• Title/Summary/Keyword: Mixed systems

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Stoichiometry and Stability of Complexes Formed between 18-Crown-6 as well as Digenzo-18-Crown-6 Ligands and a Few Metal Ions in Some Non-aqueous Binary Systems Using Square Wave Polarography

  • A. Nezhadali, Gh. Rounaghi;M. Chamasaz
    • Bulletin of the Korean Chemical Society
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    • v.21 no.7
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    • pp.685-689
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    • 2000
  • The complexation reaction between Pb2+,TI and Cd2+ions and macrocyclic ligands, 18-crown-6 ( 18C6) and dibenzo- 18-crown-6 (DB 18C6), was studied in dimethylsulfoxide (DMSO)-nitromethane (NM) and dimethyl-formamide (DMF)-nitromethane binary system s by square wave polarography (SWP) technique. The stoichiometry and stability of the complexes were determined by monitoring the shifts in half-waves or peak potentials of the polarographic waves of metal ions against the Iigand concentration. In most cases, the stability constants of complexes increase with increasing amounts of the nitromethane in mixed binary solvents used in this study. The complexes formed between 18C6 and DB18C6 and these metal cations in all cases had a stoichiometry of 1 : 1. The results obtained show that there is an inverse relationship between the formation constant of complexes and the donor number of solvents based on a Gatmann donocity scale and the stability constants show a high sensitivity to the composition of the mixed solvent systems. A linear behavior was observed for variation of log Kf of I8C6 complexes vs the composition of the mixed solvent systems in NM/DMSO and NM/DMF,but a non-linear behavior was observed in the case of DB 18C6 complexes in these binary systems. In most of the systems investigated, the Pb2+ cation forms a more stable complex with the 18C6 than other two cations and the order of selectivity of this Iigand for cations is: Pb2+ > TI+,Cd2+.

Design of Mixed Reality Visualization System for Operational Situation Using Cloud-based Geospatial Information (클라우드 기반 지리공간정보를 활용한 작전상황 혼합현실 가시화 시스템 설계)

  • Youngchan Jang;Jaeil Park;Eunji Cho;Songyun Kwak;Sang Heon Shin
    • Journal of the Korea Institute of Military Science and Technology
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    • v.27 no.1
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    • pp.60-69
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    • 2024
  • The importance of geospatial information is increasingly highlighted in the defense domain. Accurate and up-to-date geospatial data is essential for situational awareness, target analysis, and mission planning in millitary operations. The use of high-resolution geospatial data in military operations requires large storage and fast image processing capabilities. Efficient image processing is required for tasks such as extracting useful information from satellite images and creating 3D terrain for mission planning, In this paper, we designed a cloud-based operational situation mixed reality visualization system that utilizes large-scale geospatial information distributed processed on a cloud server based on the container orchestration platform Kubernetes. We implemented a prototype and confirmed the suitability of the design.

Error-Preventing Monitoring System using RFID in the Mixed-Model Automotive Parts Assembly Line (혼합형 모델 자동차부품 조립라인에서의 RFID를 이용한 오류방지 모니터링시스템)

  • Koo, Ja-Rok
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.12
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    • pp.3863-3869
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    • 2009
  • In recent years, globalization of markets and increased consumer sophistication in automotive industry have led to an increase in the variety of products and a consequent increase in the number of variants of any given product line that a manufacturer must supply. Also, the modularity trend of automotive production systems greatly affects on the production systems of automotive parts suppliers. These typically requires the implementation of cost efficient, flexible production systems, so called mixed-model assembly lines. We studied the problems of mixed-model assembly and assembly error-preventing techniques, and developed the error-preventing monitoring system using RFID in the mixed-model automotive parts assembly line. Especially, this study aimed to solve the problems and supplement the existing systems for preventing assembly errors, by developing a monitoring system using RFID to minimize the issues currently occurring in the field of automotive parts assembly, such as losses from incorrect installation and omission.

Mixed $H_{2}/H_{\infty}$ Controller Design for Descriptor Systems (디스크립터 시스템을 위한 혼합 $H_{2}/H_{\infty}$제어기의 설계)

  • Choe, Yeon-Wook
    • The Transactions of the Korean Institute of Electrical Engineers D
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    • v.53 no.7
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    • pp.483-490
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    • 2004
  • The descriptor system model has a high ability in representing dynamical systems. It can preserve physical parameters in the coefficient matrices, and describe the dynamic part, static part, and even the improper part of the system in the same form. The design of mixed $H_{2}/H_{\infty}$ controllers for linear time-invariant descriptor systems is considered in this paper. Firstly, an $H_2$ and $H_{\infty}$ synthesis problems fur a descriptor system are presented separately in terms of linear matrix inequalities (LMIs) based on the bounded real lemma. Then, we show that the existence of a mixed $H_2/H_{\infty}$ controller by which the $H_2$ norm of the second channel is minimized while keeping the $H_2$ norm bound of the first channel less than ${\gamma}$, is reduced to the linear objective minimization problem. The class of desired controllers that are assumed to have the same structure as the plant is parameterized by using the linearizing change of variables.

