according to Zr/Ti ratio. As Zr/Ti ratio is increased, electromechanical coupling factor(k$\sub$p/) and dielectric constant increased and then decreased after the ratio of Zr/Ti=50/50. Also, mechanical qualify factor(Q$\sub$m/) decreased and then increased after the ratio of Zr/Ti=50/50.

Effect of Process Variables on the Flash Butt Welding of High Strength Steel

  • Kim, Y.S.;Kang, M.J.
    • International Journal of Korean Welding Society
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    • v.3 no.2
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    • pp.24-28
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    • 2003
  • This study was aimed to evaluate the quality of flash welded joints and optimize the welding process for flash butt welding of 780MPa grade high strength steel. And then the relationship between the welding process variables and the joint quality would be established. The effect of process variables between flashing and upsetting process was elucidated. Microstructure observation of the joint indicated that the decarburized band was mainly changed with upsetting process. Width of HAZ was also related to the upsetting conditions rather than the flashing conditions. Generally maximum hardness at HAZ was correlated with Ceq of steel and the empirical relationship was obtained to estimate the HAZ properties. Tensile elongation at the joint was usually decreased with increasing the initial clamping distance. Investigation of fracture surface after tensile and bending tests reveal that the origin of cracking at the joint was oxide inclusions composed of $SiO_2$, MnO, $Al_2O_3$, and/or FeO. The amount of inclusions was dependent on the composition ratio of Mn/Si in steel. If this ratio was above 4, the amount of inclusions was low and then the resistance to cracking at the joint was enough to maintain the joint performance. It was obtained that the flashing process influenced the conditions for the energy input to establish uniform or non­uniform molten layer, while the upsetting conditions influenced the joint strength. Heat input variable during flashing process was also discussed with the joint properties.

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Long Term Monitoring of Storm Surface Runoff from Urban Pavement Road in Korea

  • Lee, C.S.;Seo, G.T.;Lee, J.H.;Yoon, Y.S.;You, J.J.;Sin, C.K.
    • Environmental Engineering Research
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    • v.13 no.4
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    • pp.184-191
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    • 2008
  • Long term monitoring was conducted to investigate a surface runoff of pollution from urban highway. The monitoring data was collected for 18 rainfall events and was used to correlate pollution load to various parameters, such as rainfall intensity, antecedent dry days and total discharge flow. Runoff coefficient and seasonal variation were also evaluated. The mean runoff coefficient of the highway was 0.823(range; $0.4687{\sim}0.9884$), and wash-off ratio for $COD_{Mn}$ and SS loads was 72.6% and 64.3%, respectively. For the initial rainfall event, the runoff EMC of $COD_{Mn}$ was high in summer and the EMC of SS was high in autumn season. However the seasonal variation of T-N and T-P was not significant. The discharged $COD_{Mn}$-EMC was $147.6\;mg/L{\sim}9.0\;mg/L$ on the generated $COD_{Mn}$-EMC of $98.8\;mg/L{\sim}8.9\;mg/L$. While the generated EMC of SS was in $285.7\;mg/L{\sim}20.0\;mg/L$ and its discharged EMC was in $190.4\;mg/L{\sim}8.0\;mg/L$. EMC of pollutants was not directly related to the first flush rainfall intensity and the antecedent dry days. But the correlation was relatively high between EMC and cumulative runoff flow volume. The trend of EMC was reduced with the cumulative runoff flow volume.

Characteristics of MnxSi1-xTe Compound Studied by Electron Magnetic Resonance and Other Experiments

  • Na, Sung-Ho;Kim, Heung-Chul;Park, Jung-Woo;Kim, Jang-Whan
    • Journal of Magnetics
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    • v.13 no.1
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    • pp.23-29
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    • 2008
  • The magnetic and other physical characteristics of $Mn_xSi_{1-x}Te$ have been investigated by electron magnetic resonance (EMR), X-ray diffraction (XRD) and other experiments. $Mn_xSi_{1-x}Te$ is found to have corundum structure for manganese contents up to 10% and also to be ferromagnetic for temperatures below 80 K. While ferromagnetic resonance signal coexists with the usual paramagnetic resonance signal, invariance of the g-factor inferred from the electron paramagnetic resonance signals throughout all temperature ranges clearly confirms that the manganese ions are in the electronic 3d5 state. The temperature dependence of EMR line-width is the same as other diluted magnetic semiconductors. From the EMR signals relaxation times $T_2$ and $T_1$ of $Mn_xSi_{1-x}Te$ compounds are estimated to be about $4.4{\times}10^{-10}s$ and $9.3{\times}10^{-8}s$ respectively and are found to vary slightly with temperature or composition change. Exchange narrowing of the EMR line-width becomes dominant for the sample in which the substitution ratio, x = 30%. For one sample, in which x = 0.5%, spin glass-like behavior is indicated by EMR signals for temperatures lower than 60 K. This behavior may authentic for samples within a certain range of x.

A Study on the Effects of Chungyeolmaksungbang on Mouse Model of Membranous Nephropathy Induced by Cationic Bovine Serum Albumin (청열막성방(淸熱膜性方)이 Cationized Bovine Serum Albumin투여로 유발된 Mouse의 Membranous Nephropathy에 미치는 영향)

  • Choi, In-Gu;Cho, Chung-Sik;Kim, Cheol-Jung
    • The Journal of Internal Korean Medicine
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    • v.29 no.1
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    • pp.104-116
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    • 2008
  • Objective : Membranous nephropathy (MN) is the most common cause of adult nephrotic syndrome worldwide. MN has been defined as granular subepithelial deposition of IgG immune complexes along the glomerular basement membrane (GBM). We aimed to identify the effects of Chungyeolmaksungbang (CYMSB) treatment on cBSA-induced in MN mouse model. Methods : The effect of Chungyeolmaksungbang treatment was studied on the morphology and protein excretion in the cationized bovine serum albumin (cBSA)induced mouse chronic serum sickness nephritis model. One group of mice was given intra-peritoneal (i.p.) immunizing doses of cBSA and complete Freund's adjuvant. One week later, these animals began a single i.p. injection of cBSA for 4 weeks. A second group followed the same injection protocol, but was given CYMSB p.o. Results : Proteinuria significantly was decreased and serum albumin was increased in the group treated with cBSA and CYMSB extract compared with the control. Serum BUN was significantly decreased on CYMSB compared with control. CD3e+/CD19 cells ratio of peripheral blood was decreased and CD4+/CD8 cells was increased. Level of $IL-1{\beta}$ was significantly decreased, and $IFN-{\gamma}$ was significantly increased. Concentration of IgG and IgM was significantly decreased compared with control. Thickness of GBM was decreased on histological analysis of kidney. Deposition of CD4 and CD8 was decreased on immunohistochemical staining of kidney. Conclusions : We conclude that CYMSB treatment may could be a useful remedy agents for treating the MN with cBSA.

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