• Title/Summary/Keyword: Mixed contaminants

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Development of the Two-Zone Model to Estimate the Air Quality in Indoor Environments (실내 공기질 평가를 위한 2구획 모델의 개발)

  • 조석호;양성환;이봉헌;정성욱;이병호
    • Journal of Environmental Science International
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    • v.7 no.6
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    • pp.745-751
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    • 1998
  • The well-mixed room model has been traditionally used to predict the concentrations of contaminants in indoor environments. However, this is inappropriate because the flow fields in many indoor environments distribute contaminants non-uniformly, due to imperfect air mixing. Thus, some means used to describe an imperfectly mixed room are needed. The simplest model that accounts for imperfect air mixing is a two-zone model. Therefore, this study on development of computer program far the two-zone model is carried out to propose techniques of estimating the concentration of contaminants in the room. To do this, an important consideration is to divide a room into two-zone, i.e. the lower and upper zone assuming that the air and contaminants are well mixed within each zone. And between the zones the air recirculation is characterized through the air exchange parameter. By this basic assumption, the equations for the conservation of mass are derived for each zone. These equations are solved by using the computational technique. The language used to develope the program is a VISUAL BASIC. The value of air exchange coefficient($f_12$) is the most difficult to forecast when the concentrations of contaminants in an imperfectly mixed room are estimated by the two-zone model. But, as the value of $f_12$ increases, the air exchange between each zone increases. When the value of $f_12$ is approximately 15, the concentrations in both zone approach each other, and the entire room may be approximately treated as a single well-mixed room. Therefore, this study is available for designing of the ventilation to improve the air quality of indoor environments. Also, the two-zone model produces the theoretical base which may be extended to the theory for the multi-zone model, that will be contributed to estimate the air pollution in large enclosures, such as shopping malls, atria buildings, atria terminals, and covered sports stadia.

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Performance Evaluation of the Multistage Soil Washing Efficiency for Remediation of Mixed-contaminated Soil with Oil and Heavy Metals (유류/중금속 복합오염토양 정화를 위한 다단 토양세척 효율평가)

  • Kim, Daeho;Park, Kwangjin;Cho, Sungheui;Kim, Chikyung
    • Journal of Soil and Groundwater Environment
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    • v.22 no.2
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    • pp.33-40
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    • 2017
  • In typical remediation practices, separate washing systems have to be applied to clean up the soils contaminated with both oil and heavy metals. In this study, we evaluated the efficiency of successive two-stage soil washing in removal of mixed-contaminants from soil matrix. Two-stage soil washing experiments were conducted using different combinations of chemical agent: 1) persulfate oxidation, followed by organic acid washing, and 2) Fenton oxidation, followed by inorganic acid washing. Persulfate oxidation-organic acid washing efficiently removed both organic and inorganic contaminants to meet the regulatory soil quality standard. The average removal rates of total petroleum hydrocarbons (TPH), Cu, Pb, and Zn were 88.9%, 82.2%, 77.5%, and 66.3% respectively, (S/L 1:10, reaction time 1 h, persulfate 0.5 M, persulfate:activator 3:1, citric acid 2 M). Fenton oxidation-inorganic acid washing also gave satisfactory performances to give 89%, 80.9%, 87.1%, and 67.7% removal of TPH, Cu, Pb, and Zn, respectively (S/L 1:10, reaction time 1 hr, hydrogen peroxide 0.3 M, hydrogen peroxide:activator 5:1, inorganic acid 1 M).

Application of optimized time domain reflectometry probe for estimating contaminants in saline soil

  • Dongsoo Lee;Jong-Sub Lee;Yong-Hoon Byun;Sang Yeob Kim
    • Geomechanics and Engineering
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    • v.33 no.3
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    • pp.291-299
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    • 2023
  • Monitoring contaminants in waste landfills on a seabed is important because the leachate affects the marine ecosystem and facility stability. The objective of this study is to optimize a time-domain reflectometry (TDR) probe using different coating materials and several electrodes to estimate contaminants in saline soil. Copper concentrations ranging from 0 mg/L to 10 mg/L were mixed in 3% salinity water to simulate contaminants in the ocean environment. Epoxy, top-coat, and varnish were used as coating materials, and two to seven electrodes were prepared to vary the number and arrangement of the electrodes. Test results showed that the varnish stably captured the increase in copper concentration, while the other coating materials became insensitive or caused leakage current. In addition, a TDR probe with more electrodes exhibited stable and distinct electromagnetic signals. Thus, the TDR probe with seven electrodes coated with varnish was effectively used to estimate contaminants in saline soil.

