• 제목/요약/키워드: Mixed Fuel

검색결과 608건 처리시간 0.025초

졸-겔법에 의한 CuO-CeO2 복합 산화물 촉매의 제조 및 CO의 선택적 산화반응에 응용 (Preparation of CuO-CeO2 mixed oxide catalyst by sol-gel method and its application to preferential oxidation of CO)

  • 황재영;함현식
    • 한국응용과학기술학회지
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    • 제34권4호
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    • pp.883-891
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    • 2017
  • 고분자 전해질 연료전지의 연료에 포함된 일산화탄소의 선택적 산화를 위하여, 귀금속 촉매를 대체하기 위한 CuO-$CeO_2$ 복합 산화물 촉매를 졸-겔법과 공침법으로 제조하였다. 졸-겔법으로 촉매 제조 시 Cu/Ce의 비와 가수분해 비를 변화시켰다. 제조한 촉매의 활성은 귀금속 촉매($Pt/{\gamma}-Al_2O_3$)와 비교하였다. Cu/Ce의 비를 변화시키면서 제조한 촉매 중 Cu/Ce의 비가 4:16인 촉매가 가장 높은 CO 전환율(90%)과 선택도(60%)를 나타내었다. 촉매의 제조에서 가수분해 비가 증가할수록 촉매 표면적이 증가하였고, 아울러 촉매 활성 또한 증가하였다. 공침법으로 제조한 촉매와 1wt% $Pt/{\gamma}-Al_2O_3$ 촉매의 가장 높은 CO 전환율은 각각 82% 및 81%인 반면, 졸-겔법으로 제조한 촉매의 경우는 90%가 얻어졌다. 이는 졸-겔법으로 제조한 촉매가 공침법으로 제조한 촉매나 귀금속 촉매보다 더 높은 촉매활성을 보임을 의미한다. CO-TPD 실험을 통하여, 낮은 온도($140^{\circ}C$)에서 CO를 탈착하는 촉매가 본 반응에서 더 높은 촉매활성을 보임을 알 수 있었다.

휘발유 가격변화와 가계소비의 상충작용 (Influence of Price Increase in Gasoline on Household Expenditure Trade-off)

  • 김숙향;황덕순
    • 대한가정학회지
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    • 제40권8호
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    • pp.153-166
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    • 2002
  • This study aims to reveal the influence of price increase in gasoline on household expenditure trade-off. The subjects were 651 households, acquired the first quarter of 1996 and 1997. This study shows the change of the auto fuel budget share in the same household and they were analyzed with the paired t-test, independent t-test. The results are as follows; 1) the price increase of auto gasoline resulted in the increase of its budget share, regardless of a household's true increase or decrease of income. 2) according to price increase in gasoline, the auto fuel budget share has been changed, therefore I divided these changes into three group on the base of it's degree of change. 3) In the group that had a decrease in auto fuel budget share compared to the degree of change, there was a trade-off between the increase in food and light & light water and the decrease of education and auto fuel budget share. Auto fuel in this group was used as discretionary good. 4) In the group that had a similar change in auto fuel budget share compared to the degree of change, there were no trade-off between expenditure items except auto fuel budget share and miscellaneous decrease. This group is the highest income group among the three groups. 5) In the group that had and increase of change in auto fuel budget share compared to the degree of change, there was a trade-off between the increase of eating-out and auto fuel, and the decrease of education and miscellaneous budget share. Auto fuel in this group was used as a discretionary good. 6) trade-off expenditure budget share showed a mixed effect between the influence of increase in gasoline price and influence of increase in true income.

에멀젼 연료의 안정성에 대한 연구 (A study of Stability of Emulsion Fuel)

  • 김문찬
    • 한국응용과학기술학회지
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    • 제37권5호
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    • pp.1330-1343
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    • 2020
  • 본 연구에서는 근해에서 선박유로 많이 사용되는 MDO(Marine Diesel Oil)를 물과 함께 혼합하고 여기에 유화제를 첨가하여 물이 10 ~ 20% 첨가된 에멀젼 연료를 만들었다. 그리고, 이 에멀젼 연료의 분산 안정성을 측정하였다. 에멀젼 연료의 분산 안정성은 30℃, 45℃, 60℃에서 10일간 평가하였다. 에멀젼 연료의 안정성은 MDO-10 > MDO-13 > MDO-16 > MDO-20 순서로 물 함량이 적은 순으로 안정한 것으로 나타났다. 한편 제조된 에멀젼 연료가 실제로 엔진에서 사용 가능한지를 엔진 다이나모메터를 사용하여 실험하였다. 유화시킨 MDO 유화물은 선박용 연료로 사용이 가능하였다. 대기오염에 대하여 물이 16% 이상 첨가된 시료들은 50% 이상의 부하 영역에서 매연은 50% 이상 감소하였으며, 질소산화물은 20% 정도의 저감 효과가 있었다.

