• Proceedings of the Korea Concrete Institute Conference
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• 2001.11a
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• pp.409-414
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• 2001

The hydration of cement paste occurs when the cement is mixed with water. During the hydration, hydration heat causes the thermal stress depending on the size of concrete and the cement content. Especially in the high-strength concrete, we must give care to the concrete due to its large cement content. In this study, conduction calorimeter and concrete insulation hydration heat meter were used to investigate the hydration heat characteristics of cement and concrete. To reduce hydration heat of high-strength concrete, several types of replacement of fly-ash and blast-furnace slag powder were used in this experiment.

• International Journal of Air-Conditioning and Refrigeration
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• v.10 no.1
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• pp.31-39
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• 2002

Microencapsulated pcm (MPCM) particles are mixed with distilled water and utilized to evaluate its characteristics and performance as a thermal storage medium transporting heat. For the present study, tetradecane ($C_14$$H_30$, $T_m$=5.5$^{\circ}C$) is capsulated in the core, coated with the melamine for their surface. The size of particles is well-controlled under 10$\mu$m in the process of in-situ polymerization with melamine-formaldehyde resin. For the experiment, the concentractions of slurries are prepared for 20 wt%, 30 wt%, and 40 wt%. The results are compared with those of water and 100% tetradecane oil. The pure water and tetradecane start solidifying within 20 minutes after introducing cooling water into the thermal storage tank whose flow rates are varied by 125 cc/min, 250 cc/min, and 500 cc/min. However, MPCM slurries are required relatively longer period of time for their phase change than pure phase change materials. That is, the entrained MPCM particles restrict their heat transfer in terms of natural convection and conduction to them.

• Journal of Welding and Joining
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• v.15 no.6
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• pp.105-115
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• 1997

A numerical study is performed to predict the thermal response of a detailed card assembly during infrared reflow soldering. The card assembly is exposed to discontinuous infrared panel heater temperature distributions and high radiative/convective heating and cooling rates at the inlet and exit of the oven. The convective, radiative and conduction heat transfer within the reflow oven as well as within the card assembly are simulated and the predictions illustrate the detailed thermal responses. The predictions show that mixed convection plays an important role with relatively high frequency effects attributed to buoyancy forces, however the thermal response of the card assembly is dominated by radiation. The predictions of the detailed card assembly thermal response can be used to select the oven operating conditions to ensure proper solder melting and minimization of thermally induced card assembly tresses and warpage.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.303-303
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• 2011

Orderings and electronic structures of organic molecules on metal substrates have been studied due to possible applications in electronic devices. In molecular systems, delocalized pi-electrons play important roles in the adsorption behaviors and electronic structures. We studied the adsorption and electronic structures of Co-Porphyrin molecules on Au(111) using scanning tunneling microscopy (STM) and spectroscopy (STS) at low temperature. Molecules form closely packed two-dimensional islands on Au(111) surface with two different types, having different shape evolutions in our energy-dependent STM observations. The Kondo resonance state, occurred by spin exchange interaction between the Co center atom and conduction electrons in the metal substrate, was observed in one type, while it was absent in the other type in scanning tunneling spectroscopy measurements. Possible origins of two molecular shapes will be discussed.

• Proceedings of the Korean Society of Laser Processing Conference
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• 2001.05a
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• pp.31-34
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• 2001

Laser cladding Processing allows rapid transfer of heat to the material being minimum conduction into base metal. The effects of CO$_2$ laser cladding with high powder were investigated. High viscosity bronze powder consists of bronze powder used at a high temperature. The material has a high viscosity So that it can be substrate. Therefore. Laser cladding can be processed on a curved or slope surface. CO$_2$ laser cladding was designed It consists of the high viscosity bronze powder the shielding gas system and the preheating system The high viscosity powder properly at 0.3g/s and 0.50g/s. Because of the metallic bond between bronze per the hardness of dilution layer was suddenly increased. Experimental as results viscosity mixed powder can be a useful cladding material.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1999.11a
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• pp.374-377
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• 1999

The purpose of this study is to research and develop solid polymer electrolyte(SPE) for Li polymer battery. This paper describes temperature dependence of conductivity, impedance spectroscopy, electrochemical properties of PVDF/PAN electrolytes as a function of a mixed ratio. PVDF/PAN based polymer electrolyte films were prepared by thermal gellification method of preweighed PVDF/PAN, plasticizer and Li salt. The conductivity of PVDF/PAN electrolytes was 10-3S/cm. 20PVDF5PANLiCIO$_4$PC$\sub$10//EC$\sub$10/ electrolyte shows the better conductivity of the others. 20P7DF5PANLiCI$_4$PC$\sub$10//EC$\sub$10/ electrolyte remains stable up to 5V vs. Li/Li$\^$+/. Steady state current method and ac impedance used for the determination of transference numbers in PVDF/PAN electrolyte film. The transference number of 20PVDF5ANLICIO$_4$/PC $\sub$10//EC$\sub$10/ electrolyte is 0.48