옥외에서 사용되는 배전급 폴리머 현수애자의 오손특성에 관한 연구

  • Lee, Byung-Sung;Han, Sang-Ok
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.50 no.7
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    • pp.340-345
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    • 2001
  • Because they have superior insulating properties and lower in price than their ceramic equivalents, polymeric insulators have been used in outdoor insulators. But polymeric insulators mainly using in an heavy contamination area of outdoor could be easily attached to contaminants such as salt and by-products of industrial processes. To understand its effect on contaminants adhered to these insulators, we dismounted polymeric insulators adhered contaminant in the field, and evaluated its electrical characteristics, CA, and ESDD. We also manufactured slurry mixed by some kaolin and salt for the artificial contamination test and measured the degree of contaminant, AC leakage current for these contaminated samples. Consequently, the adhered contaminants to its surface is likely to be affected the performance of insulation.

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Development and Application of an In Situ Technology to Treat Various Soil and Groundwater Contaminants

  • Goltz, Mark N.
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.10a
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    • pp.89-110
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    • 2003
  • The limitations of conventional soil and groundwater contamination remediation technologies have motivated a search for innovative technologies; particularly in situ technologies that do not require extraction of contaminants from the subsurface. All engineered in situ remediation systems require that the contaminant be mixed with a remedial compound. Horizontal flow treatment wells (HFTWs), an innovative technology that consists of a pair of dual-screened treatment wells, were used at a trichloroethylene (TCE) contaminated site to efficiently achieve this mixing of contaminant and remedial compound in order to effect in situ bioremediation (McCarty et al., 1998). In this paper, the potential of HFTWs to treat chlorinated aliphatic hydrocarbons (CAHs) as well as other soil and groundwater contaminants of concern, such as nitroaromatic compounds (NACs), perchlorate, and methyl-tert-butyl ether (MTBE), is examined. Through a combination of laboratory studies, model analyses, and field evaluations, the effectiveness of this innovative technology to manage these contaminants is investigated.

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Removal of Semi-volatile Soil Organic Contaminants with Microwave and Additives (극초단파(마이크로파)와 첨가제를 이용한 오염토양 내 준휘발성 유기오염물질 제거)

  • Jeong, Sangjo;Choi, Hyungjin
    • Journal of Soil and Groundwater Environment
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    • v.18 no.1
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    • pp.67-77
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    • 2013
  • To improve the energy efficiency of conventional thermal treatment, soil remediation with microwave has been studied. In this study, the remediation efficiency of contaminated soil with semi-volatile organic contaminants were evaluated with microwave oven and several additives such as water, formic acid, iron powder, sodium hydroxide (NaOH) solution, and activated carbon. For the experiment, loamy sand and sandy loam collected from Imjin river flood plain were intentionally contaminated with hexachlorobenzene and phenanthrene, respectively. The contaminated soils were treated with microwave facility and the mass removals of organic contaminants from soils were evaluated. Among additives that were added to increase the remediation efficiency, activated carbon and NaOH solution were more effective than water, iron powder, and formic acid. When 10 g of hexachlorobenzene (142.4 mg/kg-soil) or phenanthrene (2,138.8 mg/kg-soil) contaminated soil that mixed with 0.5 g iron powder, 0.5 g activated carbon and 1 ml 6.25 M NaOH solution were treated with microwave for 3 minutes, more than 95% of contaminants were removed. The degradation of hexachlorobenzene during microwave treatments with additives was confirmed by the detection of pentachlorobenzene and tetrachlorobenzene. Naphthalene and phenol were also detected as degradation products of phenanthrene during microwave treatment with additives. The results showed that adding a suitable amount of additives for microwave treatments fairly increased the efficiency of removing semi-volatile soil organic contaminants.

