• Title/Summary/Keyword: Mixed conduction

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Preparation of Conductive SrMoO3 Thin Films by RF Magnetron Sputtering and Evaluation of Their Electrical Conduction Properties (RF 마그네트론 스퍼터법을 사용한 전도성 SrMoO3 박막 제조 및 전기전도특성 평가)

  • Ryu, Hee-Uk;Sun, Ho-Jung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.6
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    • pp.468-472
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    • 2011
  • Conductive $SrMoO_3$ thin films were fabricated by RF magnetron sputtering with the powder-type sputtering target, and annealed for crystallization. When RTP (rapid thermal processing) in vacuum was applied, the fabricated thin films showed the mixed phases of $SrMoO_3$ and $SrMoO_4$, but $SrMoO_3$ phase could be promoted by the lowering of the working pressure during deposition. In order to eliminate $O_2$ gas during deposition and annealing, further lowering of the working pressure and furnace annealing in hydrogen atmosphere were tried. With the optimization of the deposition and annealing conditions, the thin film with nearly single-phase of $SrMoO_3$ was obtained, and it showed good electrical conduction properties with a low resistivity of $2.5{\times}10^{-3}{\Omega}{\cdot}cm$ at room temperature.

The Electrical Properties of $(SrPb)(CaMg)TiO_3$ Ceramics with Contents of $Bi_2O_3{\cdot}3TiO_2$ ($Bi_2O_3{\cdot}3TiO_2$의 첨가량에 따른 $(SrPb)(CaMg)TiO_3$ 세라믹의 전기적 특성)

  • Kim, Chung-Hyeok
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.2
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    • pp.111-120
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    • 1998
  • In this paper, the $(SrPb)(CaMg)TiO_3$ ceramics with paraelectric properties were fabricated by the mixed oxide method. It was investigated that which the variation of contents of $Bi_2O_3{\cdot}3TiO_2$ effects on structural, dielectrical and electrical properties of specimens. As a result, the grain size were grown with increasing the contents of $Bi_2O_3{\cdot}3TiO_2$. The relative dielectric constants were increased up to 4[mol%] of $Bi_2O_3{\cdot}3TiO_2$, and decreased more or less at a low temperature in the specimens which had more than. But the temperature coefficient. of capacitance were showed ${\pm}25$[%]. The dielectric loss were less than 0.05 in all specimens which had more than 4[mol%] of $Bi_2O_3{\cdot}3TiO_2$. In order to investigate the behavior of charged particles, the characteristics of electrical conduction were measured. As a result, the conduction current was divided into the three steps as a function of DC electric field. The first step was Ohmic region due to ionic conduction, below 15[kV/cm]. The second step was showed a saturation which seems to be related to a depolarizing field occuring in field-enforced ferroelectric phase, between 15[kV/cm] and 40[kV/cm]. The third step was attributed to Child's law related to space charge which injected from electrode, above 40[kV/cm].

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Clinical and Electrophysiological Characteristics of the Patient with 'Mononeuropathy multiplex' (다발성 단신경병증의 임상적, 전기생리학적 특성)

  • Park, Kyung-Seok;Chung, Jae-Myun;Park, Seong-Ho;Lee, Kwang-Woo
    • Annals of Clinical Neurophysiology
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    • v.4 no.1
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    • pp.34-37
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    • 2002
  • Background : The term "mononeuropathy multiplex" means simultaneous or sequential involvement of individual noncontiguous nerve trunks, evolving over days to years. The aim of this study was to delineate the causes, clinical features, and detailed electrophysiological findings in the patients with mononeuropathy multiplex. Methods : We analyzed the medical records of 22 patients with mononeuropathy multiplex confirmed on electrophysiological studies in Inje University Seoul Paik Hospital, Seoul Municipal Boramae Hospital, and Seoul National University Hospital between 1991 to 2000. Results : The number of male and female patients was equal. The mean age was 48 years with a peak incidence in the sixth decade. The etiology could be divided into vasculitis(11 patients) or non-vasculitis group. In vasculitis group, Churg-Strauss syndrome, polyarteritis nodosa, and rheumatoid arthritis were included. The non-vasculitis group included diabetes mellitus, leprosy, and Guillain-Barre syndrome. Ulnar and median nerves were most commonly involved(91%). In descending order of frequency, peroneal, posterior tibial, sural, and radial nerves were also involved. Bilateral involvement occurred most commonly in ulnar nerve. The symptoms and signs of mononeuropathy multiplex were the initial manifestations in 12 patients(55%), which was more frequent in vasculitis group(73%). Nerve conduction abnormalities could be divided into axonal, demyelinating, or mixed type. Most(91%) of the patients in vasculitis group revealed axonal type abnormalities. The location of the nerve lesion was frequently related to potential site of entrapment in demyelinating type. Conclusions : Mononeuropathy multiplex is the presenting features of the etiological disease frequently, especially in vasculitis group. Nerve conduction studies(NCS) reveals not only axonal type but also demyelinating type abnormalities. The etiological diseases were different in each type. Therefore, NCS is very helpful for the early etiological diagnosis and therapeutic implication in the patients with mononeuropathy multiplex.

