• Title/Summary/Keyword: Mineral analysis

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A Study of Mineral Quantification on Clay-Rich Rocks (점토질 암석의 광물정량 분석법 연구)

  • Byeong-Kook, Son;Gi-O, An
    • Korean Journal of Mineralogy and Petrology
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    • v.35 no.4
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    • pp.431-445
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    • 2022
  • A quantitative phase analysis method of X-ray powder diffraction was studied to determine the mineral content of clay-rich rocks practically as well as effectively. For quantitative X-ray powder diffraction analysis of the clay-rich rocks, it is necessary to prepare whole-rock powder samples with a random orientation by side mounting method. In addition, for the identification of the clay minerals in the rock, it is required to prepare an oriented mount specimen with a clay particle size of 2 ㎛ or less, ethylene glycol treatment, and heat treatment. RIR (reference intensity ratio) and Rietveld method were used for the quantitative analysis of the clay-rich rocks. It was possible to obtain the total clay and the non-clay minerals contents from the whole-rock X-ray diffraction profiles using the RIR values. In addition, it was possible to calculate the relative content of each clay mineral from the oriented X-ray diffraction profiles of the clay particle size and assign it to the total clay. In the Rietveld method of whole-rock X-ray diffraction, effective quantitative values were obtained from the Rietveld diffraction patterns excluded the region of less than 10 degrees (2θ). Similar quantitative values were shown in not only the RIR but the Rietveld methods. Therefore, the analysis results indicate a possibility of a routine quantitative analysis of clay-rich rocks in the laboratory. However, quantitative analysis of clay minerals is still a challenge because there are numerous varieties of clay minerals with different chemical and structural characteristics.

Thermogravimetric Analysis of Black Mass Components from Li-ion Battery (폐이차전지 블랙 매스(Black Mass) 구성 성분의 열중량 특성 분석)

  • Kwanho Kim;Kwangsuk You;Minkyu Kim;Hoon Lee
    • Resources Recycling
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    • v.32 no.6
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    • pp.25-33
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    • 2023
  • With the growth of the battery industry, a rapid increase in the production and usage of lithium-ion batteries is expected, and in line with this, much interest and effort is being paid to recycle waste batteries, including production scrap. Although much effort has been made to recycle cathode material, much attention has begun to recycle anode material to secure the supply chain of critical minerals and improve recycling rates. The proximate analysis that measures the content of coal can be used to analyze graphite in anode material, but it cannot accurately analyze due to the interaction between the components of the black mass. Therefore, in this study, thermogravimetric analysis of each component of black mass was measured as the temperature increased up to 950℃ in an oxygen atmosphere. As a result, in the case of cathode material, no change in mass was measured other than a mass reduction of about 5% due to oxidation of the binder and conductive material. In the case of anode material, except for a mass reduction of about 2% due to the binder, all mass reduction were due to the graphite(fixed carbon). In addition, metal conductors (Al, Cu) were oxidized and their mass increased as the temperature increased. Thermal analysis results of mixed samples of cathode/anode show similar results to the predictive values that can be calculated through each cathode and anode analysis results.

Sedimentary type Non-Metallic Mineral Potential Analysis using GIS and Weight of Evidence Model in the Gangreung Area (지리정보시스템(GIS) 및 Weight of Evidence 기법을 이용한 강릉지역의 퇴적기원의 비금속 광상부존가능성 분석)

  • Lee Sa-Ro;Oh Hyun-Joo;Min Kyung-Duck
    • Spatial Information Research
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    • v.14 no.1 s.36
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    • pp.129-150
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    • 2006
  • Mineral potential mapping is an important procedure in mineral resource assessment. The purpose of this study is to analyze mineral potential using weight of evidence model and a Geographic Information System (GIS) environment to identify areas that have not been subjected to the same degree of exploration. For this, a variety of spatial geological data were compiled, evaluated and integrated to produce a map of potential mineral in the Gangreung area, Korea. for this, a spatial database considering mineral deposit, topographic, geologic, geophysical and geochemical data was constructed for the study area using a GIS. The used mineral deposits were non-metallic(Kaolin, Porcelainstone, Silicastone, Mica, Nephrite, Limestone and Pyrophyllite) deposits of sedimentary type. The factors relating to mineral deposits were the geological data such as lithology and fault structure, geochemical data, including the abundance of Al, As, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Mo, Na, Ni, Pb, Si, Sr, V, Zn, $Cl^-,\;F^-,\;{PO_4}^{3-},\;{NO_2}^-,\;{NO_3}^-,\;SO_{42-}$, Eh, PH and conductivity and geophysical data, including the Bouguer and magnetic anomalies. These factors were used with weight of evidence model to analyze mineral potential. Probability models using the weight of evidence were applied to extract the relationship between mineral deposits and related factors, and the ratio were calculated. Then the potential indices were calculated by summation of the likelihood ratio and mineral potential maps were constructed from Geographic Information System (GIS). The mineral potential maps were then verified by comparison with the known mineral deposit areas. The result showed the 85.66% in prediction accuracy.

