• Title/Summary/Keyword: Mixture ratio

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Utrastructural Analysis of the Delignification Behaviour in P-Cresol-Water Solvent Pulping (크레졸-물 용매펄프화의 탈리그닌에 관한 초미세구조적 분석)

  • Kim, Chang-Keun;Jo, Byoung-Muk
    • Journal of the Korean Wood Science and Technology
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    • v.20 no.1
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    • pp.60-71
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    • 1992
  • To investigate the delignification behaviour in solvolysis pulping process, Populus alba ${\times}$ glandulosa H. and Pinus Kuraiensis S. et Z. were cooked with p-cresol and vater solvent(2:8, 5:5, 8:2 v/v) at $175^{\circ}C$ for 9 cooking time levels(20, 40, 60, 80, 100, 120, 140, 160, 180, min). Pulp yield, residual lignin content, de lignification rate, decarborhydration rate were determined. Delignification behaviours were analyzed by TEM. 1. The p-cresol-water solvent cooking of P. alba ${\times}$ glandulosa showed good delignification at the solvent system which the mixture ratio of p-cresol and water were 2:8(v/v), while the cooking of P. koraiensis with the p-cresol and water mixture ratio of 5:5 was no good. 2. P. alba ${\times}$ glandulosa showed three step-delignification phenomena at the solvent system which the mixture ratio of p-cresol and water were 2:8(v/v) anti 5:5(v/v). But P. koraiensis showed a first order delignification reaction at the same mixture ratio of p-cresol and water solvent system. 3. In TEM micrograph obtained for the solvent system which the mixture ratio of p-cresol and water was 5:5(v/v), the partial delignification of the cell corner of P. alba ${\times}$ glandulosa and P. koraiensis were observed at 60min. of cooking time. Complete delignification at the cell corner of P. alba ${\times}$ glandulosa was observed at 160min. and that of P. koraiensis was observed of 180min. of cooking time. 4. In optical microscopic observation, fiber separation of P. alba ${\times}$ glandulosa occured at 120min. and that of P. koraiensis began at 140min. of cooking time. 5. At the solvent system which the mixture ratio of p-cresol and water was 5:5(v/v), middle layer on secondary wall($S_2$) and cell corner of P. alba ${\times}$ glandulosa were more selectively delignified than primary wall(P) and outer layer on secondary wall($S_1$). However P. koraiensis did not showed any difference in delignification between cell wall layers and cell corner.

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Spray Characteristics on Impingement Angle Variation and Mixture ratio of Impinging Injectors (충돌각과 혼합비 변화에 따른 충돌형 분사기의 분무특성에 관한 연구)

  • Gang, Sin Jae;Song, Beom Geun;Song, Gi Jeong;Lee, Jeong Gyu
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.31 no.5
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    • pp.72-79
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    • 2003
  • Spray characteristics were investigated by impinging F-O-O-F type injector with varying the impingement angle through 15, 20 and 30 degree and the mixture ratio(O/F ratio) from 1.5 to 3.0. Experimental results show that the correlation between dispersion and impingement angle is not influenced of the mixture ratio variation, but which has influence on number density, and there is a linear correlation between dispersion and impingement angle. Velocity distribution, standard deviation and SMD of droplets are decreased as the impingement angle increases. Also, it was confirmed that the distribution of droplet size are in accordance with Rosin-Rammler and Upper-limit distribution.

A Study on Mixture Preparation in a Port Fuel Injection Sl Engine During Engine Starting (흡기포트 분사방식의 가솔린 엔진에서 냉시동시 혼합기 형성에 관한 연구)

  • 황승환;이종화;민경덕
    • Transactions of the Korean Society of Automotive Engineers
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    • v.10 no.4
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    • pp.15-22
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    • 2002
  • As the emission regulations on the automobiles have been increasingly stringent, precise control of air/fuel ration is one of the most important issues on the gasoline engines. Although many researches have been carried out to identify the fuel transport phenomena in the port fuel injection gasolines, mixture preparation in the cylinder has not been fully understood due to the complexity of fuel film behavior, In this paper, the mixture preparation during cold engine start is studied by using a Fast Response Flame ionization Detector.(FRFID) In order to estimate the transportation of injected fuel from the intake port into cylinder, the wall wetting fuel model was used. The two coefficient($\alpha$,$\beta$) of the wall-wetting fuel model was determined from the measured fuel mass that was inducted into the cylinder at the first cycle after injection cut-in. $\alpha$( ratio of directly inducted fuel mass into cylinder from injected fuel mass) and $\beta$ (ratio of indirectly inducted fuel mass into cylinder from wall wetted fuel film on the wall) was increased with increasing cooling water temperature. To reduce a air/fuel ratio fluctuation during cold engine start, the appropriate fuel injection rate was obtained from the wall wetting fuel model. Result of air/fuel ratio control, air/fuel excursion was reduced.

