• Title/Summary/Keyword: Mix Design

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Leaching Capacity and Rate of Alkali Ions from Hardened Cement Paste (시멘트 경화체의 알칼리이온 침출성능 및 침출속도)

  • Shim, Hyun-Bo;Hwang, Jun-Pil;Ann, Ki-Yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.18 no.1
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    • pp.111-118
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    • 2014
  • The present study concerns the leachability of alkali ions from hardened cement paste in terms of an increase in the pH together with the rate of alkali leaching. To evaluate the influence of mix design on the leaching capacity and rate of alkali, different water-cement ratios (W/C) and binders were used to manufacture paste specimens. The cement paste was made in the form of rectangular bucket where deionised water was subsequently supplied as solvent media. Then the specimen was wrapped in polythene film to avoid contact to atmospheric conditions, which may affect the water chemistry in the bucket. The pH of media was monitored until no further change in the pH value was observed, of which value then used to calculate the leaching capacity and rate. The influence of binder on the pH of solvent is more dominant than that of water to cement ratio: OPC paste produced the highest level of alkali leaching, whilst 30% PFA and 60% GGBS pastes imposed lower level of alkali leaching. After the monitoring of the pH, the inner bucket was ground with an increment of 1.0 mm to measure the leaching influence using the suspension consisting of paste powder and deionised water. It was found that the impact zone for OPC was about 7-8 mm, whilst 30% PFA and 60% GGBS had deeper impact depth of the alkali leaching.

The Durability of the Concrete Using Bottom Ash as Fine Aggregate (바텀애시를 잔골재로 사용한 콘크리트의 내구성능에 관한 연구)

  • Park, Seung-Ho;Lee, Jeong-Bae;Kim, Seong-Soo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.4
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    • pp.349-355
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    • 2016
  • This study is about the reuse of bottom ash, which is released as a necessity in thermal power plant. In general, coal-ash are classified as fly-ash, bottom-ash, cinder-ash. Of these, a large amount of fly ash is being recycled as cement substitutes. While, recycling rates of bottom ash are the lowest due to its porosity and high absorption. In this study, the durability of the concrete using bottom ash as a concrete fine aggregate was evaluated. The using level of the bottom ash ranges to step-by-step from 0% to 30%. According to the result of the durability test, regardless of the presence of the bottom ash, freeze-thaw durability could be secured by air entrainment. In case of the resistance to chloride ions penetration, the length change, and the effects on heavy metals, the replacement of bottom ash as fine aggregate was not critical. Although carbonation penetration was higher as the replacement level of bottom ash increased, the experiment showed that it could be possible to use bottom ash as concrete fine aggregate with proper mix design.

Comparison of Test Methods for Evaluation of Chloride Diffusion Coefficient in Concrete (콘크리트의 염소이온 확산계수 평가를 위한 시험방법 비교)

  • Lee, Chan-Young;Kim, Hong-Sam;Kim, Jin-Cheol;Cheong, Hai-Moon;Ahn, Tae-Song
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.581-584
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    • 2008
  • Generally, durability of concrete structures under marine environment is grossly declined by detrimental ions such as chlorides, which penetrate concrete and was diffused to corrode reinforcing rod. Therefore, chloride diffusion properties in concrete are important for durability evaluation and design of concrete structure. For estimation of chloride diffusion coefficient in concrete, both evaluation methods are used for steady state and non-steady state derived from Fick's 1st and 2nd law, respectively. However, as it is very difficult to evaluate diffusion coefficient for non-steady state like service environment where concrete is actually exposed, indirect evaluation method by laboratory accelerated test is generally used. In this study, comparison of chloride diffusion behavior was investigated for fixed mix proportion and age of concrete using four accelerated test methods based on domestic and foreign standards. From test results, only relative comparison between concrete mixtures was possible using ASTM C 1202 test, and diffusion coefficient for steady state was estimated as low as 1/10 of that for non-steady state. In addition, diffusion coefficient estimated by immersion test was similar to result by NT build 492 test.

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Characteristic of Microcracks with Mixing Proportional Properties of Concrete (미세균열이 콘크리트의 염소이온 침투에 미치는 영향 III; 배합조건 특성에 따른 미세균열의 특성)

