• Title/Summary/Keyword: Mineral Elements

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Studies of the Fusibility of Coal Ashes in Oxidizing and Reducing Conditions (산화성 및 환원성분위기에서 석탄회분의 용융성)

  • Park, Chu-Sik;Lee, Shi-Hun;Choi, Sang-Il;Yang, Hyun-Soo
    • Applied Chemistry for Engineering
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    • v.8 no.2
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    • pp.179-190
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    • 1997
  • To study the effects of chemical composition on the fusion temperatures of coal ashes, the chemical composition, mineral matter, and fusion temperature were studied with 54 kinds of coal ash samples including Korean anthracite coals. CaO, MgO and $Fe_2O_3$ were observed to be major fluxing elements in reducing and oxidizing atmosphere. The fluxing effect of $Fe_2O_3$ was increased more in reducing atmosphere. In a base/acid ratio, the fusion temperature decreased with increasing amounts of basic components. Nevertheless, the correlation between a fusion temperature and base/acid ratio was not shown well in a higher ratio of $Fe_2O_3/CaO$. The differences of fusion temperatures between oxidizing and reducing atmosphere showed close relationship with $SiO_2/Al_2O_3$ ratio rather than with $Fe_2O_3$ contents. Multiple regression was used to predict the fusion temperature of coal ashes, and it was established that the major predictors in oxidizing atmosphere were Base/Acid, $Fe_2O_3/CaO$, $SiO_2/Al_2O_3$, and $(SiO_2/A1_2O_3){\cdot}(Base/Acid)$ and Base/Acid, $Fe_2O_3/CaO$, $SiO_2$, and $TiO_2$ were major ones in reducing atmosphere.

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Material Characteristics and Making Techniques of the Goryeo Roof Tiles from Oegol Site of Tangjeong Area in Asan, Korea (아산 탕정지구 외골유적 출토 고려 기와의 재료과학적 특성과 제작기법)

  • Kim, Ji-Young;Lee, Chan-Hee;Cho, Seon-Yeong;Gim, Ran-Hui;Lee, Ho-Hyeong
    • Journal of Conservation Science
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    • v.25 no.3
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    • pp.299-316
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    • 2009
  • The Goryeo roof tiles from the Oegol site in Tangjeong, Asan are classified into three groups in color such as gray, red yellow and gray-yellow groups, respectively. While each group of tiles shows characteristic specific gravity, absorption ratio, LOI and vitrification degree, mineral content and distribution, and chemical composition are generally homogeneous among all groups of roof tiles. Also, all roof tiles and soils from the site show similar geochemical behavior of elements and clay-mineralization degree. This indicates that the soil from the site is probable to be a raw material of the roof tiles. Firing temperature of the roof tiles is estimated as 950 to $1,050^{\circ}C$ for the gray group, 800 to $900^{\circ}C$ for the red yellow group, and 900 to $950^{\circ}C$ for the gray-yellow group. In conclusion, roof tiles from the Oegol site is interpreted to be made of local clay without additive minerals, applying various firing conditions and standardized purifying process of raw clay materials.

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Lacquer Layers and Making Methods of the Wooden Coffin Excavated from the Nongso Tomb of Unrimri, Sunchang in Korea (순창 운림리 농소고분 출토 목관 칠 분석을 통한 제작방법 연구)