Influence of Propellant Mixture ]Ratio Variation near Chamber Wall (액체로켓엔진의 내부 벽면 근처에서의 추진제 혼합비 변화의 영향에 대한 연구)

  • Han Poong-Gyoo;Chang Haeng-Soo;Cho Yong-Ho;Kim Kyoungho
    • Proceedings of the KSME Conference
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    • 2002.08a
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    • pp.255-258
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    • 2002
  • Liquid rocket engines using liquefied natural gas (LNG) or methane as a fuel is known to have several good characteristics, such as high specific impulse compared to other hydrocarbon fuels, environment-friendly exhaust gas, low production cost, and re-usability with low soot generation in the cooling channel. In this study, experimental combustion chambers capable of using LNC and $CH_{4}$ are being researched through experimental firing tests, and within easy range of eyes' inspection, there are the periodical existence of soot or discoloration in the chamber wall surface. This result means that mixture ratio of oxidizer and fuel fluctuates periodically between outer-row injectors in the mixing head in the circumferential direction. Therefore, based on this phenomenon, the variation of mixture ratio near the chamber wall caused by the spill pattern of a shear coaxial injector was analyzed quantitatively and the thermal heat flux Into the cooling channel is modified. Then, the calculated and modified results are compared with the measured ones.

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A Study on Trend of Tensile Properties with Ratio of Water Mixture in Hydroponic Polyurethane Waterproofing Materials (수경화성 폴리우레탄 방수재의 물 혼입량에 따른 인장성능 변화 추이 연구)

  • Park, Wan-Goo;An, Hyun-Ho;Kim, Sun-Do;Kim, Dong-Bum;Park, Jin Sang;Oh, Sang-Keun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.05a
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    • pp.215-216
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    • 2016
  • Urethane waterproofing materials which currently being used most commonly in the Korean domestic market have high applicability and construct layers without forming any joints, but under the influence of low temperature and low humidity, as well as the thickness of the applied layer, the curing time of this material may become extended in construction sites. To resolve these issues, a proposed method of using water-hardening type of polyurethane waterproofing materials are being developed. However, there currently lacks any standards or evaluation methods on determining an optimal mixture ratio of water for the water-hardening polyurethane waterproofing materials. Therefore, for the establishment of a board applicability of the water-hardening polyurethane waterproofing methods in construction sites, this study objectively analyzes the changes in the performance of these materials depending on the changes of the water mixture ratio and attempts to procure the optimal ratio on the basis of forming a provisionary standard.

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Effect of $Al_2O_3/Fe$ Ratio on Characteristics of Carbon Nanotubes Prepared by Catalytic Chemical Vapor Deposition

  • Jung, Sung-Sil;Lee, Dae-Yeol;Chung, Won-Sub;Park, Ik-Min
    • Carbon letters
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    • v.5 no.2
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    • pp.81-87
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    • 2004
  • The effect of compositions of $Al_2O_3$ in the mixed $Fe/Al_2O_3$ catalysts on the synthetic behaviors of carbon nanotubes (CNTs) by catalytic chemical vapor deposition (CCVD) process was investigated in wide range of the mixture ratios of support materials. CNTs were synthesized with $Fe/Al_2O_3$ catalysis under the condition of 40 min in synthetic time, and 923 K of synthetic temperature using $C_2H_4$ and $H_2$ as synthetic and carrier gas, respectively. The carbon yield with the content of $Al_2O_3$ showed in a parabolic curve and the maximum carbon yield was 40 wt.% of $Al_2O_3$. As the mixture ratio of $Al_2O_3$ increased, decreasing tendency was observed in the diameter of CNTs. Specific surface areas of CNTs were increased with the increase of the mixture ratio of $Al_2O_3$.

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Studies on hydrophobic drug-soluble carrier coprecitates 2