  • Yoon, In-Seok;Kim, Young-Geun;Park, Ki-Bong
    • Journal of the Korea Concrete Institute
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    • v.20 no.4
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    • pp.469-475
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    • 2008
  • It is obvious that chloride penetration through cracks can threaten the durability of concrete substantially, according to the previous studies of author. It was proposed that crack depth corrseponded with critical crack width from the surface is a crucial factor in view of durability design of concrete structures. It is now necessary to deal with chloride penetration through microcracks characterized with the mixing features of concrete. The purpose of this study is examining the effect of mix proportional features of concrete such as coarse aggregate, high strengtherize of concrete and reinforcement of steel fiber on chloride penetration through cracks. Although small size of coarse aggregate can lead to many microcracks in concrete, the cracks should not impact on chloride penetration directly. On the contrary, chloride should penetrate through cracks easily in concrete with a large size of coarse aggregate because mixrocracks are connected to each other. Second, high strength concrete has an excellent performance to resist with chloride penetration. However, for cracked high strength concrete, its performance is reduced upto the level of ordinary concrete. Finally, steel fiber reinforcement is effective to reduce chloride penetration through cracks because steel fiber reinforcement can lead to reduce crack depth significantly.

Study on the Critical Threshold Chloride Content for Steel Corrosion in Concrete with Various Cement Contents (단위시멘트량이 다른 콘크리트 중에서의 철근부식 임계염화물량에 관한 연구)

  • Yang, Seung-Kyu;Kim, Dong-Suck;Um, Tai-Sun;Lee, Jong-Ryul;Kono, Katsuya
    • Journal of the Korea Concrete Institute
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    • v.20 no.4
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    • pp.415-421
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    • 2008
  • Reinforced concrete starts to corrode when the chloride ion concentration which is the sum of included in concrete and penetrated from environments exceeds a certain level of critical chloride concentration. Therefore each country regulates the upper bounds of chloride amount in concrete and the regulations are different for each country due to its circumstances. In this study, the critical threshold chloride content according to unit cement amount is empirically calculated to propose a reasonable regulation method on the chloride amount. As a result, the critical threshold chloride content increases considerably according to cement content and it agrees with the established theories. The present regulations on total chloride amount 0.3 or 0.6 kg chloride ions per $1\;m^3$ of concrete does not reflect the influences of mix design, environmental conditions and etc. So it can be said that it is more reasonable to regulate the critical threshold chloride content by the ratio of chloride amount per unit cement content than by the total chloride content in $1\;m^3$ of concrete.

Potential of Coal Gasification Slag as an Alkali-activated Cement (석탄가스화 복합발전 슬래그의 알칼리 활성 시멘트로서의 가능성)

  • Kim, Byoungkwan;Lee, Sujeong;Chon, Chul-Min;Choi, Hong-Shik
    • Resources Recycling
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    • v.27 no.2
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    • pp.38-47
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    • 2018
  • Integrated gasification combined cycle (IGCC) is a next generation energy production technology that converts coal into syngas with enhanced power generation efficiency and environmental performance. IGCC produces almost coal gasification slag as the solid by-product. IGCC slag is generated about 140,000 tons for a year although recycling of it is still in the early stages. We evaluated the potential of IGCC slag which is generated from a pilot plant in South Korea as an alkali-activated cement. Samples which were activated with the combined activator of sodium silicate solution and caustic soda had an average compressive strength of 4.5 MPa, showing expansion. Expansion of the alkali-activated slag was presumed to be caused by free CaO in the slag, although it was not detected by the ethylene glycol method. Samples that were activated with the combined activator of sodium aluminate and caustic soda had an average compressive strength of 10 MPa. Hydroxy sodalite and $C_3AH_6$ were found to be the new crystalline phases. IGCC slag can be used as an alkali-activated material, but the strength performance should be improved with proper mix design approach to calculate optimum proportions which can alleviate the expansion issue at the same time.

Experimental Study on Properties of Permeable Polymer Concrete with Blast Furnace Slag and Fly Ash (고로 슬래그와 플라이 애시를 혼입(混入)한 투수성(透水性) 폴리머 콘크리트의 특성(特性)에 관(關)한 실험적(實驗的) 연구(硏究))

  • Sung, Chan Yong;Kim, In Su;Jo, Il Ho;Youn, Joon No;Kim, Young Ik;Seo, Dae Seuk
    • Korean Journal of Agricultural Science
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    • v.26 no.2
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    • pp.49-55
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    • 1999
  • This study is performed to evaluate the properties of permeable polymer concrete with blast furnace slag and fly ash. The following conclusions are drawn: 1. The highest strength is achieved by 50% filled blast furnace slag powder and fly ash permeable polymer concrete, it is increased 36% by compressive strength and 217% by bending strength than that of the normal cement concrete, respectively. 2. The static modulus of elasticity is in the range of $100{\times}10^3{\sim}130{\times}10^3kgf/cm^2$, which is approximately 43~51% of that of the normal cement concrete. 3. The dynamic modulus of elasticity is in the range of $102{\times}10^3{\sim}130{\times}10^3kgf/cm^2$, which is approximately less compared to that of the normal cement concrete. The highest dynamic modulus is showed by 50% filled blast furnace slag powder and fly ash permeable polymer concrete. The dynamic modulus of elasticity are increased approximately 0~4% than that of the static modulus. 4. The water permeability is in the range of $4.612{\sim}5.913l/cm^2/h$, and it is largely dependent upon the mix design.