디젤기관에서의 경유-메탄올 혼합유의 연소 안전성과 연소특성에 관한 연구 (A Study on the Combustion Stability and Characteristics for D.O - Methanol Blending Oil in Diesel Engine)

  • 김상암;왕우경
    • 동력기계공학회지
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    • 제22권1호
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    • pp.48-55
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    • 2018
  • It has recently been reported that methanol fuel has been used in the product carrier with established duel fuel engine, which has been greatly reducing emissions of $CO_2$, NOx and SOx from the engine. However, to use methanol alone as fuel oil in a general diesel engine, design modification of cylinder head is needed because the ignition aid device or the duel fuel injection system is needed. On the other hand, only if the mixer is installed on the fuel oil supply line, diesel oil - methanol blending oil can be used as fuel oil for the diesel engine, but there is a problem of the phase separation when two fuels are mixed. In this study, diesel oil and methanol were blended compulsorily in preventing the phase separation with installing agitators and a fuel oil boost pump on fuel line of a test engine. Also, cylinder pressure and fuel consumption quantity were measured according to engine load and methanol blending ratio, and indicated mean effective pressure, heat release rate and combustion temperature obtained from the single zone combustion model were analyzed to investigate the effects of latent heat of vaporization of methanol on combustion stability and characteristics. As a result, the combustion stability and characteristics of 10% methanol blending oil are closest to the those of diesel oil, and it could be used as fuel oil in existing diesel engines without deterioration of engine performance and combustion characteristics.

Estimating Wildfire Fuel Load of Coarse Woody Debris using National Forest Inventory Data in South Korea

  • Choi, Suwon;Lee, Jongyeol;Han, Seung Hyun;Kim, Seongjun;Son, Yowhan
    • 한국기후변화학회지
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    • 제6권3호
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    • pp.185-191
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    • 2015
  • This study presents an estimate of on-site surface fuel loadings composed of coarse woody debris (CWD) using $5^{th}$ National Forest Inventory (NFI) data in South Korea. We classified CWD data into forest type, region and decay class, and used conversion factors by decay class and tonne of oil equivalent developed in the country. In 2010, the total wildfire fuel load of CWD was estimated as 8.9 million TOE; those of coniferous, deciduous and mixed forests were 3.5 million TOE, 2.8 million TOE and 2.6 million TOE, respectively. Gangwon Province had the highest wildfire fuel load of CWD (2.3 million TOE), whereas Seoul exhibited the lowest wildfire fuel load of CWD (0.02 million TOE). Wildfire fuel loads of CWD were estimated as 2.9 million TOE, 1.9 million TOE, 2.4 million TOE and 1.7 million TOE for decay classes I, II, III and IV, respectively. The total wildfire fuel load of CWD corresponded to the calorific value of 8.2 million tons crude oil, 2.46% of that of living trees. Proportionate to the growing stock, total wildfire fuel load of CWD was in a broad distinction by region, while its TOE $ha^{-1}$ was not. This implies that there is no need to establish different guidelines by region for management of CWD. The results of this work provide a baseline study for scientific policy guidelines on preventing wildfires by proposing CWD as wildfire fuel load.

Radiation Measurement of a Operational CANDU Reactor Fuel Handling Machine using Semiconductor Sensors (ICCAS 2003)

  • Lee, Nam-Ho;Kim, Seung-Ho;Kim, Yang-Mo
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 2003년도 ICCAS
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    • pp.1220-1224
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    • 2003
  • In this paper, we measured the radiation dose of a fuel handling machine of the CANDU type Wolsong nuclear reactor directly during operation, in spite of the high radiation level. In this paper we will describe the sensor development, measurement techniques, and results of our study. For this study, we used specially developed semiconductor sensors and matching dosimetry techniques for the mixed radiation field. MOSFET dosimeters with a thin oxide, that are tuned to a high dose, were used to measure the ionizing radiation dose. Silicon diode dosimeters with an optimum area to thickness ratio were used for the radiation damage measurements. The sensors are able to distinguish neutrons from gamma/X-rays. To measure the radiation dose, electronic sensor modules were installed on two locations of the fuel handling machine. The measurements were performed throughout one reactor maintenance cycle. The resultant annual cumulative dose of gamma/X-rays on the two spots of the fuel handling machine were 18.47 Mrad and 76.50 Mrad, and those of the neutrons were 17.51 krad and 60.67 krad. The measured radiation level is high enough to degrade certain cable insulation materials that may result in electrical insulation failure.