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Supercapacitive Properties of RuO2 and Ru-Co Mixed Oxide Deposited on Single-Walled Carbon Nanotube (단일벽 탄소나노튜브 상에 석출된 산화루테늄과 루테늄-코발트 혼합산화물의 수퍼커패시터 특성)

  • Ko, Jang Myoun;Kim, Kwang Man
    • Korean Chemical Engineering Research
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    • v.47 no.1
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    • pp.11-16
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    • 2009
  • Composite electrodes for redox supercapacitor were prepared potentiodynamically by the deposition of $RuO_2$ and the co-deposition of Ru-Co mixed oxide on the surface of single-walled carbon nanotube. Electrode of Ru-Co mixed oxide, in which Ru(13.13 wt%) and Co(2.89 wt%) were deposited on the carbon nanotube, exhibited a similar specific capacitance(${\sim}620\;F\;g^{-1}$) with $RuO_2$ electrode at a low potential scan rate($10\;mV\;s^{-1}$), but showed a superior one ($570\;F\;g^{-1}$) at a high scan rate($500\;mV\;s^{-1}$) than that of $RuO_2$($475\;F\;g^{-1}$). Such increase in the specific capacitance at high scan rate by the co-deposition of Ru and Co species was due to the structural support of Co species to provide the electronic conduction through Ru species.

Mixed Ionic and Electronic Conductivity of Lanthanum Sesquioxide (산화란타늄의 이온 및 전자전도도)

  • Keu Hong Kim;Chang Kwon Kang;Jong Hwan Lee;Jae Shi Choi
    • Journal of the Korean Chemical Society
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    • v.31 no.4
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    • pp.301-307
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    • 1987
  • The electrical conductivity of highly pure polycrystalline sample of $La_2O_3$ has been measured at temperatures from $600^{\circ}C$ to $1,050^{\circ}C$ and oxygen pressure range of $1{\times}10^{-6}$ torr to $1{\times}10^2$ torr. The defect structure and semiconductor type are investigated by measuring the temperature and oxygen pressure dependences of electrical conductivity. Sintered $La_2O_3$ exhibits the electrical conductivities in the range of $1{\times}10^{-9}\;to\;1{\times}10^{-3}\;ohm^{-1}{\cdot}cm^{-1}$ under the above oxygen pressures. The oxygen pressure dependences on electrical conductivity are characterized by 5.3 at $1,000^{\circ}C$ and 5.7 at $700^{\circ}C$ and more higher values of 9∼14 below $700^{\circ}C$. The increase in n value with decreasing temperature indicates that a simple conduction mechanism does not exist in this material. The conduction carriers are not metal vacancy but oxygen ion at lower pressures. The conduction data indicate a significant ionic conduction at lower temperatures and electronic conduction at higher temperatures.

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A Study on Nonstoichiometry and Physical Properties of the Mixed Valency Sr$_{1+x}Er _{1-x} FeO _{4-y}$ Ferrite System (혼합원자가 Sr$_{1+x}Er _{1-x} FeO _{4-y}$ 훼라이트계의 비화학양론과 물성연구)

  • Chul Hyun Yo;Kwang Sun Ryu;Mu Sil Pyun;Sung Joo Lee;Joong Gill Choi
    • Journal of the Korean Chemical Society
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    • v.35 no.2
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    • pp.99-104
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    • 1991
  • Nonstoichiometric solid solutions of Sr$_{1+x}Er _{1-x} FeO _{4-y}$ system (x = 0.00, 0.25, 0.50, 0.75 and 1.00) with layered $K_2NiF_4$ type structure were prepared at 1350$^{\circ}$C under atmospheric pressure. By the analysis of X-ray diffraction, the crystallographic structures of the solid solution of all compositions were found to be pseudo-tetragonal system. Nonstoichiometric chemical formulas have been determined by Mohr salt analysis. It shows that the amount of Fe$^{4+}$ increases with increasing x up to 0.50 and then decreases, and the value of oxygen nonstoichiometry increases with increasing x value. Mixed valency states of Fe$^{3+}$ and Fe$^{4+}$ in the sample were identified again by Mossbauer spectroscopic analysis at 298 K. Electrical conductivity varied within the semiconductivity range of 10-2 ∼ 10-7(${\Omega}$-1cm-1), activation energy for electrical conduction decreased with the increment of the mole ratio of Fe$^{4+}$ or ${\tau}$ value. The conduction mechanism could be explained by the hopping model of the conduction electrons between the valency states of Fe$^{3+}$ and Fe$^{4+}$.

