• 한국정밀공학회지
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• 제18권9호
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• pp.156-164
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• 2001

Two-dimensional solidification analysis during rheology forming process of semi-solid aluminum alloy has been studied. Two-phase fluid flow model to investigate the velocity field and temperature distribution is proposed. The proposed mathematical model is applied to the die shape of the two types. To calculate the velocity and temperature fields during rheology forming process, the earth governing equation correspondent to the liquid and solid region are adapted. Therefore, each numerical models considering the solid and liquid region existing within the semi-solid material have been developed to predict the deflect of rheology forming gnarls. The Arbitrary Boundary Maker And Cell (ABMAC) method is employed to solve the two-phase flow model of the Navier-Stokes equation. Theoretical model on the basis of the two-phase flow model is the mixture rule of solid and liquid phases. This approach is based on the liquid and solid viscosity. The liquid viscosity is pure liquid state value, however solid viscosity is considered as a function of the shear rate, solid fraction and power law curves.

• Computers and Concrete
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• 제13권3호
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• pp.309-323
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• 2014

Based on the compositions and structures of cement-based materials, the geometrical models of the tortuosity of transport paths in hardened cement pastes, mortar and concrete, which are associated with the capillary porosity, cement hydration degree, mixture particle shape, aggregate volume fraction and water-cement ratio, are established by using a geometric approach. Numerical simulations are carried out to investigate the effects of material parameters such as water-cement ratio, volume fraction of the mixtures, shape and size of aggregates and cement hydration degree, on the tortuosity of transport paths in hardened cement pastes, mortar and concrete. Results indicate that the transport tortuosity in cement-based materials decreases with the increasing of water-cement ratio, and increases with the cement hydration degree, the volume fraction of cement and aggregate, the shape factor and diameter of aggregates, and the material parameters related to cement pastes, such as the water-cement ratio, cement hydration degree and cement volume fraction, are the primary factors that influence the transport tortuosity of cement-based materials.

• Korean Chemical Engineering Research
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• 제53권2호
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• pp.216-223
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• 2015

The present work explores the potential of wet air oxidation (WAO) for pretreatment of mixed lignocellulosic biomass to enhance enzymatic convertibility. Rice husk and wheat straw mixture (1:1 mass ratio) was used as a model mixed lignocellulosic biomass. Post-WAO treatment, cellulose recovery in the solid fraction was in the range of 86% to 99%, accompanied by a significant increase in enzymatic hydrolysis of cellulose present in the solid fraction. The highest enzymatic conversion efficiency, 63% (by weight), was achieved for the mixed biomass pretreated at $195^{\circ}C$, 5 bar, 10 minutes compared to only 19% in the untreated biomass. The pretreatment under the aforesaid condition also facilitated 52% lignin removal and 67% hemicellulose solubilization. A statistical design of experiments on WAO process conditions was conducted to understand the effect of process parameters on pretreatment, and the predicted responses were found to be in close agreement with the experimental data. Enzymatic hydrolysis experiments with WAO liquid fraction as diluent showed favorable results with sugar enhancement up to $10.4gL^{-1}$.

• Bulletin of the Korean Chemical Society
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• 제31권5호
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• pp.1143-1148
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• 2010

We investigated the separation of nitrogen heterocyclic compound (NHC) contained in a model coal tar fraction comprising four kinds of NHC [indole (In), quinoline (Q), iso-quinoline (iQ), quinaldine (Qu)], three kinds of bicyclic aromatic compound (BAC) [1-methylnaphthalene (1MN), 2-methylnaphthalene (2MN), dimethylnaphthalene (DMN) mixture with ten structural isomers (DMNs; regarded as one component)], biphenyl (Bp) and phenyl ether (Pe) by liquid membrane permeation (LMP). A batch-stirred tank was used as the permeation unit. An aqueous solution of saponin and n-hexane were used as the liquid membrane and the outer oil phase, respectively. Yield and selectivity of individual NHC was much larger than that of BAC, Bp and Pe. Increasing the initial mass fraction of the saponin to the membrane solution ($C_{sap,0}$) and the initial volume fraction of O/W emulsion to total liquid in a stirred tank (${\phi}_{OW,0}$) resulted in deteriorating the yield of individual NHC, but increasing the stirring speed (N) resulted in improving the yield of each NHC. With increasing $C_{sap,0}$, the selectivity of each NHC based on DMNs increased. Increasing ${\phi}_{OW,0}$ and N resulted in decreasing the selectivity of individual NHC based on DMNs. At an experimental condition fixed, the sequence of the yield and selectivity in reference to DMNs for each NHC was Q > Qu = iQ > In. Furthermore, we compared LPM method with methanol extraction method in view of the separation efficiency (yield, selectivity) of NHC.

• 대한설비공학회:학술대회논문집
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• 대한설비공학회 2007년도 동계학술발표대회 논문집
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• pp.652-657
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• 2007

This paper is an interim report on the investigation of thermodynamic properties of $CO_2$/oil mixture refrigerant. First, liquid density of POE (poly-ol ester) and PAG (poly alkylene glycol) were measured and expressed as a function of temperature. Then, a solubility equation was developed which enables us to calculate the weight fraction of $CO_2$ for the mixture in a liquid state. An experimental apparatus with a cell was constructed to measure P-$\upsilon$-T-$\chi$ data for $CO_2$/oil mixture. The volume of the cell was determined using a certain formula considering change in volume as a function of temperature and pressure. Then, experimental data were obtained over the temperatures $40^{\circ}C$, $50^{\circ}C$, $60^{\circ}C$, $70^{\circ}C$ and $80^{\circ}C$ with various mole fractions. Finally, assuming a primitive model of ideal gas, the volume of $CO_2$/oil mixture was predicted with a relatively larger error of 5.05% for $CO_2$/PAG and 8.81% for $CO_2$/POE. The volume of $CO_2$/oil mixtures would be better predicted using an appropriate equation of state, of which results will be reported soon.

