• Title/Summary/Keyword: Mixed Compound

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A Study on Nitrification and Denitrification in Biofilter & Sulfur- Limestone Single Stream Process (바이오필터와 황-석회석을 이용한 단일흐름 공정에서의 질산화와 탈질 연구)

  • Kim, Tae-Kyu
    • Journal of Environmental Health Sciences
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    • v.32 no.5 s.92
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    • pp.469-477
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    • 2006
  • When denitrification was connected with a single stream process by using biofilter and sulfur-limestone, it was found that such connection enabled highly efficient nitrification without special unit operation of microorganisms or injection of external carbon sources which is being shown in general biological treatment processes. It was observed that in the trickling filter bed, decomposition of organic substances and highly efficient nitrification by both the forced pressure feed trickling and the air fan were simultaneously done. In the denitrification tank where sulfur-limestone was mixed at a certain ratio, limestone was used by autotrophic microorganisms as a source of supply for alkalinity, and nitrate $NO_{3}^{-}$-N was denitrified into nitrogen gas. And in the sulfur-limestone autotrophic denitrification, $NO_{3}^{-}-N\;or\;NO_{2}^{-}-N$ was denitrified as a sulfur compound in reduction state was oxidized into a final output of $SO_{4}^{-2}$. The mean concentration of the discharge water was 8.6 mg/l for T-N and 0.8 mg/l for T-P, respectively, and their mean treatment efficiency was 79.2% and 80.8%, respectively. Implementing highly efficient denitrification without injection of an external organic carbon source or internal return, it is concluded that the proposed process is suitable for a sewerage in a small village with the merits of low power consumption and easy maintenance.

Synthesis of (Ti,Al)N Powder by Interdiffusion Nitriding Method (상호확산법에 의한 (Ti,Al)N계 복합질화물의 합성)

  • Lee, Young-Ki;Kim, Jung-Yeul;Kim, Dong-Kun;Sohn, Yong-Un
    • Journal of the Korean Society for Heat Treatment
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    • v.10 no.2
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    • pp.138-149
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    • 1997
  • TiN and AlN are ceramic materials with extensive applications due to its excellent mechanical and chemical properties at elevated temperature. The purpose of this research is to develop the method for the synthesis of ternary nitride powder, titanium-aluminum-nitrogen system, which have an excellent property of both TiN and AlN. The ternary nitride such as $Ti_3AlN$, $Ti_2AlN$ and $Ti_3Al_2N_2$ can be synthesized by the interdiffusion nitriding method in Ar gas, however, the ternary nitride coexist with TiN, AlN, $Ti_3Al$ and ${\alpha}$-Ti. The ternary nitride are stable below $1400^{\circ}C$, but these are gradually decomposed into TiN, $Ti_3Al$ and AlN above $1400^{\circ}C$. The thermal oxidation characteristics of the Ti-Al-N compound synthesized by the interdiffusion nitriding method is superior to that of the TiN+AlN mixed powder, and the oxidation for both materials show the differential behaviors.

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Conductive Polymer Coated Electro-active Paper(EAPap) (전도성 고분자를 결합한 EAPap작동기에 관한 연구)

  • Yun, Sungryul;Ounaies Zoubeida;Bae, Seung-Hun;Kim, Jaehwan
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.15 no.9 s.102
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    • pp.1077-1083
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    • 2005
  • Electro-Active Paper (EAPap) is one of attractive electro-active polymer (EAP) materials for artificial muscles due to its many advantages such as light weight, biologically degradable, low cost, large displacement output, low actuation voltage and low power consumption. However, drawbacks of EAPap actuators include low force output and humidity dependence. To enhance the performance of EAPap, conductive polymer (PPy) and SWNT/conductive polymer (PANI) are coated on EAPap PPy as conductive polymer is coated on cellulose EAPap by means of electrochemical deposition. Two different dopants are used in PPy through conducting polymer processing. SWNTS are mixed with PANI in emeraldine base along with different dopants. The compound materials are coated on cellulose EAPap using spin coating system. The performance of PPy/EAPap and SWNT/PANI/EAPap are evaluated in terms of bending displacement, blocked force, and the effects of dopants, humidity, coaling time, voltage and frequency are investigated. Comparing with EAPap actuators, SWNT/PANI/EAPap actuators show $200\%$ improvement of bending displacement and $300\%$ increment of blocked force.