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The Quality Characteristics of Curcuma longa L powder Sulgitteok (강황분말 설기떡의 품질 특성)

  • Lee, Myung-Ho;Jeon, Soon-Ju;Kim, Sun-Kyung;Park, Hyang-Suk;Choi, Young-Sim
    • Culinary science and hospitality research
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    • v.17 no.5
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    • pp.184-192
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    • 2011
  • This study aims to provide preliminary data to popularize Sulgitteok with optimum mix proportion of Curcuma longa L. powder by conducting moisture content, color values, texture and quantitative descriptive evaluations on Sulgitteok with 0 to 2.4% of Curcuma longa L. powder. The chemical composition of Curcuma longa L. powder was $12.6{\pm}0.21%$ of moisture, $1.8{\pm}0.12%$ of protein, $1.0{\pm}0.00%$ of fat, $1.3{\pm}0.01%$ of ash, and that of rice flour was $11.7{\pm}0.17%$ of moisture, $7.6{\pm}0.32%$ of protein, $2.1{\pm}0.01%$ of fat, $1.6{\pm}0.01%$ of ash. As the content of Curcuma longa L. powder increased, L-values significantly decreased while a-value and b-value significantly increased. The hardness of the texture characteristics significantly increased with increasing the amount of Curcuma longa L. powder(p<0.05). As for gumminess, cohesiveness, and chewiness, there was no significant difference(p<0.05) depending on the amount of Curcuma longa L. powder. The quantitative descriptive analysis of the color, flavor, moistness and chewiness of Sulgitteok showed that one with 0.8% of Curcuma longa L. powder was evaluated the highest.

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Development of Fermented Beverage Using the Sea Tangle Extract, and Quality Characteristics Thereof (다시마추출액을 이용한 발효음료개발 및 품질특성)

  • Kim, Mi-Lim;Choi, Mi-Ae;Jeong, Ji-Suk
    • Food Science and Preservation
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    • v.15 no.1
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    • pp.21-29
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    • 2008
  • This study investigated the fermentation and quality characteristics of a fermented beverage, prepared by semi-anaerobic culture, using sea tangle extract. A central composit design using alcohol(0, 0.5, 1.0, 1.5, 2.0% [all v/v] ), sugar(0, 5, 10, 15, 20% [all w/v] ) and $65^{\circ}Brix$ citrus juice(0, 1.0, 2.0, 3.0, 4.0 % [all v/v] ) was used to find the optimal mix for fermentation. Sensory characteristics, such as color, flavor, taste, sweetness, saltiness, sourness and overall quality, were measured using a response surface methodology computer program. The optimal conditions that produced the highest acidity of 0.94 were 2.0 % ethanol, 10.17 % sucrose and 1.99 % citrus juice. The optimal conditions that produced gel 20.13 nun in thickness were 1.98% alcohol, 10.94% sucrose and 1.62% citrus juice. The overall optimal conditions that satisfied all the sensory requirements for a sea tangle beverage were 1.0% alcohol, 10.0% sucrose and 4.05% citrus juice.

Performance Based Evaluation of Concrete Material Properties from Climate Change Effect on Wind Speed and Sunlight Exposure Time Curing Condition (기후변화의 풍속과 일조시간에 따른 콘크리트 재료특성의 성능 중심 평가)

  • Kim, Tae-Kyun;Shin, Jae-Ho;Bae, Deg-Hyo;Kim, Jang-Ho Jay
    • Journal of the Korea Concrete Institute
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    • v.26 no.6
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    • pp.751-759
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    • 2014
  • Currently, due to global warming, occurrences of extreme climate phenomena such as heat wave, heavy snow, heavy rain, super typhoon are continuously increasing all over the world. Due to these extreme climate phenomena, concrete structures and infrastructures are exposed to serious deterioration and damage. However, researches on construction technologies and standards to confront the climate change generated problems are needed presently. In order to better handle these problems, the validity of the present concrete mixture proportions are evaluated considering wind speed and sunlight exposure time based on climate change record in Seoul, Korea. The specimens cured at various wind speed and sunlight exposure time conditions were tested to obtain their compressive and split tensile strengths at various curing ages. Moreover, performance based evaluation (PBE) method was used to analyze the target strength satisfaction percentage of the concrete cured for the curing conditions. From the probabilistic method of performance evaluation of concrete performance, feasibility and usability of current concrete mix design practice for climate change conditions can be evaluated.