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온실가스 감축정책에 따른 발전사업자의 대응 방안에 관한 연구 (A Study on the GENCO Adaptive Strategy for the Greenhouse Gas Mitigation Policy)

  • 최동찬;한석만;김발호
    • 전기학회논문지
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    • 제61권4호
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    • pp.522-533
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    • 2012
  • This paper presents an adaptive strategy of GENCOs for reducing the greenhouse gas by fuel mix change. Fuel mix stands for generation capacity portfolio composed of different fuel resources. Currently, the generation sector of power industry in Korea is heavily dependent on fossil fuels, therefore it is required to change the fuel mix gradually into more eco-friendly way based on renewable energies. The generation costs of renewable energies are still expensive compared to fossil fueled resources. This is why the adaptive change is more preferred at current stage and this paper proposes an optimal strategy for capacity planning based on multiple environmental scenarios on the time horizon. This study used the computer program tool named GATE-PRO (Generation And Transmission Expansion PROgram), which is a mixed-integer non-linear program developed by Hongik university and Korea Energy Economics Institute. The simulations have been carried out with the priority allocation method in the program to determine the optimal mix of NRE(New Renewable Energy). Through this process, the result proposes an economic fuel mix under emission constraints compatible with the greenhouse gas mitigation policy of the United Nations.

RPS(Renewable Portflio Standard) 제도 도입에 따른 국내 장기 전원구성 변화에 관한 연구 (A Study of the Long-term Fuel Mix with the Introduction of Renewable Portfolio Standard)

  • 이정인;한석만;김발호
    • 전기학회논문지
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    • 제58권3호
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    • pp.467-477
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    • 2009
  • Renewable Portfolio Standard (RPS) is a regulatory policy that requires the generation companies to increase the proportion of renewable energy sources such as wind, solar, LFG, fuel cell, and small hydro. Recently, Korean government decided to increase the portion of renewable energy to 3% to total electricity generation by 2012 from the current level of 0.13%. To achieve this goal, an innovative plan for market competitiveness would be required in addition to the present Feed-In-Tariff (FIT). That is Korean government has taken it into consideration to introduce a Renewable Portfolio Standard (RPS) as an alternative to FIT. This paper reviews the impact of RPS on the long-term fuel mix in 2020. The studies have been carried out with the GATE-PRO (Generation And Transmission Expansion PROgram) program, a mixed-integer non-linear program developed by Hongik university and Korea Energy Economics Institute. Detailed studies on long-term fuel mix in Korea have been carried out with four RPS scenarios of 3%, 5%, 10% and 20%. The important findings and comments on the results are given to provide an insight on future regulatory policies.

농업시설 난방을 위한 축산폐기물의 고형 연료화 연구 (Study on the Development of Solid Fuel of Animal Wastes for Heating of Agricultural Facilities)

  • 이귀현
    • Journal of Biosystems Engineering
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    • 제32권5호
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    • pp.316-323
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    • 2007
  • This study was carried out to obtain the basic data for the development of the solid fuel with investigating the characteristics of mixtures of animal wastes and wasted coal and supply it as an energy resource to agricultural farms for heating of agricultural facilities. It was investigated for the characteristics of animal wastes (swine waste, swine waste with sawdust, cattle waste), wasted coal, the mixtures of animal wastes and wasted coal with or without mixing seawater. The characteristics of solid fuel according to the mixture ratio of animal wastes and wasted coal were analyzed. The effects of seawater affecting on calorific value and thermal pyrolysis of solid fuels were investigated. The results of this study are as follows: 1) The calorific value was improved with mixing seawater into wasted coal due to chemical reaction. 2) The diverse solid fuels of various calorific values can be made with adjusting the ratio of animal wastes and wasted coal. 3) Animal wastes and wasted coal had each different reaction temperature of thermal pyrolysis and the decreasing rate of weight. 4) The mixture of animal wastes and wasted coal would be ignited easily. Therefore, the solid fuel could be ignited more conveniently when seawater is mixed with it.

DISSOLUTION AND BURNUP DETERMINATION OF IRRADIATED U-Zr ALLOY NUCLEAR FUEL BY CHEMICAL METHODS

  • Kim, Jung-Suk;Jeon, Young-Shin;Park, Soon-Dal;Song, Byung-Chul;Han, Sun-Ho;Kim, Jong-Goo
    • Nuclear Engineering and Technology
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    • 제38권3호
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    • pp.301-310
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    • 2006
  • Destructive methods were used for the burnup determination of U-Zr alloy nuclear fuel irradiated in the High-flux Advanced Neutron Application Reactor (HANARO) at KAERI. The dissolution rate of unirradiated U-Zr alloy fuel in $HNO_3$/HF mixtures was investigated for the experimental conditions of a different temperature, and initial concentrations of HF and $HNO_3$. The irradiated U-Zr alloy fuel specimen was dissolved in a mixed acid condition of 3 M HNO3 and 1 M HF at $90^{\circ}C$ for 8 hours under reflux. The total burnup was determined from measurement of the Nd isotope burnup monitors. The method includes U, Pu, $^{148}Nd,\;^P{145}Nd+^{146}Nd,\;^{144}Nd+^{143}Nd$ and total Nd isotopes determination by the isotope dilution mass spectrometric method (IDMS) using triple spikes $(^{233}U,\;^{242}Pu\;and\;^{150}Nd)$. The effective fission yield was calculated from the weighted fission yields averaged over the irradiation period. The results are compared with that obtained by the destructive -spectrometric measurement of the $^{137}Cs$ monitor.