• Economic and Environmental Geology
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• v.50 no.4
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• pp.257-266
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• 2017

Batch experiments were performed to develop the method for the pH reduction of recycled aggregate by using $scCO_2$ (supercritical $CO_2$), maintaining the pH of extraction water below 9.8. Three different aggregate types from a domestic company were used for the $scCO_2$-water-recycled aggregate reaction to investigate the low pH maintenance of aggregate during the reaction. Thirty five gram of recycled aggregate sample was mixed with 70 mL of distilled water in a Teflon beaker, which was fixed in a high pressurized stainless steel cell (150 mL of capacity). The inside of the cell was pressurized to 100 bar and each cell was located in an oven at $50^{\circ}C$ for 50 days and the pH and ion concentrations of water in the cell were measured at a different reaction time interval. The XRD and SEM-EDS analyses for the aggregate before and after the reaction were performed to identify the mineralogical change during the reaction. The extraction experiment for the aggregate was also conducted to investigate the pH change of extracted water by the $scCO_2$ treatment. The pH of the recycled aggregate without the $scCO_2$ treatment maintained over 12, but its pH dramatically decreased to below 7 after 1 hour reaction and maintained below 8 for 50 day reaction. Concentration of $Ca^{2+}$, $Si^{4+}$, $Mg^{2+}$ and $Na^+$ increased in water due to the $scCO_2$-water-recycled aggregate reaction and lots of secondary precipitates such as calcite, amorphous silicate, and hydroxide minerals were found by XRD and SEM-EDS analyses. The pH of extracted water from the recycled aggregates without the $scCO_2$ treatment maintained over 12, but the pH of extracted water with the $scCO_2$ treatment kept below 9 of pH for both of 50 day and 1 day treatment, suggesting that the recycled aggregate with the $scCO_2$ treatment can be reused in real construction sites.

• The Plant Pathology Journal
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• v.16 no.4
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• pp.216-221
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• 2000

Mixed infection of watermelon mosaic potyvirus II isolated from pumpkin (WMV-P) and cucumber green mottle mosaic tobamovirus from watermelon (CGMMV-W) caused extremely severe symptoms such as progressive silting and death of watermelon plants. Single infections of either WMV-P or CGMMV-W on the same hosts produced only vein clearing and/or mosaic on the upper leaves. In cells infected with WMV-P, potyvirus-characteristic inclusions of pinwheels, scrolls and cylindrical inclusions were present in the cytosol. Parallel arrays of virus particles in the tonoplast were also common. In cells infected with CGMMV-W, virus particles occurred as stacked-bands of scattered randomly in the cytosol and vacuoles in all type cells. Many cells also contained vesiculated mitochondria with fibril-containing vesicles. Cells infected mixedly with WMV-P and CGMMV-W contained structural features that were not observed in cells infected singly with the two viruses. A particle of WMV-P potyvirus was surrounded by evenly spaced nine particles of CGMMV-W tobamovirus, which made a unique nonagon ring. The angled layers having $60^{\circ}$-$135^{\circ}$ were alternating layer, herringbone, crosshatching and ladder figures.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.365-368
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• 2008

In recent, the crushed sand as a fine aggregate has increasingly used for concrete industry due to the shortage of natural sand from river and the growing demand for protection of natural environments. Aggregates may have a significant influence on the properties of self-compacting concrete (SCC) including self-compacting mortar (SCM). The rheological properties of SCC and SCM using crushed sand as a fine aggregate has been compared to that of SCC and SCM using natural sand and mixed sand of both. Test results indicate that the yield stress of SCM containing 50% of mixed sand present higher than those prepared with natural sand and crushed sand according to SP content. the slump values of SCC with natural sand have approximately 5-15% higher than those of SCC with crushed sand. Also the L-box test values ($H_2/H_1$) of SCC with natural sand have approximately 20-30 higher than those of SCC with crushed sand under same water/cement ratio and viscosity enhancing admixture.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.489-492
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• 2008

This study analyzed the fundamental properties and strength properties of concrete utilizing Bottom Ash as coarse aggregate for concrete. As a result, compared to non-mixture, the slump decreases about 4.5${\sim}$54.2% as the mixing ratio of Bottom Ash increases. However, influence of the air contents is very little. The bleeding shows similar slump characteristics, and the primary stage of bleeding decreases as the mixing ratio of Bottom Ash increases. As the mixing ratio of Bottom Ash increases, the compressive strength decreases. When Bottom Ash is mixed by 40%, compressive strength decreases about 1.1${\sim}$5.3%. Even when Bottom Ash is mixed over 60%, compressive strength decreases sharply and is revealed about 85.2${\sim}$87.7% of non-mixture concrete strength. To utilize Bottom Ash in large quantities, it is thought that the improvement method of strength has to be discussed such as mixing strengthening element.

• Journal of the Korea institute for structural maintenance and inspection
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• v.13 no.6 s.58
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• pp.135-147
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• 2009

In order to develop the ultra high strength concrete over 400Mpa at 28 day, Low-heat portland cement, ferro-silicon, silica-fume and steel fiber were mixed and tested under the special autoclave curing conditions. Considering the influence of Ultra high strength concrete. normal concrete is used as a comparison with low water-cement ratio possible Low-heat portland cement. Additionally, as a substitution of aggregates, we analyzed the compressive strength of Ferro Silicon by making the states of mixed and curing conditions differently. In addition, SEM films testified the development of C-S-H hydrates of Type III & Type IV, and tobermolite, zonolite due to the high temperature, high pressure of autoclave curing. Fineness of aggregate, filler and reactive materials in concrete caused 420Mpa compressive strength at 28day successfully.