Classification of Sediment Types of Tidal Flat Area in the South of Kanghwa Island using Landsat Images (Landsat 위성영상을 이용한 강화도 남단 갯벌의 퇴적 유형 분류)

  • Park, Sungwoo;Jeong, Jongchul
    • Journal of Environmental Impact Assessment
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    • v.11 no.4
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    • pp.231-238
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    • 2002
  • In this study we classified sediment types of tidal flat using Landsat-5 images. This is for groping the method which can analyze correctly various kinds of sediment faces through satellite images. This work was performed by referencing ground truth of sediment faces which was investigated in the field. With this data we classified Landsat-5 image of 1997's to grope a most suitable classification method. As a result, in case of south Kanghwa island area, it was the optimum way to compound band 4, 5, 7 of Landsat-5 TM imagery. And, this work classified 3 kinds of sediment faces - M(mud), sM(sandy mud) and (g)M(slightly gravelly mud) - in land and mixed water area. It is anticipated that if this method is applied to a image of extremely lower sea level time, it can classify the sediment types of a broad tidal flat area. This is expected to be a beginning of estimating the effect of sediment faces to the change of the tidal flat ecosystem.

Fracture Toughness of Leadframe/EMC Interface (리드프레임/EMC 계면의 파괴 인성치)

  • 이호영;유진
    • Journal of the Korean institute of surface engineering
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    • v.32 no.6
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    • pp.647-657
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    • 1999
  • Due to the inherently poor adhesion strength of Cu-based leadframe/EMC (Epoxy Molding Compound) interface, popcorn cracking of thin plastic packages frequently occurs during the solder reflow process. In the present work, in order to enhance the adhesion strength of Cu-based leadframe/EMC interface, black-oxide layer was formed on the leadframe surface by chemical oxidation of leadframe, and then oxidized leadframe sheets were molded with EMC and machined to form SDCB (Sandwiched Double-Cantilever Beam) and SBN (Sandwiched Brazil-Nut) specimens. SDCB and SBN specimens were designed to measure the adhesion strength between leadframe and EMC in terms of critical energy-release rate under quasi-Mode I ($G_{IC}$ ) and mixed Mode loading ($G_{C}$ /) conditions, respectively. Results showed that black-oxide treatment of Cu-based leadframe initially introduced pebble-like X$C_2$O crystals with smooth facets on its surface, and after the full growth of $Cu_2$O layer, acicular CuO crystals were formed atop of the $Cu_2$O layer. According to the result of SDCB test, $Cu_2$O crystals on the leadframe surface did not increase ($G_{IC}$), however, acicular CuO crystals on the $Cu_2$O layer enhanced $G_{IC}$ considerably. The main reason for the adhesion improvement seems to be associated with the adhesion of CuO to EMC by mechanical interlocking mechanism. On the other hand, as the Mode II component increased, $G_{C}$ was increased, and when the phase angle was -34$^{\circ}$, crack Kinking into EMC was occured.d.

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Applications and Analysis of Exterior Paints for the Curtain Wall Panel System based on the Autoclaved Lightweight Concrete(ALC) (경량기포콘크리트(ALC) 패널을 건축물 외장 커튼월에 적용을 위한 도료의 기초적 연구)

  • Lee, Yong-Soo;La, Hyun-Ju
    • Journal of The Korean Digital Architecture Interior Association
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    • v.12 no.3
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    • pp.59-66
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    • 2012
  • Autoclaved Lightweight Concrete(ALC) features such as a high performance insulation, the fire resistance, the advantage of easy handing construction, and lightweight panels applied the curtain wall system. ALC materials are certified as non-toxic environmental and eco-friendly productions. But ALC external panels mixed with blast furnace slag pounder and silica fume have to be coated with a stucco compound or plaster because of resisting the ambient environment. This study is that mixing tests to evaluate a performance analysis of exterior paints to be make-up pigments(organic or inorganic) coated with panel surface. Testing compared by KS F 2476; flow test, KS F 2426; compression strength test, KS F 2762; bond strength test. In results, the case of the inorganic binder, ratio of alumina cement : anhydrite is 90:10 to 80:20 at the highest level of intensity. In the case of the organic binder, adhesive strength rating at surface of ALC, the pullout strength is below 0.5 $N/mm^2$ but the normal concrete is over 2.0$N/mm^2$. A contents ratio of EVA resin is more than 3% and then bond strength is effectively.

A Study on the Manufacturing of Cellular RubBer Products with NR, SBR, NBR EPDM EPDM (NR, SBR, NBR 및 EPDM 발포(發泡)고무의 제조연구(製造硏究))