• 한국소음진동공학회논문집
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• 제26권2호
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• pp.141-147
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• 2016

Underwater cavitation is one of the most important issues because it causes not only vibration and erosion of submerged bodies but also significant flow noise problems. In this paper, flow noise due to cavitation flows around the NACA66 MOD hydrofoil is numerically investigated. The cavitation flow simulation is conducted using the Reynolds-Averaged Navier-Stokes equations based on finite difference methods. To capture the cavitation phenomena accurately and effectively, the homogeneous mixture model with the Merkle's cavitation model is applied. The predicted results are compared with available experimental data in terms of pressure coefficients and volume fraction, which confirms the validity of numerical results. Based on flow field analysis results, hydro-acoustic noise field due to the cavitation flow is predicted using the Ffowcs-Williams and Hawkings equation derived from the Lighthill's acoustic analogy. The typical lift dipole propagation patterns are identified.

• 태양에너지
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• 제15권3호
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• pp.91-103
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• 1995

튜브 내의 입구영역에서 대류와 비회복사(mon-gray radiation)가 동시에 일어날 때의 열전달 특성을 수치해석적으로 연구하였다. 작동유체는 이산화탄소, 수증기, 질소의 혼합가스라 하였고, 유동은 속도장과 온도장이 동시에 발달하는 층류 유동으로 가정하였다. 복사전달방정식을 풀기 편하게 하기 위해 P-1 근사법이 사용되었고 혼합가스의 비회흡수계수(non-gray sbsorption coefficient)는 지수광폭밴드모형(exponential wide band model)을 이용해서 구하였다. 열전달 특성에 대한 온도조건의 영향을 조사하기 위해 튜브의 축방향에 대한 평균온도와 뉴셀트수(Nusselt number)의 변화를 몇 가지 다른 온도조건에 대해 나타내었다. 속도장과 온도장이 동시에 발달하는 경우의 뉴셀트수를 속도장은 완전히 발달되어 있고 온도장만 발달하는 경우의 뉴셀트 수와 비교하였다. 또한, 가스의 성분조성이 대류와 비회복사 뉴셀트수에 미치는 영향을 조사하였다.

• 설비공학논문집
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• 제11권6호
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• pp.880-890
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• 1999

The purpose of this study is to investigate the performance of an autocascade refrigeration system using the refrigerant miktures of R744 (carbon dioxide) and R134a (1,1,1,2-tetrafluoroethane) as working fluids by simulation and experiment. Cycle simulation using a constant UA model in heat exchangers has been performed for R744/134a mixtures of the compositions in the range of from 10/90 to 30/70 by weight percentage. Variations of mass flow rate of refrigerant, compressor work, refrigeration capacity and COP with respect to mass fraction of R744/134a mixture were presented. Performance test has been executed in an autocascade refrigeration system by varying secondary fluid temperatures at evaporator and condenser inlets. Experimental results show similar trend with those from the simulation.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2003년도 추계학술발표대회 논문집
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• pp.11-15
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• 2003

In order to suppress a repulsive interfacial energy between hydrophilic clay and hydrophobic polymer matrix in preparing a polymer/clay nanocomposite, a third component of amphiphilic nature such as poly($\varepsilon$-caprolactone) (PCL) was introduced into the model system of styrene-acrylonitrile copolymers (SAN)/Na-montmorillonite. Once $\varepsilon$-caprolactone was polymerized in the presence of Na-rnontmorillonite, the successful ring-opening polymerization of $\varepsilon$-caprolactone and the well-developed exfoliated structure of PCL/Na-montmorillonite mixture were confirmed, Thereafter, SAN was melt-mixed with PCL/Na-montmorillonite nanocomposite, which resulted in that SAN matrix and PCL fraction were completely miscible to form homogeneous mixture with retention of the exfoliated state of Na-montmorillonite, exhibiting that PCL effectively stabilizes the repulsive polymer/clay interface and contributes the improvement of mechanical properties of the nanocomposites.

• International Journal of Air-Conditioning and Refrigeration
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• 제9권3호
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• pp.1-9
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• 2001

In this study, condensation heat transfer coefficients (HTCs) of nonazeotropic refrigerant mixtures of HFC32/HFC 134a and HCFC123 at various compositions were measured on a horizontal smooth tube. All data were taken at the vapor temperature of 39$^{\circ}C$ with a wall subcooling of 3~8K. Test results showed that HTCs of tested mixtures were 11.0~85.0% lowed than the ideal values calculated by the mass fraction weighting of the HTCs of the pure components. Thermal resistance due to the diffusion vapor film was partly responsible for the significant reduction of HTCs with these nonazeotropic mixtures. The measured data were compared against thc predicted ones by Colburn and Drew's film model and a good agreement was observed within a deviation of 15%.