  • Lee, Hye Youn
    • Journal of Conservation Science
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    • v.33 no.5
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    • pp.355-362
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    • 2017
  • The Nongso tomb of Sunchang was built in a relatively deep place; hence there was little damage from grave robbers. The tomb was completely filled with a large amount of charcoal, and therefore the wooden coffin was excavated in relatively good condition. On the basis of the structure of the tombs, excavated artifacts, and radiocarbon dating results, the tomb is estimated to be from between the late Goryeo and the early Joseon period. The wooden coffin excavated is double-layered structures consisting of an outer coffin and an inner coffin. The outside of the wooden coffin is thickly lacquered and decorated with yellow letters and white motifs. An analysis of the pigments' components revealed that the major component of the letters was gold (Au) and the major component of the motifs was silver (Ag). The coffin lacquer had three layers: a pigment layer, a yellowish-brown layer, and a black layer. The wooden bases of the coffins were painted with a black substance, such as soot, as mineral elements were not detected in the black layer. The yellowish-brown layer is presumed to be refined lacquer. From the analysis of the structure of the layers and pigments, we can estimate the method was adopted for making lacquer for wooden coffin. It is assumed that the method used gold leaf and gold powder. The form of the pigment and the internal structure are likely to be gold leaf, but the shape of the surface letters appears to have been formed using gold powder. This study will serve as important information for understanding lacquer making techniques at the time of the tombs' construction by confirming the making method through reproduction experiments using gold leaf and gold powder.

Studies on the N , $P_2O_5$ and $K_2O$-Application in the Mixed Sward of Alfalfa-Grass I. Effect of nitrogen fertilization on dry mixed sward of alfalfa-grasses (Alfalfa-Grass 혼파초지에 대한 3요소 시비 연구 I. 질소질비료의 시용수준이 alfalfa-grass 혼파초지의 건물 및 양분수량에 미치는 영향)

  • 박근제;최기준;이필상;김영진
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.15 no.3
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    • pp.169-174
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    • 1995
  • To investigate the effects of nitrogen(N) fertilization levels on the dry matter(DM) yield, nutrition yield, and N efficiency of forages in mixed sward of alfalfa-grasses, a field experiment arranged by randomized complete block design with five treatments(0, 70, 140, 210 and 280kg N/ha) was conducted at Livestock Experiment Station in Suwon, September, 1990 to February, 1993. During two years, average DM yields of forage increased as N fertilization level was increased, but no significant difference was found between DM 10,266kg of N 210kgha and DM 10,845kg of N 280kgha. Crude protein and energy productivity of forages increased as N fertilization level was increased, and the increasing degree was highest between N 140kg and 210kg/ha fertilization. With increasing N fertilization, mineral contents tended to decrease in P and K/Ca+ Mg equivalent ratios, to increase in Mg, but not to be regular in the other elements. Efficiency of N was highest at N 210kg/ha fertilization, which produced DM 21.6kg, net energy lactation 129.3 MJ, starch equivalent 12.3kStE and total digestible nutrients 14.5kg per Ikg N.

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Analysis of Nutritional Components and Evaluation of Functional Activities of Sasa borealis Leaf Tea (조릿대 잎차의 영양성분 분석 및 기능성 평가)

  • Jeong, Chang-Ho;Choi, Sung-Gil;Heo, Ho-Jin
    • Korean Journal of Food Science and Technology
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    • v.40 no.5
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    • pp.586-592
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    • 2008
  • In this study, the nutritional components and functional activities of Sasa borealis leaf tea were evaluated. The proximate compositions were as follows; moisture 5.68%, crude protein 16.38%, crude fat 4.68%, nitrogen free extracts 32.37%, crude fiber 32.36%, and ash 8.53%, respectively. The mineral elements were as follows: K 2,133.83, Ca 1,144.09 and P 543.00 mg%, respectively. The amino acid contents of the Sasa borealis leaf tea were very rich in proline (1,275.26 mg/100 g) and deficient in cystine (71.49 mg/100 g). The major fatty acid components were linoleic acid (50.52%), palmitic acid (18.52%), and oleic acid (14.16%). Finally, based on our sensory evaluations, the $80^{\circ}C$ extracted Sasa borealis leaf tea evidenced the best overall quality. The contents of total phenol and total flavonoids of the 80% methanol and hot water extracts were 15.09, 7.69 mg/g and 12.03, 6.12 mg/g, respectively. The DPPH and $ABTS^+$ radical scavenging activities of the 80% methanol extract from Sasa borealis leaf tea were 86.87% and 83.85% at a concentration of 1.25 mg/mL. The 80% methanol and hot water extracts evidenced reducing power and inhibitory effects against acetylcholinesterase in a dose-dependent manner.