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The Electrical Properties of Thin Film Mixed With LLDPE and EVA (LLDPE와 EVA를 혼합한 박막의 전기적 특성)

  • Lee, Jong-Pil;Shin, Hyun-Taek;Cho, Kyung-Soon;Lee, Chung-Ho;Lee, Yoon-Joo;Hong, Jin-Woong
    • Proceedings of the KIEE Conference
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    • 1999.07d
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    • pp.1667-1670
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    • 1999
  • In this paper, We are studied the electrical properties of thin film mixed with LLDPE and EVA, and the specimen is selected as Low Linear Density Polyethylene and Ethylene Vinyl Acetate produced by mixture ratio of 50:50, 60:40, 70:30 and 80:20. (thickness $100[{\mu}m],\;70[{\mu}m],\;50[{\mu}m],\;30[{\mu}m]$). As the electrical properties. one is electrical conduction characteristics of the due to mixture ratio of linear low density polyethylene (LLDPE) and ethylene vinyl acetate(EVA), the other is AC breakdown of specimens due to variation of the thickness. From the result of XRD, it is confirmed that specimen of 80 : 20 and virgin LLDPE have high peaks at $2\theta=21.4[^{\circ}]$ and the peak by the contribution of amorphous at $2{\theta}=19.5[^{\circ}]$ is constant with no relation to mixture ratio, but virgin EVA is somewhat lower.

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Mixing effect on Properties of NTC Thermistor in Mn-Co-O System (Mn-Co-O계 NTC 써미스터의 물성에 미치는 혼합의 영향)

  • Yoon, Sang-Sik;Kim, Kyung-Sik;Yoon, Sang-Ok
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.459-462
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    • 2001
  • Interface effects on properties of NTC thermistors having Mn-Co-O spinel crytal structure system are analyzed by a mixing rule in case of mixed types and layered types between CuO and $Al_{2}O_{3}$ added compounds. With adding CuO and $Al_{2}O_{3}$, The compounds form completely solid solution and their resistance and B constant are changed due to the variation of conduction electrons by their ionic substitutions. The properties of mixed NTC thermistors are depended on the logarithmic mixing rule by a dispersed phase and they show slightly lower values due to the lattice mixing affect in compared with calculated values. The resistance of layered NTC thennistors is depended upon the series mixing rule containing the value of an interface layer and effected by the variation of its thickness, and it is changed rapidly to the logarithmic mixing rule by the connection between two layers with increasing the interface layer.

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Effects of Water-Repellent on the Physical Properties of Water Paint (발수제가 수성페인트의 물리적 성능에 미치는 영향)

  • Lee, Soo-Yong;Nam, Gee-Yung;Kim, Ji-Hyun
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.3
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    • pp.259-265
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    • 2014
  • This study is to analyze durability of water-repellent paints mixed with water-repellents as outer surface finishing materials, and evaluate its feasibility. General functions and water-repelling effects were tested, and the feasibility was evaluated based on the test results. The experimental results of heat conduction durability, air permeability, absorption, and bond strength suggested that water-repellent paints mixed with water-repellents were suitable for finishing materials. Considering overall general durability performances, stable mixing ratios were 2, 5, and 8%.

Modification of C/C Composite Bipolar Plate by Addition of Electro-Conductive Carbon Black

  • Ryu, Seung-Kon;Hwang, Taek-Sung;Lee, Seung-Goo;Lee, Sun-A;Kim, Chang-Soo
    • Carbon letters
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    • v.2 no.3_4
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    • pp.165-169
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    • 2001
  • Modification of C/C composite bipolar plate for improving electrical conductivity was carried out by addition of electroconductive carbon black (EC-CB). Carbon black was carefully mixed to methanol-containing phenolic resin, impregnated into 2D-carbon fabrics, hot pressed and then carbonized to obtain composite plate. Inclusion of electro-conductive carbon black enhanced the electrical conductivity of the C/C composites by increasing the conduction path. Addition of 10 vol% carbon black increased the electrical conductivity from 5.5/${\Omega}cm$ to 32/${\Omega}cm$ and reduced the crack formation by filling effect, resulting in the increase of flexural properties of composite plate. However, at carbon black content over 10 vol%, flexural properties decreased by delaminating role of excess carbon black at the interface in C/C composites.

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