Distribution and Behavior of Mixed Contaminants, Explosives and Heavy Metals, at a Small Scale Military Shooting Range (국내 소규모 군사격장 복합오염물질(화약물질 및 중금속)의 분포 및 거동)

  • Park, Seokhyo;Bae, Bumhan;Kim, Minkyung;Chang, Yoonyoung
    • Journal of Korean Society on Water Environment
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    • v.24 no.5
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    • pp.523-532
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    • 2008
  • A phase II site investigation and feasibility study was conducted at a military mortar shooting range near the demilitarized zone (Kyunggi, South Korea) to assess the extent of contaminants migration to the nearby Imjin river in which a flood control dam is under construction. The results showed that silty-clay soils around target areas were co-contaminated with heavy metals (Cd, Cu, and Pb) and explosives (HMX, RDX, and TNT). The total amount of contaminant was estimated to be 497.1 kg-RDX, 20.6 kg-HMX, 1.4 kg-TNT, 35.2 kg-Cd, 4,331 kg-Cu, and 5,115 kg-Pb, respectively. Both heavy metals and explosives were almost equally distributed on each soil particle size fraction. Neither subsurface soil samples nor ground water samples showed signs of contamination above the environmental criteria. The major migration route of contaminants was soil particles in surface run-off during rain at which a mass discharge rate of 30.0 mg-RDX/hour was observed.

Removal of TCE using zero valent iron (ZVI) with other contaminants

  • 조현희;박재우
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.04a
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    • pp.58-61
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    • 2002
  • An alternative to pump and treat groundwater remediation is the use of reactive barriers. Zero valent iron (ZVI) is particularly useful as a reductant of chlorinated hydrocarbons because of its low cost and lack of toxicity ZVI can drive the dechlorination of chlorinated organic compounds and the reduction of chromium from the Cr(Ⅵ) to the Cr(III) state. The contaminants in subsurface environment usually exist as the mixed compounds. Therefore, the objective of this research is to study the effect of the other compounds on TCE removal by ZVI. The removal mechanism of TCE by ZVI is separated the dechlorination and sorption. TCE removal by ZVI slightly increased in presence of naphthalene as the non-reduced compound. TCE removal by ZVI remarkable decreased in presence of carbon tetrachloride, nitrate, and chromate as the reduced compounds. This research suggests that the effect of the coexisted compounds on the removal chlorinated compounds by reactive barrier technology should be considered for practical application.

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The Influence of Pore Water Contamination on the Cement Treated Sandy Soil (공극수 오염이 시멘트 고화처리된 사질토에 미치는 영향)

  • Yu, Chan
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.45 no.6
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    • pp.144-152
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    • 2003
  • Laboratory experiments were carried out to investigate the influence of pore water contamination on the treatment effect of sandy soil which was solidified by Portland cement. In the experiments, setting time of hydraulic cement that was mixed with contaminated mixing water was measured using Vicat equipment and observed the tendency of setting process with the kind of contaminants, organic or inorganic components. It was shown that organic contaminants of the mixing water affect largely on the initial setting process of hydraulic cement and inorganics, expecially heavy metals, did not affect on the initial setting process, otherwise it was appeared that setting time of the sandy soil that was contaminated with inorganic components was apparently faster than the sandy soil that did not include inorganic components even though organic concentrations was relatively low level (COD=200∼300) in the mixing water. The results of unconfined compression strength test (UCST) were well consistent with the results of Vicat equipment test.

The Characteristics of Artificial Contamination of Distribution Polymer Insulators Used for Outdoor Insulation (옥외에서 사용되는 배전용 폴리머애자의 인공오손 특성)

  • 이병성;한재홍;김찬영;한상옥
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.595-597
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    • 2000
  • Poymeric insulators using in an heavy contamination area are easily attached to contaminants such as salt and by-products of industrial processes. To understand its effect on contaminants adhered to these insulators, we manufactured slurry mixed by some kaolin and salt as artificial contaminated solution. And then put samples in its slurry, for about one minute. And these samples are dried in natural condition for 6 days. We measured the degree of contaminant, AC leakage current for these contaminated samples.

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