Geotechnical Characteristics of the Ulleung Basin Sediment, East Sea (1) - Cosolidation and Shear Waves Velocity (동해 울릉분지 심해토의 지반공학적 특성(1) - 압밀 특성, 전단파 특성에 관한 연구)

  • Kim, Youngmoon;Lee, Jongsub;Lee, Jooyong;Lee, Changho
    • Journal of the Korean GEO-environmental Society
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    • v.14 no.5
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    • pp.33-39
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    • 2013
  • A drilling exploration in deep sea is being processed to develop new energy resource in the world. In 2007, the presence of the gas hydrate had been confirmed during the UBGH1 (Ulleung Basin Gas Hydrate Expedition 1) in the Ulleung Basin. Geotechnical properties of the deep marine sediment are important factors for assessing the safety of gas production facility and productivity from the hydrate bearing sediment. In this study, comprehensive laboratory tests are conducted to investigate the geotechnical engineering characteristics of the deep marine sediments recovered from the hydrate occurrence regions during the UBGH2 (Ulleung Basin Gas Hydrate Expedition 2) in the Ulleung Basin, East Sea, Korea. The index properties of the specimens including the specific gravity, atterberg limits, specific surface, and particle size distribution are measured, and these are compared to the results reported by previous studies. A zero-lateral strain cell, which houses bender elements, is used to determine stress-dependant characteristics and shear wave velocities with the vertical effective stresses. Furthermore, the hydraulic conductivity is calculated based on the consolidation test results.

Petrological study on the intermediate to mafic lavas distributed in Janggi area (1): General geology and petrochemical characteristics (장기 지역에 분포하는 중성~염기성 용암에 관한 암석학적 연구(1): 일반 지질 및 암석화학적 특징)

  • 박주희;김춘식;김진섭;성종규;김인수;이준동;백인성
    • The Journal of the Petrological Society of Korea
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    • v.8 no.3
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    • pp.149-170
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    • 1999
  • The volcanic lavas in the Janggi area are plotted on basalt, basaltic andesite and andesite field (SiO$_2$; 48-61 wt.%) in the TAS diagram and belong to subalkaline series. Nineteen chenmical analyses of lavas show two distinct differentiation trends; tholeiitic and calc-alkaline. Calc-alkaline basaltic andesites composed of plagioclase and two-pyroxenes (cpx, opx) in their phenocrysts. Tholeiitics basaltic lavas can be classified into two sub-types. The one is porphyritic basalts composed of plagioclase, clinopyroxene and olivine phenocryst, and the other is aphyric basalt and more evolved lavas (aphyric basaltic andesite) with the same mineral phases. Incompatible elements and REE patterns show the enrichment of LILE and depletion of HFSE. This characteristics indicate that these lavas are evolved from the magmas related to subduction. Howeverm calc-alkaline basaltic andesite lavas show that slightly higher enrichment of LILE and the depletion of HFSE than those of tholeiitic basaltic lavas. On the tectonic discriminant diagram such as Ba/Th and La/Th ratios, calc-alkaline basaltic andesite lavas belong to orogenic medium to high-K suites, whereas tholeiitic basaltic lavas belong to medium-K suites and MORB. On the other diagram, such as La/Yb vs. Th/Yb, the volcanic lavas in the study area plotted in the field of oceanic arc basalt. Tholeiitic basaltic lavas are located in more prinitive environment than calc-alkaline andesitic lavas.

