• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.6
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• pp.255-261
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• 2016

$CaCO_3$ was applied in various industries including rubber, plastics, paint, paper, food additives, and acid neutralizer, etc., owing to its excellent physical and chemical characteristics as well as various appearances of crystals and many reserves. In particular, research on controlling the structure and shape of $CaCO_3$ has attracted considerable attention recently, because the whiteness and physical characteristics of $CaCO_3$ depend on the size and shapes of the particles. In this study, $CaCO_3$ was synthesized using $CaCl_2$ and $(NH4)_2CO_3$, which has multi-shapes and structures, using a self-assembly method with a hydrothermal method. The structure and morphology of the $CaCO_3$ could be controlled by adjusting the pH and precursor concentration. In particular, the pH adjustment appeared to be a critical factor for the morphology and crystal form. In addition, the calcite and cubic shape were obtained at pH 7, while the mixed calcite, aragonite structure, and rod shapes appeared at pH 7 and over. Through an analysis of the particle formation process, the formation of the calcium carbonate particles was confirmed. The physicochemical properties of the synthesized $CaCO_3$ were analyzed by SEM, XRD, EDS, FTIR, and TG/DTA.

• Resources Recycling
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• v.17 no.4
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• pp.47-56
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• 2008

The aim of this study is to produce cokes which can be used for the production of ferroalloy, for this purpose, domestic anthracite mixed with plastic was sintered at various condition. The combustion and physical properties of anthracite and plastic, coal separation, and the influence of factors on the strength of coke were investigated. The results of this study are as follows: 1. The three kinds of anthracite from the Samcheok region contained 25 to 30% ash of $100{\mu}m$ over size, and have the caloric value of 5,205 cal/g(TaeAn), 4,893 cal/g(JangSung), 4,873cal/g(KyongDong). 2. The recommendable conditions for heavy-fluid separation of the Samcheok coal are to set the specific gravity of heavy fluid to 2.4 and control the size of coal to $35{\sim}140mesh$. 3. It is concluded that phenolic resin powder, liquefied phenolic resin, SAN, and melamine resin can be used as a binder for the anthracite cokes, from the thermal analysis of various plastics. Especially, the liquefied phenolic resin was considered as the most suitable binder as it would simplify the process.

• Korean Journal of Soil Science and Fertilizer
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• v.39 no.6
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• pp.345-350
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• 2006

Recently we have interest on rice products developed by environment-friendly management. The technology of paper mulching was practised without herbicide in machine transplanting cultivation of paddy. A field experiment was conducted on Gangseo series (coarse loamy, mixed, nonacid, mesic family of Aquic Fluventic Eutrochrepts) at the National Institute of Crop Science (NICS), RDA, Suwon, Gyeonggi province, Republic of Korea in 2004. This experiment was carried out to evaluate rice growth, weed control and nitrogen efficiency by the different controlled-release fertilizer levels in paper mulching transplanting. Treatments consisted of conventional fertilization, controlled-release fertilizer (100%, 80%, 60%) compared with nitrogen amount ($110kg\;ha^{-1}$) of conventional fertilization and no nitrogen plot. Mulching paper consisted of recycled paper which was coated with biodegradable plastics. There were no differences between conventional rice transplanting and paper mulching on missing hills. Weed occurrence and control were diverse and low as fertilizer amount increased. Plant height and tiller number per hill increased as fertilizer amount decreased. There were no difference between controlled-release fertilizer 80% and conventional fertilization plot on rice growth traits. Leaf color and $NH_4{^+}-N$ in soil had similar trends. There was no difference in yield between controlled-release fertilizer 80% and conventional fertilization plot. Agronomic nitrogen-use efficiency was high as fertilizer amount decreased. Therefore, these results suggested controlled-release fertilizer 80% should be optimum amount under paper mulching transplanting of rice considering weed control, rice growth and nitrogen efficiency.

• Korean Journal of Soil Science and Fertilizer
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• v.40 no.6
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• pp.495-500
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• 2007

Recently we are interest in organic farming of rice. The technology of paper mulching was practised without herbicide in machine transplanting cultivation of paddy. A field experiment was conducted in Gangseo series (coarse loamy, mixed, nonacid, mesic family of Aquic Fluventic Eutrochrepts) at the National Institute of Crop Science (NICS), RDA, Suwon, Gyeonggi province, Republic of Korea in 2004. This experiment was carried out to evaluate soil redox potential, weed control and rice growth by the different organic matter in paper mulching transplanting. Compost, rice straw and soiling rye were incorporated as organic matter. The nitrogen amount of controlled-release fertilizer (CRF) plot was 80% compared with nitrogen amount ($110kg\;ha^{-1}$) of conventional fertilization. Mulching paper consisted of recycled paper which was coated with biodegradable plastics. There were no difference between conventional rice transplanting and paper mulching on missing hills after organic matter application. Weed control were the highest at added soiling rye plot. The redox potential of soil was the lowest in rice straw + CRF 80% plot at tillering stage. The $NH_4{^+}-N$ in soil was the highest at soiling rye + CRF 80% tillering stage. There was no difference in yield between soiling rye + CRF 80%, compost + CRF 80% and conventional fertilization plot.