Probabilistic Performance Evaluation Technique for Mixed-criticality Scheduling with Task-level Criticality-mode (작업별 중요도 모드를 적용한 혼합 중요도 스케줄링에서 확률적 성능 평가 기법)

  • Lee, Jaewoo
    • The Journal of Society for e-Business Studies
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    • v.23 no.3
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    • pp.1-12
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    • 2018
  • Mixed-criticality systems consist of components with different criticality. Recently, components are categorized depending on criticality by ISO 26262 standard and DO-178B standard in automotive and avionic domain. Existing mixed-criticality system research achieved efficient and safe scheduling through system-level criticality mode. The drawback of these approaches is performance degradation of low-criticality tasks on high-criticality mode. Task-level criticality mode is one method to address the problem and improve the performance of low-critical tasks. In this paper, we propose probabilistic performance metric for the approach. In simulation results with probabilistic performance metric, we showed that our approach has better performance than the existing approaches.

Mixed Micellization of Anionic Ammonium Dodecyl Sulfate and

  • Gang, Gye Hong;Kim, Hong Un;Im, Gyeong Hui;Jeong, No Hui
    • Bulletin of the Korean Chemical Society
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    • v.22 no.9
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    • pp.1009-1014
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    • 2001
  • In aqueous mixtures of cationic OTAC (octadecyl trimethyl ammonium chloride) and anionic ADS (ammonium dodecyl sulfate) surfactants, mixed micelles were formed at low (< 0.2 wt %) total surfactant concentrations. For these mixtures mixed micelliza tion and interaction of surfactant molecules were examined. Mixed critical micelle concentration (CMC), thermodynamic potentials of micellization, and minimum area per surfactant molecule at the interface were obtained from surface tensiometry and electrical conductometry. The mixed micellar compositions and the estimation of interacting forces were determined on the basis of a regular solution model. The CMCs were reduced, although not substantial, and synergistic behavior of the ADS and OTAC in the mixed micelles was observed. The CMC reductions in this anionic/cationic system were comparable to those in nonionic/anionic surfactant systems. The interaction parameter $\beta$ of the regular solution model was estimated to be -5 and this negative value of $\beta$ indicated an overall attractive force in the mixed state.

An intelligent mixed mode algorithm of a master controller using position and rate mode (위치.속도 제어 방식을 이용한 매스터 컨트롤러 지능형 혼합 제어 알고리즘)

  • 김기홍;권동수
    • 제어로봇시스템학회:학술대회논문집
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    • 1997.10a
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    • pp.245-248
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    • 1997
  • The control modes used in teleoperation are position control mode, and rate control mode. This paper presents the problems of the conventional control modes, through simulation, proposes an intelligent mixed control mode that converts the operation mode between the position mode and the rate mode intelligently by judging the operator's intention using the real-time measurement data. The effectiveness of the proposed intelligent mixed control mode is demonstrated and compared to other typical control modes through simulation and actual experiment.

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Model Grouping in a Mixed-model Assembly Line (조립생산 시스템에서의 혼합 모델 그룹화)

  • Kim, Yearn-Min;Seo, Yoon-Ho
    • IE interfaces
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    • v.9 no.2
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    • pp.39-45
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    • 1996
  • This paper investigates the problems of grouping N products on an assembly line with an objective of maximizing the option grouping rate. Before developing a mixed model grouping algorithm, simulation studies are committed for developing operating rules and evaluating the layout production systems. A mixed model grouping algorithm is suggested and it is applied to the color selection lane in automobile production system, which reveals a high mixed model grouping rate.

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The effect of an EML sequence and an interlayer on the performance of the phosphorescent-fluorescent mixed WOLEDs

  • Baek, Heume-Il;Lee, Chang-Hee
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.1215-1218
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    • 2008
  • We investigate the effect of a light emitting layer (EML) sequence and an interlayer on the performance of the phosphorescent-fluorescent mixed white organic light emitting diodes. Two types of phosphorescent-fluorescent mixed system were evaluated. The proper position of each primary color EML was crucial to obtain best performance in each system whereas the effect of an interlayer was found to be different in both systems.

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Mixed Wave Function for Heavy Fermion Compounds

  • Bang, Yun-Kyu
    • Progress in Superconductivity
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    • v.11 no.2
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    • pp.135-140
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    • 2010
  • We propose a variational wave function for the ground state of the magnetic heavy fermion (HF) systems, in which both the Kondo and the RKKY interactions are variationally incorporated and the local f-orbital state exists as a linear combination of a full local moment state and a fully compensated state (mixed wave state). We describe the mechanism for the mixed wave ground state based on the large-N treatment of the Kondo lattice Hamiltonian added with RKKY interaction. With the mixed wave ground state we can explain several puzzling experiments in magnetic HF compounds such as a small value of local moment, coexistence of the antiferromagnetic (AFM) and the paramagnetic (PM) phases, local quantum criticality, etc.