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Chemical Components and Anti-oxidant Activities of Black Currant (블랙 커런트의 화학성분 및 항산화 활성)

  • Jeong, Chang-Ho;Jang, Chi-Weon;Lee, Koo-Yul;Kim, Il-Hun;Shim, Ki-Hwan
    • Food Science and Preservation
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    • v.19 no.2
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    • pp.263-270
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    • 2012
  • The chemical components and anti-oxidant activities of black currant were investigated. The pH, soluble solid and total acidity values were 3.36, 15.11 $^{\circ}Brix$, and 1.65%, respectively. The Hunter L, a, and b values were 18.20, 5.13, and 1.08, respectively. The proximate compositions were as follows; moisture, 77.64%; nitrogen free extract, 17.41%; crude fiber, 3.08%; crude protein, 1.28%; crude ash, 0.31%; and crude lipid, 0.28%, respectively. The mineral elements were K (177.36 mg/100 g), P (54.74 mg/100 g), and Ca (26.45 mg/100 g). The free sugar components were glucose (7.71%) and fructose (5.88%). The amino acid contents of the black currant were very rich in glutamic acid (105.73 mg/100 g) and deficient in cystine (5.29 mg/100 g). The ascorbic acid and total phenolic contents were 112.19 mg/100 g and 34.48 mg GAE/g, respectively. The ABTS and DPPH radical scavenging activity levels were 99.48% and 89.03% at the 10 and 1.25 mg/mL concentrations. The reducing power and FRAP of the black currant were dose-dependent. Thus, black currant can be an effective source of functional food substances, i.e., natural anti-oxidants.

Sedimentary Facies and Environmental Changes of the Nakdong River Estuary and Adjacent Coastal Area (낙동강 하구와 주변 연안역의 표층 퇴적상 및 퇴적환경 변화)

  • KIM Seok-Yun;HA Jeong-Su
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.34 no.3
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    • pp.268-278
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    • 2001
  • To investigate sedimentary facies and environmental changes of the Nakdong River Estuary and its adjacent coastal area, the grain size analysis and measurement of organic matter, calcium carbonate, clay mineral and metallic elements were carried out for forty surface sediment samples. Based on regional distribution pattern and characteristics of the surface sediments, sedimentary facies in the study area can be divided into sand facies (TYPE I), mud facies (TYPE II) and sand-mud mixed facies (TYPE III). TYPE III is the transition of TYPE I and TYPE II in every aspects of sediment characteristics. It suggests that TYPE III may have been formed by the mixture of two different source of sediment : one derived from Nakdong River and the other resuspended fine-grained sediments from the Jinhae Bay by winnowing action during floods or storms. Among many aspects of environmental change after the construction of the Nakdong Barrage, the most significant is the increase of sand content off the sand barrier region. It could be explained by several reasons including decreased input of fine-grained sediment from river, increased hydrodynamic energy level off the sand barrier region and artificial effects such as dredging and dumping.

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Chemical Composition and Antimicrobial Activities of Houttuynia cordata Thunb. (어성초의 화학성분 및 항미생물 활성)

  • Kim, Keun-Young;Chung, Dong-Ok;Chung, Hee-Jong
    • Korean Journal of Food Science and Technology
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    • v.29 no.3
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    • pp.400-406
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    • 1997
  • Chemical composition and antimicrobial activity of Houttuynia cordata Thunb. were investigated to develop a natural food preservative from it. Aspartic acid, glutamic acid, glycine and arginine were major amino acids of Houttuynia cordata Thunb., but were present in a trace amount. Free sugars were composed of glucose, fructose, sucrose and maltose and major fatty acids were linolenic acid, linoleic acid, oleic acid, and palmitic acid. Mineral elements were potassium, calcium, magnesium, iron, zinc, and copper. Antimicrobial activities were shown in acidic, neutral and phenolic fraction of Houttuynia cordata Thunb., but not in basic fraction. Among the four fractions, neutral fraction showed the strongest antimicrobial activities against microorganisms tested, such as Pseudomnas aeruginosa, Micrococcus luteus, Bacillus subtilis, Aspergillus parasiticus and Aspergillus flavus. Minimum inhibitory concentration (MIC) and minimum lethal concentration (MLC) of the neutral fraction varied according to microoganisms tested. The lowest values of MIC (0.0075 g eq./mL) and MLC (0.10 g eq./mL) were obtained from Pseudomonas aeruginosa.

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