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Plant Analysis Methods for Evaluating Mineral Nutrient

  • Lee, Ye-Jin;Sung, Jwa-Kyung;Lee, Seul-Bi;Lim, Jung-Eun;Song, Yo-Sung;Lee, Deog-Bae;Hong, Suk-Young
    • Korean Journal of Soil Science and Fertilizer
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    • v.50 no.2
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    • pp.93-99
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    • 2017
  • Analysis of mineral nutrients in plant is required for evaluating diagnosis of plant nutritional status. Pretreatment procedure for the analysis of plant can be varied depending on elements to be analyzed. Wet-digestion is suitable for total nitrogen, phosphate and cations, however, digestion solution including nitric acid is not suitable for nitrogen analysis. Incineration procedure is required to analyze chloride, silicate and total sulfur. After digestion, total nitrogen is analyzed by Kjeldahl method, and phosphate is detected at 470nm by colorimetric analysis with ammonium meta vanadate. Cations and micro elements are determined by titration or colorimetry, also, these elements can be measured by Atomic absorption spectrometer (AAS) or Inductively coupled plasma spectrometer (ICP).

Usefulness of Manual Analysis of Bone Mineral Density Using Dual Energy X-ray Absorptiometry (이중에너지엑스선흡수기(Dual energy X-ray Absorptiometry: DXA)를 이용한 골밀도검사 결과분석에서 수동분석법의 유용성 평가)

  • Kim, Eun Hye;Kwak, Jong Gil;Kim, Ho Sung
    • Journal of Radiation Industry
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    • v.12 no.4
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    • pp.317-324
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    • 2018
  • The results of bone mineral density analysis using DXA were compared between automatic and manual methods. The purpose of this paper is to verify the range of errors of each analysis method in the same patient and select a proper method to minimize errors. Comparisons between automatic and manual analysis methods were made using BMD, BMC and AREA. Basal and follow up examinations were performed with the patients of normal, osteopenia and osteoporosis. In the basal examinations, the precision errors between automatic and manual method showed 1.9% in normal, 3.1% in osteopenia and 3.8% in osteoporosis. In case of follow up studies, the precision errors between automatic and manual method showed 2.3% in normal, 3.2% in osteopenia and 3.5% in osteoporosis. BMC and AREA also showed a tendency to increase precision errors on osteopenia and osteoporosis. Therefore, a manual method would be a better option to minimize errors in patients with osteopenia and osteoporosis.

Geology and Mineralization of Mwanza and Kongolo in DR Congo Tin belt (콩고민주공화국 무완자-콩골로 지역 주석광화대의 지질 및 광화작용)

  • Yang, Seok-Jun;Park, Sung-Won;Koh, Sang-Mo
    • Economic and Environmental Geology
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    • v.45 no.6
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    • pp.709-719
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    • 2012
  • Prospection was performed on the tin mineralized belt in Mwanza and Kongolo areas of Katanga, DR Congo. Most of deposits in Katanga areas are related to the granites which are located in Kibaran belt in NE and SW trends of mid Proterozoic. Metasedimentary rocks in the Kibaran belt are intruded by granites, and tin, niobium and tantalum deposits are especially developed along with tin-granite. Cassiterite, coltan and gold are developed in the pegmatite, quartz vein and greisen in related to the tin-granite in Mwanza and Katanga areas, and they are exploited by artisan in the smale scale. And we conducted the works with the alluviums and stream sediments in the case of no outcrops. With the results of analysis of samples, we will choose a few potential mineralized zones and con-tinue to prosepect precisely.