• Bulletin of the Korean Chemical Society
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• v.9 no.1
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• pp.21-24
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• 1988

The electrical conductivitv of the system $ThO_2-Ho_2O_3$ was measured in the temperature range 600-$1100^{\circ}C$ and $Po_2$range $10^{-5}-2{\times}10^{-1}$ atm. The mean value of activation energy was 1.45 eV. The observed conductivity dependence on $Po_2$ was ${Po_2}^{1/4}$ at $Po_2$'s above $10^{-3}$ atm and was independent on oxygen partial pressure at $Po_2$'s below $10^{-3}$ atm. It is suggested that these dependences are due to a mixed ionic plus electron hole conduction by Vo defect.

• Bulletin of the Korean Chemical Society
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• v.16 no.3
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• pp.261-264
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• 1995

A series of samples of the Nd1-x(Ba0.40Mg0.60)1+xFeO4-y (x=0.00, 0.10, 0.20, and 0.30) system has been synthesized at 1450 ℃ under an atmospheric air pressure. The x-ray powder diffraction analysis of the solid solutions assigns the structure of all the compositions to orthorhombic system. Mohr salt analysis shows that τ and y values increase with x value and nonstoichiometric chemical formulas of the system can be formulated from the x, τ, and y values. Oxygen vacancies are distributed along c-axis in the perovskite layer. The magnetic ordering temperature remains unchanged with x value. Electrical conductivity and activation energy depend only on the mixed valence state of Fe ion. Conduction mechanism can be suggested as the hopping of electron between eg orbitals of Fe3+ and Fe4+ ions through Fe3+-O-Fe4+ bonds. Magnetic susceptibility and electrical conductivity are discussed with the nonstoichiometric chemical formulas.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.22 no.8
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• pp.1111-1120
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• 1998

Spray Drying Absorber(SDA) system, where the combustion product gas is mixed with atomized limestone-slurry droplets and then the chemical reaction of $SO_2$ with alkaline components of the liquid droplets forms sulfates, has been widely used to eliminate $SO_2$ gas from coal fired power plants and waste incinerators. Liquid atomization is necessary because it can maximize the reaction efficiency by increasing the total surface area and dispersion angle of the alkaline components. First, numerical calculations using FLUENT are carried out to investigate $SO_2$ concentration distribution and thus to calculate $SO_2$ removal efficiency. So to attain the optimized spray conditions, then an electrostatic spraying system is set up and spray visualization is performed to show the effect of an electric field on overall droplet size. Next, the effect of an electric field on the concentrations of $SO_2$ is experimentally examined. Field strength is varied from -10 kV to 10 kV and configurations of conduction charging and induction charging are utilized. Consequently, the electrostatic removal efficiency of 501 increases about 30% with the applied voltage of ${\pm}10kV$ but is independent of polarity of the applied voltage. It Is also found that the conduction charging configuration results in higher efficiency of $SO_2$ removal that the induction charging configuration. Finally, the effect of slurry temperature on $SO_2$ removal is studied. The temperature influences on the electrostatic removal efficiency of $SO_2$.

• Steel and Composite Structures
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• v.30 no.3
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• pp.281-292
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• 2019

In this paper, analysis of critical fluid velocity and heat transfer in the nanocomposite pipes conveying nanofluid is presented. The pipe is reinforced by carbon nanotubes (CNTs) and the fluid is mixed by $AL_2O_3$ nanoparticles. The material properties of the nanocomposite pipe and nanofluid are considered temperature-dependent and the structure is subjected to magnetic field. The forces of fluid viscosity and turbulent pressure are obtained using momentum equations of fluid. Based on energy balance, the convection of inner and outer fluids, conduction of pipe and heat generation are considered. For mathematical modeling of the nanocomposite pipes, the first order shear deformation theory (FSDT) and energy method are used. Utilizing the Lagrange method, the coupled pipe-nanofluid motion equations are derived. Applying a semi-analytical method, the motion equations are solved for obtaining the critical fluid velocity and critical Reynolds and Nusselt numbers. The effects of CNTs volume percent, $AL_2O_3$ nanoparticles volume percent, length to radius ratio of the pipe and shell surface roughness were shown on the critical fluid velocity, critical Reynolds and Nusselt numbers. The results are validated with other published work which shows the accuracy of obtained results of this work. Numerical results indicate that for heat generation of $Q=10MW/m^3$, adding 6% $AL_2O_3$ nanoparticles to the fluid increases 20% the critical fluid velocity and 15% the Nusselt number which can be useful for heat exchangers.