  • Choi, Sei-Young;Paik, Nam-Chul
    • Elastomers and Composites
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    • v.16 no.1
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    • pp.3-13
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    • 1981
  • The purpose of this dissertation is to study the physical properties of cellular rubber products for industrial use. Vulcanization characteristics were investigated by usingcure curve that had obtained by means of Rheometer. The results of physical properties, vulcanization characteristics and foaming states are as follows. 1. The test results for vulcanization characteristics of NR compounds indicated that in the recipe R-1. When accelerator D is used, the optimum conditions of vulcanizate are obtained, while formula R-2 and R-3 have shown higher torgue at curing time, $1{\sim}2$ minutes. Cellular rubber product test in terms of compression set and compression deflection has also met the requirements of SAE. 2. For SBR compounds, S-1 formula was the best in terns of vulcanization characteristics, and for the blowing structure of cellular rubber products, formula S-3 in which accelerator M is added was fair. All other test results, such as compression set and compression deflection properties met SAE requirements. 3. NBR compound (N-1) including accelerator TT was the best in terms of vulcanization characteristic and also blowing structure. All other properties listed above met requirements, particulary for oil resistance test. 4. In the test of EPDM compounds, when mixed accelerator, M and TT, is used(formula E-1) the best results were obtained. Since EPDM is hydrocarbon elastomer, oil resistance test failed. All other properties met the requirement specified in SAE.

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Development of Cholinesterase Inhibitors Using (a)-Lipoic Acid-benzyl Piperazine Hybrid Molecules

  • Kim, Beom-Cheol;Lee, Seung-Hwan;Jang, Mi;Shon, Min Young;Park, Jeong Ho
    • Bulletin of the Korean Chemical Society
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    • v.34 no.11
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    • pp.3322-3326
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    • 2013
  • A series of hybrid molecules between (${\alpha}$)-lipoic acid (ALA) and benzyl piperazines were synthesized and their in vitro cholinesterase [acetylcholinesterase (AChE) and butyrylcholinesterase (BuChE)] inhibitory activities were evaluated. Even though the parent compounds did not show any inhibitory activity against cholinesterase (ChE), all hybrid molecules showed BuChE inhibitory activity. Some hybrid compounds also displayed AChE inhibitory activity. Specifically, ALA-1-(3-methylbenzyl)piperazine (15) was shown to be an effective inhibitor of both BuChE ($IC_{50}=2.3{\pm}0.7{\mu}M$) and AChE ($IC_{50}=30.31{\pm}0.64{\mu}M$). An inhibition kinetic study using compound 15 indicated a mixed inhibition type. Its binding affinity ($K_i$) value to BuChE is $2.91{\pm}0.15{\mu}M$.

Determination of Trace Elements of Ge and P in a Gold Bonding Wire by Inductively Coupled Plasma Atomic Emission Spectrometry

  • Choi, Sung-Min;Lee, Gae-Ho;Han, Jae-Kil
    • Bulletin of the Korean Chemical Society
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    • v.29 no.2
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    • pp.393-397
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    • 2008
  • Inductively coupled plasma atomic emission spectrometry (ICP-AES) was used to determine the presence of germanium and phosphorus in a pure gold bonding wire. The samples were dissolved with hydrobromic acid and nitric acid at room temperature. The quantitation limits were 0.012 mg L-1 at 265.118 nm for Ge and 0.009 mg L-1 at 177.495 nm for P. Using the mixed acid digestion formula of DIW+HBr+HNO3, the recoveries were in the range of 98-100% and the relative standard deviation was within 1.1-2.3%. On the other hand, the amount of Ge decreased by about 16.2% using DIW+HCl+HNO3, due to the formation of a volatile compound. The Ge contents determined using the external method and the standard addition method were 9.45 mg kg-1 and 9.24 mg kg-1, respectively, and the P contents, using the same methods, were 22.49 mg kg-1 and 23.09 mg kg-1, respectively. Both methods were successfully used to determine the trace amounts of P and Ge in the pure gold bonding wire samples.

Interactive Toxic Effects of Heavy Metals and Diesel on Vibrio fischeri (발광박테리아(Vibrio fischeri)에 대한 중금속 및 디젤의 혼합 독성 영향)

  • Jung, Hyun;Park, Sookhyun;Hwang, Yu Sik
    • Journal of Korean Society on Water Environment
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    • v.30 no.4
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    • pp.403-408
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    • 2014
  • The toxicity of heavy metals (Zn, Pb) and diesel, in single and binary solution was investigated using the photobacterium Vibrio fischeri (Microtox test) as a test organism. In this experiment, the concentration of water soluble fraction of diesel was based on the total petroleum hydrocarbon (TPH). The toxicity of each single compound showed the following $EC_{50}$ (15min): Zn 1.90 mg/L, Pb 0.31 mg/L, TPH 2.09 mg/L. The observed toxicity of binary mixtures increased, depending on the concentration of the mixed substance. The effects were defined as synergistic, antagonistic, or additive, in accordance with the sign of difference between the predicted and observed toxicity at binary mixtures. The interactive effects between zinc and lead were synergistic, on the other hand, antagonistic and additive effects were found in each metal and TPH mixtures on the bioluminescence of V. fischeri.