MINERAL CONCENTRATION IN RICE STRAW AND SOIL IN KYONGBUK PROVINCE, KOREA

  • Ramirez, C.E.;Kumagai, H.;Hosoi, E.;Yano, F.;Yano, H.;Jung, K.K.;Kim, S.W.
    • Asian-Australasian Journal of Animal Sciences
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    • v.7 no.1
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    • pp.125-129
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    • 1994
  • A field survey was carried out in Korea to assess the mineral composition of rice straw since it is a cheap and available cattle feedstuff. Forage and soil samples were collected in 4 localities in the Kyongbuk province. Soil analysis were also carried out in order to establish the relationships between soil composition and mineral content in the rice straw. Based on NRC tables, the rice straw samples provided adequate amounts of Mg, Ca, K, S, Mo, Mn and Zn. Percentages of samples deficient in P, Na, Cu and Se were 83, 50, 67 and 83 respectively. Soil samples, whose mean pH was 5.8 and mean organic matter content was 3.99%, were comparatively acidic and had high organic matter content. They also had high amounts of extractable Fe and Mn. Correlation coefficients between mineral content in soil and rice straw were low, i.e., 0.42 for Me (p < 0.05), and 0.37 for Mo (p < 0.05). The low or nonexistent correlation between soil and forage composition indicates the difficulty of establishing appropriate methods of mineral availability to the plants.

Analysis on the Temperature Distribution Characteristics of Insulating oil of Transformer Using the Vegetable oil and Mineral oil (식물성 절연유와 광유가 사용된 유입변압기의 온도분포 특성)

  • An, Jung-Sik;Shim, Meoung-Seop;Jung, Joong-Il;Kim, Nam-Ryul;Huh, Chang-Su
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.1215_1216
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    • 2009
  • Most transformer use insulating and cooling fluids derived from petroleum crude oil, but mineral oil is some possibility of environmental pollution and fire with explosion. vegetable oil fluids extracted from seed has superior biodegradation and fire-resistant properties including an exceptionally high fire point enhancing fire safety. In this study, it is aimed at the practicality of substituting natural ester dielectric fluid for mineral oil in liquid insulation system of transformers. As a rise in coil winding temperature has a direct influence on transformer life time, it is important to evaluate the temperature rise of coil winding in vegetable oil in comparison with mineral oil. Three transformers for the test are designed with 10KVA, 13.2KV, one phase unit. The temperature are directly measured in insulating oil of these transformers with the two sorts of natural ester and mineral oil dielectric fluid respectively. Temperature of vegetable oil transformers was similar to temperature of mineral oil transformer in the same design at 80% load and above.

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An Analysis of the Changes in Bone Mineral Density in Long-Stay Patients of a Geriatric Hospital in Relation to Physical Therapy

  • Lee, Sang-Min;Kim, Soon-Hee;Kim, Ji-Sung;Wang, Joong-San;Kim, Sung-Won;Kim, Nyeon-Jun;Lee, Sook-Hee;Min, Kyoung-Ok
    • Journal of International Academy of Physical Therapy Research
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    • v.2 no.2
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    • pp.267-273
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    • 2011
  • The purpose of this study is to examine the changes in bone mineral density in long-stay patients of a geriatric hospital in relation to physical therapy, thereby providing basic data for preventing the onset or deterioration of osteoporosis in inpatients of geriatric hospitals or relevant facilities. The subjects of this study were 133 elderly patients who had been in H geriatric hospital in Yongin-si for more than four years. Their bone mineral density T-scores at admission and those after four years were measured to compare and analyze the changes in bone mineral density in relation to physical therapy. According to the results, the decrease in T-score for the group without physical therapy was greater by .40 than that for the group with physical therapy, indicating a statistically significant difference between the two groups(p<.01). Accordingly, physical therapy proved to be effective in preventing bone mineral density loss and maintaining the current density.

The Properties of Concrete Compressive Strength used Rice Straw Ash (소성된 볏짚을 혼입한 콘크리트 압축강도 특성)

  • Kim, Young-Soo;Shin, Sang-Yeop;Jeong, Euy-Chang
    • Journal of the Regional Association of Architectural Institute of Korea
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    • v.21 no.5
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    • pp.117-124
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    • 2019
  • When manufacturing concrete, several mineral admixture is added to improve the basic physical property and durability and to make economical concrete. Such mineral admixture includes fly ash, granulated blast furnace slag, silica fume, etc., and not only the studies about mixing these mineral admixtures but also the studies for the development of new materials have been steadily in progress. Recently, some researchers have found, as a part of the development of new materials, the rice straw ash can also be used as a pozzolanic material for concrete considering similar chemical properties of rice straw ash to that of rice husk ash. But there has been insufficient amount of study about it. So, this study was to investigate the possibility as mineral admixture of agriculture by-product, by analyzing properties of concretes using rice straw ash with replacement ratio in comparison with other mineral admixture. In order to measure amount of SiO2 of rice straw ash, XRF(X-ray fluorescence) analysis was tested. For the measure pozzolanic reaction of rice straw ash, pH change and color change was tested according to curing day. Also to evaluate properties of concrete using rice straw ash, slump test, air contents test and compressive strength was tested.