  • Shin, Sang-Chul
    • Archives of Pharmacal Research
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    • v.2 no.1
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    • pp.49-64
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    • 1979
  • In an atempt to elucidate further physicochemical properties of furosemide-PVP coprecipitates, extensive investigations such as TLC, UV,IR, NMR, X-ray diffraction, TGA and DTA studies were carried out for the furosemide test systems. X-ray diffraction studies revealed that the pure furosemide and the furosemide contained within a physical mixture were crystalline in nature. However, there was no crystallinity evident in the 1:5 furosemide-PVP 40,000 coprecipitate system, even after standing for two years. The various ratio furosemide-PVP 40,000 coprecipitate systems revealed that the coprecipitate containing a greater amount of PVP 40,000 than that of furosemide showed a crystalline state of furosemide and that the minimum amounts of PVP to make amorphous form of furosemide was 1:1 ratio of furosemide to PVP. From the furosemide-PVP coprecipitate systems with PVP of different molecular weights of 10,000, 40,000 and 360,000, all the 1:1 ratio coprecipitates did not exhibit any crystallinity of furosemide, whereas all the 2:1 ratio coprecipitates showed a presence of crystalline furosemide. All the coprecipitated preparations with PEG 4,000 and with PEG 6,000 showed the diffraction peaks indicating the presence of crystalline furosemide. The comparison of infrared spectra of the physical mixture and the coprecipitate showed an interaction such as association between the functional groups of furosemide and PVP in the molecular level, whereas the studies by TLC, UV and NMR showed its dissociation in methanol solution. The weight losses in TGA curves showed all the same patterns. However, a little different transition form in DTA thermograms was shown between the physical mixture and the coprecipitate, indicating the different thermal property.

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Engineering Characteristics of Non-sintering Binder-stabilized Mixture using Industrial By-Products (산업부산물을 이용한 비소성 고화제 혼합토의 역학적 특성)

  • Yun, Dae-Ho;Mun, Kyoung-Ju;Kim, Yun-Tae
    • Journal of Ocean Engineering and Technology
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    • v.28 no.2
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    • pp.140-146
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    • 2014
  • This study investigated the engineering characteristics of non-sintering binder-stabilized mixtures consisting of different ratios of a hardening agent(3%, 6%, 9%, 12%) for recycling industrial by-products through several series of laboratory tests. The hardening agents consisted of two kinds of non-sintering binders(NSB-1, NSB-2), which were developed by using inter-chemical reactions among blast furnace slag, phospho-gypsum, and an alkali activator. In addition, ordinary Portland cement(OPC) was used to compare the engineering characteristics of the stabilized mixture. An unconfined compressive test showed that the unconfined compressive strength increased with the curing time and mixing ratio. Experimental test results indicated that the 7-day strength of the NSB-1 mixture was similar to that of the OPC mixture. However, its 28-day strength was higher than that of the OPC mixture. The secant module of elasticity showed a range of $E_{50}=(42-109)q_u$ regardless of the agents. Based on the results of triaxial tests, the cohesion and friction angle increased with the mixing ratio.

Biological Removal of a VOC Mixture in a Two-stage Bioreactor (이단미생물반응조에서 혼합 VOCs의 생분해 특성)

  • Song, Ji-Hyeon
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.6
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    • pp.758-766
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    • 2006
  • A two-stage bioreactor, which consists of a biotrickling filter module and a biofilter module in series, was investigated for the enhanced treatment of a VOC mixture, toluene and methyl ethyl ketone (MEK). Throughout the experiments, the overall inlet loading rate was maintained at approximately $43g/m^3/hr$, but the inlet ratios of the VOCs were modified. The experimental results showed that the different ratios of the VOC mixture resulted in changes of overall removal efficiencies, elimination capacities (ECs) and microbial accumulation on the surface of each packing material. The ratio of inlet toluene to MEK at 50 : 150 was found to be most effective in terms of the overall removal efficiency, because, at this condition, MEK (i.e., the hydrophilic compound) was mostly removed in the biotrickling filter module and the following biofilter module was used to remove toluene. It was also found that when the inlet loading rate of the VOC mixture was serially increased stepwise within short-term periods, the ECs for toluene dropped significantly but the ECs for MEK increased at the ratio of the VOC mixture. These results implied that substrate interaction and/or substrate preferable utilization might have an effect on the biological removal of each compound in the two-stage bioreactor; therefore, the bioreactor should be operated in the condition where the substrate interaction could be minimized in order to maximize overall performance of the two-stage bioreactor.

Experimental Study on the Performance of Heat Pump Using Refrigerant Mixture R22/R142b (R22/R142b 혼합냉매를 사용한 열펌프의 성능)

  • Kim, M.S.;Chang, S.D.;Ro, S.T.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.4 no.1
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    • pp.33-47
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    • 1992
  • Experimental investigation on the performance of a heat pump system using refrigerant mixtures is done. The condenser and the evaporator are double pipe heat exchangers of counter flow type and the compressor is driven by a variable speed motor. The refrigerant mixture used in the experiment is R22/R142b. Experiments are performed by changing the compressor speed, composition on ratio of mixture, and the average temperatures of condenser and evaporator. The compressor work, heating capacity and the coefficient of performance are calculated. Results show that the heating capacity can be changed by varying the mass flow rate of refrigerant mixtures to meet the heating load. It is shown that the capacity control by changing the composition ratio is more effective than by changing the compressor speed. Under the condition where the external conditions are fixed and the heating loads are equal, the coefficient of performance has its maximum value near 50 : 50 mass fraction of the refrigerant mixture in this study.

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