• Journal of the Korea Concrete Institute
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• v.16 no.1 s.79
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• pp.79-87
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• 2004

The qualify of lightweight aggregate made from waste PET bottle(WPLA) and the workability, the unit weight and strength property of concrete with WPLA were investigated for the purpose of recycling the waste PET bottles as lightweight concrete fine aggregate. This study indicated a good result that WPLA should be replaced with less than $50\%$ of natural fine aggregate. When WPLA was replaced with $50\%$ of natural fine aggregate, the specific gravity and water absorption of mixed fine aggregate were greatly reduced about 23 and $75\%$ respectively in comparison with those of river sand. The quality of WPLA affected on the properties of lightweight aggregate concrete. The workability of fresh concrete with WPLA(WPLAC) was improved with increasing the replacement ratio of WPLA and water cement ratio. Slump increasing ratio of the former showed about $45 {\~} 120\%$ because that a specific gravity of fine aggregate was decreased from 2.6 to 1.7. The unit weight of concrete with $75\%$ WPLA was decreased about $17\%$ in comparison with that of control concrete. Furthermore, the compressive strength of concrete with 25 and $50 \%$ WPLA at the age of 28 days increased higher than 30 MPa regardless with water cement ratio (W/C=45, 49 and $53\%$) of this study. Specific strength of concrete with $25\%$ WPLA, $15.11{\times}10^3 MPa{\cdot}m^3/kg$, was higher than that of contro concrete in water cement ratio of $49\%$. The compressive strength-splitting tensile strength ratio and compressive strength-modulus of elasticity ratio of WPLAC were similar to that of nomal lightweight aggregate concrete. This results showed a good estimation that WPLA will be able to recycled as a fine aggregate for lightweight concrete.

• Computers and Concrete
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• v.17 no.6
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• pp.787-799
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• 2016

Climate anomalies in recent years, numerous natural disasters caused by landslides and a large amount of entrained sands and stones in Taiwan have created significant disasters and greater difficulties in subsequent reconstruction. How to respond to these problems efficaciously is an important issue. In this study, the sands and stones were doped with recycled materials (waste LCD glass sand, slag powder), and material was mixed for recycled ready-mixed soil. The study is based on security and economic principles, using flowability test to determine the water-binder ratio (W/B=2.4, 2.6, and 2.8), a fixed soil: sand ratio of 6:4 and a soil: sand: glass ratio of 6:2:2 as fine aggregate. Slag (at concentrations of 0%, 20%, and 40%) replaced the cement. The following tests were conducted: flowability, initial setting time, unit weight, drop-weight and compressive strength. The results show that the slump values are 220 -290 mm, the slump flow values are 460 -1030 mm, and the tube flow values are 240-590 mm, all conforming to the objectives of the design. The initial setting times are 945-1695 min. The unit weight deviations are 0.1-0.6%. The three groups of mixtures conform to the specification, being below 7.6 cm in the drop-weight test. In the compressive strength test, the water-binder ratios for 2.4 are optimal ($13.78-17.84kgf/cm^2$). The results show that Recycled ready-mixed soil materials (RRMSM) possesses excellent flowability. The other properties, applied to backfill engineering, can effectively save costs and are conducive to environmental protection.

• Magazine of the Korea Concrete Institute
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• v.7 no.3
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• pp.149-155
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• 1995

An experimental study was carried out to investigate the strength implovlng effect of stone dust in no fines concrete. The cement aggregate ratios of 1:6, 1:8 and 1:10 and several water-cemment ratios between 30% and 56% were chosen for the mix design of no-fines concrete. For the no-fines concrete with stone dust, the weight ratio of cement to stone dust 1:1 was adopted and super plasticizer, 1.5% of cement in weight, was used to obtain proper and workable state of concrete. The compressive and tensile strength test were performed and the results for the different mix designs were compared with each other. The results show that the compressive strength of no-fines concrete can be improved by 38% and the tensile strength by 17%~72% for the same w/c, when the same weight of stone dust as cement is mixed together.

• Proceedings of the KIEE Conference
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• 2008.10a
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• pp.165-166
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• 2008

We investigate characteristics of J-aggregation as take advantage of LB technic. In order to confirm the applications possible for the molecular electronic device, the morphological properties of merocyanine dye were investigated by AFM. ${\pi}-A$ curves investigated the surface pressure of the LB film from a liquid to a solid state ranged between 90 and 100 mN/m. We observed aggregation and it's characteristics by using visible reflection spectroscopy. We have observed morphology of merocyanine dye on gold surface by STM. focuses on results obtained in mercocyanide dye of J-aggregation. When LB films of merocyanine dye are mixed with arachidic acid, J-aggregate formation is exhibited. J-aggregate formation has been serving as typical systems in revealing the physical and structural aspects of nano-sized molecular aggregates constructed as muiltilayers.

• Journal of Environmental Science International
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• v.19 no.5
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• pp.639-646
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• 2010

Differently from fly ash, the bottom ash produced from incinerated urban solid waste has been treated as an industrial waste matter, and almost reclaimed a tract form the sea. If this waste material is applicable to foam concrete as an fine aggregate, however, it may be worthy of environmental preservation by recycling of waste material as well as reducing self-weight of high-rising structure and long-span bridge. This research has an objective of evaluating the effects of application of bottom ash on the mechanical properties of foam concrete. Thus, the ratio of bottom ash to cement was selected as a variable for experiment and the effect was tested by compression strength, flexural strength, absorption ratio, density, expansion factor. It can be observed from experiments that the application ratios have different effects on the material parameters considered in this experiment, thus major relationship between application ratio and each material parameter were finally introduced. The result of this study can be applied to decide a optimal mix design proportion of foam light-weight concrete while bottom ash is used as an fine aggregate of the concrete.